Nitrogen retention in the riparian zone of catchments underlain by discontinuous permafrost

1. Riparian zones function as important ecotones that reduce nitrate concentration in groundwater and inputs into streams. In the boreal forest of interior Alaska, permafrost confines subsurface flow through the riparian zone to shallow organic horizons, where plant uptake of nitrate and denitrification are typically high. 2. In this study, riparian zone nitrogen retention was examined in a high permafrost catchment (approximately 53% of land area underlain by permafrost) and a low permafrost catchment (approximately 3%). To estimate the contribution of the riparian zone to catchment nitrogen retention, we analysed groundwater chemistry using an end‐member mixing model. 3. Stream nitrate concentration was over twofold greater in the low permafrost catchment than the high permafrost catchment. Riparian groundwater was not significantly different between catchments, averaging 13 μm overall. Nitrogen retention, measured using the end‐member mixing model, averaged 0.75 and 0.22 mmol N m^?2 day^?1 in low and high permafrost catchments, respectively, over the summer. The retention rate of nitrogen in the riparian zone was 10–15% of the export in stream flow. 4. Our results indicate that the riparian zone functions as an important sink for groundwater nitrate and dissolved organic carbon (DOC). However, differences in stream nitrate and DOC concentrations between catchments cannot be explained by solute inputs from riparian groundwater to the stream and differences between streams are probably attributable to deeper groundwater inputs or flows from springs that bypass the riparian zone.     

Catchment- and site-scale influences of forest cover and longitudinal forest position on the distribution of a diadromous fish

1. The hydrologic connectivity between landscape elements and streams means that fragmentation of terrestrial habitats could affect the distribution of stream faunas at multiple spatial scales. We investigated how catchment‐ and site‐scale influences, including proportion and position of forest cover within a catchment, and presence of riparian forest cover affected the distribution of a diadromous fish. 2. The occurrence of koaro (Galaxias brevipinnis) in 50‐m stream reaches with either forested or non‐forested riparian margins at 172 sites in 24 catchments on Banks Peninsula, South Island, New Zealand was analysed. Proportions of catchments forested and the dominant position (upland or lowland) of forest within catchments were determined using geographical information system spatial analysis tools. 3. Multivariate analysis of variance indicated forest position and proportion forested at the catchment accounted for the majority of the variation in the overall proportion of sites in a catchment with koaro. 4. Where forest was predominantly in the lower part of the catchments, the presence of riparian cover was important in explaining the proportion of sites with koaro. However, where forest was predominantly in the upper part of the catchment, the effect of riparian forest was not as strong. In the absence of riparian forest cover, no patterns of koaro distribution with respect to catchment forest cover or forest position were detected. 5. These results indicate that landscape elements, such as the proportion and position of catchment forest, operating at catchment‐scales, influence the distribution of diadromous fish but their influence depends on the presence of riparian vegetation, a site‐scale factor.     

Atmospheric deposition, mass balances, and processes regulating streamwater solute concentrations in mixed-conifer catchments of the Sierra Nevada, California

Solute concentrations in atmospheric deposition and stream water were measuredfrom 1984 through 1993 to determine the fate and mobility of solutes in twogauged mixed-conifer catchments (Tharp's and Log creeks) located in theSierra Nevada, California. The two catchments contain mature forest standsdominated by Abies concolor (white fir), Sequoiadendron giganteum (giantsequoia), Abies magnifica (red fir) and Pinus lambertiana (sugar pine).Ammonium, Cl^-, Ca²⁺ and NO^- ₃were highest in concentration of the solutes measured in wet deposition;bulk deposition was highest in SO^{2- 4}, NH⁺ ₄,Cl^- and H⁺. Net retention ofH⁺, NO₃ ^-, NH₄ ⁺,SO₄ ^2- and Cl^- occurred in both catchments.Discharge was dominated by spring snowmelt with the largest export yieldsfor acid neutralizing capacity (ANC), SiO₂, andCa²⁺. Export yields of H⁺,NO₃ ^-, NH₄ ⁺ and PO₄ ^3-were relatively small (0.5 kg ha^-1 y^-1).Discharge-concentration relationships for ANC, SiO₂,Na⁺, K⁺, Ca²⁺ andMg²⁺ were inverse and their concentrations in stream waterwere primarily influenced by discharge and annual differences in the relativecontributions of snowmelt and groundwater. The mobility of these solutes iscontrolled by the rates of mineral weathering and ion exchange. The positiverelationship of SO₄ ^2- concentration with increasingdischarge suggests that atmospherically deposited SO₄ ^2-is temporarily stored and that its release is controlled by the extent of soilwater flushing.     

