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1.
Life-cycle assessment concepts and methods are currently being applied to evaluate integrated municipal solid waste management strategies throughout the world. The Research Triangle Institute and the U.S. Environmental Protection Agency are working to develop a computer-based decision support tool to evaluate integrated municipal solid waste management strategies in the United States. The waste management unit processes included in this tool are waste collection, transfer stations, recovery, compost, combustion, and landfill. Additional unit processes included are electrical energy production, transportation, and remanufacturing. The process models include methodologies for environmental and cost analysis. The environmental methodology calculates life cycle inventory type data for the different unit processes. The cost methodology calculates annualized construction and equipment capital costs and operating costs per ton processed at the facility. The resulting environmental and cost parameters are allocated to individual components of the waste stream by process specific allocation methodologies. All of this information is implemented into the decision support tool to provide a life-cycle management evaluation of integrated municipal solid waste management strategies.  相似文献   

2.
Life Cycle Assessment is becoming an important tool for guiding environmental design improvements in the automotive industry. This paper reports the life cycle inventory profiles for two fuel tank systems based on a collaborative effort between the National Pollution Prevention Center at the University of Michigan, General Motors Research and Development, and the National Risk Management Research Laboratory of the U.S. Environmental Protection Agency. Two 31 gallon functionally equivalent fuel tank systems used on a 1996 light duty vehicle were investigated: a multi-layer HDPE tank with a steel shield and PVC coated steel straps, and a steel tank with a HDPE shield and painted steel straps. Overall, the HDPE fuel tank system is environmentally preferable to the steel tank system based on the set of inventory results presented in this investigation. The Life Cycle Inventory analysis indicated lower energy burdens for the HDPE tank system and comparable solid waste burdens for both systems. The total life cycle energy consumption for the steel and HDPE tank systems were 4.9 GJ and 3.6 GJ per tank, respectively. The energy consumption and most of the air pollutants inventoried occurred as a consequence of the use phase. The solid wastes were generated primatily during the material production phase for the steel tank (13 kg) and during the end-of-life management phase for the HDPE tank (14 kg). This study also highlights data analysis and modeling challenges, including manufacturing and use phase allocation methods.  相似文献   

3.
Beverage producers in the United States choose packaging based on cost and consumer preference. Monolayer high‐density polyethylene (HDPE) and gable‐top carton containers have long dominated the U.S. fluid milk market, but pressure for more sustainable packaging is increasing. We present a broad discussion on environmental sustainability of 18 fluid milk containers through life cycle assessment. Because different container types require unique milk processing, distribution, and disposal and incur or avoid milk losses, fluid milk delivery systems (FMDSs) are evaluated, rather than containers in isolation. By assessing FMDSs, a complete measure of containers’ environmental sustainability was obtained. Despite conservative assumptions about milk losses, differences in container size, milk processing, distribution, and container recycling, pair‐wise cradle‐to‐grave comparisons of FMDSs show there are no superior FMDSs. But, 500‐ to 1,000‐milliliter FMDSs are potentially superior to ≥half gallon if they prevent milk losses. Thus, the future of FMDSs in the United States depends on the industry's ability to prevent distribution (12%) and consumption milk losses (20% to 35%). Farm‐gate‐to‐grave comparisons showed that chilled HDPE FMDSs are superior to other plastic and chilled paperboard FMDSs for climate‐change impact, but the result is inconclusive for chilled HDPE to ambient (unrefrigerated) paperboard or plastic pouch FMDS comparisons. Plastic pouch FMDSs show potential to reduce nonrenewable fossil energy, but need to be recyclable. Ambient FMDSs are superior to chilled FMDSs for water depletion. Eight‐ounce paperboard FMDSs are superior to 8‐ounce plastic FMDSs. Thus, alternative FMDSs may improve environmental sustainability of the U.S. postfarm fluid milk supply chain.  相似文献   

