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1.
The photovoltaic performance of perovskite solar cells (PVSCs) is extremely dependent on the morphology and crystallization of the perovskite film, which is affected by the deposition method. In this work, a new approach is demonstrated for forming the PbI 2 nanostructure and the use of high CH 3NH 3I concentration which are adopted to form high‐quality (smooth and PbI 2 residue‐free) perovskite film with better photovoltaic performances. On the one hand, self‐assembled porous PbI 2 is formed by incorporating small amount of rationally chosen additives into the PbI 2 precursor solutions, which significantly facilitate the conversion of perovskite without any PbI 2 residue. On the other hand, by employing a relatively high CH 3NH 3I concentration, a firmly crystallized and uniform CH 3NH 3PbI 3 film is formed. As a result, a promising power conversion efficiency of 16.21% is achieved in planar‐heterojunction PVSCs. Furthermore, it is experimentally demonstrated that the PbI 2 residue in perovskite film has a negative effect on the long‐term stability of devices. 相似文献
2.
During the fabrication of lateral-structured photodetectors based on CH 3NH 3PbI 3 film, antisolvents represented by toluene are usually used to accelerate the crystallization of perovskite. Using antisolvent not only leads to the formation of shrinkage holes at the bottom of the perovskite layer, but the toxicity of antisolvents would also hinder the industrial preparation of perovskite devices. An antisolvent-free method is a possible solution to avoid these problems. Here, we report a lateral-structured photodetector based on an antisolvent-free method. The lateral photodetector exhibited a high responsivity of 1.75 A⋅W −1 and specific detectivity (D*) of 3.54 × 10 12 Jones. In particular, the results indicated that the solvent had an influence on perovskite film morphology, crystallization, and device performance. The prepared CH 3NH 3PbI 3 film presented needle-like crystals and low performance with single precursor solvent N, N-dimethylformamide (DMF). In comparison, appropriate mixing of dimethyl sulfoxide (DMSO) could improve the morphology, crystallization, and performance of the film. In addition, the solvent volume ratio of the precursor had a profound effect on the performance of the as-prepared photodetectors. At a DMSO:DMF volume ratio of 5:5, the as-prepared film had massive perovskite crystals and fewer defects, resulting in optimal device performance, which can be explained by Urbach energy. 相似文献
3.
A high level of automation is desirable to facilitate the lab‐to‐fab process transfer of the emerging perovskite‐based solar technology. Here, an automated aerosol‐jet printing technique is introduced for precisely controlling the thin‐film perovskite growth in a planar heterojunction p–i–n solar cell device structure. The roles of some of the user defined parameters from a computer‐aided design file are studied for the reproducible fabrication of pure CH 3NH 3PbI 3 thin films under near ambient conditions. Preliminary power conversion efficiencies up to 15.4% are achieved when such films are incorporated in a poly(3,4‐ethylenedioxythiophene):polystyrene sulfonate‐perovskite‐phenyl‐C71‐butyric acid methyl ester type device format. It is further shown that the deposition of atomized materials in the form of a gaseous mist helps to form a highly uniform and PbI 2 residue‐free CH 3NH 3PbI 3 film and offers advantages over the conventional two‐step solution approach by avoiding the detrimental solid–liquid interface induced perovskite crystallization. Ultimately, by integrating full 3D motion control, the fabrication of perovskite layers directly on a 3D curved surface becomes possible. This work suggests that 3D automation with aerosol‐jet printing, once fully optimized, could form a universal platform for the lab‐to‐fab process transfer of solution‐based perovskite photovoltaics and steer development of new design strategies for numerous embedded structural power applications. 相似文献
4.
Organic–inorganic hybrid lead halide perovskites are emerging as highly promising candidates for highly efficient thin film photovoltaics due to their excellent optoelectronic properties and low‐temperature process capability. However, the long‐term stability in ambient air still is a key issue limiting their further practical applications. Herein, the enhancement of both performance and stability of perovskite solar cells is reported by employing 2D and 3D heterostructured perovskite films with unique nanoplate/nanocrystalline morphology. The 2D/3D heterostructured perovskites combine advantages of the high‐performance lead‐based perovskite 3D CH 3NH 3PbI 3 (MAPbI 3) and the air‐stable bismuth‐based quasi‐perovskite 2D MA 3Bi 2I 9. In the 2D/3D heterostructure, the hydrophobic MA 3Bi 2I 9 platelets vertically situate between the MAPbI 3 grains, forming a lattice‐like structure to tightly enclose the 3D MAPbI 3 perovskite grains. The solar cell based on the optimal 2D/3D (9.2%) heterostructured film achieves a high efficiency of 18.97%, with remarkably reduced hysteresis and significantly improved stability. The work demonstrates that construction of 2D/3D heterostructured films by hybridizing different species of perovskite materials is a feasible way to simultaneously enhance both efficiency and stability of perovskite solar cells. 相似文献
5.