Contrasting nutrient exports from a forested and an agricultural catchment in south-eastern Australia

Dissolved organic carbon (DOC) and total and inorganic nitrogen and phosphorus concentrations were determined over 3 years in headwater streams draining two adjacent catchments. The catchments are currently under different land use; pasture/grazing vs plantation forestry. The objectives of the work were to quantify C and nutrient export from these landuses and elucidate the factors regulating export. In both catchments, stream water dissolved inorganic nutrient concentrations exhibited strong seasonal variations. Concentrations were highest during runoff events in late summer and autumn and rapidly declined as discharge increased during winter and spring. The annual variation of stream water N and P concentrations indicated that these nutrients accumulated in the catchments during dry summer periods and were flushed to the streams during autumn storm events. By contrast, stream water DOC concentrations did not exhibit seasonal variation. Higher DOC and NO₃ ⁻ concentrations were observed in the stream of the forest catchment, reflecting greater input and subsequent breakdown of leaf-litter in the forest catchment. Annual export of DOC was lower from the forested catchment due to the reduced discharge from this catchment. In contrast however, annual export of nitrate was higher from the forest catchment suggesting that there was an additional NO₃ ⁻ source or reduction of a NO₃ ⁻ sink. We hypothesize that the denitrification capacity of the forested catchment has been significantly reduced as a consequence of increased evapotranspiration and subsequent decrease in streamflow and associated reduction in the near stream saturated area.     

Nutrient runoff dynamics in a rural catchment: Influence of land-use changes, climatic fluctuations and ecotechnological measures

The main trend in land-use changes in the Porijõgi River catchment, south Estonia, is a significant increase in abandoned lands (from 1.7% in 1987 to 10.5% in 1997), and a decrease in arable lands (from 41.8 to 23.9%). Significant climatic fluctuations occurred during the last decades. Milder winters (increase of air temperature in February from −7.9 to −5.5°C during the period 1950–1997) and a change in the precipitation pattern have influenced the mean annual water discharge. This results in more intensive material flow during colder seasons and decreased water runoff in summer. During the period 1987–1997 the runoff of total-N, total-P, SO₄, and organic material (after BOD₅) decreased from 25.9 to 5.1, from 0.32 to 0.13, from 78 to 48, and from 7.4 to 3.5 kg ha⁻¹ year⁻¹, respectively. Most significant was a 4–20-fold decrease in agricultural subcatchments while in the forested upper-course catchment the changes were insignificant. Variations of total-N, and total-P runoff in both the entire catchment and its agricultural subcatchments are well described by the change of land use (including fertilization intensity), soil parameters and water discharge. In small agricultural subcatchments the rate of fertilization was found to be the most important factor affecting nitrogen runoff, while land-use pattern plays the main role in larger mosaic catchments. Ecotechnological measures (e.g. riparian buffer zones and buffer strips, constructed wetlands) to control nutrient flows from agricultural catchments are very important.     