4.
The life-cycle energy, greenhouse gas emissions, and costs of a contemporary 2,450 sq ft (228 m3) U.S. residential home (the standard home, or SH) were evaluated to study opportunities for conserving energy throughout pre-use (materials production and construction), use (including maintenance and improvement), and demolition phases. Home construction and maintenance materials and appliances were inventoried totaling 306 metric tons. The use phase accounted for 91% of the total life-cycle energy consumption over a 50-year home life. A functionally equivalent energy-efficient house (EEH) was modeled that incorporated 11 energy efficiency strategies. These strategies led to a dramatic reduction in the EEH total life-cycle energy; 6,400 GJ for the EEH compared to 16,000 GJ for the SH. For energy-efficient homes, embodied energy of materials is important; pre-use energy accounted for 26% of life-cycle energy. The discounted (4%) life-cycle cost, consisting of mortgage, energy, maintenance, and improvement payments varied between 426,700 and 454,300 for a SH using four energy price forecast scenarios. In the case of the EEH, energy cost savings were offset by higher mortgage costs, resulting in total life-cycle cost between 434,100 and 443,200. Life-cycle greenhouse gas emissions were 1,010 metric tons CO2 equivalent for an SH and 370 metric tons for an EEH.  相似文献   

5.
Product Environmental Life-Cycle Assessment Using Input-Output Techniques   总被引:1,自引:0,他引:1  
Life-cycle assessment (LCA) facilitates a systems view in environmental evaluation of products, materials, and processes. Life-cycle assessment attempts to quantify environmental burdens over the entire life-cycle of a product from raw material extraction, manufacturing, and use to ultimate disposal. However, current methods for LCA suffer from problems of subjective boundary definition, inflexibility, high cost, data confidentiality, and aggregation.
This paper proposes alternative models to conduct quick, cost effective, and yet comprehensive life-cycle assessments. The core of the analytical model consists of the 498 sector economic input-output tables for the U.S. economy augmented with various sector-level environmental impact vectors. The environmental impacts covered include global warming, acidification, energy use, non-renewable ores consumption, eutrophication, conventional pollutant emissions and toxic releases to the environment. Alternative models are proposed for environmental assessment of individual products, processes, and life-cycle stages by selective disaggregation of aggregate input-output data or by creation of hypothetical new commodity sectors. To demonstrate the method, a case study comparing the life-cycle environmental performance of steel and plastic automobile fuel tank systems is presented.  相似文献   

6.
Integrated Environmental and Economic Assessment of Products and Processes   总被引:1,自引:0,他引:1  
The eco-efficiency analysis method developed and used by the Öko-Institut analyzes different alternatives that fulfill a defined consumer need, from an environmental as well as an economic perspective.
Like life-cycle assessment (LCA), eco-efficiency analysis makes possible the setting of priorities in purchasing decisions or can be used to show optimization potentials in product development processes.
Eco-efficiency analysis builds upon two methods: LCA, according to ISO 14040 ff. (to assess the environmental aspects of products and processes), and life-cycle costing. Life-cycle costing results in a single figure—the total costs of ownership to one or several actors. The environmental impacts can be evaluated and aggregated as a single score or the impact category indicator results can be kept separate. In either case two single scores can be compared: the total environmental burden or the impact category indicator results, and the total costs of ownership of the alternatives under consideration.
The results can then be plotted in two-dimensional graphs that show the effectiveness of certain measures in environmental and economic terms. The efficiency is expressed as a numerical ratio of environmental savings to difference in costs.
Together with furnishing more detailed results and a discussion of additional benefits or potential barriers, eco-efficiency analysis broadens the basis for decision-making processes.  相似文献   

7.

Purpose

Pharmaceutical and biological materials require thermally controlled environments when being transported between manufacturers, clinics, and hospitals. It is the purpose of this report to compare the life cycle impacts of two distinct logistical approaches to packaging commonly used in cold chain logistics and to identify the method of least environmental burden. The approaches of interest are single-use packaging utilizing containers insulated with either polyurethane or polystyrene and reusable packaging utilizing containers with vacuum-insulated panels.

Methods

This study has taken a cradle-to-grave perspective, which covers material extraction, manufacture, assembly, usage, transportation, and end-of-life realities. The functional unit of comparison is a 2-year clinical trial consisting of 30,000 individual package shipments able to maintain roughly 12 L of payload at a controlled 2–8 °C temperature range for approximately 96 h. Published life-cycle inventory data were used for process and material emissions. A population-centered averaging method was used to estimate transportation distances to and from clinical sites during container use. Environmental impacts of the study include global warming potential, eutrophication potential, acidification potential, photochemical oxidation potential, human toxicity potential, and postconsumer waste.

