Low Loss Plasmonic Bragg Gratings with a Trench Plasmonic Waveguide

Plasmonics - We designed plasmonic Bragg gratings based on a plasmonic trench waveguide and calculated the characteristics of the designed structure. Conventional plasmonic Bragg gratings are...     

Absorption Enhancements in Plasmonic Solar Cells Coated with Metallic Nanoparticles

We find that three mechanisms lead to the absorption enhancements of light in a thin-film amorphous silicon solar cell coated with a periodic array of silver nanoparticles on the rear surface according to our simulation. They are localized surface plasmon modes of the silver nanoparticles, Fabry–Pérot resonant cavity modes and waveguide effects. Each enhancing mechanism can yield a maximum absorption enhancement of over two times at the corresponding resonant wavelengths when the nanoparticles cover 20 % of the solar cell surface, and an average absorption enhancement of up to 57 % can be achieved in the AM 1.5 G solar spectrum. The absorption enhancements can also be tuned in spectrum to optimize the total absorption in a plasmonic solar cell.     

Ferroelectric Hybrid Plasmonic Waveguide for All-Optical Logic Gate Applications

A ferroelectric hybrid plasmonic waveguide, made of a polycrystal lithium niobate waveguide separated from a gold film by a silicon dioxide isolation layer, is fabricated by use of laser molecular beam epitaxy growth, electron beam evaporation, and focused ion beam etching. Strong subwavelength mode confinement and excellent long-range propagation are achieved simultaneously for the hybrid plasmonic mode. An all-optical logic OR gate is also realized based on the ferroelectric hybrid plasmonic waveguide. This may provide a way for the study of all-optical logic gates and integrated photonic circuits.     

Plasmonic Effects of Dual-Metal Nanoparticle Layers for High-Performance Quantum Dot Solar Cells

To improve quantum dot solar cell performance, it is crucial to make efficient use of the available incident sunlight to ensure that the absorption is maximized. The ability of metal nanoparticles to concentrate incident sunlight via plasmon resonance can enhance the overall absorption of photovoltaic cells due to the strong confinement that results from near-field coupling or far-field scattering plasmonic effects. Therefore, to simultaneously and synergistically utilize both plasmonic effects, the placement of different plasmonic nanostructures at the appropriate locations in the device structure is also critical. Here, we introduce two different plasmonic nanoparticles, Au and Ag, to a colloidal PbS quantum dot heterojunction at the top and bottom interface of the electrodes for further improvement of the absorption in the visible and near-infrared spectral regions. The Ag nanoparticles exhibit strong scattering whereas the Au nanoparticles exhibit an intense optical effect in the wavelength region where the absorption of light of the PbS quantum dot is strongest. It is found that these dual-plasmon layers provide significantly improved short-circuit current and power conversion efficiency without any form of trade-off in terms of the fill factor and open-circuit voltage, which may result from the indirect contact between the plasmonic nanoparticles and colloidal quantum dot films.

     

Influence of Substrate on Plasmon-Induced Absorption Enhancements

A set of periodic plasmonic nanostructures is designed and fabricated as a means to investigate light absorption in single-crystal silicon thin-film structures with silicon-on-insulator (SOI) wafers as a model system. It is shown both computationally and experimentally that plasmon-induced absorption enhancement is remarkably higher for such devices than for thick or semi-infinite structures or for the thin-film amorphous silicon solar cells reported in the literature. Experimental photocurrent enhancements of the orders of 12 and 20 are demonstrated for non-optimized 2200-nm-thick photoconductive and 300-nm-thick photovoltaic test structures, respectively. Theoretical absorption enhancements as high as 80 are predicted to be achievable for the similar structures. The features of the spectral enhancements observed are attributed to several interacting resonance phenomena: not just to the favourable scattering of light by the periodic plasmonic nanoparticle arrays into the SOI device layer and coupling to the waveguide modes interacting with the plasmonic array but also to the Fabry-Pérot type interferences in the layered structure. We show that the latter effect gives a significant contribution to the spectral features of the enhancements, although frequently ignored in the discussions of previous reports.

     

Optical Saturable Absorption in Gold Nanoparticles

In this work, we present the experimental study of the nonlinear absorption of gold nanospheres and nanorods in aqueous suspension, using picosecond white-light supercontinuum open-aperture Z-scan. We demonstrate a saturable absorption effect in all particle suspensions at low-pulse energy. In the high-pulse energy regime, the apparent reverse-saturable absorption, observed in gold nanorods, was determined to be induced by photodegradation. Using the Lorentzian deconvolution method for the absorption spectra, we explain the variations on nonlinear optical effects and prove that saturable absorption only occurs within the plasmonic bands.     

