Cadmium Flows Caused by the Worldwide Production of Primary Zinc Metal

Material flows of the economic cycle can contain toxic substances, which enter the economy as impurities in raw materials or are intentionally added as minor or even main constituents during the manufacture of industrial or consumer goods. Cadmium, predominantly associated with zinc minerals, is a by-product of the primary zinc production. Cadmium is generated when zinc is extracted from zinc ores and concentrates, an intermediate product resulting from flotation processing after the zinc ore has been mined and milled. Information on the amount of cadmium generated from zinc extraction is rarely published. In this article, we assess generation and fate of cadmium accumulating worldwide in the production of primary zinc from ores and concentrates. Model calculations for the beginning of the 21st century show that annually about 30,000 tonnes of cadmium were generated, but only approximately 16,000 tonnes were converted to primary cadmium metal, key material for the production of other cadmium compounds (e.g., cadmium oxide), and cadmium-containing goods (e.g., nickel−cadmium batteries). Hence, about 14,000 tonnes of cadmium must have been transferred somewhere else. The fate of about 5,500 tonnes can be plausibly explained, but it is difficult to determine what happens to the rest.     

Urban Metabolism

Urban metabolism studies have been established for only a few cities worldwide, and difficulties obtaining adequate statistical data are universal. Constraints and peculiarities call for innovative methods to quantify the materials entering and leaving city boundaries. Such methods include the extrapolation of data at the country or the region level based, namely, on sales, population, commuters, workers, and waste produced.
The work described in this article offers a new methodology developed specifically for quantifying urban material flows, making possible the regular compilation of data pertinent to the characterization of a city's metabolism. This methodology was tested in a case study that characterized the urban metabolism of the city of Lisbon by quantifying Lisbon's material balance for 2004. With this aim, four variables were characterized and linked to material flows associated with the city: absolute consumption of materials/products per category, throughput of materials in the urban system per material category, material intensity of economic activities, and waste flows per treatment technology.
Results show that annual material consumption in Lisbon totals 11.223 million tonnes (20 tonnes per capita), and material outputs sum 2.149 million tonnes. Nonrenewable resources represent almost 80% of the total material consumption, and renewables consumption (biomass) constitutes only 18% of the total consumption. The remaining portion is made up of nonspecified materials.
A seemingly excessive consumption amount of nonrenewable materials compared to renewables may be the result of a large investment in building construction and a significant shift toward private car traveling, to the detriment of public transportation.     

Rationale for and Interpretation of Economy-Wide Materials Flow Analysis and Derived Indicators

Economy-wide material flow analysis (MFA) and derived indicators have been developed to monitor and assess the metabolic performance of economies, that is, with respect to the internal economic flows and the exchange of materials with the environment and with other economies. Indicators such as direct material input (DMI) and direct material consumption (DMC) measure material use related to either production or consumption. Domestic hidden flows (HF) account for unused domestic extraction, and foreign HF represent the upstream primary resource requirements of the imports. DMI and domestic and foreign HF account for the total material requirement (TMR) of an economy. Subtracting the exports and their HF provides the total material consumption (TMC).
DMI and TMR are used to measure the (de-) coupling of resource use and economic growth, providing the basis for resource efficiency indicators. Accounting for TMR allows detection of shifts from domestic to foreign resource requirements. Net addition to stock (NAS) measures the physical growth of an economy. It indicates the distance from flow equilibrium of inputs and outputs that may be regarded as a necessary condition of a sustainable mature metabolism.
We discuss the extent to which MFA-based indicators can also be used to assess the environmental performance. For that purpose we consider different impacts of material flows, and different scales and perspectives of the analysis, and distinguish between turnover-based indicators of generic environmental pressure and impact-based indicators of specific environmental pressure. Indicators such as TMR and TMC are regarded as generic pressure indicators that may not be used to indicate specific environmental impacts. The TMR of industrial countries is discussed with respect to the question of whether volume and composition may be regarded as unsustainable.     