Results and discussion

The average single-use approach emits 1,122 tonnes of CO2e compared with 241 tonnes with the reusable approach over the functional unit. This is roughly a 75 % difference in global warming potential between the two approaches. Similar differences exist in other impact categories with the reusable approach showing 60 % less acidification potential, 65 % less eutrophication potential, 85 % less photochemical ozone potential, 85 % less human toxicity potential, and 95 % less postconsumer waste. The cradle-to-gate emissions of the single-use container were the overwhelming cause of its high environmental burden as 30,000 units were required to satisfy the functional unit rather than 772 for the reusable approach. The reusable container was about half the mass of the average single-use container, which lowered its transportation emissions below the single-use approach despite an extra leg of travel.

Conclusions

The reusable logistical approach has shown to impose a significantly smaller environmental burden in all impact categories of interest. A sensitivity analysis has shown some leeway in the degree of the environmental advantage of the reusable approach, but it confirms the conclusion as no case proved otherwise.  相似文献   

8.
An Internet-based environmentally conscious decision support tool (EcoDS) has been developed for life-cycle management EcoDS involves an initial vertical streamlining step, where the significant life-cycle stages, stressors, and impact categories are selected and cross-correlated. Because the streamlining is performed prior to the inventory, the approach expedites data collection. Comparisons among alternative product designs or manufacturing processes are based on two metrics: financial risk (or cost) and "residual" risk. For purposes of evaluation these two indicators are individually aggregated using a user or organization-specified value system. A salient feature of EcoDS is that this output can be condensed into a single summary matrix akin to a hybrid pro forma income statement and environmental balance sheet. The clear delineation between the tradeoffs involved in each alternative facilitates decision making by upper management. A case study on painting attematives is presented to illustrate the methodology  相似文献   

9.
The environmental impact of the management of biodegradable waste in Stockholm, based mainly on incineration and landfilling, was compared to systems with significant nutrient recycling; large-scale composting, anaerobic digestion, and separate collection and utilization of urine. The systems' emissions, residual products, energy turnover, and resource consumption were evaluated from a life-cycle perspective, using a computerized model, ORWARE (ORganic WAste REsearch model).
Transportation was of relatively low importance to overall environmental impact, even at high rates of nutrient recycling. This is remarkable considering the geographical setting of Stockholm, with high population density and little nearby farmland. Ancillary systems, such as generation of electricity and district heating, were crucial for the overall outcome.
Increased recycling of nutrients in solid biodegradable waste in Stockholm can reduce net environmental impact, whereas separation of human urine to be spread as fertilizer cannot yet be introduced without increased acidification. Increased nutrient recycling from solid biodegradable waste inevitably increases spreading of metals on arable land. Urine is by far the least contaminated residual product. Spreading of all other residuals would be limited by their metal content.  相似文献   

10.
Parametric life-cycle assessment (LCA) models have been integrated with traditional design tools and used to demonstrate the rapid elucidation of holistic, analytical trade-offs among detailed design variations. A different approach is needed, however, if analytical environmental assessment is to be incorporated in very early design stages. During early stages, there may be competing product concepts with dramatic differences. Detailed information is scarce, and decisions must be made quickly.
This article explores an approximate method for providing preliminary LCAs. In this method, learning algorithms trained using the known characteristics of existing products might allow environmental aspects of new product concepts to be approximated quickly during conceptual design without defining new models. Artificial neural networks are trained to generalize on product attributes, which are characteristics of product concepts, and environmental inventory data from pre-existing LCAs. The product design team then queries the trained artificial model with new high-level attributes to quickly obtain an impact assessment for a new product concept. Foundations for the learning system approach are established, and then an application within the distributed object-based modeling environment (DOME) is provided. Tests have shown that it is possible to predict life-cycle energy consumption, and that the method could be used to predict solid waste, greenhouse effect, ozone depletion, acidification, eutrophication, winter and summer smog.  相似文献   