Synthesis,Characterization, and Functionalization of Hybrid Au/CdS and Au/ZnS Core/Shell Nanoparticles

Plasmonic nanoparticles are an attractive material for light harvesting applications due to their easily modified surface, high surface area and large extinction coefficients which can be tuned across the visible spectrum. Research into the plasmonic enhancement of optical transitions has become popular, due to the possibility of altering and in some cases improving photo-absorption or emission properties of nearby chromophores such as molecular dyes or quantum dots. The electric field of the plasmon can couple with the excitation dipole of a chromophore, perturbing the electronic states involved in the transition and leading to increased absorption and emission rates. These enhancements can also be negated at close distances by energy transfer mechanism, making the spatial arrangement of the two species critical. Ultimately, enhancement of light harvesting efficiency in plasmonic solar cells could lead to thinner and, therefore, lower cost devices. The development of hybrid core/shell particles could offer a solution to this issue. The addition of a dielectric spacer between a gold nanoparticles and a chromophore is the proposed method to control the exciton plasmon coupling strength and thereby balance losses with the plasmonic gains. A detailed procedure for the coating of gold nanoparticles with CdS and ZnS semiconductor shells is presented. The nanoparticles show high uniformity with size control in both the core gold particles and shell species allowing for a more accurate investigation into the plasmonic enhancement of external chromophores.     

Design and Optimization of Open-cladded Plasmonic Waveguides for CMOS Integration on Si3N4 Platform

Herein, we present a design analysis and optimization of open-cladded plasmonic waveguides on a Si₃N₄ photonic waveguide platform targeting CMOS-compatible manufacturing. For this purpose, two design approaches have been followed aiming to efficiently transfer light from the hosting photonic platform to the plasmonic waveguide and vice versa: (i) an in-plane, end-fire coupling configuration based on a thin-film plasmonic structure and (ii) an out-of-plane directional coupling scheme based on a hybrid slot waveguide. A comprehensive numerical study has been conducted, initially deploying gold as the reference metal material for validating the numerical models with already published experimental results, and then aluminum and copper have been investigated for CMOS manufacturing revealing similar performance. To further enhance coupling efficiency from the photonic to the plasmonic part, implementation of plasmonic tapering schemes was examined. After thorough investigation, plasmo-photonic structures with coupling losses per single interface in the order of 1 dB or even in the sub-dB level are proposed, which additionally exhibit increased tolerance to deviations of critical geometrical parameters and enable CMOS-compatible manufacturing.

     

Enhanced Optical Absorption and Spectral Photocurrent in a-Si:H by Single- and Double-Layer Silver Plasmonic Interfaces

Single and double plasmonic interfaces consisting of silver nanoparticles embedded in media with different dielectric constants including SiO₂, SiN_x, and Al:ZnO have been fabricated by a self-assembled dewetting technique and integrated to amorphous silicon films. Single plasmonic interfaces exhibit plasmonic resonances whose frequency is red-shifted with increasing particle size and with the thickness of a dielectric spacer layer. Double plasmonic interfaces consisting of two different particle sizes exhibit resonances consisting of double minima in the transmittance spectra. The optical extinction of a-Si:H deposited on these interfaces is broadened into the red indicating higher absorption and/or scattering at wavelengths higher than those typically absorbed by a-Si:H without plasmonic interfaces. While the photocurrent shows an overall decrease for the samples with the interfaces, significant enhancement of photocurrent is observed near the low-energy edge of the bandgap (600–700 nm). These results correlate well with the broadened extinction spectra of the interfaces and are interpreted in terms of enhanced absorption in that region.     

An Ultrahigh Narrowband Absorber Close to the Information Communication Window

Plasmonics - In this paper, we demonstrate a plasmonic ultrahigh narrowband perfect absorber, which realizes an absorption intensity of up to 99.99% in the near-infrared electromagnetic spectrum...     

Optimization Strategy Aided by an Interplay Between Plasmonic Material and Nanoarray Geometry for Light Trapping Application in Thin-Film Photovoltaics

In this article, we have developed an optimization strategy taking into consideration the interplay between the choice of plasmonic material and geometrical parameters that lead to enhanced photocurrent density. We have demonstrated this by computing the optical absorption, using finite difference time domain technique, due to front-end placed aluminum and silver nanosphere arrays on 1- μm-thick film of silicon. Results from this optimization procedure indicate that over a broad wavelength range (～600 nm onwards), absorption enhancement is primarily due to waveguiding effects and is independent of the plasmonic material. However, the significance of the plasmonic material becomes noticeable at lower wavelengths. The optimization yielded an inter-particle distance of 325 nm and nanosphere radius of 75 nm that corresponds to maximum photocurrent density for both aluminum and silver. Furthermore, it was noticed that the presence of a native oxide layer on aluminum does not deteriorate the enhancement significantly. In fact, the photocurrent density enhancement due to partially oxidized aluminum nanospheres is found to be better than using silver nanospheres.     