Producer Responsibility Organizations Development and Operations

Extended producer responsibility (EPR) regulations are now in effect in 27 European Union member states and are applicable to up to 100 million tonnes of waste packaging, batteries, automobiles, and electrical and electronic products annually. This article investigates the implementation of EPR through a case study of European Recycling Platform (ERP) UK Ltd., the UK arm of one of the largest producer responsibility organizations (PROs) in Europe, recycling more than 1.5 million tonnes of waste electrical and electronic equipment to date. Previous research is extremely limited on the detailed operations of PROs. This case is presented as an example illustrating typical operational challenges PROs face in implementing EPR, such as how PROs gain an understanding of the waste management infrastructure and legislation in each country, collect sufficient volumes of waste using cost‐effective arrangements, and maintain uninterrupted collection, treatment, and recycling services. The case study provides new insights and context on the practical implementation of EPR regulations relevant for both policy makers and researchers.     

The weight of islands: Leveraging Grenada's material stocks to adapt to climate change

The building stock consumes large amounts of resources for maintenance and expansion which is only exacerbated by disaster events where large‐scale reconstruction must occur quickly. Recent research has shown the potential for application of material stock (MS) accounts for informing disaster risk planning. In this research, we present a methodological approach to analyze the vulnerability of the material stock in buildings to extreme weather events and sea‐level rise (SLR) due to climate change. The main island of Grenada, a Small Island Developing State (SIDS) in the Caribbean region, was used as a case study. A bottom‐up approach based on a geographic information system (GIS) is used to calculate the total MS of aggregate, timber, concrete, and steel in buildings. The total MS in buildings in 2014 was calculated to be 11.9 million tonnes (Mt), which is equivalent to 112 tonnes per capita. Material gross addition to stock (GAS) between 1993 to 2009 was 6.8 Mt and the average value over the time period was 4.0 tonnes per capita per year. In the year following Hurricane Ivan (2004), the per capita GAS for timber increased by 172%, while for other metals, GAS spiked by 103% (compared to average growth rates of 11% and 8%, respectively, between 1993 and 2009). We also ran a future “Ivan‐II” scenario and estimated a hypothetical loss of between 135 and 216 kilotonnes (kt) of timber from the building stock. The potential impact of SLR is also assessed, with an estimated 1.6 Mt of building material stock exposed under a 2‐m scenario. We argue that spatial material stock accounts have an important application in planning for resilience and provide indication of the link between natural disaster recovery and resource use patterns.     

Global Material Flows and Resource Productivity: Forty Years of Evidence

The international industrial ecology (IE) research community and United Nations (UN) Environment have, for the first time, agreed on an authoritative and comprehensive data set for global material extraction and trade covering 40 years of global economic activity and natural resource use. This new data set is becoming the standard information source for decision making at the UN in the context of the post‐2015 development agenda, which acknowledges the strong links between sustainable natural resource management, economic prosperity, and human well‐being. Only if economic growth and human development can become substantially decoupled from accelerating material use, waste, and emissions can the tensions inherent in the Sustainable Development Goals be resolved and inclusive human development be achieved. In this paper, we summarize the key findings of the assessment study to make the IE research community aware of this new global research resource. The global results show a massive increase in materials extraction from 22 billion tonnes (Bt) in 1970 to 70 Bt in 2010, and an acceleration in material extraction since 2000. This acceleration has occurred at a time when global population growth has slowed and global economic growth has stalled. The global surge in material extraction has been driven by growing wealth and consumption and accelerating trade. A material footprint perspective shows that demand for materials has grown even in the wealthiest parts of the world. Low‐income countries have benefited least from growing global resource availability and have continued to deliver primary materials to high‐income countries while experiencing few improvements in their domestic material living standards. Material efficiency, the amount of primary materials required per unit of economic activity, has declined since around 2000 because of a shift of global production from very material‐efficient economies to less‐efficient ones. This global trend of recoupling economic activity with material use, driven by industrialization and urbanization in the global South, most notably Asia, has negative impacts on a suite of environmental and social issues, including natural resource depletion, climate change, loss of biodiversity, and uneven economic development. This research is a good example of the IE research community providing information for evidence‐based policy making on the global stage and testament to the growing importance of IE research in achieving global sustainable development.     

