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为保证公立医院服务质量,推动公立医院改革,最终达到促进社会和谐的目标,必须完善和重建我国公立医院监督模式。基于社会学和管理学的双重角度,基于新一轮医药卫生体制改革的要求,针对我国公立医院监督的突出问题,提出构建公立医院多元监督的模式。 相似文献
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建立管理者有效激励机制,化解公立医院法人治理结构下的委托代理问题是公立医院体制改革的重要保障。该激励机制通过弥合管理者与所有者的价值及行为取向差异,促使管理者自觉自愿地履行并实现公共利益。但由于机制建立过程中存在效益目标不明晰、绩效水平难于考量等难题。为此,需以公共利益为导向设置董事机构,加强效益评价指标体系和外部监管制度建设,同时创新激励手段,从而提高公立医院法人治理结构下的整体绩效。 相似文献
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法人治理结构下,公立医院医师绩效考核尤为重要。但目前的医师绩效考核机制中存在公益性缺乏、重过程轻结果、搭便车和激励惰性以及重热门轻冷门等问题。为此,本文在实证调研和文献分析的基础上,借助德尔菲法和层次分析法,基于公益性、公平性、全面性、客观性和可操作性四个原则,选取人才素质类、价值贡献类和工作效果类三个方面指标,构建出新型公立医院医师绩效考核标准体系。
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利用文献研究法,回顾国外医院院长职业化的发展历程,分析其发展现状,并与我国医院院长管理现状进行对比分析,从中总结对我国公立医院院长职业化改革的启示。 相似文献
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Two new zincophosphites [C6H14N2]0.5[Zn(H2PO3)2] 1 and [C4H12N2]0.5[(CH3)2NH2][Zn2(HPO3)3] 2 have been solvothermally synthesized in mixed solvents of N,N-dimethylformamide (DMF) and 1,4-dioxane (DOA), respectively. Single-crystal X-ray diffraction analysis reveals that compound 1 exhibits a neutral inorganic chain formed by ZnO4 and HPO2(OH) units. Interestingly, the left- and right-handed hydrogen-bonded helical chains are alternately formed via the hydrogen-bonds between two adjacent chains. Compound 2 exhibits a layer structure with 4- and 12-MRs formed by ZnO4 and HPO3 units, in which two kinds of organic amine molecules both act as countercations to compensate the overall negative electrostatic charge of the anionic network. 相似文献
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Take-aki Koizumi 《Inorganica chimica acta》2008,361(7):2131-2138
The molecular structure of an o-phenylenediamine unit-containing oligophenylene (1), Ph-Ph′-Ph′(2,3-NH2)-Ph′-Ph (Ph = phenyl; Ph′ = p-phenylene; Ph′(2,3-NH2) = 2,3-diamino-p-phenylene), was determined by X-ray crystallography. 1 has a twisted structure, and forms an intermolecular C-H?π interaction network. The -NH2 group of 1 was air-oxidized to an imine, NH, group in the presence of [RuCl2(bpy)2] (bpy = 2,2′-bipyridyl) and gave a ruthenium(II)-benzoquinone diimine complex [Ru(2)(bpy)2](PF6)2 (2: Ph-Ph′-Ph′(2,3-imine)-Ph′-Ph). The molecular structure of [Ru(2)(bpy)2](PF6)2 was confirmed by X-ray crystallography. [Ru(2)(bpy)2](PF6)2 underwent two-step electrochemical reduction with E1/2 = −0.889 V and −1.531 V versus Fc+/Fc. The E1/2’s were located at higher potentials by 91 mV and 117 mV, respectively, than those of reported [Ru(bqdi)(bpy)2](PF6)2 (bqdi = benzoquinone diimine). Electrochemical oxidation of [Ru(2)(bpy)2](PF6)2 occurred at a lower potential by 180 mV than that of [Ru(bqdi)(bpy)2](PF6)2. Occurrence of the easier reduction and oxidation of [Ru(2)(bpy)2](PF6)2 than those of [Ru(bqdi)(bpy)2](PF6)2 is ascribed to the presence of a large π-conjugation system in 2. 相似文献
