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Donor–Acceptor Type Dopant‐Free,Polymeric Hole Transport Material for Planar Perovskite Solar Cells (19.8%)
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Organic–inorganic hybrid perovskite has led to the development of new solar cells with outstanding efficiency. In perovskite solar cells (PSCs), perovskite is sandwiched between a working electrode (fluorine‐doped tin oxide) and a counter electrode (gold, Au). In order to transport charges and block opposite charges, charge transport layers are inserted between perovskite and the electrodes. In particular, a hole transport layer is important because it generally prevents perovskite from exposure to air. Therefore, it is necessary to investigate dopant‐free and hydrophobic polymeric hole transport materials (HTMs). In this study, a novel polymeric HTM (PTEG) is synthesized by controlling the solubility using a tetraethylene glycol group. The planar‐PSC employing PTEG exhibits an efficiency of 19.8% without any dopants, which corresponds to the highest value reported to date. This study offers a fundamental strategy for designing and synthesizing various polymeric HTMs. 相似文献
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Qiong Wang Edoardo Mosconi Christian Wolff Junming Li Dieter Neher Filippo De Angelis Gian Paolo Suranna Roberto Grisorio Antonio Abate 《Liver Transplantation》2019,9(28)
Two new hole selective materials (HSMs) based on dangling methylsulfanyl groups connected to the C‐9 position of the fluorene core are synthesized and applied in perovskite solar cells. Being structurally similar to a half of Spiro‐OMeTAD molecule, these HSMs (referred as FS and DFS) share similar redox potentials but are endowed with slightly higher hole mobility, due to the planarity and large extension of their structure. Competitive power conversion efficiency (up to 18.6%) is achieved by using the new HSMs in suitable perovskite solar cells. Time‐resolved photoluminescence decay measurements and electrochemical impedance spectroscopy show more efficient charge extraction at the HSM/perovskite interface with respect to Spiro‐OMeTAD, which is reflected in higher photocurrents exhibited by DFS/FS‐integrated perovskite solar cells. Density functional theory simulations reveal that the interactions of methylammonium with methylsulfanyl groups in DFS/FS strengthen their electrostatic attraction with the perovskite surface, providing an additional path for hole extraction compared to the sole presence of methoxy groups in Spiro‐OMeTAD. Importantly, the low‐cost synthesis of FS makes it significantly attractive for the future commercialization of perovskite solar cells. 相似文献
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Qingzhi An Qing Sun Andreas Weu David Becker‐Koch Fabian Paulus Sebastian Arndt Fabian Stuck A. Stephen K. Hashmi Nir Tessler Yana Vaynzof 《Liver Transplantation》2019,9(33)
Four π‐extended phosphoniumfluorene electrolytes (π‐PFEs) are introduced as hole‐blocking layers (HBL) in inverted architecture planar perovskite solar cells with the structure of ITO/PEDOT:PSS/MAPbI3/PCBM/HBL/Ag. The deep‐lying highest occupied molecular orbital energy level of the π‐PFEs effectively blocks holes, decreasing contact recombination. It is demonstrated that the incorporation of π‐PFEs introduces a dipole moment at the PCBM/Ag interface, resulting in significant enhancement of the built‐in potential of the device. This enhancement results in an increase in the open‐circuit voltage of the device by up to 120 mV, when compared to the commonly used bathocuproine HBL. The results are confirmed both experimentally and by numerical simulation. This work demonstrates that interfacial engineering of the transport layer/contact interface by small molecule electrolytes is a promising route to suppress nonradiative recombination in perovskite devices and compensates for a nonideal energetic alignment at the hole‐transport layer/perovskite interface. 相似文献
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Efficient Indium‐Doped TiOx Electron Transport Layers for High‐Performance Perovskite Solar Cells and Perovskite‐Silicon Tandems
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Jun Peng The Duong Xianzhong Zhou Heping Shen Yiliang Wu Hemant Kumar Mulmudi Yimao Wan Dingyong Zhong Juntao Li Takuya Tsuzuki Klaus J. Weber Kylie R. Catchpole Thomas P. White 《Liver Transplantation》2017,7(4)