Regional material flow accounts for China: Examining China's natural resource use at the provincial and national level

Over the last three decades, China has experienced the most dynamic economic development lifting living standards and resulting in fast‐growing use of natural resources. In the past, the focus has been on national MFA accounts which do not do justice to the second largest economy, home to 19% of the world population and having 30% of global material use. In this research, we calculate material extraction for China at the regional level during 1995–2015 using the most recent available statistical data and applying the most up‐to‐date international calculation methods. In particular, we combine a bottom‐up and top‐down approach for constructing the dataset of China's economically used Domestic Extraction (DEU) in an integrated way. This approach also improves the Chinese national material flow accounts and allows us to present a reliable database of DE of materials for China to date. Our new dataset provides the basis for calculating material footprints and environmental impacts of China's regions. The dataset enables us to evaluate regional resource efficiency trends in China. We find that during the past two decades, China's material use has grown strongly from 11.7 billion tonnes in 1995 to 35.4 billion tonnes in 2015. Material use has accelerated between 2000 and 2010 but slowed down between 2010 and 2015 reflecting the economic contraction caused by the Global Financial Crisis which reduced the global demand for China's manufacturing and a reorientation of China's economic policy settings toward quality of growth. Unsurprisingly, different regions play different roles in the supply chain of materials, achieving different economic performances resulting in very diverse material efficiency outcomes. This information is important to allow for a targeted policy approach to increase resource efficiency, reduce environmental impacts of resource use, and grow wellbeing in China with large positive implications for global sustainability. This study provides the basis for the development of relevant resource management policies for different regions in the future.     

Regional Patterns in Global Resource Extraction

This article presents an account of global resource extraction for the year 1999 by material groups, world regions, and development status. The account is based on materials flow analysis methodology and provides benchmark information for political strategies toward sustainable resource management. It shows that currently around 50 thousand megatons of resources are extracted yearly on a global scale, which results in a yearly global average resource use of around 8 tonnes per capita. Assuming further growth in world regions not yet close to the levels of resource use in the industrial cores—such as India or China—numbers could easily double once these parts of the world come to fully incorporate the industrial mode of production and consumption. This article contributes to information on resource use indicators, complementing and enriching information from economic accounting in order to facilitate political measures toward a sustainable use of resources.     

The United Kingdom's Fossil Resource Consumption Between 1968 and 2000

This article presents the trends of two indicators measuring fossil resource consumption in the United Kingdom (UK). First, a domestic material consumption (DMC) indicator for fossil resources (DMC_fossil) in the mass unit million tonnes is calculated. DMC_fossil shows that between 1970 and 2000 UK fossil resource consumption decreased by 10%, which suggests absolute dematerialization for this resource. Investigation into the mix of fossil resources during this period highlighted the shift from the heavy fossil resource coal to the lighter, more energy‐dense natural gas, which resulted in decreased mass of resource required. Second, an alternative indicator, resource consumption by a nation (RCN) for fossil resources (RCN_fossil) was calculated, which includes the indirect fossil resources attributable to traded goods and is measured in million tonnes of oil equivalent. RCN_fossil shows that between 1970 and 2000 United Kingdom's fossil resource consumption increased by 14%, which emphasizes that even though there has been a decrease in the mass of fossil resources demanded, it has been accompanied by an increase in the volume of resource consumed. Additionally, deconstruction of RCN_fossil shows that indirectly used resources attributable to exports and imports for the United Kingdom are significant. RCN_fossil indicates that on the basis of past trends, fossil resources attributable to UK imports will overtake fossil resources attributable to its exports, which will make it dependent on imported resources. We conclude that further debate on appropriate aggregate and complementary indicators is needed.     