Influence of land use on stream ecosystem function in a Mediterranean catchment

1. Due to the hierarchical organization of stream networks, land use changes occurring at larger spatial scales (i.e. the catchment) can affect physical, chemical and biological characteristics at lower spatial scales, ultimately altering stream structure and function. Anthropogenic effects on streams have primarily been documented using structural metrics such as water chemistry, channel alteration and algal biomass. Functional parameters, including metrics of nutrient retention and metabolism, are now being widely used as indicators of stream condition. 2. Within this hierarchical context, we used a multivariate approach to examine how structural and functional (i.e. nutrient retention and metabolism) attributes of streams are related to catchment variables, including land use. The study was done in 13 streams located within a single Mediterranean catchment, but draining sub‐catchments with contrasting land use. 3. At the catchment scale, results showed two contrasting land use gradients: (i) from forested‐ to urban‐dominated catchments and (ii) from low to moderate agricultural‐dominated catchments. Variation in structural and functional parameters was strongly related to these land use gradients. Specifically, NH₄⁺ demand (measured as the uptake velocity, V_f) decreased along the gradient from forested‐ to urban‐dominated catchments primarily in response to increases in stream nutrient concentrations [NH₄⁺, dissolved organic nitrogen (DON) and carbon (DOC)]. Both primary production and respiration increased along the gradient of agricultural development in response to increases in algal biomass (chlorophyll a). Soluble reactive phosphorus demand was not related to any of the land use gradients. 4. Our results illustrate the connections among factors operating at different spatial scales (i.e. from catchments to streams) and their distinct influence on stream ecosystem function. Managers should take into consideration these connections when designing stream management and restoration plans. Because ecologically successful stream management and restoration is expected to restore function as well as structure to streams, the use of appropriate measures of functional processes is required. Nutrient retention and metabolism parameters are good candidates to fill this gap.     

Impacts of land use at the catchment scale constrain the habitat benefits of stream riparian buffers

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Solute export from forested and partially deforested chatchments in the central Amazon

The hydrochemical responses to slash-and-burnagriculture in a small rainforest catchment of thecentral Amazon were investigated for one year. Disturbances in the partially deforested catchmentbegan in 1987, and during the study a 2-ha plot was cut(July 1989) and burned (October 1989) in preparationfor the cultivation of manioc; the partially deforestedcatchment was approximately 80% deforested at the timeof this study. Solute fluxes exported by base flowwere estimated from solute concentrations of stream watermeasured at least once per week. Solute fluxesfor storm flow were estimated by measuring streamwaterconcentrations during two storms. Baseflow runoffrepresented about 94% of the water outflow from thestudy basin and was the dominant pathway of soluteexport. Total rainfall during the study period was2754 mm of which 2080 mm was exported from thepartially deforested catchment as stream runoff. Theratio of surface runoff to annual rainfall for asimilar study conducted in the same catchment whilecompletely forested in 1984 was lower than after thecatchment was 80% deforested in 1990 (0.57 versus0.76), while evapotranspiration (ET) was lower by about afactor of two in 1990 compared to 1984. Particulateremoval from the partially deforested catchment was 151kg ha^–1 yr^–1. Nutrient losses from thepartially deforested catchment were higher than thosemeasured when the catchment was undisturbed in 1984 byfactors of 1.4, 1.8, and 2.1 for total inorganicnitrogen (TIN), total dissolved nitrogen (TDN), and totalnitrogen (TN); and by factors of 4.0, 6.6, and 7.9 for solublereactive phosphate (PO^3– ₄), total dissolvedphosphorus (TDP), and total phosphorus (TP),respectively. These data show that deforestation andcolonization in upland catchments of the central Amazonalter the hydrochemical balance of streams bydecreasing ET, thereby increasing discharge and soluteexport.     

