Environmental Assessment of Single‐Walled Carbon Nanotube Processes

The environmental assessment of nanomanufacturing during the initial process design phase should lead to the development of competitive, safe, and environmentally responsible engineering and commercialization. Given the potential benefits and concerns regarding the use of single‐walled carbon nanotubes (SWNTs), three SWNT production processes have been investigated to assess their associated environmental impacts. These processes include arc ablation (arc), chemical vapor deposition (CVD), and high‐pressure carbon monoxide (HiPco). Without consideration of the currently unknown impacts of SWNT dispersion or other health impacts, life cycle assessment (LCA) methodology is used to analyze the environmental impact and provide a baseline for the environmental footprint of each manufacturing process. Although the technical attributes of the product resulting from each process may not be fully comparable, this study presents comparisons that show that the life cycle impacts are dominated by energy, specifically the electricity used in production. Under base case yield conditions, HiPco shows the lowest environmental impact, while the arc process has the lowest impact under best case yield conditions.     

The Environmental Importance of Energy Use in Chemical Production

In many cases, policy makers and laymen perceive harmful emissions from chemical plants as the most important source of environmental impacts in chemical production. As a result, regulations and environmental efforts have tended to focus on this area. Concerns about energy use and greenhouse gas emissions, however, are increasing in all industrial sectors. Using a life cycle assessment (LCA) approach, we analyzed the full environmental impacts of producing 99 chemical products in Western Europe from cradle to factory gate. We applied several life cycle impact assessment (LCIA) methods to cover various impact areas. Our analysis shows that for both organic and inorganic chemical production in industrial countries, energy‐related impacts often represent more than half and sometimes up to 80% of the total impacts, according to a range of LCIA methods. Resource use for material feedstock is also important, whereas direct emissions from chemical plants may make up only 5% to 10% of the total environmental impacts. Additionally, the energy‐related impacts of organic chemical production increase with the complexity of the chemicals. The results of this study offer important information for policy makers and sustainability experts in the chemical industry striving to reduce environmental impacts. We identify more sustainable energy production and use as an important option for improvements in the environmental profile of chemical production in industrial countries, especially for the production of advanced organic and fine chemicals.     

Alternatives for Reducing the Environmental Impact of the Main Residue From a Desalination Plant

One of the most important problems today is the scarcity of fresh water safe enough for human, industrial, and agricultural use. Desalination is an alternative source of fresh water supply in areas with severe problems of water availability. Desalination plants generate a huge amount of brine as the main residual from the plant (about 55% of collected seawater). Because of that, it is important to determine the best environmental option for the brine disposal. This article makes a global environmental analysis, under Spanish conditions, of a desalination plant and an environmental assessment of different final brine disposals, representing a range of the most common alternatives: direct disposal, wastewater treatment plant (WWTP) outflow dilution, and dilution with seawater. The environmental profile of the plant operation and a comparison of the brine final disposal alternatives were established by means of the life cycle assessment (LCA) methodology. From an analysis of the whole plant we observed that the highest environmental impact was caused by energy consumption, especially at the reverse osmosis stage, while the most relevant waste was brine. From an analysis of brine final disposal we have elaborated a comparison of the advantages and detriments of the three alternatives. As all of them might be suitable in different specific situations, the results might be useful in decisions about final brine disposal.     

Reducing Life Cycle Environmental Impacts of Waste Electrical and Electronic Equipment Recycling

Collection and treatment of waste from electrical and electronic equipment (WEEE) is regulated in the European Union by the WEEE Directive. Producers are responsible for take‐back and recycling of discarded equipment. Valuable materials are, however, at risk of “getting lost” in current processes. Thus, strategies to minimize losses are sought after. The material hygiene (MH) concept was introduced to address this issue. Structural features, which are important for the outcome of reuse, recovery, and recycling, were investigated in an earlier field study of discarded dishwashers. It was proposed that a prestep, manual removal of copper prior to shredding could increase the purity of recovered material fractions. This article builds on the field study and theoretical reasoning underlying the MH concept. Dishwashers are assumed to be designed for disassembly when the prestep is introduced. A limited life cycle assessment was performed to determine whether the proposed prestep may be environmentally beneficial in a life cycle perspective. Two alternatives were analyzed: Case 1: the current shredding process. Case 2: prestep removal of copper before shredding. Targeted disassembly prior to shredding may reduce the abiotic depletion and global warming potential in a life cycle perspective. The prestep results in increased copper recovery, but, more important, copper contamination of the recovered steel fractions is reduced. The results also highlight the importance of minimizing energy consumption in all process stages.     