In addition to a good perovskite light absorbing layer, the hole and electron transport layers play a crucial role in achieving high‐efficiency perovskite solar cells. Here, a simple, one‐step, solution‐based method is introduced for fabricating high quality indium‐doped titanium oxide electron transport layers. It is shown that indium‐doping improves both the conductivity of the transport layer and the band alignment at the ETL/perovskite interface compared to pure TiO2, boosting the fill‐factor and voltage of perovskite cells. Using the optimized transport layers, a high steady‐state efficiency of 17.9% for CH3NH3PbI3‐based cells and 19.3% for Cs0.05(MA0.17FA0.83)0.95Pb(I0.83Br0.17)3‐based cells is demonstrated, corresponding to absolute efficiency gains of 4.4% and 1.2% respectively compared to TiO2‐based control cells. In addition, a steady‐state efficiency of 16.6% for a semi‐transparent cell is reported and it is used to achieve a four‐terminal perovskite‐silicon tandem cell with a steady‐state efficiency of 24.5%. 相似文献
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Chuantian Zuo Andrew D. Scully Doojin Vak Wenliang Tan Xuechen Jiao Christopher R. McNeill Dechan Angmo Liming Ding Mei Gao 《Liver Transplantation》2019,9(4)
2D organic–inorganic hybrid Ruddlesden–Popper perovskites have emerged recently as candidates for the light‐absorbing layer in solar cell technology due largely to their impressive operational stability compared with their 3D‐perovskite counterparts. The methods reported to date for the preparation of efficient 2D perovksite layers for solar cells involve a nonscalable spin‐coating step. In this work, a facile, spin‐coating‐free, directly scalable drop‐cast method is reported for depositing precursor solutions that self‐assemble into highly oriented, uniform 2D‐perovskite films in air, yielding perovskite solar cells with power conversion efficiencies (PCE) of up to 14.9% (certified PCE of 14.33% ± 0.34 at 0.078 cm2). This is the highest PCE to date for a solar cell with 2D‐perovskite layers fabricated by nonspin‐coating method. The PCEs of the cells display no evidence of degradation after storage in a nitrogen glovebox for more than 5 months. 2D‐perovskite layer deposition using a slot‐die process is also investigated for the first time. Perovskite solar cells fabricated using batch slot‐die coating on a glass substrate or R2R slot‐die coating on a flexible substrate produced PCEs of 12.5% and 8.0%, respectively. 相似文献
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Strategic Synthesis of Ultrasmall NiCo2O4 NPs as Hole Transport Layer for Highly Efficient Perovskite Solar Cells
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Dan Ouyang Junyan Xiao Fei Ye Zhanfeng Huang Hong Zhang Lu Zhu Jiaqi Cheng Wallace C. H. Choy 《Liver Transplantation》2018,8(16)
This study proposes a novel strategy of controllable deamination of Co–NH3 complexes in a system containing Ni(OH)2 to synthesize ultrasmall ternary oxide nanoparticles (NPs), NiCo2O4. Through this approach, ultrasmall (5 nm on average) and well‐dispersed NiCo2O4 NPs without exotic ligands are obtained, which enables the formation of uniform and pin‐hole free films. The tightly covered NiCo2O4 films also facilitate the formation of large perovskite grains and thus reduce film defects. The results show that with the NiCo2O4 NPs as the hole transport layer (HTL), the perovskite solar cells reach a high power conversion efficiency (PCE) of 18.23% and a promising stability (maintained ≈90% PCE after 500 h light soaking). To the best of the author's knowledge, it is the first time that spinel NiCo2O4 NPs have been applied as hole transport layer in perovskite solar cells successfully. This work not only demonstrates the potential applications of ternary oxide NiCo2O4 as HTLs in hybrid perovskite solar cells but also provides an insight into the design and synthesis of ultrasmall and ligand‐free NPs HTLs to enable cost‐effective photovoltaic devices. 相似文献
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Ke Gao Bo Xu Chaoshen Hong Xueliang Shi Hongbin Liu Xiaosong Li Linghai Xie Alex K‐Y Jen 《Liver Transplantation》2018,8(22)