Effects of prescribed burning and drought on the solute chemistry of mixed-conifer forest streams of the Sierra Nevada, California

Solute concentrations in atmospheric depositionand stream water were measured in two mixed-conifercatchments (Tharps and Log creeks) in the SierraNevada of California from 1984 through 1995, a periodincluding a 6-year drought and a prescribed burn inone catchment. The effects of prescribed burning inthe Tharps Creek catchment significantly increasedthe concentrations of most solutes in stream water. In the first year after prescribed burning, the VWM(volume-weighted mean) concentrations of acid anionsin stream water increased proportionally more thanthose of the base cations, and ANC (acid neutralizingcapacity) more than doubled. Sulfate and NO ₃ ^- increased proportionally more in streamwater than any other ions after the fire, but pre- andpost-burn VWM pH were not significantlydifferent. VWM SO ₄ ^2- and NO ₃ ^- concentrations the first year after burning occurredwere about 16- and 2,000-fold above pre-burnbaselines, respectively, while that of Cl^-increased 4-fold. Net retention (precipitationinputs minus streamwater outputs) of H⁺,NO ₃ ^- , NH ₃ ⁺ , SO ₄ ^2- and Cl^- occurred in both catchments, except afterprescribed burning of the Tharps Creek catchment inthe fall of 1990, which caused a net export ofSO ₄ ^2- , Cl^- and K⁺ thefirst year after the burn. Most solutes remained abovepre-disturbance concentrations by the end of the thirdyear after burning, whereas H⁺ and SiO₂remained below. Periodic increases in theconcentrations of Na⁺, Ca²⁺ and SO ₄ ^2- , and decreases in ANC and SiO₂occurred during a 6-year drought monitored in theadjacent undisturbed catchment of Log Creek.     

Importance of scale,land‐use,and stream network properties for riparian plant communities along an urban gradient

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DOC and DIC in Flowpaths of Amazonian Headwater Catchments with Hydrologically Contrasting Soils

Organic and inorganic carbon (C) fluxes transported by water were evaluated for dominant hydrologic flowpaths on two adjacent headwater catchments in the Brazilian Amazon with distinct soils and hydrologic responses from September 2003 through April 2005. The Ultisol-dominated catchment produced 30% greater volume of storm-related quickflow (overland flow and shallow subsurface flow) compared to the Oxisol-dominated catchment. Quickflow fluxes were equivalent to 3.2 ± 0.2% of event precipitation for the Ultisol catchment, compared to 2.5 ± 0.3% for the Oxisol-dominated watershed (mean response ±1 SE, n = 27 storms for each watershed). Hydrologic responses were also faster on the Ultisol watershed, with time to peak flow occurring 10 min earlier on average as compared to the runoff response on the Oxisol watershed. These different hydrologic responses are attributed primarily to large differences in saturated hydraulic conductivity (K _s). Overland flow was found to be an important feature on both watersheds. This was evidenced by the response rates of overland flow detectors (OFDs) during the rainy season, with overland flow intercepted by 54 ± 0.5% and 65 ± 0.5% of OFDs for the Oxisol and Ultisol watersheds respectively during biweekly periods. Small volumes of quickflow correspond to large fluxes of dissolved organic C (DOC); DOC concentrations of the hydrologic flowpaths that comprise quickflow are an order of magnitude higher than groundwater flowpaths fueling base flow (19.6 ± 1.7 mg l⁻¹ DOC for overland flow and 8.8 ± 0.7 mg l⁻¹ DOC for shallow subsurface flow versus 0.50 ± 0.04,mg l⁻¹ DOC in emergent groundwater). Concentrations of dissolved inorganic C (DIC, as dissolved CO₂–C plus HCO₃⁻–C) in groundwater were found to be an order of magnitude greater than quickflow DIC concentrations (21.5 mg l⁻¹ DIC in emergent groundwater versus 1.1 mg l⁻¹ DIC in overland flow). The importance of deeper flowpaths in the transport of inorganic C to streams is indicated by the 40:1 ratio of DIC:DOC for emergent groundwater. Dissolved CO₂–C represented 92% of DIC in emergent groundwater. Results from this study illustrate a highly dynamic and tightly coupled linkage between the C cycle and the hydrologic cycle for both Ultisol and Oxisol landscapes: organic C fluxes strongly tied to flowpaths associated with quickflow, and inorganic C (particularly dissolved CO₂) transported via deeper flowpaths.     