An Approach for Calculating the Environmental External Costs of the Belgian Building Sector

This article describes an approach developed to estimate the environmental external costs of the Belgian building sector. Several existing methods and related data sets for determining the monetary value of environmental impacts were reviewed and compared in light of their relevance to an impact assessment of the construction sector. This study concludes that the methods available consider different impacts and differ substantially in monetary values for identical impacts. A harmonized and transparent method is recommended to improve the feasibility and acceptance of internalizing external costs; agreement on the impacts to be assessed and their external costs based on current insights is important. Here, a new method is proposed for a life cycle impact assessment‐based valuation of environmental external costs for application to the Belgian building sector. To enable a comprehensive assessment, it became clear that solely considering “key” pollutants is insufficient. Although this article focuses on the development and not on the implementation of the method proposed, implementation revealed that the life cycle environmental external cost of new buildings (meeting current insulation standards or better) is relatively small compared to the life cycle financial cost.     

Dimensionality Reduction and Visualization of the Environmental Impacts of Domestic Appliances

There is an increasing worldwide concern about the problem of dealing with the waste electrical and electronic equipment (WEEE), given the high volume of appliances that are disposed of every day. In this article, an environmental evaluation of WEEE is performed that combines life cycle assessment (LCA) methodology and multivariate statistical techniques. Because LCA handles a large number of data in its different phases, when one is trying to uncover the structure of large multidimensional data sets, multivariate statistical techniques can provide useful information. In particular, principal‐component analysis and multidimensional scaling are two important dimension‐reducing tools that have been shown to be of help in understanding this type of complex multivariate data set. In this article, we use a variable selection method that reduces the number of categories for which the environmental impacts have to be computed; this step is especially useful when the number of impact categories or the number of products or processes to benchmark increases. We provide a detailed illustration showing how we have used the proposed approach to analyze and interpret the environmental impacts of different domestic appliances.     

Life Cycle Environmental and Cost Impacts of Using an Algal Turf Scrubber to Treat Dairy Wastewater

Using algae to simultaneously treat wastewater and produce energy products has potential environmental and economic benefits. This study evaluates the life cycle energy, greenhouse gas (GHG) emissions, eutrophication potential, and cost impacts of incorporating an algal turf scrubber (ATS) into a treatment process for dairy wastewater. A life cycle inventory and cost model was developed to simulate an ATS treatment system where harvested algae would be used to generate biogas for process heat and electricity generation. Modeling results show that using an ATS significantly reduces eutrophication impacts by reducing chemical oxygen demand, nitrogen, and phosphorus in the wastewater. With low water recirculation rates through the ATS and high algae productivity, inclusion of the ATS results in net energy displacement and a reduction of GHG emissions compared to a system with no ATS. However, if high water recirculation rates are used or if algae biosolids from the digester are dried, the system results in a net increase in energy consumption and GHG emissions. The life cycle treatment cost was estimated to be $1.42 USD per cubic meter of treated wastewater. At this cost, using an ATS would only be cost effective for dairies if they received monetary credits for improved water quality on the order of $3.83 per kilogram of nitrogen and $9.57 per kilogram of phosphorus through, for example, nutrient trading programs.     

