Tunable Plasmon-Induced Transparency of Double Continuous Metal Films Sandwiched with a Plasmonic Array

Making a continuous metal film with near-unity transparency has received more and more attention in recent years because of its potential applications for various optoelectronic devices. Here, we theoretically show that a high tunable plasmon-induced transparency metal film structure can be performed by double continuous metal films inserted with a two-dimensional hexagonal lattice array of plasmonic nanopariticles. The proposed structure shows near-unity anti-reflection and intensively enhanced transmission via the cooperative effects of strong resonant near-field light input and output coupling by the plasmonic array and the excitation of surface electromagnetic waves of the metal films. The optical response can be efficiently mediated by varying the sizes of nanoparticles and the separated distance between the metal array and the metal films. With the merits of high transparency, sub-wavelength sizes and wholly retained metal characteristics including high conductivity via using the pure metallic materials, the structure proposed here suggests various potential applications in optoelectronic integrated circuits.     

High Optical Transmission in a Hybrid Plasmonic-Optical Structure with a Continuous Metal Film

Metals are naturally opaque for electromagnetic (EM) waves below violet frequency due to the Coulomb screening effect. In this letter, we demonstrate high optical transparency of a seamless continuous metal film by sandwiching it in a hybrid plasmonic-optical structure. The proposed structure consists of a plasmonic array and an optical cavity, which exhibits magnetic plasmon (MP) resonance and optical Fabry-Perot (FP) resonance, respectively. An optical transparency of 84% in the near-IR regime is achieved making use of interaction between the plasmonic and optical modes. Furthermore, spectral tunability of the high transparency is demonstrated and robustness under oblique incidence is examined. This work may give insights into plasmonic-optical interactions and may be a potential candidate for transparent electrodes.     

Highest Efficiency Plasmonic Polycrystalline Silicon Thin-Film Solar Cells by Optimization of Plasmonic Nanoparticle Fabrication

Excitation of surface plasmons in metallic nanoparticles is a promising method for increasing the light absorption in solar cells and hence the cell photocurrent. Comprehensive optimization of a nanoparticle fabrication process for enhanced performance of polycrystalline silicon thin-film solar cells is presented. Three factors were studied: the Ag precursor film thickness, annealing temperature and time. The thickness of the precursor film was 10, 14 and 20 nm; annealing temperature was 190, 200, 230 and 260 °C; and annealing time was varied between 20 and 95 min. Performance enhancement due to light-scattering by nanoparticles was calculated by comparing absorption, short-circuit current density and energy conversion efficiency in solar cells with and without nanoparticles formed under different process conditions. Nanoparticles formed from 14-nm-thick Ag precursor film annealed at 230 °C for 53 min result in the highest absorption enhancement in the 700–1,100 nm wavelength range, in the highest enhancement of total short-circuit current density. The highest photocurrent enhancement was 33.5 %, which was achieved by the cell with the highest absorption enhancement in the 700–1,100 nm range. The plasmonic cell efficiency of 5.32 % was achieved without a back reflector and 5.95 % with the back reflector; which is the highest reported efficiency for plasmonic thin-film solar cells.     

Study of Broadband Tunable Properties of Surface Plasmon Resonances of Noble Metal Nanoparticles Using Mie Scattering Theory: Plasmonic Perovskite Interaction

We suggest semi-analytical approach to study the optical properties of noble metal nanoparticles and their interaction to the perovskite material (methyl ammonia lead halide: CH₃NH₃PbI₃). Metal nanoparticles embedded in perovskite matrix exhibits broadband surface plasmon resonances, and the tunability of these plasmonic resonances is highly sensitive to particle size. The calculation of optical cross section have been done using Mie scattering theory which is applicable to arbitrary size and spherical-shape metal nanoparticles. We have taken five different radii ranging from 15 to 100 nm to understand the plasmonic resonances and its spectral width in the wavelength range 300 to 800 nm. Out of these noble metal nanoparticles, silver have highest scattering efficiency nearly of the order of 18 for the case of 15 nm radii at resonance wavelength 613 nm. Our finding reveals a new concept to understand the applications of plasmonic resonances in order to enhance the photon absorption inside the thin film of perovskite.     