Synthesis of nano hydroxyapatite from Hypopthalmichthys molitrix (silver carp) bone waste by two different methods: a comparative biophysical and in vitro evaluation on osteoblast MG63 cell lines

Biotechnology Letters - More than a thousand tonnes of fish bone wastes can be transformed into biomedical products annually. Alkaline hydrolysis and thermal calcification were used to create...     

Effect of municipal sludge on the respiratory activity of a cropland soil

Summary The respiratory activity of a cropland soil which received between 100 and 120 tonnes (dry) of municipal sludge ha⁻¹ annually over a five year period, was examined manometrically. The soil contained an average of 34 mg Cd kg⁻¹. Compared to soil from conventionally managed fields, the biological consumption of gaseous oxygen by sludge-treated soil was four times greater than its untreated conventionally fertilized counterpart. This enhanced level of biological activity was restricted to the surface 25 cm of soil at the disposal site. There was no indication that increased soil cadmium levels had impaired the overall respiratory activity of the sludge treated soil.     

Coal Tar‐Containing Asphalt Resource or Hazardous Waste?

Abstract: Coal tar was used in Sweden for the production of asphalt and for the drenching of stabilization gravel until 1973. The tar has high concentrations of polycyclic aromatic hydrocarbons (PAH), some of which may be strongly carcinogenic. Approximately 20 million tonnes of tar-containing asphalt is present in the public roads in Sweden. Used asphalt from rebuilding can be classified as hazardous waste according to the Swedish Waste Act. The cost of treating the material removed as hazardous waste can be very high due to the large amount that has to be treated, and the total environmental benefit is unclear. The transport of used asphalt to landfill or combustion will affect other environmental targets. The present project, based on three case studies of road projects in Sweden, evaluates the consequences of four scenarios for handling the material: reuse, landfill, biological treatment, and incineration. The results show that reuse of the coal tar-containing materials in new road construction is the most favorable alternative in terms of cost, material use, land use, energy consumption, and air emissions.     

Nitrogen and Phosphorus in the Finnish Energy System, 1900–2003

In producing power, humans move the nutrients nitrogen (N) and phosphorus (P) from their long‐term geological and biological stocks and release or emit them in soil, water, and the atmosphere. In Finland, peat combustion is an important driver of N and P fluxes from the environment to human economy. The flows of N and P in the Finnish energy system were quantified with partial substance flow analysis, and the driving forces of emissions of nitrogen oxides (NOx) were analyzed using the ImPACT model. In the year 2000 in Finland, 140,000 tonnes of nitrogen entered the energy system, mainly in peat and hard coal. Combustion released an estimated 66,000 tonnes of N as nitrogen oxides (NOx) and nitrous oxides (N2O) and another 74,000 tonnes as elemental N2. Most of the emissions were borne in traffic. At the same time, 6,000 tonnes of P was estimated to enter the Finnish energy system, mostly in peat and wood. Ash was mainly used in earth construction and disposed in landfills; thus negligible levels of P were recycled back to nature. During the twentieth century, fuel‐borne input of N increased 20‐fold, and of P 8‐fold. In 1900–1950, the increasing use of hard coal slowly boosted N input, whereas wood fuels were the main carrier of P. Since 1970, the fluxes have been on the rise. NOx emissions leveled off in the 1980s, though, and then declined in conjunction with improvements in combustion technologies such as NOx removal (de‐NOx) technologies in energy production and catalytic converters in cars.     

Long-term changes in Krill biomass and distribution in the Barents Sea: are the changes mainly related to capelin stock size and temperature conditions?

