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1.
Nutrients in pore waters from Dead Sea sediments   总被引:2,自引:1,他引:1  
Pore waters were separated from 50 cm-long cores of Dead Sea sediments raised from waters depths of 25, 30 and 318 m. The salinity of the pore water is close to that of the overlying water at 225–230 g l–1 chloride. The titration alkalinity of the pore water is about 60 % of the overlying water, and sulfate is also depleted. Ammonia and phosphate concentrations are higher than those of the water column with up to 50 mg l–1 N-NH3 (ten times increase) and 350 µg l–1 P-PO inf4 sup3– (four to eight times increase). Early diagenetic reactions are a result of decomposition of organic matter and of water-sediment interactions, resulting in aragonite precipitation, phosphate removal to the sediments, probably by absorption on iron-oxyhydroxides followed by remobilization, reduction of sulfate and formation of iron sulfides and accumulation of ammonia. Mass balance calculations show that pore water contribute about 80% of the ammonia and 30% of the phosphate input into the Dead Sea water column. On the other hand, the sediments act as a sink for carbonate and sulfate.  相似文献   

2.
The distribution of dissolved reactive phosphate, nitrate and nitrite in the waters as well as total organic carbon, total phosphorus and Kjeldahl nitrogen in the sediments of the Shatt al-Arab Estuary and the NW Arabian Gulf were studied from November 1979 to April 1980. The Shatt al-Arab waters contain 0.18 to 0.70 µg-at P-PO inf4 sup3– l–1, 26.12 to 52.39 µg-at N-N0 inf3 sup– l–1 and 0.53 to 0.70 µg-at N-NO inf2 sup– l–1, indicating that this river should be considered a source of nutrients to the Arabian Gulf. It is concluded that most of the nitrate is supplied in dissolved form, while an appreciable amount of phosphate is absorbed to fine suspended particles and released at higher salinities. Total organic carbon in surficial sediments was found to vary between 0.14% and 0.96%. These rather low values are attributed to dilution by dust fallout, which is a major cource of sediments in this area.  相似文献   

3.
Abstract. Changes are described in aquatic vegetation in oligotrophic, groundwater-fed Rhine floodplain streams in Alsace (eastern France), resulting from disturbance. Disturbance factors include changes in nutrients, either permanent ones - effluent from a waste water treatment plant or trout hatcheries - or periodic ones: flooding. Regular inputs of high levels of phosphate and ammonia modified the macrophyte vegetation in these streams. The floristic composition, which was characteristic of oligotrophic waters upstream of the eutrophicated sector, changed to that of a eutrophic situation as originally found downstream. Periodic disturbance by floods which normally occur once a year, irregularly eutrophicates the small streams, causing the development of a mixture of eutrophic and oligotrophic species. Six macrophyte communities are distinguished, indicating different trophic levels. The aquatic vegetation is adapted to the variations of phosphate and ammonia levels. Hence, aquatic macrophytes can be used as bio-indicators of fluctuations in water nutrient levels in relation to the type of disturbance.  相似文献   

4.
Solute, nutrient and bacterial inputs to the River Rhône from the interstitial habitat of a gravel bar and the floodplain aquifer were investigated during an artificial drought. Eight springs were investigated: four groundwater-fed springs in the floodplain, located at the bottom of the bank; and four interstitial-fed springs located at the downstream end of a gravel bar. During this period, the inflows of groundwater to the river represented an average input of 0.77 mg l–1 of nitrogen (of which 93.3% were nitrates), 0.0187 mg l–1 of total phosphorus (of which 42.2% was orthophosphate), 3.56 mg l–1 of silica, 2.315 ± 0.703 mg l–1 of dissolved organic carbon (DOC, of which 47% was biodegradable) and 7.3 × 104 ± 3.7 × 104 bacteria per ml (of which 8.8% were active). Silica, DOC, biodegradable DOC, and bacteria concentrations displayed temporal variations during the study, which seem to be linked to the biological activity of the groundwater biofilm. There was a strong heterogeneity between the two types of groundwater that flow to the river: concentrations of calcium and alkalinity were higher in bank springs than in gravel bars springs. In these latters, sulfate, sodium, nitrogen, phosphorus were significantly higher.  相似文献   

