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1.
The concentrations of arsenic (As), cadmium (Cd), mercury (Hg), and lead (Pb) were determined in samples of food items widely consumed by the population of Catalonia, Spain. All samples were randomly acquired in 12 cities of Catalonia between March and June of 2006 and analyzed by inductively coupled plasma mass spectrometry. The dietary intake of these elements was estimated for various age–gender groups of population: children, adolescents, adults, and seniors. In order to determine the temporal trend on the dietary exposure to As, Cd, Hg, and Pb, the current results were compared with those of a previous survey (2000). In the present market basket study, for a standard male adult of 70-kg body weight living in Catalonia, the dietary intakes of As, Cd, Hg, and Pb were 261.01, 9.80, 12.61, and 45.13 μg/day, respectively, while in the 2000 survey, these intakes were 223.59, 15.73, 21.22, and 28.37 μg/day, for As, Cd, Hg, and Pb, respectively. For As, the only food groups currently contributing with measurable amounts to intake of total As were fish and shellfish and cereals, while for Cd the highest contribution to total intake corresponded to pulses, tubers, and cereals. For Hg, the contribution was only due to fish and shellfish, while cereals were the group with the highest contribution to total Pb intake. The estimated intakes of As, Cd, Hg, and Pb are notably lower than the respective provisional tolerable weekly intakes, which indicate that these intakes should not mean additional health risks for the consumers.  相似文献   

2.
The concentrations of As, Be, Cd, Cr, Hg, Mn, Ni, Pb, Sn, Tl, and V were determined in hair of 96 school children and in blood of 144 adults living in the vicinity of a hazardous waste incinerator (HWI) (Constantí, Tarragona County, Catalonia, NE Spain). The results were compared with those obtained in previous (1998 and 2002) surveys performed in the same area. Data were analyzed in terms of age, sex, and specific place of residence. Current mean concentrations in hair ranged between not detected (ND) (As, Be, and Tl) and 1.31 μg/g for Cr. In blood, Be, Hg, Mn, Sn, and Tl levels were under the respective detection limits. The mean blood concentrations of the remaining elements ranged from 0.34 μg/dL for Cd, to 2.40 μg/dL for Pb. Significant differences in hair and blood in relation to gender were only noted for Pb in blood. In general terms, metal concentrations in hair and blood from subjects living in Tarragona County are lower than most levels reported for other countries in recent years.  相似文献   

3.
The concentrations of arsenic (As), beryllium (Be), cadmium (cd), chromium (Cr), mercury (Hg), manganese (Mn), nickel (Ni), lead (Pb), tin (Sn), thallium (Tl), and vanadium (V) were determined in a number of food items purchased in zones of Tarragona, County (Catalonia, Spain) near a hazardous waste incinerator (HWI), which has been operating since 1999. Food samples corresponded to the following groups: meat, fish and seafood, pulses, cereals, vegetables, fruits, tubers, whole milk, yogurt, eggs, and sugar. Be and Tl were under their respective limits of detection in all samples. For the analyzed trace elements, the dietary intake by the general population of Tarragona was 458.5 μg/d for As, 14.3 μg/d for Cd, 88.3 μg/d for Cr, 5.3 μg/d for Hg, 2421.4 μg/d for Mn, 138.3 μg/d for Ni, 44.8 μg/d for Pb, 34.6 μg/d for Sn, and 28.9 μg/d for V. Results were compared with those found in a baseline survey carried out in the same area during the construction of the HWI (1996–1998). In general terms, the dietary intake of metals in 2003 was comparatively similar to those found in the baseline survey. For the most toxic elements (As, Cd, Hg, and Pb), it was under their respective Provisional Tolerable Weekly Intake (PTWI) estabished by the FAO/WHO.  相似文献   

4.
We conducted an investigation of heavy metal concentrations in Manila clams (Ruditapes philippinarum) and surface sediments after the Dalian Port oil spill. Samples were collected from three mariculture zones (Jinshitan, Dalijia, and Pikou) along the Dalian coast. Heavy metal concentrations in R. philippinarum were consistent and ranked in decreasing order of Zn > Cu > As > Cr > Pb > Cd > Hg, while concentrations in surface sediments were ranked as Zn > Cr > Cu > Pb > As > Cd > Hg, respectively. Bioaccumulation of Zn, Cd, and Hg had obviously occurred in R. philippinarum. Statistically significant correlations (p?<?0.05) between concentrations of Pb, Cd, and Hg in R. philippinarum and in surface sediments were observed. Except for Cr and As, heavy metal concentrations in R. philippinarum were well within the legal limits for human consumption.  相似文献   