Optimization of Optoelectronic Plasmonic Structures

We discuss the interplay between surface plasmon polaritons (SPPs) and localized shape resonances (LSRs) in a plasmonic structure working as a photo-coupler for a GaAs quantum well photodetector. For a targeted electronic inter-subband transition inside the quantum well, maximum photon absorption is found by compromising two effects: the mode overlapping with incident light and the lifetime of the resonant photons. Under the optimal conditions, the LSR mediates the coupling between the incident light and plasmonic structure while the SPP provides long-lived resonance which is limited ultimately by metal loss. The present work provides insight to the design of plasmonic photo-couplers in semiconductor optoelectronic applications.     

Coupled-Resonator-Induced Fano Resonances for Plasmonic Sensing with Ultra-High Figure of Merits

Fano resonances are numerically predicted in an ultracompact plasmonic structure, comprising a metal-isolator-metal (MIM) waveguide side-coupled with two identical stub resonators. This phenomenon can be well explained by the analytic model and the relative phase analysis based on the scattering matrix theory. In sensing applications, the sensitivity of the proposed structure is about 1.1?×?10³ nm/RIU and its figure of merit is as high as 2?×?10⁵ at λ?=?980 nm, which is due to the sharp asymmetric Fano line-shape with an ultra-low transmittance at this wavelength. This plasmonic structure with such high figure of merits and footprints of only about 0.2 μm² may find important applications in the on-chip nano-sensors.     

Super-Resolution Long-Depth Focusing by Radially Polarized Light Irradiation Through Plasmonic Lens in Optical Meso-field

In this paper, we propose a novel plasmonic lens design consisting of an annular slit and concentric grooves. The simulation results show that under radially polarized illumination, a super-resolution long depth of focus (DOF) spot can be achieved in optical meso-field due to the constructive interference of scattered light by the concentric grooves. We also analyze the influence of depth-tuned annular grooves on focusing performance, including focal length, DOF, and full-width half-maximum. Moreover, focusing efficiency can be enhanced (～350 %) by introducing a circular metallic grating which surrounds the annular slit. This plasmonic lens has potential applications in nano-imaging and nano-photolithography.     

Tunable Extraordinary Optical Transmission in a Metal Film Perforated with Two-Level Subwavelength Cylindrical Holes

We propose a novel plasmonic metal structure composed of a silver film perforated with a two-dimensional square array of two-level cylindrical holes on a silica substrate. The transmission properties of this structure are theoretically calculated by the finite-difference time-domain (FDTD) method. Double-enhanced transmission peaks are achieved in the visible and infrared regions, which mainly originate from the excitation of localized surface plasmon resonances (LSPRs), the hybridization of plasmon modes, and the optical cavity mode formed in the holes. The enhanced transmission behaviors can be effectively tailored by changing the geometrical parameters and dielectric materials filled in the holes. These findings indicate that our proposed structure has potential applications in highly integrated optoelectronic devices.     

Investigating the Characteristics of a Double Circular Ring Resonators Slow Light Device Based on the Plasmonics-Induced Transparency Coupled with Metal-Dielectric-Metal Waveguide System