5.
Hydrological and chemical structures off the Rhône River estuary resulting from the introduction of the river flow into the Mediterranean Sea are described. The effect of the fresh-water/sea-water interface on the distribution of inorganic and organic matter off the Rhône river is investigated. Strong vertical gradients of inorganic and dissolved organic matter such as lipids characterized the first few meters in this area (from 83.7 to 0.6 N-NO3 µgat l–1, from 6.39 to 0.92 N-NH4 µgat l–1 and from 299 to 73 µg l–1 of total dissolved lipids). At the interface, substantial increases of particulate organic (PON: from 45 µg l–1 at surface to 118 µg l–1 at the interface, POC: from 462 to 876 µg l–1, total particulate lipids: from 33 to 648 µg l–1) and suspended matter in general (from 18 to 22.2 mg l–1) were observed. High phytoplanktonic production may account for some of this enrichment, although passive accumulation might also be involved.  相似文献   

6.
The applicability of batch respirometry, as a simple technique for monitoring off-line nitrifying activity and kinetic parameters, was evaluated using two sets of ammonia and nitrite concentrations. The O2 uptake rate (OUR) profiles obtained from the assays were adjusted to a substrate inhibition model. The maximum specific ammonia-oxidizing biomass activity (rSmax) was 0.079 g N-NH4 + g VSS–1 d–1 with a half saturation coefficient (KS) of 11 mg N-NH4 + l–1 and an inhibition coefficient (Ki) of 3300 mg N-NH4 + l–1. Besides, the maximum specific value of nitrite-oxidizing activity was 0.082 g N-NO2 g VSS–1 d–1 with a KS of 4.1 mg N-NO2 l–1 and Ki of 1400 mg N-NO2 l–1.  相似文献   

7.
8.
The sources of groundwater and the patterns in groundwater dissolved N and DOC concentration in the floodplain of a subtropical stream (Wollombi Brook, New South Wales) were studied over a 2-year period using three piezometer transects. While the stream was generally a discharge area for regional groundwater, this source represented only a small contribution to either the water or N budget of the alluvial aquifer. Groundwater–surface water interactions appeared mostly driven by cycles of bank recharge and discharge between the stream and the alluvial aquifer. DON and NH4+ were the principal forms of dissolved N in groundwater, consistent with the primarily suboxic to anoxic conditions in the alluvial aquifer. A plume of groundwater NO3 was found at one transect where oxic conditions persisted within the riparian zone. The origin of the NO3 plume was hypothesized to be soil NO3 from the riparian zone flushed to the water table during recharge events. When present, NO3 did not reach surface water because conditions in the alluvial aquifer in the vicinity of the stream were always reduced. The concentration of groundwater DOC was variable across the floodplain and may be related to the extent of the vegetation cover. Overall, transformation and recycling of N during lateral exchange processes, as opposed to discharge of new N inputs from regional groundwater, appears to primarily control N cycling during groundwater–surface water interactions in this subtropical floodplain.  相似文献   