5.
The effects of dissolved Pb, Cd and Hg on growth and survivalof adult Biomphalaria glabrata Say. uninfected and infectedwith Schistosoma mansoni Sambon, were examined. Pb at concentrationsfrom 0.25–100 µM, Cd from 0.075–0.25 µMand Hg from 0.25–1 µM significantly reduced growthand survival of normal snails. With each metal the effects increasedwith increasing concentration. The LC 25 at 2 wks exposure was82 ± 19, 0.22 ± 0.04 and 0.94 ± 0.13 µM(x ± S.E.) for Pb, Cd and Hg, respectively. Snails exposedto heavy metals continued to be reproductively active, but theegg production was highly variable and no significant effectof heavy metal exposure was demonstrated. Infection also decreasedsurvival and growth of snail hosts and infected individualsexposed to heavy metals displayed the greatest mortality. TheLC 25 for infected snails at 2 wks exposure was 8 ± 3,0.9 ± 0.02 and 0.29 ± 0.08 for Pb, Cd and Hg respectively.A significant interaction between heavy metal exposure and infectionwas apparent. Infected snails were not reproductively active.Cercarial shedding by infected snails was significantly reducedin the presence of heavy metals and by 6 wks shedding had ceasedat the highest metal concentrations. (Received 20 May 1996; accepted 31 July 1996)  相似文献   

6.
Arctic environments are commonly considered to be relatively pristine because of minimal local human activity. However, these areas receive air pollution from lower latitude regions. Our goal was to determine concentrations of metals (Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, and Zn) in dominant species of vascular plants, mosses, lichens, algae, and in the biological soil crust (BSC), and topsoil (0–3 cm) from various types of tundra in the southwestern part of Spitsbergen, Norway. Results indicate that mosses are more efficient bioaccumulators of Cd, Co, Cr, Cu, Fe, Mn, and Zn than lichens. The highest levels of Co, Cr, Cu, Fe, Hg, Mn, Ni, and Pb were found in the BSC, and the moss species Racomitrium lanuginosum, Sanionia uncinata, and Straminergon stramineum from the polygonal tundra, initial cyanobacteria-moss wet tundra, snow bed cyanobacteria-moss tundra, and flow water moss tundra alimented by melting ice or snow. The observed higher concentrations of Cu and lower concentrations of Hg in mosses, lichens, and vascular plants compared with values observed 20 years earlier were apparently associated with changes in the atmospheric deposition of contaminants over Spitsbergen due to changes in the long-distance transport of anthropogenic emissions from industrialized areas. Prasiola crispa and Salix polaris may be useful bioindicators of Cd and Zn, and the BSC, R. lanuginosum, S. uncinata, and S. stramineum as bioindicators of Co, Cr, Cu, Fe, Hg, Mn, Ni, and Pb. These results may be extrapolated across other areas of Spitsbergen with similar climates.  相似文献   

7.
The main purpose of this study was to establish the temporal trend in the daily dietary intake of arsenic (As), cadmium (Cd), mercury (Hg), and lead (Pb) by the population of Catalonia, Spain. Concentrations of these elements were determined in samples of a number of food items widely consumed in that country. The dietary intake of As, Cd, Hg, and Pb was then estimated for various age–gender groups of population: children, adolescents, adults, and seniors. In the present study, the dietary intakes of As, inorganic As, Cd, Hg, methylmercury, and Pb were 328.37, 16.22, 19.47, 11.39, 10.25, and 101.47 μg/day, respectively, while in a previous (2006) survey, the dietary intakes of As, inorganic As, Cd, Hg, methylmercury, and Pb were 261.01, 33.17, 9.80, 12.61, 11.35, and 45.13 μg/day, respectively. The estimated intakes of Cd, Hg, and Pb are still notably lower than the respective PTWIs, while that of inorganic As is also lower than its BMDL01. In summary, the results of this study indicate that, currently, the dietary intakes of As, Cd, Hg, and Pb should not mean additional health risks for the consumers.  相似文献   