The synthesis and growth of perovskite films with controlled crystallinity and microstructure for highly efficient and stable solar cells is a critical issue. In this work, thiourea is introduced into the CH 3NH 3PbI 3 precursor with two‐step sequential ethyl acetate (EA) interfacial processing. This is shown for the first time to grow compact microsized and monolithically grained perovskite films. X‐ray diffraction patterns and infrared spectroscopy are used to prove that thiourea significantly impacts the perovskite crystallinity and morphology by forming the intermediate phase MAI·PbI 2·S?C(NH 2) 2. Afterward, the residual thiourea which coursed charge recombination is completely extracted by the sequential EA processing. The product has improved light harvesting, suppressed defect state, and enhanced charge separation and transport. The sequentially EA processed perovskite solar cells offer an impressive 18.46% power conversion efficiency and excellent stability in ambient air. More importantly, the EA postprocessed perovskite solar cells also have excellent voltage response under ultraweak light (0.05% sun) with promising utility in photodetectors and photoelectric sensors. 相似文献
6.
Recently, the stability of organic–inorganic perovskite thin films under thermal, photo, and moisture stresses has become a major concern for further commercialization due to the high volatility of the organic cations in the prototype perovskite composition (CH 3NH 3PbI 3). All inorganic cesium (Cs) based perovskite is an alternative to avoid the release or decomposition of organic cations. Moreover, substituting Pb with Sn in the organic–inorganic lead halide perovskites has been demonstrated to narrow the bandgap to 1.2–1.4 eV for high‐performance perovskite solar cells. In this work, a series of CsPb 1?xSn xIBr 2 perovskite alloys via one‐step antisolvent method is demonstrated. These perovskite films present tunable bandgaps from 2.04 to 1.64 eV. Consequently, the CsPb 0.75Sn 0.25IBr 2 with homogeneous and densely crystallized morphology shows a remarkable power conversion efficiency of 11.53% and a high Voc of 1.21 V with a much improved phase stability and illumination stability. This work provides a possibility for designing and synthesizing novel inorganic halide perovskites as the next generation of photovoltaic materials. 相似文献
7.
The influence of monovalent cation halide additives on the optical, excitonic, and electrical properties of CH 3NH 3PbI 3 perovskite is reported. Monovalent cation halide with similar ionic radii to Pb 2+, including Cu +, Na +, and Ag +, have been added to explore the possibility of doping. Significant reduction of sub‐bandgap optical absorption and lower energetic disorder along with a shift in the Fermi level of the perovskite in the presence of these cations has been observed. The bulk hole mobility of the additive‐based perovskites as estimated using the space charge limited current method exhibits an increase of up to an order of magnitude compared to the pristine perovskites with a significant decrease in the activation energy. Consequentially, enhancement in the photovoltaic parameters of additive‐based solar cells is achieved. An increase in open circuit voltage for AgI (≈1.02 vs 0.95 V for the pristine) and photocurrent density for NaI‐ and CuBr‐based solar cells (≈23 vs 21 mA cm ?2 for the pristine) has been observed. This enhanced photovoltaic performance can be attributed to the formation of uniform and continuous perovskite film, better conversion, and loading of perovskite, as well as the enhancement in the bulk charge transport along with a minimization of disorder, pointing towards possible surface passivation. 相似文献
8.
Light management holds great promise of realizing high‐performance perovskite solar cells by improving the sunlight absorption with lower recombination current and thus higher power conversion efficiency (PCE). Here, a convenient and scalable light trapping scheme is demonstrated by incorporating bioinspired moth‐eye nanostructures into the metal back electrode via soft imprinting technique to enhance the light harvesting in organic–inorganic lead halide perovskite solar cells. Compared to the flat reference cell with a methylammonium lead halide perovskite (CH 3NH 3PbI 3?x Cl x ) absorber, 14.3% of short‐circuit current improvement is achieved for the patterned devices with moth‐eye nanostructures, yielding an increased PCE up to 16.31% without sacrificing the open‐circuit voltage and fill factor. The experimental and theoretical characterizations verify that the cell performance enhancement is mainly ascribed by the broadband polarization‐insensitive light scattering and surface plasmonic effects due to the patterned metal back electrode. It is noteworthy that this light trapping strategy is fully compatible with solution‐processed perovskite solar cells and opens up many opportunities toward the future photovoltaic applications. 相似文献
9.