9.
Guérold  F.  Vein  D.  Jacquemin  G.  Pihan  J. C. 《Hydrobiologia》1995,(1):141-148
The physico-chemical characteristics and the macroinvertebrate communities of six streams draining a small granitic catchment located in the Vosges mountains (northeastern France) have been studied. Among the streams, five were affected by acidification and characterised by low pH (mean pH: 4.90 to 5.90), low HCO inf3 sup– concentrations (mean concentration: 0–16 µeq l–1) and elevated aluminium concentrations (mean concentration: 154–278 µg l–1). Only one stream was typical of waters draining granitic bedrock (mean pH: 6.90; mean aluminium concentration: 79 µg 1–1; mean HCO inf3 sup– concentration: 152 µeq l–1).The macroinvertebrates communities of the acidified streams were strongly affected compared to the non-acidified one. Richness, abundance and diversity (Shannon index) were significantly lower when acidification occurred. All the major taxonomic groups were affected, but Molluscs and Ephemeroptera were the most acid-sensitive or organisms, whereas Plecoptera and Oligochaetes were dominant. However, recolonization of acidified streams was possible during summer low flow when the global water quality slightly increased.
Résumé Les caractéristiques physico-chimiques et les peuplements de macroinvertébrés benthiques de six ruisseaux drainant un bassin versant granitique du massif vosgien ont été étudiés. Parmi les cours d'eau, cinq sont caractérisés par des faibles valeurs moyennes de pH (4.90 à 5.90), et d'alcalinité (HCO inf3 sup– : 0–16 µeq l–1) et par des concentrations moyennes en aluminium élevées (154–278 µg l–1) Seul un ruisseau apparaît typique du massif (pH: 6.90; aluminium: 79 g l–1 et HCO inf3 sup– : 152 µeq l–1).Les peuplements de macroinvertébrés des ruisseaux acidifiés sont sévèrement affectés. La richesse, l'abondance et la diversité (indice de Shannon) sont alors significativement plus faibles que dans le cours d'eau non acidifié. Tous les groupes faunistiques majeurs sont touchés, mais les Mollusques et les Ephémèroptères sont les organismes les plus sensibles à l'acidification, tandis que les Plécoptères et les Oligochètes sont dominants. Toutefois, il a été mis en évidence une recolonisation possible des rivières acidifiées par certaines espèces, durant la période d'étiage estivale quand la qualité de l'eau s'améliore.
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10.
Spatial variability in selected chemical, physical and biological parameters was examined in waters draining relatively pristine tropical forests spanning elevations from 35 to 2600 meters above sea level in a volcanic landscape on Costa Rica's Caribbean slope. Waters were sampled within three different vegetative life zones and two transition zones. Water temperatures ranged from 24–25 °C in streams draining lower elevations (35–250 m) in tropical wet forest, to 10 °C in a crater lake at 2600 m in montane forest. Ambient phosphorus levels (60–300 µg SRP L–1; 66–405 µg TP L–1) were high at sites within six pristine drainages at elevations between 35–350 m, while other undisturbed streams within and above this range in elevation were low (typically <30.0 µg SRP L–1). High ambient phosphorus levels within a given stream were not diagnostic of riparian swamp forest. Phosphorus levels (but not nitrate) were highly correlated with conductivity, Cl, Na, Ca, Mg and SO4. Results indicate two major stream types: 1) phosphorus-poor streams characterized by low levels of dissolved solids reflecting local weathering processes; and 2) phosphorus-rich streams characterized by relatively high Cl, SO4, Na, Mg, Ca and other dissolved solids, reflecting dissolution of basaltic rock at distant sources and/or input of volcanic brines. Phosphorus-poor streams were located within the entire elevation range, while phosphorus-rich streams were predominately located at the terminus of Pleistocene lava flows at low elevations. Results indicate that deep groundwater inputs, rich in phosphorus and other dissolved solids, surface from basaltic aquifers at breaks in landform along faults and/or where the foothills of the central mountain range merge with the coastal plain.  相似文献   

11.
Castillo  María M. 《Hydrobiologia》2000,437(1-3):57-69
Seasonal fluctuation in river stage strongly affects the ecological functioning of tropical floodplain lakes. This study was conducted to assess the influence of hydrological seasonality on bacterial production and abundance in two floodplain lakes of the Autana River, a blackwater river in the Middle Orinoco basin, Venezuela. Water samples for nutrient chemistry, chlorophyll a, and microbiological determinations were collected in two floodplain lakes and in the mainstem of the river during 1997–98. DOC and chlorophyll a concentrations were similar between mainstem and lake sites during high water when river and lakes were well connected but became different during the period of low water when the interaction was minimal. Higher values of bacterial production were observed in the floodplain lakes (0.62–1.03 g C l–1 h–1) compared to the mainstem sites (0.17–0.19 g C l–1 h–1) during the period of low water, while during the period of high water river and lake sites showed similar levels (0.04 g C l–1 h–1). Bacterial numbers followed bacterial production in the floodplain lakes, reaching higher numbers during the period of low water (1.41–2.40 × 106 cells ml–1). Availability of substrate and inorganic nutrients, pH, and inputs and losses of bacterial cells could be determining the observed seasonal patterns in bacterial production and abundance. The Autana lakes exhibited a strong seasonal pattern in the chemical and biological conditions, showing higher productivity during the lentic phase that lasted between 5 and 6 months.  相似文献   