Solution chemistry profiles of mixed-conifer forests before and after fire

Solution chemistry profiles of mixed-conifer forests in granitic catchments of the Sierra Nevada were measured for three years before (1987–1990) and three years after (1990–1993) prescribed fire. Wet deposition, throughfall and soil solution samplers were installed in both white-fir and giant-sequoia dominated forest stands underlain by poorly developed inceptisols. Stream water chemistry was monitored as part of an ongoing study of catchment outputs. Calcium, NO ₃ ^– and Cl^– were the major ions in precipitation. Canopy leaching increased mean concentrations of all major ions, especially K⁺ and Ca²⁺. Water flux through the soil occurred largely during spring snowmelt. Forest floor leachate represented the most concentrated solutions of major ions. Interaction with the mineral soil decreased mean concentrations of most species and the average composition of soil solutions closely resembled stream water at baseflow. Bicarbonate alkalinity, Ca²⁺, Mg²⁺, and Na⁺ were enriched in stream water relative to precipitation whereas inputs of H⁺, NH ₄ ⁺ , NO ₃ ^– and SO ₄ ^2– were retained within the catchments.Burning of the forest understory and litter layer increased solute concentrations in soil solution and stream water. Mean soil solution Ca²⁺, Mg²⁺ and K⁺ concentrations increased more than 10 fold, but the relative predominance of these cations was not affected by burning. Sulfate concentration, which was very low in soil solutions of undisturbed stands (<25 mmol_c m^–3), increased more than 100 times following fire. Ammonium concentration exhibited a rapid, short-term increase and then a decrease below pre-burn levels. Changes in soil solution chemistry were reflected in catchment outputs.Corresponding author.     

Upscaling understanding of nitrogen dynamics associated with overland flow in a semi-arid environment

An experiment was designed to further the empirical understanding of the effects of scale on fluxes of water and dissolved nitrogen from hillslopes in semi-arid shrubland. It was hypothesised that the behaviour of dissolved nitrogen is related to the scale of the contributing hillslope/catchment area and dynamics of the overland flow as has been demonstrated to be the case for soil erosion (Parsons et al. 2006). Data from four hillslope scales (ca. 21–300 m²) and one subcatchment (ca. 1,500 m²), collected over two monsoon seasons, support this hypothesis and demonstrate that the key controls of average dissolved nitrogen yields are flow discharge and plot scale. The slope of the best-fit line describing the relationship between flow discharge and total dissolved nitrogen (TDN) yields descreases with increasing scale, from 0.0183 at 21.01 m², 0.0092 at 56.84 m², 0.0059 at 115.94 m², 0.0024 at 302.19 m² to 0.0004 at 1,500 m². An implication of these findings is that care must be taken when upscaling results describing nutrient behaviour from small, plot experiments, as this behaviour appears to be scale dependent. For example, average yields of TDN in overland flow increase to a maximum with increasing plot area until an area of 50 m² is reached, and decline with increasing plot size thereafter. Thus, studies that rely upon fixed plot scales may misrepresent catchment- or landscape-scale fluxes as they do not describe the changing relationship between overland flow and nutrient fluxes with increasing spatial scale. Further investigations into intra-event behaviour illustrate that nitrogen losses from natural rainfall/runoff events are supply limited as over the course of the events monitored, decreasing concentrations illustrate a pattern of nutrient exhaustion. When events are compared at the same sites through the monsoon season, however, the anticipated seasonal exhaustion effect is not present. This work provides an empirical basis to upscale the understanding of dissolved nitrogen behaviour from small hillslope plots to catchment scales in degraded semi-arid environments.     