The emission wavelength of organic–inorganic hybrid perovskite quantum dots (QDs) can be tuned by controlling reaction time relevant to the halide exchange. It is because halide exchange with different time would lead to different molar ratio of halides in perovskite QDs such as Cl and Br. Here, to research the ligand's effect on the halide exchange, this work synthesized 3‐mercaptopropionic acid (MPA)‐capped CH 3NH 3PbBr xCl 3‐x QDs. It was found that SH ? of MPA appeared to inhibit the halide exchange during the reation. Moreover, although the MPA‐capped CH 3NH 3PbBr xCl 3‐x QDs did not contain the chiral centre, they exhibit the optical rotation. This may provide a method for chirality manipulation of perovskite. 相似文献
10.
We suggest semi-analytical approach to study the optical properties of noble metal nanoparticles and their interaction to the perovskite material (methyl ammonia lead halide: CH 3NH 3PbI 3). Metal nanoparticles embedded in perovskite matrix exhibits broadband surface plasmon resonances, and the tunability of these plasmonic resonances is highly sensitive to particle size. The calculation of optical cross section have been done using Mie scattering theory which is applicable to arbitrary size and spherical-shape metal nanoparticles. We have taken five different radii ranging from 15 to 100 nm to understand the plasmonic resonances and its spectral width in the wavelength range 300 to 800 nm. Out of these noble metal nanoparticles, silver have highest scattering efficiency nearly of the order of 18 for the case of 15 nm radii at resonance wavelength 613 nm. Our finding reveals a new concept to understand the applications of plasmonic resonances in order to enhance the photon absorption inside the thin film of perovskite. 相似文献
11.
Remarkable power conversion efficiencies (PCE) of metal–halide perovskite solar cells (PSCs) are overshadowed by concerns about their ultimate stability, which is arguably the prime obstacle to commercialization of this promising technology. Herein, the problem is addressed by introducing ethane‐1,2‐diammonium ( +NH 3(CH 2) 2NH 3+, EDA 2+) cations into the methyl ammonium (CH 3NH 3+, MA +) lead iodide perovskite, which enables, inter alia, systematic tuning of the morphology, electronic structure, light absorption, and photoluminescence properties of the perovskite films. Incorporation of <5 mol% EDA 2+ induces strain in the perovskite crystal structure with no new phase formed. With 0.8 mol% EDA 2+, PCE of the MAPbI 3‐based PSCs (aperture of 0.16 cm 2) improves from 16.7% ± 0.6% to 17.9% ± 0.4% under 1 sun irradiation, and fabrication of larger area devices (aperture 1.04 cm 2) with a certified PCE of 15.2% ± 0.5% is demonstrated. Most importantly, EDA 2+/MA +‐based solar cells retain 75% of the initial performance after 72 h of continuous operation at 50% relative humidity and 50 °C under 1 sun illumination, whereas the MAPbI 3 devices degrade by approximately 90% within only 15 h. This substantial improvement in stability is attributed to the steric and coulombic interactions of embedded EDA 2+ in the perovskite structure. 相似文献
12.
Two chemically tailored new conjugated copolymers, HSL1 and HSL2, were developed and applied as hole selective layers to improve the anode interface of fullerene/perovskite planar heterojunction solar cells. The introduction of polar functional groups on the polymer side chains increases the surface energy of the hole selective layers (HSLs), which promote better wetting with the perovskite films and lead to better films with full coverage and high crystallinity. The deep highest occupied molecular orbital levels of the HSLs align well with the valence band of the perovskite semiconductors, resulted in increase photovoltage. The high lying lowest unoccupied molecule orbital level provides sufficient electron blocking ability to prevent electrons from reaching the anode and reduces the interfacial trap‐assisted recombination at the poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate)/perovskite interface, resulting in a longer charge‐recombination lifetime and shorter charge‐extraction time. In the presence of the HSLs, high‐performance CH 3NH 3PbI x Cl 3? x perovskite solar cells with a power conversion efficiency (PCE) of 16.6% ( V oc: 1.07 V) and CH 3NH 3Pb(I 0.3Br 0.7) x Cl 3? x cells with a PCE of 10.3% ( V oc: 1.34 V) can be realized. 相似文献
13.