11.
Remanufacturing restores used automotive engines to like-new condition, providing engines that are functionally equivalent to a new engine at much lower environmental and economic costs than the manufacture of a new engine. A life-cycle assessment (LCA) model was developed to investigate the energy savings and pollution prevention that are achieved in the United States through remanufacturing a midsized automotive gasoline engine compared to an original equipment manufacturer manufacturing a new one. A typical full-service machine shop, which is representative of 55% of the engine remanufacturers in the United States, was inventoried, and three scenarios for part replacement were analyzed. The life-cycle model showed that the remanufactured engine could be produced with 68% to 83% less energy and 73% to 87% fewer carbon dioxide emissions. The life-cycle model showed significant savings for other air emissions as well, with 48% to 88% carbon monoxide (CO) reductions, 72% to 85% nitrogen oxide (NOx) reductions, 71% to 84% sulfur oxide (SOx) reductions, and 50% to 61% nonmethane hydrocarbon reductions. Raw material consumption was reduced by 26% to 90%, and solid waste generation was reduced by 65% to 88%. The comparison of environmental burdens is accompanied by an economic survey of suppliers of new and remanufactured automotive engines showing a price difference for the consumer of between 30% and 53% for the remanufactured engine, with the greatest savings realized when the remanufactured engine is purchased directly from the remanufacturer.  相似文献   

12.
A Decision Support Framework for Sustainable Waste Management   总被引:1,自引:0,他引:1  
This article describes a decision support framework for the evaluation of scenarios for the integrated management of municipal solid waste within a local government area (LGA).
The work is initially focused on local government (i.e., municipal councils) in the state of Queensland, Australia; however, it is broadly applicable to LGAs anywhere. The goal is to achieve sustainable waste management practices by balancing global and regional environmental impacts, social impacts at the local community level, and economic impacts. The framework integrates life-cycle assessment (LCA) with other environmental, social, and economic tools. For this study, social and economic impacts are assumed to be similar across developed countries of the world. LCA was streamlined at both the life-cycle inventory and life-cycle impact assessment stages.
For this process, spatial resolution is introduced into the LCA process to account for impacts occurring at the local and regional levels. This has been done by considering social impacts on the local community and by use of a regional procedure for LCA data for emissions to the environment that may have impacts at the regional level.
The integration follows the structured approach of the pressure-state-response (PSR) model suggested by the Organisation for Economic Cooperation and Development (OECD). This PSR model has been extended to encompass nonenvironmental issues and to guide the process of applying multiple tools.
The framework primarily focuses on decision analysis and interpretation processes. Multiattribute utility theory (MAUT) is used to assist with the integration of qualitative and quantitative information. MAUT provides a well-structured approach to information assessment and facilitates objective, transparent decisions. A commercially available decision analysis software package based on MAUT has been used as the platform for the framework developed in this study.  相似文献   

13.

Background, aim, and scope  

Life-cycle thinking and life-cycle approaches are concepts that are getting increased attention worldwide and in particular in EU Policies related to sustainability. The European Commission is launching a number of activities to strengthen life-cycle thinking in policy and business. EU policies aim to decrease waste generation through new waste prevention initiatives, better use of resources and shift to more sustainable consumption patterns. The approach to waste management is based on three principles: waste prevention, recycling and reuse and improving the final disposal and monitoring. In particular, concerning the prevention and recycling of waste, the definition of a waste hierarchy should be the basis for the prioritisation of waste management options. The benefit of using Life Cycle Assessment (LCA) in analysing waste management systems is the provision of a comprehensive view of the processes and impacts involved. However, it is also clear that the studies will always be open for criticism as they are simplifications of reality. Moreover, in order to become the LCA, a leading tool within businesses and government to understand and manage risks or opportunities related to waste management and treatment technologies, there are methodological choices required and a number of aspects that still need to be worked out. It is therefore important to review open and grey literatures, EU guidelines, relevant environmental indicators and databases for the waste sector and data easily usable in waste policy decision-making, with an agreed approach and methodology based on life-cycle thinking. The following survey gathers and describes the existing guidelines and methodologies based on life-cycle thinking and applicable in waste policy decision-making.  相似文献   