Krill plays a significant role in the Barents Sea ecosystem, providing energy transport between different trophic levels. The current paper presents the results of a long-term study (1980–2009) based on pelagic trawl catches from August to September. Our investigations show that the krill species were distributed widely in the Barents Sea and that the largest krill concentrations were restricted to the west-central and eastern parts of the Barents Sea. The current paper presents the relative biomass indices, and the estimates must be interpreted as minimum biomass. The mean annual krill biomass was estimated to be 22 million tonnes in wet weight, with the highest values being as much as 48 million tonnes. Capelin is the largest pelagic stock, and in some years, their biomass can amount to 4–7 million tonnes, which can impose high predation pressure on krill. When their biomass is high, capelin may consume close to 26 million tonnes annually. The predation from pelagic (herring and blue whiting) and bottom (cod and haddock) fish species was much lower, being 9 and 1 million tonnes, respectively. A negative relationship between krill biomass and capelin stock size above 74°N was observed during the study period. However, during the last decade, the krill biomass has increased despite heavy predation from capelin in some years. A positive significant linear relationship between the mean annual Kola temperature and the krill biomass seems to indicate that the recent warming conditions have favourable impacts on the krill populations in the Barents Sea.     

How City Dwellers Affect Their Resource Hinterland

This article links databases on household consumption, industrial production, economic turnover, employment, water use, and greenhouse gas emissions into a spatially explicit model. The causal sequence starts with households demanding a certain consumer basket. This demand requires production in a complex supply-chain network of interdependent industry sectors. Even though the household may be confined to a particular geographical location, say a dwelling in a city, the industries producing the indirect inputs for the commodities that the household demands will be dispersed all over Australia and probably beyond. Industrial production represents local points of economic activity, employment, water use, and emissions that have local economic, social, and environmental impacts. The consumer basket of a typical household is followed in Australia's two largest cities—Sydney and Melbourne—along its upstream supply chains and to numerous production sites within Australia. The spatial spread is described by means of a detailed regional interindustry model. Through industry-specific emissions profiles, industrial production is then translated into local impacts. We show that annually a typical household is responsible for producing approximately 80 tonnes of greenhouse gas emissions, uses around 3 million liters of water, causes about A$140,000 to circulate in the wider economy, and provides labor worth just under three full-time employment-years. We also introduce maps that visually demonstrate how a very localized household affects the environment across an entire continent. Our model is unprecedented in its spatial and sectoral detail, at least for Australia.     

Filament formation and robust strand exchange activities of the rice DMC1A and DMC1B proteins

The DMC1 protein, a meiosis-specific DNA recombinase, catalyzes strand exchange between homologous chromosomes. In rice, two Dmc1 genes, Dmc1A and Dmc1B, have been reported. Although the Oryza sativa DMC1A protein has been partially characterized, however the biochemical properties of the DMC1B protein have not been defined. In the present study, we expressed the Oryza sativa DMC1A and DMC1B proteins in bacteria and purified them. The purified DMC1A and DMC1B proteins formed helical filaments along single-stranded DNA (ssDNA) and double-stranded DNA (dsDNA), and promoted robust strand exchange between ssDNA and dsDNA over five thousand base pairs in the presence of RPA, as a co-factor. The DMC1A and DMC1B proteins also promoted strand exchange in the absence of RPA with long DNA substrates containing several thousand base pairs. In contrast, the human DMC1 protein strictly required RPA to promote strand exchange with these long DNA substrates. The strand-exchange activity of the Oryza sativa DMC1A protein was much higher than that of the DMC1B protein. Consistently, the DNA-binding activity of the DMC1A protein was higher than that of the DMC1B protein. These biochemical differences between the DMC1A and DMC1B proteins may provide important insight into their functional differences during meiosis in rice.     