The production of highly efficient single‐ and multijunction metal halide perovskite (MHP) solar cells requires careful optimization of the optical and electrical properties of these devices. Here, precise control of CH 3NH 3PbI 3 perovskite layers is demonstrated in solar cell devices through the use of dual source coevaporation. Light absorption and device performance are tracked for incorporated MHP films ranging from ≈67 nm to ≈1.4 µm thickness and transfer‐matrix optical modeling is utilized to quantify optical losses that arise from interference effects. Based on these results, a device with 19.2% steady‐state power conversion efficiency is achieved through incorporation of a perovskite film with near‐optimum predicted thickness (≈709 nm). Significantly, a clear signature of photon reabsorption is observed in perovskite films that have the same thickness (≈709 nm) as in the optimized device. Despite the positive effect of photon recycling associated with photon reabsorption, devices with thicker (>750 nm) MHP layers exhibit poor performance owing to competing nonradiative charge recombination in a “dead‐volume” of MHP. Overall, these findings demonstrate the need for fine control over MHP thickness to achieve the highest efficiency cells, and accurate consideration of photon reabsorption, optical interference, and charge transport properties. 相似文献
14.
Reduced graphene oxide (rGO) is added in the [6,6]‐Phenyl‐C61‐butyric acid methyl ester (PCBM) electron transport layer (ETL) of planar inverted perovskite solar cells (PSCs), resulting in a power conversion efficiency (PCE) improvement of ≈12%, with a hysteresis‐free PCE of 14.5%, compared to 12.9% for the pristine PCBM based device. The universality of the method is demonstrated in PSCs based on CH 3NH 3PbI 3?x Cl x and CH 3NH 3PbI 3 perovskites, deposited through one step and two step spin coating process, respectively. After a comprehensive spectroscopic characterization of both devices, it is clear that the introduction of rGO in PCBM ETL results in an important increase of the ETL conductivity, together with reduced series resistance and surface roughness. As a result, a significant photoluminescence quenching of such perovskite/ETL is observed, confirming the increased measured short circuit current density. Transient absorption measurements reveal that in the rGO‐based device, the relaxation process of the excited electrons is significantly faster compared to the reference, which implies that the charge injection rate is significantly faster for the first. Furthermore, the light soaking effect is significantly reduced. Finally, aging measurements reveal that the rGO stabilizes the ELT/perovskite interface, which results in the stabilization of perovskite crystal structure after prolonged illumination. 相似文献
15.
Indoor photovoltaics are promising to enable self‐powered electronic devices for the Internet of Things. Here, reported is a triple‐anion CH 3NH 3PbI 2?xBrCl x perovskite film, of which the bandgap is specially designed for indoor light harvesting to achieve a record high efficiency of 36.2% with distinctive high open circuit voltage ( Voc) of 1.028 V under standard 1000 lux fluorescent light. The involvement of both bromide and chloride suppresses the trap‐states and nonradiative recombination loss, exhibiting a remarkable ideality factor of 1.097. The introduction of chloride successfully restrains the halide segregation of iodide and bromide, stabilizing the triple‐anion perovskite film. The devices show an excellent long‐term performance, sustaining over 95% of original efficiency under continuous light soaking over 2000 h. These findings show the importance and potential of I/Br/Cl triple‐anion perovskite with tailored bandgap and suppressed trap‐states in stable and efficient indoor light recycling. 相似文献
16.
Replacing toxic solvents with nonhazardous solvents is one of the key challenges for industrial scale commercialization of thin film perovskite photovoltaics. Here, nonhazardous solvent/alcohol/acid systems are presented for the single‐step deposition of pinhole‐free perovskite layers with combined lead halide precursors of Pb(CH 3CO 2) 2·3H 2O, PbCl 2, and CH 3NH 3I. Comparable performance to standard hazardous inks is achieved: devices with 15.1% power conversion efficiency are demonstrated and maintain 13.5% tracked for 5 min at maximum power point. Blade coated 4 cm 2 solar modules fabricated with highest performing device ink attain 11.9% in power conversion efficiency. 相似文献
17.
We demonstrate the optical response of metal nanoparticles and their interaction with organic-inorganic perovskite (methyl ammonia lead halide (CH3NH3PbI3)) environment using discrete dipole approximation (DDA) simulation technique. Important optical properties like absorption, scattering, and electric field calculations for metal nanoparticle using different geometry have been analyzed. The metal nanoparticles embedded in the perovskite media strongly support surface plasmon resonances (SPRs). The plasmonic interaction of metal nanoparticles with perovskite matrix is a strong function of MNP’s shape, size, and surrounding environment that can manipulate the optical properties considerably. The cylindrical shape of MNPs embedded in perovskite environment supports the SPR which is highly tunable to subwavelength range of 400–800 nm. Wide range of particle sizes has been selected for Ag, Au, and Al spherical and cylindrical nanostructures surrounded by perovskite matrix for simulation. The chosen hybrid material and anisotropy of structure together make a complex function for resonance shape and width. Among all MNPs, 70-nm spherical silver nanoparticle (NP) and cylindrical Ag NP having diameter of 50 nm and length of 70 nm (aspect ratio 1.4) generate strong electric field intensity that facilitates increased photon absorption. The plasmonic perovskite interaction plays an important role to improve the absorption of photon inside the thin film perovskite environment that may be applicable to photovoltaics and photonics. 相似文献
18.