14.
Life-cycle assessment (LCA) is a technique for systematically analyzing a product from cradle-to-grave, that is, from resource extraction through manufacture and use to disposal. LCA is a mixed or hybrid analytical system. An inventory phase analyzes system inputs of energy and materials along with outputs of emissions and wastes throughout life cycle, usually as quantitative mass loadings. An impact assessment phase then examines these loadings in light of potential environmental issues using a mixed spectrum of qualitative and quantitative methods. The constraints imposed by inventory's loss of spatial, temporal, dose-response, and threshold information raise concerns about the accuracy of impact assessment. The degree of constraint varies widely according to the environmental issue in question and models used to extrapolate the inventory data. LCA results may have limited value in two areas: (I) local and/ortransient biophysical processes and (2) issues involving biological parameters, such as biodiversity, habitat alteration, and toxicity. The end result is that impact assessment does not measure actual effects or impacts, nor does it calculate the likelihood of an effect or risk Rather, LCA impact assessment results are largely directional environmental indicaton. The accuracy and usefulness of indicators need to be assessed individually and in a circumstance-specific manner prior to decision making. This limits LCAs usefulness as the sole basis for comprehensive assessments and the comparisons of alternatives. In conclusion, LCA may identify potential issues from a systemwide perspective, but more-focused assessments using other analytical techniques are often necessary to resolve the issues.  相似文献   

15.
Background This article describes two projects conducted recently by Sound Resource Management (SRMG) – one for the San Luis Obispo County Integrated Waste Management Authority (SLO IWMA) and the other for the Washington State Department of Ecology (WA Ecology). For both projects we used life cycle assessment (LCA) techniques to evaluate the environmental burdens associated with collection and management of municipal solid waste. Both projects compared environmental burdens from curbside collection for recycling, processing, and market shipment of recyclable materials picked up from households and/or businesses against environmental burdens from curbside collection and disposal of mixed solid waste. Method logy. The SLO IWMA project compared curbside recycling for households and businesses against curbside collection of mixed refuse for deposition in a landfill where landfill gas is collected and used for energy generation. The WA Ecology project compared residential curbside recycling in three regions of Washington State against the collection and deposition of those same materials in landfills where landfill gas is collected and flared. In the fourth Washington region (the urban east encompassing Spokane) the WA Ecology project compared curbside recycling against collection and deposition in a wasteto- energy (WTE) combustion facility used to generate electricity for sale on the regional energy grid. During the time period covered by the SLO study, households and businesses used either one or two containers, depending on the collection company, to separate and set out materials for recycling in San Luis Obispo County. During the time of the WA study households used either two or three containers for the residential curbside recycling programs surveyed for that study. Typically participants in collection programs requiring separation of materials into more than one container used one of the containers to separate at least glass bottles and jars from other recyclable materials. For the WA Ecology project SRMG used life cycle inventory (LCI) techniques to estimate atmospheric emissions of ten pollutants, waterborne emissions of seventeen pollutants, and emissions of industrial solid waste, as well as total energy consumption, associated with curbside recycling and disposal methods for managing municipal solid waste. Emissions estimates came from the Decision Support Tool (DST) developed for assessing the cost and environmental burdens of integrated solid waste management strategies by North Carolina State University (NCSU) in conjunction with Research Triangle Institute (RTI) and the US Environmental Protection Agency (US EPA)1. RTI used the DST to estimate environmental emissions during the life cycle of products. RTI provided those estimates to SRMG for analysis in the WA Ecology project2. For the SLO IWMA project SRMG also used LCI techniques and data from the Municipal Solid Waste Life- Cycle Database (Database), prepared by RTI with the support of US EPA during DST model development, to estimate environmental emissions from solid waste management practices3. Once we developed the LCI data for each project, SRMG then prepared a life cycle environmental impacts assessment of the environmental burdens associated with these emissions using the Environmental Problems approach discussed in the methodology section of this article. Finally, for the WA study we also developed estimates of the economic costs of certain environmental impacts in order to assess whether recycling was cost effective from a societal point of view. Conclusions Recycling of newspaper, cardboard, mixed paper, glass bottles and jars, aluminum cans, tin-plated steel cans, plastic bottles, and other conventionally recoverable materials found in household and business municipal solid wastes consumes less energy and imposes lower environmental burdens than disposal of solid waste materials via landfilling or incineration, even after accounting for energy that may be recovered from waste materials at either type disposal facility. This result holds for a variety of environmental impacts, including global warming, acidification, eutrophication, disability adjusted life year (DALY) losses from emission of criteria air pollutants, human toxicity and ecological toxicity. The basic reason for this conclusion is that energy conservation and pollution prevention engendered by using recycled rather than virgin materials as feedstocks for manufacturing new products tends to be an order of magnitude greater than the additional energy and environmental burdens imposed by curbside collection trucks, recycled material processing facilities, and transportation of processed recyclables to end-use markets. Furthermore, the energy grid offsets and associated reductions in environmental burdens yielded by generation of energy from landfill gas or from waste combustion are substantially smaller then the upstream energy and pollution offsets attained by manufacturing products with processed recyclables, even after accounting for energy usage and pollutant emissions during collection, processing and transportation to end-use markets for recycled materials. The analysis that leads to this conclusion included a direct comparison of the collection for recycling versus collection for disposal of the same quantity and composition of materials handled through existing curbside recycling programs in Washington State. This comparison provides a better approximation to marginal energy usage and environmental burdens of recycling versus disposal for recyclable materials in solid waste than does a comparison of the energy and environmental impacts of recycling versus management methods for handling typical mixed refuse, where that refuse includes organics and non-recyclables in addition to whatever recyclable materials may remain in the garbage. Finally, the analysis also suggests that, under reasonable assumptions regarding the economic cost of impacts from pollutant emissions, the societal benefits of recycling outweigh its costs.  相似文献   