Determination of the Surface Plasmon Polariton Extraction Efficiency from a Self-Assembled Plasmonic Crystal

Plasmonics - We experimentally measure and analytically describe the fluorescence enhancement obtained by depositing CdSe/CdS nanocrystals onto a gold plasmonic crystal, a two-dimensional grating...     

Zirconium Nitride for Plasmonic Cloaking of Visible Nanowire Photodetectors

Light scattered by a photodetector disturbs the probing field, resulting in noise. Cloaking is an effective method to reduce this noise. Here we investigate theoretically an emerging plasmonic material, zirconium nitride (ZrN), as a plasmonic cloak for silicon (Si) nanowire-based photodetectors and compare it with a traditional plasmonic material, gold (Au). Using Mie formalism, we have obtained the scattering cancelation across the visible spectrum. We found that ZrN cloaks produce a significant decrease in the scattering from bare Si nanowires, which is 40% greater than that obtained with Au cloaks in the wavelength region of 400–500 nm. The scattering cancelations become comparable at 550 nm, with Au providing a better scattering cancelation compared to ZrN over the wavelength region of 600–700 nm. To include the absorption and provide a measure of overall performance on noise reduction, a figure of merit (FOM), defined as the ratio of the absorption efficiency and the scattering efficiency of the cloaked nanowire to that of the bare Si nanowire, was calculated. We show that the optimized ZrN cloak provides up to 3 times enhancement of the FOM over a bare Si NW and a 60% improvement over an optimized Au-cloaked NW, in the wavelength region of 400–500 nm. An optimized Au-cloaked NW shows up to 17.69 times improvement in the wavelength region of 600–700 nm over a bare Si NW and up to a 2.7 times improvement over an optimized ZrN-cloaked NW. We also predicted the optimal dimensions for the cloaked NWs with respect to the largest FOM at various wavelengths between 400 and 650 nm.

     

A Comparative Plasmonic Study of Nanoporous and Evaporated Gold Films

Previously, we have reported that nanoporous gold (NPG) films prepared by a chemical dealloying method have distinctive plasmonic properties, i.e., they can simultaneously support localized and propagating surface plasmon resonance modes (l-SPR and p-SPR, respectively). In this study, the plasmonic properties of NPG are quantified through direct comparison with thermally evaporated gold (EG) films. Cyclic voltammetry and electrochemical impedance spectroscopy experiments reveal that the NPG films have 4–8.5 times more accessible surface area than EG films. Assemblies of streptavidin–latex beads generate p-SPR responses on both NPG and EG films that correlate well with the bead density obtained from scanning electron microscopy (SEM) images. A layer-by-layer assembly experiment on NPG involving biotinylated anti-avidin IgG and avidin, studied by l-SPR and SEM, shows that the l-SPR signal is directly linked to the accessibility of the interior of the NPG porosity, an adjustable experimental parameter that can be set by the dealloying condition and time. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Grating-based surface plasmon resonance detection of core-shell nanoparticle mediated DNA hybridization

In this report, we have investigated enhanced surface plasmon resonance (SPR) detection of DNA hybridization using gold core - silica shell nanoparticles in localized plasmonic fields. The plasmonic fields were localized by periodic linear gratings. Experimental results measured for hybridization of 24-mer single-stranded DNA oligomers suggest that core-shell nanoparticles (CSNPs) on gratings of 400 nm period provide enhanced optical signatures by 36 times over conventional thin film-based SPR detection. CSNP-mediated DNA hybridization produced 3 times larger angular shift compared to gold nanoparticles of the same core size. We have also analyzed the effect of structural variation. The enhancement using CSNPs was associated with increased surface area and index contrast that is combined by improved plasmon coupling with localized fields on gratings. The combined approach for conjugated measurement of a biomolecular interaction on grating structures is expected to lower the limit of detection to the order of a few tens of fg/mm(2).     

Two-dimensional PtSe2 Theoretically Enhanced Goos-Hänchen Shift Sensitive Plasmonic Biosensors

Platinum diselenide (PtSe₂), an emerging two-dimensional transition metal dichalcogenide, exhibits thickness-dependent refractive index, and hence, intriguing optical properties. Here, we employ it as a plasmonic sensing substrate to achieve significant enhancement in Goos-Hänchen shift sensitivity. Through systematic optimization of all parameters, four optimum sensing configurations have been achieved at different wavelengths ranging from visible to near-infrared region, where the Goos-Hänchen shift sensitivity receives four times enhancement in comparison with the conventional bare gold sensing substrate. There is a linear range of Goos-Hänchen shift with the tiny change of refractive index for each optimal configuration. The detection limit of the refractive index change can be as low as 5 × 10⁻⁷ RIU which is estimated to be lower by 2 orders of magnitude, and the corresponding sensitivity of biomolecules has a 1000-fold increment compared with that of bare gold-based sensors.