Judicious choice of transport layer in organic–inorganic halide perovskite solar cells can be one of the essential parameters in photovoltaic design and fabrication techniques. This article reports the effect of optically generated dipoles in transport layer on the photovoltaic actions in active layer in perovskite solar cells with the architecture of indium tin oxide (ITO)/TiO x /CH 3NH 3PbI 3–x Cl x /hole transport layer (HTL)/Au. Here, PTB7‐thieno[3,4‐b]thiophene‐ alt‐benzodithiophene and P3HT‐poly(3‐hexylthiophene) are separately used as the HTL with significant and negligible photoinduced dipoles, respectively. Electric field‐induced photoluminescence quenching provides the first‐hand evidence to indicate that the photoinduced dipoles are partially aligned in the amorphous PTB7 layer under the influence of device built‐in field. By monitoring the recombination process through magneto‐photocurrent measurements under device operation condition, it is shown that the photoinduced dipoles in PTB7 layer can decrease the recombination of photogenerated carriers in the active layer in perovskite solar cells. Furthermore, the capacitance measurements suggest that the photoinduced dipoles in PTB7 can decrease charge accumulation at the electrode interface. Therefore, the studies indicate the important role of photoinduced dipoles in the HTL on charge recombination dynamics and provide a fundamental insight on how the polarization in transport layer can influence the device performance in perovskite solar cells. 相似文献
19.
Carbon‐based hole transport material (HTM)‐free perovskite solar cells (PSCs) have shown much promise for practical applications because of their high stability and low cost. However, the efficiencies of this kind of PSCs are still relatively low, especially for the simplest paintable carbon‐based PSCs, in comparison with the organic HTM‐based PSCs. This can be imputed to the perovskite deposition methods that are not very suitable for this kind of devices. A solvent engineering strategy based on two‐step sequential method is exploited to prepare a high‐quality perovskite layer for the paintable carbon‐based PSCs in which the solvent for CH 3NH 3I (MAI) solution at the second step is changed from isopropanol (IPA) to a mixed solvent of IPA/Cyclohexane (CYHEX). This mixed solvent not only accelerates the conversion of PbI 2 to CH 3NH 3PbI 3 but also suppresses the Ostwald ripening process resulting in a high‐quality perovskite layer, e.g., pure phase, even surface, and compact capping layer. The paintable carbon‐based PSCs fabricated from IPA/CYHEX solvent exhibits a considerable enhancement in photovoltaic performance and performance reproducibility in comparison with that from pure IPA, especially on fill factor (FF), owing mainly to the better contact of perovskite/carbon interface, lower trap density in perovskite, higher light absorption ability, and faster charge transport of perovskite layer. As a result, the highest power conversion efficiency (PCE) of 14.38% is obtained, which is a record value for carbon‐based HTM‐free PSCs. Furthermore, a PCE of as high as 10% is achieved for the large area device (1 cm 2), also the highest of its kind. 相似文献
20.
Organic–inorganic hybrid perovskite solar cells based on CH 3NH 3PbI 3 have achieved great success with efficiencies exceeding 20%. However, there are increasing concerns over some reported efficiencies as the cells are susceptible to current–voltage ( I–V) hysteresis effects. It is therefore essential that the origins and mechanisms of the I–V hysteresis can clearly be understood to minimize or eradicate these hysteresis effects completely for reliable quantification. Here, a detailed electro‐optical study is presented that indicates the hysteresis originates from lingering processes persisting from sub‐second to tens of seconds. Photocurrent transients, photoluminescence, electroluminescence, quasi‐steady state photoinduced absorption processes, and X‐ray diffraction in the perovskite solar cell configuration have been monitored. The slow processes originate from the structural response of the CH 3NH 3PbI 3 upon E‐field application and/or charge accumulation, possibly involving methylammonium ions rotation/displacement and lattice distortion. The charge accumulation can arise from inefficient charge transfer at the perovskite interfaces, where it plays a pivotal role in the hysteresis. These findings underpin the significance of efficient charge transfer in reducing the hysteresis effects. Further improvements of CH 3NH 3PbI 3‐based perovskite solar cells are possible through careful surface engineering of existing TiO 2 or through a judicious choice of alternative interfacial layers. 相似文献
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