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The title compounds were made by reacting bis(diphenylphosphino)methane (dppm) with reduced solutions of OsCl64? and Ru2OCl104?. The crystal and molecular structures of these compounds have been determined form three-dimensional X-ray study. The cis-isomers crystallize with one CHCl3 per molecule of the complex. All three compounds crystallize in the monoclinic space group P21/n with unit cell dimensions as follows: Cis-OsCl2(dppm)2·CHCl3: a = 13.415(4) Å, b = 22.859(4) Å, c = 16.693(3) Å, β = 105.77(3)°, V = 4926(3) Å3, Z = 4. cis-RuCl2(dppm)2·CHCl3: a = 13.442(3) Å, b = 22.833(7) Å, c = 16.750(4) Å, β = 105.53(2)°, V = 4953(3) Å3, Z = 4. trans-RuCl2(dppm)2: a = 11.368(7) Å, b = 10.656(6) Å, c = 18.832(12) Å; β = 103.90(6)°, V = 2213(7) Å3; Z = 2. The structures were refined to R = 0.044 (Rw = 0.055) for cis-OsCl2(dppm)2·CHCl3; R = 0.065 (Rw = 0.079) for cis-RuCl2(dppm)2·CHCl3 and R = 0.028 (Rw = 0.038) for trans-RuCl2(dppm)2. The complexes are six coordinate with stable four-membered chelate rings. The PMP angle in the chelate rings is ca. 71° in each case. 相似文献
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Several niobium and tantalum compounds were prepared that contain either the diamidoamine ligand, [(3,4,5-F3C6H2NCH2CH2)2NMe]2− ([F3N2NMe]2−), or the triamidoamine ligand, [(3,5-Cl2C6H3NCH2CH2)3N]3− ([Cl2N2NMe]3−). The former include [F3N2NMe]TaCl3, [F3N2NMe]NbCl3, [F3N2NMe]TaMe3, [F3N2NMe]NbMe3, [(F3N2NMe)TaMe2][MeB(C6F5)3], [F3N2NMe]Ta(CHSiMe3)(CH2SiMe3), [F3N2NMe]Ta(CH2-t-Bu)Cl2, [F3N2NMe]Ta(CH-t-Bu)(CH3), and [F3N2NMe]Ta(η2-C2H4)(CH2CH3). The latter include [Cl2N2NMe]TaCl2, [Cl2N2NMe]TaMe2, [Cl2N2NMe]Ta(η2-C2H4), and [Cl2N2NMe]Ta(η2-C2H2).X-ray diffraction studies were carried out on [F3N2NMe]Ta(CHSiMe3)(CH2SiMe3), [F3N2NMe]Ta(η2-C2H4)(CH2CH3), and [Cl2N2NMe]TaMe2.. 相似文献
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Pavel A. Abramov Rita Hernandez-Molina Alexander V. Virovets Pedro Gili Vladimir P. Fedin 《Inorganica chimica acta》2010,363(13):3330-3337
Reaction of [Mo2O2(μ-S)2(H2O)6]2+ with Mo(CO)6 or metallic Mo under hydrothermal conditions (140 °C, 4 M HCl) gives oxido-sulfido cluster aqua complex [Mo3(μ3-S)(μ-O)2(μ-S)(H2O)9]4+ (1). Similarly, [W3(μ3-S)(μ-O)2(μ-S)(H2O)9]4+ (2) is obtained from [W2O2(μ-S)2(H2O)6]2+ and W(CO)6. While reaction of [Mo2O2(μ-S)2(H2O)6]2+ with W(CO)6 mainly proceeds as simple reduction to give 1, [W2O2(μ-S)2(H2O)6]2+ with Mo(CO)6 produces new mixed-metal cluster [W2Mo(μ3-S)(μ-O)2(μ-S)(H2O)9]4+ (3) as main product. From solutions of 1 in HCl supramolecular adduct with cucurbit[6]uril (CB[6]) {[Mo3O2S2(H2O)6Cl3]2CB[6]}Cl2⋅18H2O (4) was isolated and structurally characterized. The aqua complexes were converted into acetylacetonates [M3O2S2(acac)3(py)3]PF6 (M3 = Mo3, W3, W2Mo; 5a-c), which were characterized by X-ray single crystal analysis, electrospray ionization mass spectrometry and 1H NMR spectroscopy. Crystal structure of (H5O2)(Me4N)4[W3(μ3-S)(μ2-S)(μ2-O)2(NCS)9] (6), obtained from 2, is also reported. 相似文献
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Vito Di Noto Roberto Zannetti Silvano Bresadola Antonio Marigo Carla Marega 《Inorganica chimica acta》1991,190(2)
The reaction of α-MgCl2 with boiling ethyl acetate affords MgCI2(CH3COOC2H5)2·
(CH3COOC2H5), which is obtained as crystals suitable for X-ray analysis only from the mother liquor. M=315.5, orthorhombic, space group P21221 (No. 18), a=25.077(3), b=8.616(1), c=7.345(1) Å, V=1587.0(3) Å3, Z=4, Dx=1.32 g cm−3,λ A(Mo Kα)=0.71069 Å, μ=4.17 cm−1, F(000)=664, T=298 K, observed reflections: 1667, R=0.059 and Rw=0.069. The structure is composed of polymeric chains of MgCl2(CH3COOC2H5)2 and the ethyl acetate molecules occupy a mutually trans position. 相似文献