16.
The concept of eco-efficiency is increasingly being applied to judge the combined environmental and economic performance of product systems, processes, and/or companies. Ecoefficiency is often defined as the ratio of economic value added to environmental impact added. This definition is not appropriate for end-of-pipe treatment technologies because these technologies aim at improving the environmental performance of technical processes at the cost of financial expense. Therefore, an indicator for the assessment of end-of-pipe technologies has been proposed. This indicator, called environmental cost efficiency (ECE), is defined as the ratio of net environmental benefits to the difference in costs. ECE is applied to four end-of-pipe technologies for the treatment of municipal solid waste: sanitary landfill, mechanical-biological treatment, modern grate incineration, and a staged thermal process (pyrolysis and gasification). A life-cycle assessment was performed on these processes to quantify the net environmental benefit. Moreover, the approximate net costs (costs minus benefits) were quantified. The results show that, relative to grate incineration, sanitary landfills and mechanical-biological treatment are less costly but environmentally more harmful. We calculated the ECE for all combinations of technologies. The results indicate that the staged thermal process may be the most environmentally cost-efficient alternative to all other treatment technologies in the long run, followed by mechanical-biological treatment and grate incineration.  相似文献   

17.
Environmental policy is oriented toward integrated pollution prevention, taking into consideration all environmental media (air, water, land) and energy consumption. Therefore, methods for assessing environmentally relevant installations are needed which take economic, technical, and especially ecological criteria into account simultaneously. Mass and energy flow models are used for the representation of production processes and form the basis for the inventory phase in life-cycle assessment (LCA). For the interpretation of LCA results and the weighting of the aggregated impact assessment indicators, approaches of multicriterion analysis (MCA) have been proposed. These can analyze ecological aspects as well as economic and technical criteria. Recent developments in LCA focus on decision support for policy makers or decision boards. Appropriate support for investment decisions on environmentally relevant installations, however, is rare.
Based on a case study of the sector called surface coating, an MCA of environmentally relevant installations is described. With the help of a mass and energy flow management system, alternative scenarios, depicting the use of solvent-reduced materials and environmentally friendly techniques, are modeled for the job coater processes in case studies of coating of mobile phones and coating of polyvinyl chloride (PVC) parts destined for the automobile industry. The modeled scenarios are further analyzed by using a multicriterion decision support module. The application of the outranking approach PROMETHEE is illustrated. A further investigation of the derived ranking can be obtained through sensitivity analyses. Moreover, the results derived by PROMETHEE are compared with the outcomes of the multicriterion approaches multiattribute utility theory and analytical hierarchy process.  相似文献   