We have numerically investigated an analog of electromagnetically induced transparency (EIT) in a metal-dielectric-metal (MDM) waveguide bend. The geometry consists of two asymmetrical stubs extending parallel to an arm of a straight MDM waveguide bend. Finite-difference time-domain simulations show that a transparent window is located at 1550 nm, which is the phenomenon of plasmonic-induced transparency (PIT). Signal wavelength is assumed to be 820 nm. The velocity of the plasmonic mode can be largely slowed down while propagating along the MDM bends. Multiple-peak plasmon-induced transparency can be realized by cascading multiple cavities with different lengths and suitable cavity-cavity separations. Large group index up to 73 can be obtained at the PIT window. Our proposed configuration may thus be applied to storing and stopping light in plasmonic waveguide bends. In addition, the relationship between the transmission characteristics and the geometric parameters including the radius of the nano-ring, the coupling distance, and the deviation length between the stub and the nano-ring is studied in a step further. The velocity of the plasmonic mode can be largely slowed down while propagating along the MDM bends. For indirect coupling, formation of transparency window is determined by resonance detuning, but, evolution of transparency is mainly attributed to the change of the coupling distance. Theoretical results may provide a guideline for control of light in highly integrated optical circuits. The characteristics of our plasmonic system indicate a significant potential application in integrated optical circuits such as optical storage, ultrafast plasmonic switch, highly performance filter, and slow light devices.     

Broadband Plasmon-Induced Transparency in Plasmonic Metasurfaces Based on Bright-Dark-Bright Mode Coupling

Plasmon-induced transparency (PIT), an analog of electromagnetically induced transparency, originates from destructive interference of plasmonic resonators with different quality factors and brings about the extreme dispersion within the narrow transparency window, promising remarkable potential for slow light, nonlinear optics and biochemical sensors. However, sometimes a broad transmission frequency band is more desirable for other applications such as bandpass filters. In general, strong coupling between bright and dark plasmon modes in coupled resonant systems leads to wide transparency bandwidth at the PIT resonance. Based on multi-oscillator coupling theory, a metasurface structure consisting of three perpendicularly connected metallic nanobars is purposefully designed and numerically demonstrated to support broadband PIT spectral response. The near-field patterns indicate that the broadening of the transparent band results from the constructive interference of dual excitations of the single non-radiative (dark) resonator by the two radiative (bright) antennas. These results show that this scheme of bright-dark-bright mode coupling is significantly beneficial for designing filters operating over a broad frequency range.

     

Enhancing LSPR Sensitivity of Au Gratings through Graphene Coupling to Au Film

A particular interesting plasmonic system is that of metallic nanostructures interacting with metal films. As the localized surface plasmon resonance (LSPR) behavior of gold nanostructures (Au NPs) on the top of a gold thin film is exquisitely sensitive to the spacer distance of the film-Au NPs, we investigate in the present work the influence of a few-layered graphene spacer on the LSPR behavior of the NPs. The idea is to evidence the role of few-layered graphene as one of the thinnest possible spacer. We first show that the coupling to the Au film induces a strong lowering at around 507 nm and sharpening of the main LSPR of the Au NPs. Moreover, a blue shift in the main LSP resonance of about 13 nm is observed in the presence of a few-layered graphene spacer when compared to the case where gold nanostructures are directly linked to a gold thin film. Numerical simulations suggest that this LSP mode is dipolar and that the hot spots of the electric field are pushed to the top corners of the NPs, which makes it very sensitive to surrounding medium optical index changes and thus appealing for sensing applications. A figure of merit of such a system (gold/graphene/Au NPs) is 2.8, as compared to 2.1 for gold/Au NPs. This represents a 33 % gain in sensitivity and opens-up new sensing strategies.     

Ultra-thin Semiconductor/Metal Resonant Superabsorbers

The design of thin-film semiconductor absorbers is a long-sought-after goal of crucial importance for optoelectronic devices. We propose a new strategy that achieves multi-band optical absorption in an ultra-thin semiconductor-insulator-metal nanostructure. The whole thickness of the absorber is just 60 nm, which is less than λ/12. The ultra-thin semiconductor resonators are used as the photonic coupling elements. The plasmonic metal layer with the thickness about 15 nm simultaneously acts as the transmission cancel layer and the plasmon source for resonant coupling with the optical near-field energy. The combined semiconductor resonators and the thin metal film produce strong electromagnetic field coupling and confinement effects, which mainly contribute to the efficient light trapping for the multi-band strong light absorption. The semiconductors such as Si, GaAs, and Ge are confirmed with the capability to show high light absorption via this simple hybrid metal-semiconductor resonant system. These features pave new insight on ultra-thin semiconductor absorbers and hold potential applications for optoelectronics such as nonlinear optics, hot-electron excitation and extraction, and the related devices.