8.
Postpartum scalp hair samples from 82 term-pregnancy mother/neonate pairs were analyzed for their concentration of zinc (Zn), copper (Cu), cadmium (Cd), and lead (Pb), using inductively coupled plasma-mass spectrometry. Maternal and neonatal Zn concentrations had geometric means (and 99% confidence intervals) of 122.5 μg/g (117.9–131.5 μg/g) and 146.9 μg (141.5–156.7 μg/g) respectively. Corresponding Cu values were 18.4 μg/g (17.6–23.8 μg/g) and 6.7 μg/g (6.3–7.6 μg/g). Those of Cd were 0.49 μg/g (0.47–0.69 μg/g) in the mothers and 0.57 μg/g (0.55–0.86 μg/g) in the neonates. For Pb, they were 7.95 μg/g (7.60–9.32 μg/g) and 4.56 μg/g (4.39–5.56 μg/g). Cigaret smoking, despite its relatively low prevalence (19.5%), was associated with lower Zn and higher Cd and Pb concentrations and in lower Zn/Cd and Zn/Pb molar concentration ratios. Smoking also altered interelemental relationships, particularly those of Zn with Cd and Pb and those between Cd and Pb. Smoking frequency appeared to show negative dose-response effects on maternal and neonatal Zn concentrations, Zn/Pb molar concentration ratios, and birth weight. Mothers with a history of oral contraceptive (OC) usage had significantly higher Cu concentrations and lower Zn/Cu molar concentration ratios than nonusers, with the highest Cu concentrations and lowest Zn/Cu values being associated with third-generation OCs. No similar effects were elicited in the respective neonatal Cu concentrations. Neither alcohol consumption nor prenatal supplementation with iron and/or folic acid had discernible effects on the maternal or neonatal elemental concentrations. The data from this study suggest that in a given population of term-pregnancy mothers and neonates, significant interindividual variations in hair trace element concentrations can occur, irrespective of commonality of general environment, and that lifestyle factors, including cigaret smoking and OC usage history, can be significant contributory factors to such variations. The data are discussed in relation to the effects of smoking-associated exposure to Cd and Pb exposure on Zn availability for placental transfer, as well as on the quantitative maternal Zn supply levels to the fetus resulting from the known tendency of smokers to have lower dietary intakes of Zn. The higher Cu concentrations in OC users are discussed in relation to altered Cu metabolism, characterized by increased synthesis of the Cu-binding protein, ceruloplasmin, as an acute-phase antioxidant response to altered lipid profile and increased lipid oxidation.  相似文献   

9.
The effect of Cd, Cu, Zn, Hg, and Pb solutions at various concentrations, on the restoration potential of the leaves ofPortulaca oleracea was tested. All the trace metals completely affected the shoot regeneration. The degree of their effect on root regeneration, however, varied. Early initiation of parental leaf decay was also observed. The order of their relative effect on the regeneration process was: Cd > Cu > Zn > Hg > Pb.  相似文献   

10.
The lelvels of seven heavy metals and their toxicity towardGanoderma lucidum under various cultivation conditions were assessed. The contents of Mn, Cu, Zn, Cd, Hg, Pb and U in the fruitbodies of cultivatedG. lucidum, and sawdust substrates were determined to be at trace levels for U, 0.01–0.1 μg/g for Cd and Hg, and 1–5 μg/g for Pb, 10–120 μg/g for Mn, Cu and Zn. The effects of heavy metals, on the growth of mycelia ofG. lucidium in pure cultures were examined over a wide range of concentrations (10–3,000 μg/ml), and their toxicities were found to decrease in the order: Hg>Cd>Cu>U>Pb>Mn=Zn. The translocation and accumulation of Zn from contaminated substrates (at 10 μg/g) in fruitbodies were investigated by using65Zn tracer, andG. lucidum was found to take up Zn with an efficiency of >60%, leading to accumulation of >100 μ/g, in fruitbodies and >80 μ/g Zn in basidiospores.  相似文献   