18.
This article presents a generic method to assist product and process designers in measuring resource use and environmental discharges based on the relationships between process flow inputs and outputs and their activity levels. It combines activity-based costing from conventional accounting with life-cycle inventories. The method is demonstrated on four electronic assembly product and process designs. The demonstration exhibits the disaggregation and allocation of costs and effluents from various manufacturing operations. This activity-based environmental allocation approach may be integrated with inventory analysis-the first step in full and streamlined life-cycle assessments, design for environment evaluation methods, environmental management activities, and new production planning models that consider environmental impacts.  相似文献   

19.
Abstract: Obtaining reliable results from life-cycle assessment studies is often quite difficult because life-cycle inventory (LCI) data are usually erroneous, incomplete, and even physically meaningless. The real data must satisfy the laws of thermodynamics, so the quality of LCI data may be enhanced by adjusting them to satisfy these laws. This is not a new idea, but a formal thermodynamically sound and statistically rigorous approach for accomplishing this task is not yet available. This article proposes such an approach based on methods for data rectification developed in process systems engineering. This approach exploits redundancy in the available data and models and solves a constrained optimization problem to remove random errors and estimate some missing values. The quality of the results and presence of gross errors are determined by statistical tests on the constraints and measurements. The accuracy of the rectified data is strongly dependent on the accuracy and completeness of the available models, which should capture information such as the life-cycle network, stream compositions, and reactions. Such models are often not provided in LCI databases, so the proposed approach tackles many new challenges that are not encountered in process data rectification. An iterative approach is developed that relies on increasingly detailed information about the life-cycle processes from the user. A comprehensive application of the method to the chlor-alkali inventory being compiled by the National Renewable Energy Laboratory demonstrates the benefits and challenges of this approach.  相似文献   

20.

Purpose

Disposable beverage bottles made of polyethylene terephthalate (PET) stand in sharp contrast to many other disposable plastic packaging systems in the US for their high level of post-consumer recovery for recycling. This is due in part to container deposit programs in several US states, such as the California Redemption Value (CRV) program. We investigate the impacts of PET bottle recycling in the CRV program to evaluate its effectiveness at reducing environmental burdens.

Methods

We develop a life cycle model using standard process LCA techniques. We use the US LCI database to describe the energy production infrastructure and the production of primary materials. We describe the inventory and logistical requirements for materials recovery on the basis of state-maintained statistics and interviews with operators and industry representatives. We report inventory indicators describing energy, freight, and waste disposal requirements. We report several impact indicators based on CML and TRACI-2.0 techniques. We apply system expansion to compare post-consumer activities to produce secondary polymer against equivalent primary production.

Results and discussion

While bottle collection is distributed across the state, processing is more centralized and occurs primarily near urban centers. The average distance traveled by a bottle from discard to recovery is 145–175 km. Recycling requires 0.45–0.66 MJ of primary energy/L of beverage, versus 3.96 MJ during the pre-consumer phase. Post-consumer environmental impacts are significantly lower than pre-consumer impacts, with the exception of eutrophication. The results are robust to model sensitivity, with allocation of fuel for bottle collection being the most significant parameter. Curbside collection is slightly more energy efficient than consumer drop-off, and is subject to smaller parametric uncertainty. Recycling has the potential for net environmental benefits in five of seven impact categories, the exceptions being smog (marginal benefits) and eutrophication (increased impacts).

Conclusions

California’s decentralized program for collecting and processing PET bottles has produced a system which generates a large stream of post-consumer material with minimal environmental impact. The selection of a reclamation locale is the most significant factor influencing post-consumer impacts. If secondary PET displaces primary material, several environmental burdens can be reduced.

Recommendations and perspectives

Our results suggest that deposit programs on disposable packaging are an effective policy mechanism to increase material recovery and reduce environmental burdens. Deposit programs for other packaging systems should be considered.  相似文献   

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