12.
Denitrification is a major mechanism for nitrogen removal from nitrogen-rich waters, but it requires oxygen-poor conditions. We assessed denitrification rates in nitrate-rich but also oxygen-rich river water during its stay in a floodplain. We measured diurnal oxygen fluctuations in floodwater along the river Rhine, and carried out an experiment to assess denitrification rates during day, evening and night. Denitrification in floodwater and flooded sediment were measured, comparing activity of periphyton and sediment from agricultural grasslands and reedbeds. Floodwater along the river Rhine was oxygen-saturated (> 10 mg O2/L) during the day, but oxygen largely disappeared during the night (0.4–0.8 mg O2/L). Independent of oxygen concentrations, denitrification in surface water alone hardly occurred. In flooded sediments, however, denitrification rates were much higher (1.1–1.5 mg N m–2 h–1), particularly at dark and oxygen-poor conditions (nighttime). In the experimental jars, reedbed-periphyton bacteria achieved similar denitrification rates as bacteria in sediment, but overall periphyton denitrification was of minor importance when calculated per square meter. Apart from oxygen levels, maximum denitrification appeared to be regulated by nitrate diffusion from water into the sediment, as the maximum quantity of N denitrified in the sediment equalled the quantity of N lossed from the surface water. Assessed 24-hr denitrification rates in the flooded floodplains (c. 15 mg N m–2 d–1) were similar in grasslands and reedbeds, and were rather low compared to rates in other floodplains.  相似文献   

13.
Nitrogen fixation by periphyton and plankton was measured on the Amazon flood-plain using the acetylene reduction method calibrated with15N-N2. The average ratio (± SD) of moles C2H4 reduced per mole N2-N fixed was 3.4 ± 0.7, similar to other studies. Periphyton and plankton had high rates of light-dependent nitrogen fixation, with dark nitrogen fixation averaging 26% of the average rates in the light. The average daily (24 h) rates for periphyton nitrogen fixation in 1989 and 1990 were 1.79 and 0.51 mmol N2-N·m–2·d–1 respectively, which are comparable to summer rates in many temperate cyanobacterial assemblages. Nitrogen fixation was depressed at N03 concentrations as low as 0.5 M, and was below detection limits at concentrations of 4 M, which occurred during periods of river flooding. Planktonic nitrogen fixation rates were high (0.5–0.8 mmol N2-N·m–2·d–1) during the high-water and drainage phases of the annual hydrograph when the floodplain waters were draining towards the river (low NO3 ), but rates were undetectable (< 0.05 mmol N2-N·m–2·d–1) when there was river flooding (high NO3 ). Nitrogen fixation by periphyton and plankton in 1989–1990 accounted for approximately 8% of previously reported total annual nitrogen inputs to the floodplain at Lake Calado.  相似文献   

14.
Synopsis Ecological fish production in one parapotamal arm of the Middle Danube inland delta in Slovakia, based on 10 samplings during 5 consecutive years, ranged from 349 to 3272 (bar|x = 1066) kg ha–1 in total production (PT) and from 39 to 662 (bar|x = 204) kg ha–1 in available production (PA). Young-of-the-year fish made up an estimated 49–62% (bar|x = 54) of the PT. According to the food production/food consumption budget calculated by three different methods, less than half of the PT is of autochthonous origin, while most is from other sources. Floodplain fish production includes two components: fish originating within the floodplain and fish that are temporary immigrants. The latter component varies considerably in response to the hydrological regime. To assess the PT in riverine ecosystems, different seasons and years are needed to give realistic values.This paper is dedicated to my friend and sometime co-worker, Eugene K. Balon, at the occasion of his 65th birthday and transition to University Professor Emeritus. He was one of the first ichthyologists to undertake quantitative studies in large rivers in the late 1950's, when most fish biologists thought that fishes inhabit only the sea, lakes, reservoirs and small streams.  相似文献   