11.
This study is a part of a monitoring program for the determination of metals in various human tissues of the population living in the vicinity of a new hazardous waste incinerator (HWI) in Constantí (Tarragona County, Spain). Concentrations of arsenic (As), beryllium (Be), cadmium (Cd), chromium (Cr), mercury (Hg), manganese (Mn), nickel (Ni), lead (Pb), tin (Sn), thallium (Tl), and vanadium (V) were determined in brain, bone, kidney, liver, and lung autopsy samples collected in 2003 from 22 individuals who had been living for at least 10 yr in the area under evaluation. Results were compared with the metal levels obtained in a baseline study, which was performed during the construction of the HWI (1996–1998). In the present survey, As, Be, Tl, and V levels were not detected in any of the analyzed tissues, while Cr concentrations were very close to the limit of detection. The highest levels of Cd and Hg were found in kidney (17.46 μg/g and 0.23 μg/g, respectively), those of Mn in liver (1.07 μg/g), and those of Ni, Pb, and Sn in bone (1.16 μg/g, 2.11 μg/g, and 0.34 μg/g, respectively). In comparison to the results of the baseline study, a general reduction of most metal concentrations was observed in the current survey.  相似文献   

12.
通过对贵州木油厂汞矿区4种藓类植物(真藓、卵蒴真藓、羽枝青藓和圆枝粗枝藓)及其生长基质中的Cu、Zn、Ca、Mg、Cd、Pb、Hg、As 8种元素进行测定分析,以揭示藓类植物与生长基质中重金属元素及其污染程度的关系.结果表明:(1)贵州木油厂汞矿区藓类植物生长基质中Cu、Hg和As元素的平均含量分别是相应国标值的1.29倍、300倍和1.69倍,说明该矿区已受到Cu、Hg和As的污染,且Hg污染特别严重.(2)羽枝青藓的As、Zn、Cd和Pb含量均最高,圆枝粗枝藓的Cu、Ca、Mg和Hg含量均最高,对重金属具有较强的耐受性.(3)羽枝青藓和圆枝粗枝藓对Zn均强烈富集,其富集系数分别为6.14和3.364;羽枝青藓、卵蒴真藓和真藓对Pb均强烈富集,其富集系数分别为13.769、9.547和3.004;表明羽枝青藓对Zn和Pb的富集能力最强,可用于土壤Zn和Pb的污染治理.(4)4种藓类植物对Cu 的富集系数为0.915~1.184,卵蒴真藓和圆枝粗枝藓对Hg的富集系数分别为0.542和0.682,圆枝粗枝藓对As的富集系数为0.74,均为同一水平,表明4种藓类植物可指示其生长基质中Cu、Hg和As的含量.(5)元素间的相关分析显示,木油厂汞矿的Cd和As之间呈显著负相关(P<0.05),表明两元素间有拮抗作用.  相似文献   

13.
采集了贡嘎山海螺沟原始森林区的7种主要苔藓,分析了其重金属(Hg、Cr、Cd、Ni、Pb、Cu、Mn、Zn和Fe)含量,并选择两种分布较广的赤茎藓和多枝砂藓进行汞吸附试验.结果表明,贡嘎山海螺沟原始森林区7种苔藓的重金属含量均较低,除Cd含量与欧美地区背景值相当外,其他均低于欧美地区的背景含量,表明该地区大气未受重金属污染,大气环境质量良好. 两种苔藓对汞的吸附是一个主动快速的过程,2 h左右即达到吸附平衡,其吸附特征能很好地用Langmuir和Freundlich方程拟合,由Langmuir方程计算的两种苔藓对汞的最大吸附量分别为15.24和8.19 mg·g-1,表明它们具有较强的汞吸附能力,可用作大气汞污染的指示生物.  相似文献   

14.
第二松花江下游稻田土壤重金属含量特征及来源分析   总被引:2,自引:0,他引:2  
于2008年秋季,在长期引用第二松花江(二松)江水进行灌溉的前郭灌区,采集了具有不同灌溉历史的稻田耕层土壤样品65个,测定了土壤中7种重金属含量,分析重金属在表层土壤中的累积特征,探讨发生累积的重金属的输入途径和来源.结果表明:稻田土壤中Cu、Pb、Zn、Cd、Ni、As、Hg的含量分别为14.1~28.4、37.6~57.4、53.3~84.4、0.044~0.367、18.4~37.0、3.25~12.11、0.031~0.155 mg·kg-1.Pb、Hg、Cd表现出明显的累积趋势,其含量超过基线值的比例分别为100.0%、38.7%和66.1%,其余重金属元素未出现累积现象.随着灌溉历史的增长,稻田土壤中Pb含量呈逐渐降低趋势,Hg含量呈逐渐升高趋势.Cd含量与灌溉历史的关系不明显.稻田土壤中累积的Pb主要与过去使用含Pb汽油产生的废气沉降有关;Hg主要来源于曾受污染的二松江水,随引水灌溉输入;Cd主要来源于化肥、农药等农用化学品的施用.尽管本区稻田土壤中Pb、Hg、Cd出现明显累积现象,但其生态风险水平很低,不会对当地农业生产及粮食安全构成威胁.  相似文献   