生命周期管理研究述评

生命周期管理起源于生命周期思想,它是生命周期思想在实践中的具体应用,是面向可持续生产和消费,对产品、工艺和服务的全生命周期环境影响进行的综合管理,是解决复合生态系统中结构无序、效率不高和代谢冗余的有效途径,是基于生命周期评价原则与框架的一种环境管理手段或环境管理体系。全面回顾了生命周期管理的起源与内涵,阐述了生命周期管理与生命周期评价的区别与联系,梳理了生命周期管理与环境管理体系的关系。对生命周期管理在产品、企业、行业及城市等层次上的具体应用进行了总结与述评,并对其今后需深入研究的方向进行了展望。     

Impact Assessment of Biodiversity and Carbon Pools from Land Use and Land Use Changes in Life Cycle Assessment,Exemplified with Forestry Operations in Norway

There is a strong need for methods within life cycle assessment (LCA) that enable the inclusion of all complex aspects related to land use and land use change (LULUC). This article presents a case study of the use of one hectare (ha) of forest managed for the production of wood for bioenergy production. Both permanent and temporary changes in above‐ground biomass are assessed together with the impact on biodiversity caused by LULUC as a result of forestry activities. The impact is measured as a product of time and area requirements, as well as by changes in carbon pools and impacts on biodiversity as a consequence of different management options. To elaborate the usefulness of the method as well as its dependency on assumptions, a range of scenarios are introduced in the study. The results show that the impact on climate change from LULUC dominates the results, compared to the impact from forestry operations. This clearly demonstrates the need to include LULUC in an LCA of forestry products. For impacts both on climate change and biodiversity, the results show large variability based on what assumptions are made; and impacts can be either positive or negative. Consequently, a mere measure of land used does not provide any meaning in LCA, as it is not possible to know whether this contributes a positive or negative impact.     

Energy Use and Environmental Impacts of the Swedish Building and Real Estate Management Sector

One of the key features of environmental policy integration in Sweden is sector responsibility. The National Board of Housing, Building and Planning is responsible for the building and real estate management sector and should, as a part of this responsibility, assess the environmental impacts of this sector. The aim of this study is to suggest and demonstrate a method for such an assessment. The suggested method is a life cycle assessment, based on an input‐output analysis. The method can be used for regular monitoring and for prioritization between different improving measures. For the assessment to sufficiently cover the Swedish Environmental Quality Objectives, complementary information is needed, in particular with respect to the indoor environment. According to the results, the real estate management sector contributes between 10% and 40% of Swedish energy use; use of hazardous chemical products; generation of solid waste; emissions of gases contributing to climate change; and human toxicological impacts, including nitrogen oxides (NOx) and particulates. Transport and production of nonrenewable building materials contribute significantly to several of the emissions. Heating of buildings contributes more to energy use than to climate change, due to the use of renewable energy sources. To reduce climate change, measures should therefore prioritize not only heating of buildings but also the important upstream processes.     

Development of a Consumer Environmental Index and Results for Washington State Consumers

Consumer choices affect sustainability of societal systems, and state governments increasingly are interested in environmental impacts of consumption. This article describes a Consumer Environmental Index (CEI) to track the impacts of product purchase, use, and disposal and applies this initial CEI to Washington State in the United States. CEI has modules for product and service use, upstream resource extraction and manufacturing, and downstream disposal. CEI uses hybrid life cycle assessment (LCA) methods, combined with purchasing data from the Bureau of Labor Statistics (BLS) Consumer Expenditure Survey. For Washington State, when human health and ecosystem toxicity impact was assessed with the TRACI/CalTOX methods, weighted aggregate and per consumer impacts in all categories increased during the 6 years from 2000 to 2005. For impacts per real dollar spent, only the CEI's climate change component declined, falling nearly 7% between 2000 and 2005. Purchasing details in the BLS expenditure surveys enable the CEI to track environmental impact details on 700 individual categories of products and services. For example, sugar, motor oil, and wood heat appear to have serious environmental impacts, whereas recycling of paper, cardboard, and food and beverage container discards can be as effective at reducing greenhouse gas emissions as cutting vehicle fuel usage nearly in half. Such results may serve to increase understanding of environmentally effective actions to reduce climate, human health, and ecosystem impacts of consumption.     