Hole‐transporting materials (HTMs) are essential for enabling highly efficient perovskite solar cells (PVSCs) to extract and transport the hole carriers. Among numerous HTMs that are studied so far, the single‐spiro‐based compounds are the most frequently used HTMs for achieving highly efficient PVSCs. In fact, all the new spiro‐based HTMs reported so far that render PVSCs over 20% are based on spiro[fluorene‐9,9′‐xanthene] or spiro [cyclopenta [2,1‐b:3,4b′]dithiophene‐4,9′‐fluorene] cores; therefore, there is a need to diversify the design of their structures for further improving their function and performance. In addition, the fundamental understanding of structure–performance relationships for the spiro‐based HTMs is still lagging, for example, how molecular configuration, spiro numbers, and heteroatoms in spiro‐rings impact the efficacy of HTMs. To address these needs, two novel H‐shaped HTMs, G1 and G2 based on the di‐spiro‐rings as the cores are designed and synthesized. The combined good film‐forming properties, better interactions with perovskite, slightly deeper highest occupied molecular orbital, higher mobility and conductivity, as well as more efficient charge transfer for G2 help devices reach a very impressive power conversion efficiency of 20.2% and good stability. This is the first report of demonstrating the feasibility of using di‐spiro‐based HTMs for highly efficient PVSCs. 相似文献
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Solution Processable Inorganic–Organic Double‐Layered Hole Transport Layer for Highly Stable Planar Perovskite Solar Cells
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Perovskite solar cells (PSCs) have reached their highest efficiency with 2,2′,7,7′‐tetrakis(N,N′‐di‐p‐methoxyphenylamine)‐9,9′‐spirobifluorene (spiro‐OMeTAD). However, this material can cause problems with respect to reproducibility and stability. Herein, a solution‐processable inorganic–organic double layer based on tungsten oxide (WO3) and spiro‐OMeTAD is reported as a hole transport layer in PSCs. The device equipped with a WO3/spiro‐OMeTAD layer achieves the highest efficiency (21.44%) in the tin (IV) oxide planar structure. The electronic properties of the double layer are thoroughly analyzed using photoluminescence, space‐charge–limited current, and electrochemical impedance spectroscopy. The WO3/spiro‐OMeTAD layer exhibits better hole extraction ability and faster hole mobility. The WO3 layer particularly improves the open‐circuit voltage (VOC) by lowering the quasi‐Fermi energy level for holes and reducing charge recombination, resulting in high VOC (1.17 V in the champion cell). In addition, the WO3 layer as a scaffold layer promotes the formation of a uniform and pinhole‐free spiro‐OMeTAD overlayer in the WO3/spiro‐OMeTAD layer. High stability under thermal and humid conditions stems from this property. The study presents a facile approach for improving the efficiency and stability of PSCs by stacking an organic layer on an inorganic layer. 相似文献
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Hong Duc Pham Terry Chien‐Jen Yang Sagar M. Jain Gregory J. Wilson Prashant Sonar 《Liver Transplantation》2020,10(13)
There has been considerable progress over the last decade in development of the perovskite solar cells (PSCs), with reported performances now surpassing 25.2% power conversion efficiency. Both long‐term stability and component costs of PSCs remain to be addressed by the research community, using hole transporting materials (HTMs) such as 2,2′,7,7′‐tetrakis(N,N′‐di‐pmethoxyphenylamino)‐9,9′‐spirbiuorene(Spiro‐OMeTAD) and poly[bis(4‐phenyl)(2,4,6‐trimethylphenyl)amine] (PTAA). HTMs are essential for high‐performance PSC devices. Although effective, these materials require a relatively high degree of doping with additives to improve charge mobility and interlayer/substrate compatibility, introducing doping‐induced stability issues with these HTMs, and further, additional costs and experimental complexity associated with using these doped materials. This article reviews dopant‐free organic HTMs for PSCs, outlining reports of structures with promising properties toward achieving low‐cost, effective, and scalable materials for devices with long‐term stability. It summarizes recent literature reports on non‐doped, alternative, and more stable HTMs used in PSCs as essential components for high‐efficiency cells, categorizing HTMs as reported for different PSC architectures in addition to use of dopant‐free small molecular and polymeric HTMs. Finally, an outlook and critical assessment of dopant‐free organic HTMs toward commercial application and insight into the development of stable PSC devices is provided. 相似文献