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Ge Wang 《Inorganica chimica acta》2005,358(4):933-940
Adding one equivalent of H2O2 to compounds of stoichiometry MoCl2(O)2(OPR3)2, OPR3 = OPMePh2 or OPPh3, leads to the formation of oxo-peroxo compounds MoCl2(O)(O2)(OPR3)2. The compound MoCl2(O)(O2)(OPMePh2)2 crystallized with an unequal disorder, 63%:37%, between the oxo and peroxo ligands, as verified by single-crystal X-ray diffractometry, and can be isolated in reasonable yields. MoCl2(O)(O2)(OPPh3)2, was not isolated in pure form, co-crystallized with MoCl2(O)2(OPPh3)2 in two ratios, 18%:82% and 12%:88%, respectively, and did not contain any disorder in the arrangement of the oxo and peroxo groups. These complexes accomplish the isomerization of various allylic alcohols. A mechanism of this reaction has been constructed based on 18O isotopic studies and involves exchange between the alcohol and metal bonded O atoms. 相似文献
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The hydrothermal reaction of cobalt(II)oxalate di-hydrate, zinc oxide, and triethyl-orthophosphate, using 1,2-diaminoethane as structure directing template in water, produced two major crystal phases in almost equal amount: the purple crystals of [NH3-CH2CH2NH3][Co0.7Zn1.3(PO4)2] (1) and the red burgundy crystals of Co6.2(OH)4(PO4)4Zn1.80 (2), a new adamite type phase. The structure of [NH3-CH2CH2NH3] [Co0.7Zn1.3(PO4)2] (1) exhibits a 3D open framework built from PO4 and (Co/Zn)O4 tetrahedra, and (Co/Zn)O5 trigonal bipyramids, forming two major channels, an 8-membered ring channel and a 16-membered ring channel, that host the ethanediammonium ions. The Co6.2(OH)4(PO4)4Zn1.80 (2) is isomorphous with adamite-type M2(OH)XO4 structure, with a condensed vertex and edge sharing network of (Co/Zn)O5, and distorted CoO6, and PO4 subunits. The cobalt preference for higher coordination numbers is displayed in this structure, where the octahedral sites are wholly occupied by cobalt. Thermal analysis confirmed that these compounds display high thermal stability. 相似文献
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Hydrothermal methods were used to prepare [Cu(O3PC10H6CO2H)] (1) and [Cu(bpy)(HO3PC10H6CO2)]·2H2O (2·2H2O), where H2O3PC10H6CO2H is 2,6-carboxynaphthalene phosphonic acid (H3cnp). The two-dimensional structure of 1 consists of layers of edge-sharing {CuO6} octahedra, producing an AlCl3- type structure of fused hexagonal rings of copper octahedra, enclosing voids of hexagonal profile. The layer composition is CuO3 or CuO6/2 as each oxygen bridges two copper sites. The Hcnp ligands project from either face of the copper “oxide” layer. Adjacent layers interact through hydrogen bonding interactions between the pendant -CO2H groups of the ligand. Coordination of the bipyridine ligand in [Cu(HO3PC10H6CO2)] (2) obstructs expansion in two-dimensions, and the material exhibits a chain structure. The chain is constructed of binuclear units of edge-sharing ‘4+1’ {CuO3N2} square pyramids linked through the dipodal {HO3PC10H6CO2}2− ligands. 相似文献