Life Cycle Assessment of Medium Surge Arresters in the Context of Size‐Reduction Design

Zinc oxide (ZnO) polycrystalline ceramics are the focal point of lightning arrester technology. These semiconductor materials are able to switch rapidly from high to low impedance while handling large amounts of electrical energy. Since the early 1970s, considerable efforts have been made to improve the specific energy absorption capacity and device reliability of such components. This document describes a case study carried out on the life cycle impacts of three different designs of electroceramics made of ZnO. Results show that the best design involves decreasing the diameter while maintaining the thickness of the compound. Of the production, transport, use, and end‐of‐life phases, the use phase is found to contribute by far the most to environmental impacts, with leakage currents in the 10^?6 ampere range. The next‐largest impacts come in the transport and production stages. Sensitivity analysis shows that impacts associated with the production stage originate from ZnO production and are related to the by‐products (heavy metals) of zinc metallurgy.     

Environmental Damage Assessment of Carbon Capture and Storage

An end‐point life cycle impact assessment is used to evaluate the damages of electricity generation from fossil fuel‐based power plants with carbon dioxide capture and storage (CCS) technology. Pulverized coal (PC), integrated gasification combined cycle (IGCC), and natural gas combined cycle (NGCC) power plants are assessed for carbon dioxide (CO₂) capture, pipeline transport, and storage in a geological formation. Results show that the CCS systems reduce the climate change‐related damages but increase the damages from toxicity, acidification, eutrophication, and resource consumption. Based on the currently available damage calculation methods, it is concluded that the benefit of reducing damage from climate change is larger than the increases in other damage categories, such as health effects from particulates or toxic chemicals. CCS significantly reduces the overall environmental damage, with a net reduction of 60% to 70% in human health damage and 65% to 75% in ecosystem damage. Most of the damage is due to fuel production and combustion processes. The energy and infrastructure demands of CCS cause increases in the depletion of natural resources by 33% for PC, 19% for IGCC, and 18% for NGCC power plants, mostly due to increased fossil fuel consumption.     

Environmental Impact and Intensity of Processes in Selected Services Companies

The study fills the gap in existing literature by comparing the economic costs and environmental impacts of processes in four services companies in Europe and the United States. Process-based life cycle assessment (LCA) and the case study method are used to compare companies both on four global-scale impacts and on environmental intensity (impacts per unit cost). The study builds on prior publications on the environmental contribution of processes. The processes include all the activities of the companies that result in an entry into the bookkeeping records. The results show that despite the substantial differences in organizational characteristics and line of business, all the cases had similar environmental contributions and intensity profiles. Wages, which accounted for over half of the costs, were assumed not to cause any environmental impacts. By contrast, the office premises, which generated less than 10% of the costs, caused around 50% of the environmental impacts. At a more general level, the results suggest that both the high environmental impact and the high intensity are attributed mostly to a few premises-related processes in the services industry. The results also seem to imply that the companies could gain added value by using life cycle assessment in determining the significant environmental impacts of their operations.     

Evaluation of the Metals Industry's Position on Recycling and its Implications for Environmental Emissions

A healthy debate on the treatment of metals recycling in the life cycle assessment (LCA) community has persisted for more than a decade. While no clear consensus across stakeholder groups has emerged, the metals industry has endorsed a set of recycling “facts” that support a single approach, end‐of‐life recycling, for evaluating the environmental benefits of metals recycling. In this article we draw from research conducted in several disciplines and find that three key tenets of the metals industry capture the theoretical potential of metals recycling from a metallurgical standpoint rather than reflecting observed behavior. We then discuss the implications of these conclusions on environmental emissions from metals production and recycling. Evidence is provided that, contrary to the position of the metals industry, metals are not necessarily recycled at high rates, are recycled only a small number of times before final disposal, and are sometimes limited in recycling potential by the economics of contaminant removal. The analysis concludes that metal recycled from old scrap largely serves as an imperfect substitute for primary metal. As a result, large‐scale displacement of primary production and its associated environmental emissions is currently limited to a few specific instances.     