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Pengbin Ru Enbing Bi Yao Zhang Yanbo Wang Weiyu Kong Yongming Sha Wentao Tang Peng Zhang Yongzhen Wu Wei Chen Xudong Yang Han Chen Liyuan Han 《Liver Transplantation》2020,10(12)
Inverted perovskite solar cells (PSCs) with low‐temperature processed hole transporting materials (HTMs) suffer from poor performance due to the inferior hole‐extraction capability at the HTM/perovskite interfaces. Here, molecules with controlled electron affinity enable a HTM with conductivity improved by more than ten times and a decreased energy gap between the Fermi level and the valence band from 0.60 to 0.24 eV, leading to the enhancement of hole‐extraction capacity by five times. As a result, the 3,6‐difluoro‐2,5,7,7,8,8‐hexacyanoquinodimethane molecules are used for the first time enhancing open‐circuit voltage (Voc) and fill factor (FF) of the PSCs, which enable rigid‐and flexible‐based inverted perovskite devices achieving highest power conversion efficiencies of 22.13% and 20.01%, respectively. This new method significantly enhances the Voc and FF of the PSCs, which can be widely combined with HTMs based on not only NiOx but also PTAA, PEDOTT:PSS, and CuSCN, providing a new way of realizing efficient inverted PSCs. 相似文献
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Feng Qi Xiang Deng Xin Wu Lijun Huo Yiqun Xiao Xinhui Lu Zonglong Zhu Alex K.‐Y. Jen 《Liver Transplantation》2019,9(42)
Although perovskite solar cells (PVSCs) have achieved rapid progress in the past few years, most of the high‐performance device results are based on the doped small molecule hole‐transporting material (HTM), spiro‐OMeTAD, which affects their long‐term stability. In addition, some defects from under‐coordinated Pb atoms on the surface of perovskite films can also result in nonradiative recombination to affect device performance. To alleviate these problems, a dopant‐free HTM based on a donor‐acceptor polymer, PBT1‐C, synthesized from the copolymerization between the benzodithiophene and 1,3‐bis(4‐(2‐ethylhexyl)thiophen‐2‐yl)‐5,7‐bis(2‐alkyl)benzo[1,2‐c:4,5‐c′]dithiophene‐4,8‐dione units is introduced. PBT1‐C not only possesses excellent hole mobility, but is also able to passivate the surface traps of the perovskite films. The derived PVSC shows a high power conversion efficiency of 19.06% with a very high fill factor of 81.22%, which is the highest reported for dopant‐free polymeric HTMs. The results from photoluminescence and trap density of states measurements validate that PBT1‐C can effectively passivate both surface and grain boundary traps of the perovskite. 相似文献
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Highly Efficient and Stable Perovskite Solar Cells Using a Dopant‐Free Inexpensive Small Molecule as the Hole‐Transporting Material
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Yong Li Kyle R. Scheel Robert G. Clevenger Wan Shou Heng Pan Kathleen V. Kilway Zhonghua Peng 《Liver Transplantation》2018,8(23)
The hole transporting layer (HTL) plays an important role in realizing efficient and stable perovskite solar cells (PSCs). In spite of intensive research efforts toward the development of HTL materials, low‐cost, dopant‐free hole transporting materials that lead to efficient and stable PSCs remain elusive. Herein, a simple polycyclic heteroaromatic hydrocarbon‐based small molecule, 2,5,9,12‐tetra(tert‐butyl)diacenaphtho[1,2‐b:1′,2′‐d]thiophenen, as an efficient HTL material in PSCs is presented. This molecule is easy to synthesize and inexpensive. It is hydrophobic and exhibits excellent film‐forming properties on perovskites. It has unusually high hole mobility and a desirable highest occupied molecular orbital energy level, making it an ideal HTL material. PSCs fabricated using both the n‐i‐p planar and mesoscopic architectures with this compound as the HTL show efficiencies as high as 15.59% and 18.17%, respectively, with minimal hysteresis and high long term stability under ambient conditions. 相似文献