     

Annealing Process in the Refurbishment of the Plasmonic Photonic Structures Fabricated Using Colloidal Gold Nanoparticles

Solution-processible fabrication techniques have been demonstrated with promising features for realizing different types of plasmonic devices, which combine interference lithography, spin-coating of the colloidal gold nanoparticles, and subsequent annealing process at a temperature of 200–300 °C. However, the resultant device needs to be improved in the following considerations: (1) The photoresist master grating needs to be removed for the applications in optoelectronic or sensor devices and (2) each lattice site of the photonic crystals is still composed of closely contacted gold nanoparticles. Actually, these metallic photonic structures can be refurbished through a further annealing process. Using an annealing temperature above 450 °C, we have successfully removed the remaining photoresist and make the gold nanoparticles join into a solid homogenous unit on each lattice site after being fully molten. Thus, high-quality gold nanostructures with excellent plasmonic response can be obtained. This accomplished an improved recipe for the solution-processible fabrication of plasmonic nanostructures. The corresponding devices with improved optical properties become more suitable for biosensors and optoelectronic devices.     

Extraordinary Optical Transmission Performances of Nanosandwiched Grating for Wideband Multi-Function Integration

In this paper, we present a peculiar metal-dielectric-metal (MDM) nanosandwich grating structure that can achieve extraordinary optical transmission performances at normal incidence in the ultraviolet-visible-near infrared (UV-VIS-NIR) regions. The proposed structure shows three obvious spectrum characteristics: it can obtain high transmittance up to 80 % in NUV region and efficiently blocking visible wavelengths for transverse-magnetic (TM) polarized incidence; a broadband NIR polarizer can be inspired in the wavelength range from 950 to 1400 nm; more surprisingly, these performances do not deteriorated until 30° tilting angle. Compared to other grating structures with single metal overlayer, it shows wider band-stop characteristics and higher broadband transmission transmittance and extinction ratio (ER) in the investigated wavebands. We analyze the underlying physical mechanism by using numerical simulation, which is primarily attributed to metal ultraviolet transparency, surface plasmon polariton (SPP) at metal/dielectric interface, Fabry–Perot (FP)-like cavity mode within this dielectric grating, and optical magnetic resonance especially in the dielectric interlayer of the MDM sandwiched structure. This structure is very important for developing high-performance subwavelength multifunctional integrated optical devices.     

Magneto-optical Studies of Noble Metal-Magnetic Dielectric Systems

The extraordinary optical transmission and Faraday effects of the bilayer heterostructure consisting of a metallic film perforated with subwavelength hole arrays and a uniform dielectric film magnetized perpendicular to its plane were systematically studied by three-dimensional finite-difference time-domain method. Results of the calculation found that for the magneto-plasmonic crystals under polarized incident light with transverse magnetic mode, the resonant transmittance reached 36.9%, the Faraday rotation acquired 1.216°, and the ellipticity got a positive value of 0.840. The value of Faraday rotation and ellipticity is respectively 15.2 and 93.3 times enhancement of the 0.08° and ?0.009 of the bare BIG film at the wavelength. In the transverse electric mode, the Faraday effects of the systems also had a large enhancement in contrast to the bare magnetic film. The magneto-optical effects of the systems could be manipulated by polarization mode of incident light, geometry of perforated subwavelength hole arrays, and thickness of metallic and magnetic films. Evolution of the magneto-optical properties on the structural parameters was also analyzed. Possible mechanisms underlying the extraordinary phenomena were profoundly discussed. All these results indicated that the systems could find potential applications in magneto-optical devices such as data storages, sensors, and telecommunications.     