The biogeochemistry of pristine,headwater Precambrian shield watersheds: an analysis of material transport within a heterogeneous landscape

The hydrology and elemental transport within five low order Precambrian shield catchments was investigated during 1988–90. Catchments were subdivided and instrumented to examine the vertical and horizontal fluxes of elements within and between two distinct landscape types: open, lichen-covered bedrock outcrops and patches of conifer forest. The dominant hydrologic pathways were Horton overland flow in the lichen-bedrock areas and shallow subsurface flow through organic rich LFH (forest floor) and Ah soil horizons in the forested areas. Annual runoff coefficients ranged from 0.3 to 0.7. Runoff chemistry was acidic (pH 4.01–4.72), with organic anion equivalents (RCOO^-), comprising 60 and 69% of the anion charge total for bedrock and forest runoff, respectively. Forested plots exported more H⁺ (2.6x), DOC (1.4x), Al (1.6x) and Fe (1.8x) and less N (0.40x), P (0.13x), particulate C (0.08x), Ca²⁺ (0.38x), Mg²⁺ (0.83x), Na⁺ (0.85x) and K⁺ (0.32x) per unit area than the bedrock-lichen plots. The catchments exhibited a net export of H⁺ (34), Mg²⁺ (24), Na⁺ (20), K⁺ (4) (units in eq ha^-1 yr^-1) and C (16), Si (5.6), Al (1.6) and Fe (0.47) (units kg ha^-1 yr^-1). The catchments retained N (5.66), P (0.08), Mn (0.03) (units kg ha^-1 yr^-1), and Ca²⁺ (37), and Cl^- (3) (units eq ha^-1 yr^-1). The strong retention of Ca²⁺ within the treed soil islands resulted in extremely low export rates of base cations (-15 to 38 eq ha^-1 yr^-1). The spatial distribution and hydrologic and biogeochemical linkages associated with each landscape unit interact to control element transport within the study catchments.     

Chemical composition of water-bodies in the English Lake District: relationships between chloride and other major ions related to solid geology, and a tentative budget for Windermere

SUMMARY.

• 1 Mean tarnwater concentrations of CI^- and other ions (Na ⁺, K⁺, Ca²⁺, Mg²⁺, SO₄^2-+ NO₃^-) decrease with increasing distance from the sea and altitude but are also related to solid geology. Lowest concentrations occur on slow-weathering igneous rocks (Borrow-dale Volcanics); minima of c. 100 μequiv. CI^-I^-1 are similar to the volume-weighted mean for bulk precipitation. At least 10–20% of Na⁺ is leached from upland catchments, giving Na⁺/CI^- ratios greater than the equivalent ratio (0.86) in seawater and precipitation. Evapotranspiration at 20–30% annual rainfall accounts for CI^- concentrations in many tarns on igneous rocks but not all; some CI^- may be leached from the rocks in upland catchments and come from groundwaters at low altitudes near the sea. Sea-spray has little influence on tarnwaters near the coast.
• 2 On sedimentary rocks overall mean CI^- concentrations are 27–73% higher than equivalent means on Borrowdale Volcanics; concentrations of other ions are also higher. A 5-fold to 10-fold range of CI^-concentrations is not simply due to increased evapotranspiration. Na⁺/CI^- ratios are < 0.86, especially on Skiddaw Slates where tarnwaters contain 10% or more excess CI^- balanced by Ca²⁺, apparently derived from groundwaters rich in CaCI₂. On other sedimentary rocks (Silurian Slates and Carboniferous, Triassic and Permian series) tarn waters display a similar but less pronounced excess of CI^- and Ca^2-+ relative to Na⁺. Some extra CI^- may be captured by dry deposition on vegetation but a portion, perhaps 15–30% of the total, apparently comes from the rocks or from groundwaters via deep aquifers in contact with seawater or connate water.
• 3 Anthropogenic sources on the catchments are also considered: deicing salt used on highways in winter accounts for a 27% increase of CI^- in Windermere South Basin over a 20-year period.