15.
In this study, we evaluated concentrations of twelve essential and non-essential elements (As, Cd, Co, Cu, Pb, Mg, Mn, Hg, Mo, Se, Ag, and Zn) in tissues of ringed seals (Phoca hispida) and polar bears (Ursus maritimus) of arctic Alaska (USA). All samples were collected between 1995-97 in conjunction with subsistence harvests. The essential elements are reported to help develop reference ranges for health status determination and to help assess known or suspected interactions affecting toxicoses of cadmium (Cd) and mercury (Hg). In some tissues, Cd, Hg, and selenium (Se) were present at concentrations that have been associated with toxicoses in some domestic animals. Nevertheless, tissue levels of all elements were within ranges that have been reported previously in other pinnipeds and polar bears. Significant associations included: Cd with Zn or Cu; Cu with Zn or Ag; and Hg with Se, Zn, or Cu. This study found hepatic Hg:Se molar ratios to be lower than unity and different between the two species. Based upon significant differences in mean tissue elemental concentrations for polar bear versus ringed seal, we concluded that biomagnification factors (bear/seal) were significant for: Cu in liver and muscle; Pb in kidney; Se in kidney and muscle; Zn in liver and muscle; and Hg in liver. Possible explanations for observed elemental correlations (i.e., interactions) and ancillary mechanisms of Cd and Hg detoxification are discussed.  相似文献   

16.
The aim of this paper was to determine the level of five elements, two essential for life [zinc (Zn) and copper (Cu)] and three distinctly toxic [lead (Pb), cadmium (Cd), and mercury (Hg)], in four types of biological material in bones of the dog Canis lupus familiaris. The experiment was carried out on bones from the hip joints of dogs. The samples of cartilage, compact bone, spongy bone, and cartilage with adjacent compact bone came from 26 domestic dogs from northwestern Poland. Concentrations of Cu, Zn, Pb, and Cd were determined by ICP-AES (atomic absorption spectrophotometry) in inductively coupled argon plasma, using a Perkin-Elmer Optima 2000 DV. Determination of Hg concentration was performed by atomic absorption spectroscopy. In the examined bone material from the dog, the greatest concentrations (median) were observed for Zn and the lowest for Hg (98 mg Zn/kg and 0.0015 mg Hg/kg dw, respectively). In cartilage and spongy bone, metal concentrations could be arranged in the following descending order: Zn > Pb > Cu > Cd > Hg. In compact bone, the order was slightly different: Zn > Pb > Cd > Cu > Hg (from median 70 mg/kg dw to 0.002 mg/kg dw). The comparisons of metal concentrations between the examined bone materials showed distinct differences only in relation to Hg: between concentrations in spongy bone, compact bone, and in cartilage, being greater in cartilage than in compact bone, and lower again in spongy bone.  相似文献   

17.
三亚市果蔬地重金属空间分布及其污染评价   总被引:2,自引:0,他引:2  
通过野外调查采样,采用标准对比法和地累积指数法,评价了三亚市果蔬地表层土壤重金属的污染状况。结果表明:土壤中Hg、Cd、Cr、Pb和As5种重金属的积累不显著,其平均值均未超过国家环境质量二级标准(GB15618-1995);但Hg、Cd和Pb的平均值高于海南岛农用地的自然背景值,表明存在区域轻度污染;Cr、Hg、Pb和As4种重金属元素的变异系数均>1,表明土壤中Cr、Hg、Pb和As的分布极不均匀。同时,利用地理信息系统(GIS)Krging插值方法得到了5种重金属的空间分布图,显示出不同重金属元素的空间分异特征,为三亚市果蔬地的可持续开发利用提供指导。  相似文献   

