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41.
Antonio Gomez Sanchez Manuel Mancera Francisco Rosado Manuel Rico 《Carbohydrate research》1984,134(1):75-82
3,4,5,6,7-Penta-O-acetyl-1,2-dideoxy-1-nitro-d-gluco-hept-1-enitol reacts with methyl acetoacetate in an unusual Michael reaction, giving the normal adduct (6), and a bicyclic derivative (9) that arises from quasi-dimerization of the former when a high concentration of the base is used. Acetylation of compound 9 gives the hydroxylamine O-acetate (10).From the reactions of 3,4,5,6,7-penta-O-acetyl-1,2-dideoxy-1-nitro-d-galacto-hept-1-enitol with ethyl and tert-butyl acetoacetate, the normal adducts (7 and 8) were isolated. The structures of compounds 6 to 10 were established on the basis of their spectral properties (u.v., i.r., mass, and 1H- and 13C-n.m.r.) 相似文献
42.
A.S.C. Wan T.L. Ngiam S.L. Leung M.L. Go P.W.S. Heng P.N. Natarajan A. Shafiee M. Vossoghi F. Savabi C.G. Francisco R. Freire R. Hernandez J.A. Salazar E. Suarez G.A.Garcia De La Mora Y.Grillasca R. O. Jimeno 《Steroids》1983,41(3):309-320
The synthesis of esters of norethisterone (17α-ethynyl-17β-hydroxy-estr-4-en-3-one) with acids containing a benzene ring is described, two methods of esterification being compared in terms of yield and convenience. The activities of these esters as long-acting contraceptive agents have been evaluated. 相似文献
43.
C G Francisco R Freire R Hernandez J A Salazar E Suarez G A García de la Mora J A Noguez A Acosta O Jimeno 《Steroids》1983,41(3):267-275
The synthesis of nine new esters of norethisterone (17 alpha-ethynyl-17 beta-hydroxyestr-4-en-3-one) is described, with the esterifying acids bearing an acetylenic or olefinic function in a chain of eight or nine carbon atoms, for evaluation as long-acting contraceptive agents. 相似文献
44.
Antonio G. Gonzalez Jaime Bermejo Barrera Francisco J. Tolfdo Marante 《Phytochemistry》1983,22(4):1049-1050
The fruit bodies of the Basidiomycete Scleroderma polyrhizum have been shown to contain the steroids ergosta-4,6,8(14) 22-tetraen-3-one and 5α,8α-epidoxyergosta-6,22-dien-3β-ol and also palmitic and oleic acids. 相似文献
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The results of 11 experiments with Drosophila species show that fertility is not a reducible property: the fertility of a mating pair cannot be predicted from the average fertility of the two genotypes involved. We propose a model of fertility selection that does not assume additivity (or multiplicativity) but assumes random mating and that the genotypic frequencies are in Hardy-Weinberg equilibrium. Numerical simulations show that removal of the assumption of Hardy-Weinberg frequencies does not significantly change the equilibrium frequencies predicted by the model. 相似文献
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Identification of the membrane component of the anion pump encoded by the arsenical resistance operon of R-factor R773 总被引:10,自引:2,他引:8
The arsenical resistance (ars) operon of the conjugative R-factor R773 encodes an ATP-driven anion extrusion pump, producing bacterial resistance to arsenicals. There are three structural genes, of which the product of the middle gene, arsB, has not previously been identified. From nucleotide sequence data, the ArsB protein is predicted to be a 45577 Dalton hydrophobic protein. A mini-Mu transposition procedure was used to construct an arsB-lacZ gene fusion, producing a hybrid ArsB-beta-galactosidase protein which was localized in the inner membrane. The operon was cloned into a T7 RNA polymerase expression vector. In addition to the previously identified ArsA and ArsC proteins, the cells synthesized an inner membrane protein with an apparent mass of 36 kD identified as the ArsB protein. 相似文献