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Organic‐inorganic halide perovskite materials have become a shining star in the photovoltaic field due to their unique properties, such as high absorption coefficient, optimal bandgap, and high defect tolerance, which also lead to the breathtaking increase in power conversion efficiency from 3.8% to over 22% in just seven years. Although the highest efficiency was obtained from the TiO2 mesoporous structure, there are increasing studies focusing on the planar structure device due to its processibility for large‐scale production. In particular, the planar p‐i‐n structure has attracted increasing attention on account of its tremendous advantages in, among other things, eliminating hysteresis alongside a competitive certified efficiency of over 20%. Crucial for the device performance enhancement has been the interface engineering for the past few years, especially for such planar p‐i‐n devices. The interface engineering aims to optimize device properties, such as charge transfer, defect passivation, band alignment, etc. Herein, recent progress on the interface engineering of planar p‐i‐n structure devices is reviewed. This review is mainly focused on the interface design between each layer in p‐i‐n structure devices, as well as grain boundaries, which are the interfaces between polycrystalline perovskite domains. Promising research directions are also suggested for further improvements. 相似文献
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Toward Long‐Term Stable and Highly Efficient Perovskite Solar Cells via Effective Charge Transporting Materials
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Perovskite solar cells (PSCs) have advanced quickly with their power conversion efficiency approaching the record of silicon solar cells. However, there is still a big challenge to obtain both high efficiency and long‐term stability for future commercialization of PSCs. The major instability issue is associated with the decomposition or phase transition of perovskite materials that are believed to be intrinsically unstable under outdoor working conditions. Herein, the authors review the approaches that marked important progress in developing new functional electron/hole transporting materials that enabled highly efficient and stable PSCs. The findings that accelerate charge diffusion and that suppress the irrevocable loss of ions diffusing out of perovskite materials and other diffusion processes are highlighted. In addition, derivative interface engineering methods to control the diffusion process of charges/ions/molecules are also reviewed. Finally, the authors propose key research issues in charge transporting materials and interface engineering with regard to the important diffusion processes that will be one of the keys to realize highly efficient and long‐term stable PSCs. 相似文献
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4‐Tert‐butylpyridine Free Organic Hole Transporting Materials for Stable and Efficient Planar Perovskite Solar Cells
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Bo Xu Zonglong Zhu Jinbao Zhang Hongbin Liu Chu‐Chen Chueh Xiaosong Li Alex K.‐Y. Jen 《Liver Transplantation》2017,7(19)
4‐Tert ‐butylpyridine (t BP) is an important additive in triarylamine‐based organic hole‐transporting materials (HTMs) for improving the efficiency and steady‐state performance of perovskite solar cells (PVSCs). However, the low boiling point of t BP (196 °C) significantly affects the long‐term stability and device performance of PVSCs. Herein, the design and synthesis of a series of covalently linked Spiro[fluorene‐9,9′‐xanthene] (SFX)‐based organic HTMs and pyridine derivatives to realize efficient and stable planar PVSCs are reported. One of the tailored HTMs, N2,N2,N7,N7‐tetrakis(4‐methoxyphenyl)‐3′,6′‐bis(pyridin‐4‐ylmethoxy) spiro[fluorene‐9,9′‐xanthene]‐2,7‐diamine ( XPP ) with two para‐position substituted pyridines that immobilized on the SFX core unit shows a high power conversion efficiency (PCE) of 17.2% in planar CH3NH3PbI3‐based PVSCs under 100 mW cm?2 AM 1.5G solar illumination, which is much higher than the efficiency of 5.5% that using the well‐known 2,2′,7,7′‐tetrakis‐(N ,N ‐di‐p ‐methoxy‐phenyl‐amine)9,9′‐spirobifluorene (Spiro‐OMeTAD) as HTM (without t BP) under the same condition. Most importantly, the pyridine‐functionalized HTM‐based PVSCs without t BP as additive show much better long‐term stability than that of the state‐of‐the‐art HTM Spiro‐OMeTAD‐based solar cells that containing t BP as additive. This is the first case that the t BP‐free HTMs are demonstrated in PVSCs with high PCEs and good stability. It paves the way to develop highly efficient and stable t BP‐free HTMs for PVSCs toward commercial applications. 相似文献