Backlighting the European Indium Recycling Potentials

With increased understanding of the effects of human activities on the environment and added awareness of the increasing societal value of natural resources, researchers have begun to focus on the characterization of elemental cycles. Indium has captured significant attention due to the potential for supply shortages and nonexistent recycling at end of life. Such a combination of potentially critical features is magnified for countries that depend on imports of indium, notably many European countries. With the aims of analyzing the dynamics of material flows and of estimating the magnitude of secondary indium sources available for recycling, the anthropogenic indium cycle in Europe has been investigated by material flow analysis. The results showed that the region is a major consumer of finished goods containing indium, and the cumulative addition of indium in urban mines was estimated at about 500 tonnes of indium. We discuss these results from the perspective of closing the metal cycle in the region. Securing access to critical raw materials is a priority for Europe, but the preference for recycling metal urban mines risks to remain only theoretical for indium unless innovations in waste collection and processing unlock the development of technologies that are economically feasible and environmentally sustainable.     

Asian population frequencies and haplotype distribution of killer cell immunoglobulin-like receptor (KIR) genes among Chinese, Malay, and Indian in Singapore

Killer cell immunoglobulin-like receptors (KIR) gene frequencies have been shown to be distinctly different between populations and contribute to functional variation in the immune response. We have investigated KIR gene frequencies in 370 individuals representing three Asian populations in Singapore and report here the distribution of 14 KIR genes (2DL1, 2DL2, 2DL3, 2DL4, 2DL5, 2DS1, 2DS2, 2DS3, 2DS4, 2DS5, 3DL1, 3DL2, 3DL3, 3DS1) with two pseudogenes (2DP1, 3DP1) among Singapore Chinese (n = 210); Singapore Malay (n = 80), and Singapore Indian (n = 80). Four framework genes (KIR3DL3, 3DP1, 2DL4, 3DL2) and a nonframework pseudogene 2DP1 were detected in all samples while KIR2DS2, 2DL2, 2DL5, and 2DS5 had the greatest significant variation across the three populations. Fifteen significant linkage patterns, consistent with associations between genes of A and B haplotypes, were observed. Eighty-four distinct KIR profiles were determined in our populations, 38 of which had not been described in other populations. KIR haplotype studies were performed using nine Singapore Chinese families comprising 34 individuals. All genotypes could be resolved into corresponding pairs of existing haplotypes with eight distinct KIR genotypes and eight different haplotypes. The haplotype A2 with frequency of 63.9% was dominant in Singapore Chinese, comparable to that reported in Korean and Chinese Han. The A haplotypes predominate in Singapore Chinese, with ratio of A to B haplotypes of approximately 3:1. Comparison with KIR frequencies in other populations showed that Singapore Chinese shared similar distributions with Chinese Han, Japanese, and Korean; Singapore Indian was found to be comparable with North Indian Hindus while Singapore Malay resembled the Thai. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

The Metabolic Transition in Japan

The notion of a (socio‐) metabolic transition has been used to describe fundamental changes in socioeconomic energy and material use during industrialization. During the last century, Japan developed from a largely agrarian economy to one of the world's leading industrial nations. It is one of the few industrial countries that has experienced prolonged dematerialization and recently has adopted a rigorous resource policy. This article investigates changes in Japan's metabolism during industrialization on the basis of a material flow account for the period from 1878 to 2005. It presents annual data for material extraction, trade, and domestic consumption by major material group and explores the relations among population growth, economic development, and material (and energy) use. During the observed period, the size of Japan's metabolism grew by a factor of 40, and the share of mineral and fossil materials in domestic material consumption (DMC) grew to more than 90%. Much of the growth in the Japanese metabolism was based on imported materials and occurred in only 20 years after World War II (WWII), when Japan rapidly built up large stocks of built infrastructure, developed heavy industry, and adopted patterns of mass production and consumption. The surge in material use came to an abrupt halt with the first oil crisis, however. Material use stabilized, and the economy eventually began to dematerialize. Although gross domestic product (GDP) grew much faster than material use, improvements in material intensity are a relatively recent phenomenon. Japan emerges as a role model for the metabolic transition but is also exceptional in many ways.