Plasmonic Ladder-Like Structure for NIR Polarizer

Polarization-dependent light transmission property is investigated in two-dimensional plasmonic ladder-like structure in the Near-infrared (NIR) regime of 900 to 1600 nm. The plasmonic ladder-like structures are fabricated using cost-effective laser interference lithography. Optical transmission studies reveal that in the stated NIR regime, the structure has nearly 30 % absolute transmission with respect to air when the long axis is aligned parallel to the polarization axis of the incident excitation and has negligible transmission at the crossed polarization state. The findings have potential implications in designing large area flat NIR polarizers.     

Tunable Plasmonically Induced Transparency with Asymmetric Multi-rectangle Resonators

Plasmonically induced transparency (PIT) effect in a metal–insulator–metal waveguide coupled to asymmetric multi-rectangle resonators is investigated numerically. By adjusting parameters of resonators, we cannot only realize single, double, or treble PIT peaks in the compact structure, but also induce an off-to-on PIT optical response. Numerical simulation by finite element method was conducted to verify our designs. This proposed structure, hence has potential applications for ultra-compact optoelectronic devices at communication band.

     

High‐Performance,Transparent, Dye‐Sensitized Solar Cells for See‐Through Photovoltaic Windows

Dye‐sensitized solar cells (DSCs) have attracted great interest as one of the most promising photovoltaic technologies, and transparent DSCs show potential applications as photovoltaic windows. However, the competition between light absorption for photocurrent generation and light transmittance for obtaining high transparency limits the performance of transparent DSCs. Here, transparent DSCs exhibiting a high light transmittance of 60.3% and high energy conversion efficiency (3.66%) are reported. The strategy is to create a cocktail system composed of ultraviolet and near‐infrared dye sensitizers that selectively and efficiently harvest light in the invisible or low‐eye‐sensitivity region while transmitting light in high‐eye‐sensitivity regions. This new design provides a reasonable approach for realizing high efficiency and transparency DSCs that have potential applications as photovoltaic windows.     

Simultaneous Excitation of Surface Plasmon Polaritons on Both Interfaces in an Asymmetric Dielectric-Metal Corrugated Structure

The simultaneous excitation of plasmon polaritons on both surfaces of metal film was studied for asymmetric dielectric-metal-dielectric corrugated structures. Due to the small resonant absorption of the incident light on the transmission side of the structure, we investigated the enhancement of the surface plasmon polaritons on the mentioned side by controlling the structure parameters. When the illuminate light changes from normal incidence to non-normal incidence, the resonant absorption peak splits into a doublet. The simultaneous excitation of surface plasmon polaritons on both surfaces of the metal film can be achieved by controlling the incident angle. Since the wave vector matching condition is not satisfied, there is no coupling between the plasmon polaritons modes on the two surfaces of the corrugated metallic film. The excitation and control of the non-coupled surface plasmon polartions simultaneously propagating on the different interfaces of one metallic film have potential applications for designing novel compact and tunable nano-photonic devices at visible frequency.     

Tunable Omnidirectional Broadband Band-Stop Filter in Symmetric Hybrid Plasmonic Structures

We numerically investigate a symmetric hybrid waveguide-plasmon system composed of a periodic metallic nanowires pairs array embedded in symmetric dielectric sandwich layers for band-stop filtering in the optical frequency range. The proposed symmetric system shows an omnidirectional broadband absorption enhancement with flat band-stop transmission induced by the coupling and hybridization of photonic and plasmonic modes. The transmission stop band bandwidth ranging from 80 to 585 nm is observed. The bandwidth of the proposed system can be further manipulated by tailoring their geometrics for potential applications in plasmonic-assisted broadband optical filtering.