     

Effects of Catchment and Riparian Landscape Setting on Water Chemistry and Seasonal Evolution of Water Quality in the Upper Han River Basin,China

Six-year (2005–2010) evolution of water chemistry (Cl⁻, NO₃ ⁻, SO₄ ²⁻, HCO₃ ⁻, Na⁺, K⁺, Ca²⁺ and Mg²⁺) and their interactions with morphological properties (i.e., slope and area), land cover, and hydrological seasonality were examined to identify controlling factors and processes governing patterns of stream water quality in the upper Han River, China. Correlation analysis and stepwise multiple regression models revealed significant correlations between ions (i.e., Cl⁻, SO₄ ²⁻, Na⁺ and K⁺) and land cover (i.e., vegetation and bare land) over the entire catchment in both high- and low-flow periods, and in the buffer zone the correlation was much more stronger in the low-flow period. Catchment with steeper slope (>15°) was negatively correlated with major ions, largely due to multicollinearity of basin characteristics. Land cover within the buffer zone explained slightly less of major elements than at catchment scale in the rainy season, whereas in the dry season, land cover along the river networks in particular this within 100 m riparian zone much better explained major elements rather than this over the entire catchment. Anthropogenic land uses (i.e., urban and agriculture) however could not explain water chemical variables, albeit EC, TDS, anthropogenic markers (Cl⁻, NO₃ ⁻, SO₄ ²), Na⁺, K⁺ and Ca²⁺ significantly increased during 2005–2010, which was corroborated by principal component analyses (PCA) that indicated anthropogenic inputs. Observations demonstrated much higher solute concentrations in the industrial-polluted river. Our results suggested that seasonal evolution of water quality in combined with spatial analysis at multiple scales should be a vital part of identifying the controls on spatio-temporal patterns of water quality.     

Biogeochemical Budgets in a Mediterranean Catchment with High Rates of Atmospheric N Deposition – Importance of Scale and Temporal Asynchrony

In this study biogeochemical export in a set of catchments that vary from 6 ha to almost 1500 ha is investigated. Studying catchments across this large range of scales enables us to investigate the scale dependence and fundamental processes controlling catchment biogeochemical export that would not have been possible with a more limited data set. The Devil Canyon catchment, in the San Bernardino Mountains, California, has some of the highest atmospheric N deposition rates in the world (40–90 kg ha⁻¹year⁻¹ at the crest of the catchment). These high rates of deposition have translated into consistently high levels of NO⁻in 3 some streams of the San Bernardino Mountains. However, the streams of the Devil Canyon catchment have widely varying dissolved inorganic nitrogen (DIN) concentrations and export. These differences are also, to a more limited extent, present for dissolved organic carbon (DOC) but not in other dissolved species (Cl⁻, SO²⁻₄,Ca²⁺ and other weathering products). As catchment size increases DIN and DOC concentrations first increase until catchment area is ∼150 ha but then decrease as catchment scale increases beyond that size. The scale dependence of DIN export implies that catchments at different spatial scales are at different degrees of N saturation. The reason for this scale effect appears to be the dominance of flushing of DIN out of soil at small scales due to the temporal asynchrony between nutrient availability and biological N demand, the groundwater exfiltration of this flushed DIN at intermediate scales and the removal of this DIN from streamflow through in-stream processes and groundwater–surface water interaction at larger scales. While the particular scale effect observed here may not occur over the same range in catchment area in other ecosystems, it is likely that other ecosystems have similar scale dependant export for DIN and DOC.     

Tracing the Sources of Exported Nitrate in the Turkey Lakes Watershed Using 15N/14N and 18O/16O isotopic ratios