Methodological Aspects of Applying Life Cycle Assessment to Industrial Symbioses

In view of recent studies of the historical development and current status of industrial symbiosis (IS), life cycle assessment (LCA) is proposed as a general framework for quantifying the environmental performance of by‐product exchange. Recent guidelines for LCA (International Reference Life Cycle Data System [ILCD] guidelines) are applied to answer the main research questions in the IS literature reviewed. A typology of five main research questions is proposed: (1) analysis, (2) improvement, and (3) expansion of existing systems; (4) design of new eco‐industrial parks, and (5) restructuring of circular economies. The LCA guidelines were found useful in framing the question and choosing an appropriate reference case for comparison. The selection of a correct reference case reduces the risk of overestimating the benefits of by‐product exchange. In the analysis of existing systems, environmentally extended input‐output analysis (EEIOA) can be used to streamline the analysis and provide an industry average baseline for comparison. However, when large‐scale changes are applied to the system, more sophisticated tools are necessary for assessment of the consequences, from market analysis to general equilibrium modeling and future scenario work. Such a rigorous application of systems analysis was not found in the current IS literature, but would benefit the field substantially, especially when the environmental impact of large‐scale economic changes is analyzed.     

Life Cycle Assessment of Urban Wastewater Reclamation and Reuse Alternatives

Continuous population growth is causing increased water contamination. Uneven distribution of water resources and periodic droughts have forced governments to seek new water sources: reclaimed and desalinated water. Wastewater recovery is a tool for better management of the water resources that are diverted from the natural water cycle to the anthropic one. The main objective of this work is to assess the stages of operation of a Spanish Mediterranean wastewater treatment plant to identify the stages with the highest environmental impact, to establish the environmental loads associated with wastewater reuse, and to evaluate alternative final destinations for wastewater. Tertiary treatment does not represent a significant increment in the impact of the total treatment at the plant. The impact of reclaiming 1 cubic meter (m³) of wastewater represents 0.16 kilograms of carbon dioxide per cubic meter (kg CO₂/m³), compared to 0.83 kg CO₂/m³ associated with basic wastewater treatment (primary, secondary, and sludge treatment). From a comparison of the alternatives for wastewater final destination, we observe that replacing potable water means a freshwater savings of 1.1 m³, whereas replacing desalinated water means important energy savings, reflected in all of the indicators. To ensure the availability of potable water to all of the population—especially in areas where water is scarce—governments should promote reusing wastewater under safe conditions as much as possible.     

Computation of Operational and Environmental Benchmarks Within Selected Galician Fishing Fleets

Increasing the eco‐efficiency of fishing fleets is currently a major target issue in the seafood sector. This objective has been influenced in recent years by soaring fuel prices, a fact particularly relevant to a sector whose vessels present high energy consumption rates. Efforts to minimize fuel consumption in fishing fleets result in economic benefits and also in important reductions regarding environmental impacts. In this article, we combine life cycle assessment (LCA) and data envelopment analysis (DEA) to jointly discuss the operational and environmental performances of a set of multiple, similar entities. We applied the “five‐step LCA + DEA method” to a wide range of vessels for selected Galician fisheries, including deep‐sea, offshore, and coastal fleets. The environmental consequences of operational inefficiencies were quantified and target performance values benchmarked for inefficient vessels. We assessed the potential environmental performance of target vessels to verify eco‐efficiency criteria (lower input consumption levels, lower environmental impacts). Results revealed the strong dependence of environmental impacts on one major operational input: fuel consumption. The most intensive fuel‐consuming fleets, such as deep sea trawling, were found to entail the diesel consumption levels nearest to the efficiency values. Despite the reduced environmental contributions linked to other operational inputs, such as hull material, antifouling paint, or nets, these may contribute to substantial economic savings when minimized. Finally, given that Galicia is a major fishing region, many of the conclusions and perspectives obtained in this study may be extrapolated to other fishing fleets at the international level.