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The N-carboxyanhydride of δ-benzyl L -α-aminoadipate polymerizes when initiated by strong base through an “active monomer” mechanism. This is shown by the isolation of 6-oxo-L -pipecolic acid from the product mixture, since this byproduct could only arise from an “active monomer” pathway. This study also specifies conditions for preparing high molecular weight poly(δ-benzyl L -α-aminoadipate) in high yield.  相似文献   

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