     

Tuning Plasmonic Properties of Truncated Gold Nanospheres by Coating

The influence of TiO₂ coating on resonant properties of gold nanoisland films deposited on silica substrates was studied numerically and in experiments. The model describing plasmonic properties of a metal truncated nanosphere placed on a substrate and covered by a thin dielectric layer has been developed. The model allows calculating a particle polarizability spectrum and, respectively, its surface plasmon resonance (SPR) wavelength for any given cover thickness, particle radius and truncation parameter, and dielectric functions of the particle, the substrate, the coating layer, and the surrounding medium. Dependence of the SPR position calculated for truncated gold nanospheres has coincided with the measured one for the gold nanoisland films covered with titania of different thicknesses. In the experiments, gold films with thickness of 5 nm were deposited on a silica glass substrate, annealed at 500 °C to form nanoislands of 20 nm in diameter, and covered with amorphous titania layers using atomic layer deposition technique. The resulting structures were characterized with scanning electron microscopy and optical absorption spectroscopy. The measured dependence of the SPR position on titania film thickness corresponded to the one calculated for truncated sphere-shaped nanoparticles with the truncation angle of ~50°. We demonstrated the possibility of tuning the SPR position within ~100 nm range by depositing to 30 nm thick titania layer.

     

Optothermally Controlled Charge Transfer Plasmons in Au-Ge<Subscript>2</Subscript>Sb<Subscript>2</Subscript>Te<Subscript>5</Subscript> Core-Shell Dimers

Functional and reversible plasmonic resonances across the visible and near-infrared spectrum have opened new avenues for developing advanced next-generation nanophotonic devices. In this study, by using optothermally controlled phase-change material (PCM) for plasmonic nanostructures, we successfully induced highly tunable charge transfer plasmon (CTP) resonance modes. To this end, we have chosen a two-member dimer assembly consisting of gold cores and Ge₂Sb₂Te₅ (GST) shells in distant, touching, and overlapping regimes. We show that switching between amorphous (dielectric) and crystalline (conductive) phases of GST allows for achieving tunable dipolar and CTP resonances and enables an effective interplay between these modes along the near-infrared spectrum. By analyzing electromagnetically calculated spectral responses for the dimer antenna in tunneling and direct charge transfer regimes, we confirmed that the induced CTPs in touching and overlapping regimes are highly controllable and pronounced in comparison to the quantum tunneling regime. We also use the precise, fast, and controllable switching between dipolar and CTP resonant modes to develop a telecommunication switch based on a simple metallodielectric dimer. The proposed structures can help designing optothermally controlled devices without morphological variations in the geometry of the design, and having strong potential for advanced plasmon modulation and fast data routing.     

Remote Excitation Polarization-Dependent Surface Photochemical Reaction by Plasmonic Waveguide

For the first time, we report remote excitation polarization-dependent surface photochemical reaction by plasmonic waveguide. Remote excitation polarization-dependent surface-enhanced Raman scattering (SERS) spectra indicate a surface photochemical reaction that p-aminothiophenol is converted to p,p′-dimercaptoazobenzene (DMAB) induced by the plasmonic waveguide. Surface plasmon polaritons generated at the end of a silver nanowire can propagate efficiently along the nanowire, and be coupled by nanoparticles near the nanowire as a nanoantenna. Massive electromagnetic enhancement is generated in the nanogap between the nanowire and the nanoparticles. The remote excitation polarization-dependent SERS spectra can be obtained experimentally in the nanogaps; furthermore, the remote excitation polarization-dependent SERS spectra of DMAB reveal the occurrence of this surface catalytic reaction. Theoretical simulations using finite-difference time-domain methods strongly support our experimental results.     

Direct Fabrication Route to Plastic-Supported Gold Nanoparticles for Flexible NIR-SERS

Stable gold nanoparticles with surface plasmon resonance tunable from visible (Vis) to near-infrared (NIR) are deposited via a direct sputtering methodology on large area polyethylene terephthalate (PET) to be used as effective, flexible NIR surface-enhanced Raman scattering (SERS) substrates. An O₂ plasma treatment of PET is used to tailor growth dynamics, geometry, and plasmonic properties of nanoparticles. The O₂ plasma treatment of PET results also in effective improvement of nanoparticle anchoring on the plastic substrate, providing more stable, flexible SERS systems. The functionality of fabricated SERS substrates has been tested using benzylthiol, and SERS enhancement factors in the range 10⁴ have been achieved, which are comparable with those reported in literature for gold nanostructures fabricated on silicon substrate. These results attest the great potentiality of this methodology for the production of cost-effective flexible and reusable large-scale SERS substrates.