Nitrate produced by bacterially mediated nitrification in soils is isotopically distinct from atmospheric nitrate in precipitation. ¹⁵N/¹⁴N and ¹⁸O/¹⁶O isotopic ratios of nitrate can therefore be used to distinguish between these two sources of nitrate in surface waters and groundwaters. Two forested catchments in the Turkey Lakes Watershed (TLW) near Sault Ste. Marie, Ontario, Canada were studied to determine the relative contributions of atmospheric and microbial nitrate to nitrate export. The TLW is reasonably undisturbed and receives a moderate amount of inorganic nitrogen bulk deposition (8.7 kg N · ha⁻¹· yr⁻¹) yet it exhibits unusually low inorganic nitrogen retention (average = 65% of deposition). The measured isotopic ratios for nitrate in precipitation ranged from +35 to +59‰ (VSMOW) for δ¹⁸O and −4 to +0.8‰ (AIR) for δ¹⁵N. Nitrate produced from nitrification at the TLW is expected to have an average isotope value of approximately −1.0‰ for δ¹⁸O and a value of about 0 to +6‰ for δ¹⁵N, thus, the isotopic separation between atmospheric and soil sources of nitrate is substantial. Nitrate produced by nitrification of ammonium appears to be the dominant source of the nitrate exported in both catchments, even during the snowmelt period. These whole catchment results are consistent with the results of small but intensive plot scale studies that have shown that the majority of the nitrate leached from these catchments is microbial in origin. The isotopic composition of stream nitrate provides information about N-cycling in the forested upland and riparian zones on a whole catchment basis. Received 5 October 1999; accepted 18 August 2000     

Stream ecosystem responses to spatially variable land cover: an empirically based model for developing riparian restoration strategies

1. The restoration of native, forested riparian habitats is a widely accepted method for improving degraded streams. Little is known, however, about how the width, extent and continuity of forested vegetation along stream networks affect stream ecosystems. 2. To increase the likelihood of achieving restoration goals, restoration practitioners require quantitative tools to guide the development of restoration strategies in different catchment settings. We present an empirically based model that establishes a relationship between a ‘stress’ imposed at different locations along a stream by the spatial pattern of land cover within catchments, and the response of biologically determined ecosystem characteristics to this stress. The model provides a spatially explicit, quantitative framework for predicting the effects of changes in catchment land cover composition and spatial configuration on specific characteristics of stream ecosystems. 3. We used geospatial datasets and biological data for attached algae and benthic macroinvertebrates in streams to estimate model parameters for 40 sites in 33 distinct catchments within the mid‐Atlantic Piedmont region of the eastern U.S. Model parameters were estimated using a genetic optimisation algorithm. R² values for the resulting relationships between catchment land cover and biological characteristics of streams were substantially improved over R² values for spatially aggregated regression models based on whole‐catchment land cover. 4. Using model parameters estimated for the mid‐Atlantic Piedmont, we show how the model can be used to guide restoration planning in a case study of a small catchment. The model predicts the quantitative change in biological characteristics of the stream, such as indices of species diversity and species composition, that would occur with the implementation of a hypothetical restoration project.     

The influence of catchment characteristics on the seasonality of carbon and nitrogen species concentrations in upland rivers of Northern Scotland

Data from 13 catchments with no arable land in Northern Scotland were used to develop empirical linear regression models of average monthly NO₃ ^? concentrations and average summer and winter concentrations for NH₄ ⁺, dissolved organic N (DON) and dissolved organic carbon (DOC) as a function of catchment characteristics. All catchments displayed a pronounced seasonal NO₃ ^? cycle. Variation in monthly mean NO₃ ^? concentration within and between catchments could be predicted from mean monthly air temperature using separate regression equations for temperatures < and ≥ 5 °C. Soil type, climate and land use influenced NH₄ ⁺ concentrations. In summer, concentrations of NH₄ ⁺ were largest in catchments with extensive areas of brown forest soils, which are less acidic and more base-rich than other upland soils. However, concentrations declined with increasing conifer cover and summer rainfall. In winter, however, % conifer cover had a positive effect, while higher temperature and higher humus iron podzol cover had negative influences. DON concentration decreased with increasing catchment elevation in both summer and winter. Surprisingly, concentrations of DON only displayed a positive relationship with percentage peat cover in the summer. The most important factor controlling DOC concentration was soil type, with a positive relationship being observed between DOC and peat and humus iron podzol coverage. Elevation was also important, but only in the winter when concentrations were negatively correlated with maximum catchment elevation. Overall, multivariate regression equations explained the spatial and seasonal variability in N species concentrations over a range of catchments within Northern Scotland.