15.
The turnover times of glucose, averaged for 0–10 m in the upper waters of Lake Kinneret and measured by the addition of single or multiple concentrations of substrate, ranged from 23 to 188 hours and 1 to 87 hours respectively. Potential uptake rates (estimated as Vmax) ranged from 0.095 to 1.94 µg glucose l–1h–1, while measured uptake rates varied from 0.09 to 1.1 µg glucose l–1h–1. Concentrations of dissolved carbohydrates and glucose averaged 0.71 mg glucose equivalents l–1 and 39 µg glucose l–1 respectively. No evident relationships between glucose cycling and any fractions of dissolved organic matter, phytoplankton biomass or primary productivity were found. Turnover times were generally most rapid immediately after the decline of the spring Peridinium bloom. The respiration percentage of incorporated glucose ranged from 25% to 61% with highest values during the summer months. Respiration may be influenced by the nature of the indigenous bacterial population as well as by temperature. Daily heterotrophic glucose carbon uptake was about 9% of the photosynthetic incorporation and could provide a bacterial yield of about 7 × 104 ml–1d–1.  相似文献   

16.
Methods were developed for analyzing total organochlorine (TOCl) and total organobromine (TOBr) in different kinds of water, sediment and biological samples. Sediment samples were extracted with alkaline propanone and biological samples with a neutral propanone + water solution. Neutron activation analysis (NAA) was used for the halogen determination. The detection limits for TOCl and TOBr are respectively 5 and 0.5 µg l–1 for water (sample size 100 ml) and 0.3 and 0.1 µg g–1 dw (sample size 1 g) for sediment and biological samples. Recoveries for common organochlorine compounds were usually over 90%.TOCl concentrations measured in waters in a natural condition were below 15 µg l–1; and in polluted waters, from 100 to 500 µg l–1, and occasionally to 2000 µg l–1. TOBr concentrations were generally well below 10 µg 1–1.  相似文献   

17.
The major ion chemistry of some southern African saline systems   总被引:1,自引:1,他引:0  
J. A. Day 《Hydrobiologia》1993,267(1-3):37-59
Africa south of about 23° S has few natural athalassic lakes, saline or freshwater. South Africa, however, is rich in temporary pans, many of which are saline, while permanent saline springs occur along the coastal strip of the Namib Desert in Namibia. This paper examines the chemistry of the major ions in 67 Namibian waters, 47 of which have not previously been reported in the literature, and compares them with 66 South African waters, five of which have not previously been reported, and with saline lakes in East Africa.The highest value for total dissolved solids in South African waters was 276 g l–1 (Koekiespan, south-western Cape) and the highest for Namibian waters were 160 g l–1 (Hosabes, a small spring on a gypsous crust) and 302 g l–1 (a salt pan at Oranjemund at the mouth of the Orange River). The dominant ions in fresh waters in the region are Ca2+ and HCO inf3 /CO inf3 2– in the interior and in Namibia, and Na2+ and Cl+ on the south and east coasts. Regardless of the geochemistry of their substrata, the dominant ions in the saline waters throughout the region are Na+ and Cl. Thus differential precipitation of CaCO3 and CaSO4, as a result of evaporative concentration at high salinities, appears to be the determinant of the proportions of the major ions in these systems.The permanent springs on gypsous crusts along the coast of Namibia, although dominated by Na+ and Cl ions, contain considerable quantities of both Ca2+ and SO 4 2– ions.  相似文献   

18.
Temperature, dissolved oxygen and dissolved methane profiles were measured during autumn and summer, in a shallow floodplain lake in south-eastern Australia to determine the effects of water-column stability on methane and oxygen dynamics. The water column was well mixed in autumn. Strong thermal stratification developed in the late afternoon in summer, with top-to-bottom temperature differences of up to 6 °C. Methane concentrations in surface waters varied over a daily cycle by an 18-fold range in summer, but only by a 2-fold range in autumn. The implication of short-term temporal variation is that static chambers deployed on the water surface for short times (less than a day) in summer will significantly underestimate the diffusive component of methane emissions across the water–atmosphere interface. There was a marked diel variation in dissolved oxygen concentrations in summer, with the highest oxygen values (commonly 5–8 mg l–1) occurring in the surface waters in late afternoon; the bottom waters were then devoid of oxygen (< 0.2 mg l–1). Because of high respiratory demands, even the surface water layers could be nearly anoxic by morning in summer. The concentration of dissolved oxygen in the surface waters was always less than the equilibrium value. When the water column became thermally stratified in summer, the dissolved oxygen and methane maxima were spatially separated, and planktonic methanotrophy would be limited to a moving zone, at variable depth, in the water column. In summer the whole-wetland rates of oxygen production and respiration, calculated from long-term (5 h) shifts in dissolved oxygen concentrations over a diel period, were approximately 6–10 and 3–6 mmol m–3 h–1, respectively. These values correspond to net and gross primary production rates of 0.7–1.2 and 1.0–1.9 g C m–3 day–1, respectively.  相似文献   