18.
In the present work the extent and variation of Zn, Cd, Pb, Cu, and Hg loading in undisturbed surface soil (0–5 cm) and the vertical transport of the metals in soil profiles are studied in the vicinity of a zinc smelter in Norway. Three major controlling factors on the metal concentrations in soil have been assessed: 1) distance from the anthropogenic point source; 2) organic matter content (O.M.); and 3) the prevailing wind directions. Moreover metal distributions in proximal soil profiles in 1972 and 2003 are compared. Current concentrations of Zn, Cd, Pb, Cu, and Hg in surface soil reach 14000, 60, 980, 430, and 7.0 mg·kg ? 1 , respectively, near the smelter and decrease regularly with distance in the northerly direction according to the regression model (y = ax? b ). The Zn concentrations are significantly different from the background range up to 30 km from the smelter, whereas the other metals approach background at only 10 km distance. Subsurface concentration peaks of Pb, Cu, and Hg are found at greater depth in soil profiles than peaks of Zn and Cd. Levels of Zn, Cd, and Pb in surface soil seem to have decreased from 1972 to 2003, whereas for Cu the levels appear not to be significantly different.  相似文献   

19.
In this study, we evaluated concentrations of twelve essential and non-essential elements (As, Cd, Co, Cu, Pb, Mg, Mn, Hg, Mo, Se, Ag, and Zn) in tissues of bowhead (Balaena mysticetus) and beluga (Delphinapterus leucas) whales from arctic Alaska (USA) and northwestern Canada. Tissue samples were collected between 1983 and 1997, mostly in 1995-97. The essential elements are reported to develop reference ranges for health status determination, and to help assess known or suspected interactions affecting toxicoses of cadmium (Cd) and mercury (Hg). In some tissues, Cd, Hg, and selenium (Se) were present at concentrations that have been associated with toxicoses in some domestic animals. Nevertheless, tissue levels of all elements were within ranges that have been reported previously in marine mammals. While mean Ag concentrations in beluga whale liver were relatively high (15.91 micrograms/g ww), Ag was not associated with hepatic Se levels or age, contrary to previous findings. Significant associations included: Cd with age, Zn, or Cu; Cu with age, Zn or Ag; and Hg with age, Se, Zn, or Cu. This study found hepatic Hg:Se molar ratios to be consistently lower than unity and different between species. Possible explanations for observed elemental correlations (i.e., interactions) and ancillary mechanisms of Cd and Hg detoxification are discussed.  相似文献   

20.
Abstract

A total of 83 dust samples were collected from the streets of Urumqi city in NW China and analyzed for the concentrations of As, Cd, Cr, Cu, Hg, Mn, Ni, Pb, and Zn elements. The spatial distribution, contamination levels, main sources, and potential health risks of these trace elements were determined based on geostatistical analysis, geo-accumulation index, multivariate analysis, and the health risk assessment model introduced by the USEPA, respectively. The obtained results indicate that the average concentrations of Cd, Cr, Cu, Hg, Ni, Pb, and Zn exceed the corresponding background values determined in Xinjiang soils by factors of 2.0, 1.35, 1.38, 8.24, 1.28, 2.09, and 3.26, respectively. The spatial distribution patterns of the nine trace elements in street dust were found to be substantially heterogeneous, and the contamination level decreased in the following order: Hg?>?Zn?>?Pb?>?Cd?>?Cr?>?Cu?>?As?>?Ni?>?Mn. Based on the identified concentrations, the collected dust samples were found to be moderately polluted by Hg, and not polluted by As, Cr, Cu, Mn, and Ni. The remaining elements, Cd, Pb, and Zn lie on the borderline between non-pollution and moderate pollution levels. Furthermore, it was shown that Mn and Zn in street dusts originate from both, natural and anthropogenic sources, while As, Cd, Cr, Cu, Hg, Ni, and Pb are mainly produced by anthropogenic sources. Overall, the carcinogenic and non-carcinogenic health risks of the analyzed elements, instigated primarily by oral ingestion of street dusts, were found to be within the acceptable range for both, children and adults. As and Cr are the main non-carcinogenic elements, whereas Cr is the major carcinogenic element among the investigated dust-bound metals in the study area.  相似文献   

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