19.
Despite proven utility as ecotoxicological testorganisms in marine systems, harpacticoidcopepods have not been used in freshwaterbiomonitoring. Here we assess the value ofBryocamptus zschokkei, a common member ofmeiofaunal stream communities, as a testorganism for lotic systems by measuring theeffects of copper on acute (survival ofovigerous females) and sub-lethal (offspringproduction, juvenile [i.e. naupliar andcopepodite] development times) end points. Allovigerous females survived exposure atconcentrations <180 µg Cu l–1, butat >180 µg Cu l–1, mortalityincreased with exposure times up to 72 h;seventy-two and ninety-six hour LC50s wereidentical (290 µg Cu l–1). After sixtydays, total offspring production per femaledeclined with increasing copperconcentration; no offspring were producedat 150 µg Cu l–1 and significantlyfewer offspring were produced at 100 µg Cul–1 compared with the control. In thejuvenile development tests, nauplii andcopepodites did not survive at 150 µg Cul–1, but there was no significant effecton development times at lower Cu concentrations(0–100 µg Cu l–1). Comparison oflaboratory-derived, toxicity end points withdata for B. zschokkei populations incopper-contaminated streams in south-westEngland, demonstrated that significant declinesin the number of surviving offspring closelymatched concentrations of copper across whichdeclines in field populations occurred. Theseresults indicate that B. zschokkei haspotential as an ecologically-relevant testorganism for lotic systems.  相似文献   

20.
Floodplain restoration has been advocated as a means to restore several ecological services associated with floodplains: water quality improvement, fish rearing habitat, wildlife habitat, flood control, and groundwater recharge. A history of agricultural encroachment on the lower Cosumnes River has resulted in extensive channelization and levee construction. In fall 1998, an experimental floodplain was established by breaching a levee in order to restore the connection between the main channel and its historic floodplain. In this study, we examined how effective this newly restored floodplain was at processing nitrate (NO 3 ) before reentering the main channel downstream. Two methods were used to examine nitrate loss. In December 2001, we determined denitrification potentials of the floodplain soils before seasonal flooding inundated the floodplain. Next, we conducted a series of field soil column (mesocosm) experiments from March to June 2002 to study NO 3 -N loss from the overlying water in both sandy and clayey soils and at three levels of NO 3 -N (ambient, +1 mg N l−1, +5 mg N l−1). In addition, we examined NO 3 -N loss from mesocosms with water only to determine if loss was related primarily to soil or water column processes. Denitrification potentials were highly variable ranging from 1.6 to 769 ng N2O–N cm−3 h−1. In addition, the denitrification potential was highly correlated with the amount of bioavailable carbon indicating that carbon was a limiting factor for denitrification. Nitrate-N loss rates from mesocosms ranged from 2.9 to 21.0 μg N l−1 h−1 over all treatments and all 3 months examined. Significant loss of NO 3 -N (60–93%) from the water only treatment only occurred in June when warmer temperatures and solar radiation most likely increased NO 3 -N uptake by phytoplankton. When scaled up, potential NO 3 -N loss from the restored floodplain represented 0.6–4.4% of the annual N load from the Lower Cosumnes River during a typical wet year and ~24% during a dry year. During dry water years, the effectiveness of the floodplain for reducing nitrate is limited by the amount of N supplied to the floodplain. Results from this study suggest that restored floodplains can be an effective NO 3 sink.  相似文献   

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