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1.

Purpose

The UK carbonated drinks sector was worth £8 billion in 2010 and is growing at an annual rate of 4.9 %. In an attempt to provide a better understanding of the environmental impacts of this sector, this paper presents, for the first time, the full life cycle impacts of carbonated soft drinks manufactured and consumed in the UK. Two functional units are considered: 1 l of packaged drink and total annual production of carbonated drinks in the UK. The latter has been used to estimate the impacts at the sectoral level. The system boundary is from ‘cradle to grave’. Different packaging used for carbonated drinks is considered: glass bottles (0.75 l), aluminium cans (0.33 l) and polyethylene terephthalate (PET) bottles (0.5 and 2 l).

Materials and methods

The study has been carried out following the ISO 14040/44 life cycle assessment (LCA) methodology. Data have been sourced from a drink manufacturer as well as the CCaLC, Ecoinvent and Gabi databases. The LCA software tools CCaLC v2.0 and GaBi 4.3 have been used for LCA modelling. The environmental impacts have been estimated according to the CML 2001 method.

Results and discussion

Packaging is the main hotspot for most environmental impacts, contributing between 59 and 77 %. The ingredients account between 7 and 14 % mainly due to sugar; the manufacturing stage contributes 5–10 %, largely due to the energy for filling and packaging. Refrigeration of the drink at retailer increases global warming potential by up to 33 %. Transport contributes up to 7 % to the total impacts.

Conclusions

The drink packaged in 2 l PET bottles is the most sustainable option for most impacts, including the carbon footprint, while the drink in glass bottles is the worst option. However, reusing glass bottles three times would make the carbon footprint of the drink in glass bottles comparable to that in aluminium cans and 0.5 l PET bottles. If recycling of PET bottles is increased to 60 %, the glass bottle would need to be reused 20 times to make their carbon footprints comparable. The estimates at the sectoral level indicate that the carbonated drinks in the UK are responsible for over 1.5 million tonnes of CO2 eq. emissions per year. This represented 13 % of the GHG emissions from the whole food and drink sector or 0.26 % of the UK total emissions in 2010.  相似文献   

2.

Purpose

The oft-cited waste hierarchy is considered an important rule of thumb to identify preferential waste management options and places waste prevention at the top. Nevertheless, it has been claimed that waste prevention can sometimes be less favorable than recycling because (1) recycling decreases only the primary production of materials, whereas waste prevention may reduce a combination of both primary and low-impact secondary production, and (2) waste prevention decreases the quantity of material recycled downstream and the avoided impacts associated with recycling. In response to this claim, this study evaluates the life cycle effects of waste prevention activities (WPAs) on a residential waste management system.

Methods

This life cycle assessment (LCA) contrasts the net impacts of a large residential solid waste management system (including sanitary landfilling, anaerobic digestion, composting, and recycling) with a system that incorporates five WPAs, implemented at plausible levels (preventing a total of 3.6 % of waste generation tonnage) without diminishing product service consumption. WPAs addressed in this LCA reduce the collected tonnage of addressed advertising mail, disposable plastic shopping bags, newspapers, wine and spirit packaging, and yard waste (grass).

Results and discussion

In all cases, the WPAs reduce the net midpoint and endpoint level impacts of the residential waste management system. If WPAs are incorporated, the lower impacts from waste collection, transportation, sorting, and disposal as well as from the avoided upstream production of goods, more than compensate for the diminished net benefits associated with recycling and the displaced electricity from landfill gas utilization.

Conclusions

The results substantiate the uppermost placement of waste prevention within the waste hierarchy. Moreover, further environmental benefits from waste prevention can be realized by targeting WPAs at goods that will be landfilled and at those with low recycled content.  相似文献   

3.

Purpose

The number of scrap tires generated in China has grown dramatically every year. Generation of ground rubber from scrap tires is the dominant management option in China. It is necessary to assess the environmental impacts of ground rubber production from scrap tires to provide technical advices on a cleaner production.

Methods

Production of ground rubber from recycled scrap tires consist of three steps: rubber powder preparation, devulcanization, and refining. A process life cycle assessment (LCA) of ground rubber production from scrap tires is carried out, and Eco-indicator 99 method coupled with ecoinvent database is applied to evaluate the environmental impacts of this process.

Results and discussion

During the ground rubber production stage, the impact factor of respiratory inorganic is the most serious one. Devulcanization has the highest environmental load of about 66.2 %. Moreover, improvement on the flue gas treatment contributes to a cleaner production and a more environmental-friendly process. Applying clean energy can largely reduce environmental load by about 21.5 %.

Conclusions

The results can be a guidance to reduce environmental load when producing ground rubber from scrap tires. Meanwhile, increasing energy efficiency, improving environmental protection equipment, and applying clean energy are the effective measures to achieve this goal.  相似文献   

4.

Purpose

This paper compares environmental impacts of two packaging options for contrast media offered by GE Healthcare: +PLUSPAK? polymer bottle and traditional glass bottle. The study includes all relevant life cycle stages from manufacturing to use and final disposal of the bottles and includes evaluation of a variety of end-of-life disposal scenarios. The study was performed in accordance with the international standards ISO 14040/14044, and a third-party critical review was conducted.

Methods

The functional unit is defined as the packaging of contrast media required to deliver one dose of 96 mL to a patient for an X-ray procedure. Primary data are from GE Healthcare and its suppliers; secondary data are from the ecoinvent database and the literature. A variety of end-of-life disposal scenarios are explored using both cutoff and market-based allocation. Impact assessment includes human health (midpoint) and ecosystems and resources (end point) categories from ReCiPe (H) and cumulative energy demand. Sensitivity analyses include (1) bottle size, (2) secondary packaging, (3) manufacturing electricity, (4) glass recycled content, (5) scrap rate, (6) distribution transport, (7) contrast media, and (8) choice of impact assessment method. Uncertainty analysis is performed to determine how data quality affects the study conclusions.

Results and discussion

This study indicates that the polymer bottle outperforms the glass bottle in every environmental impact category considered. Bottle components are the most significant contributors, and the vial body has the highest impacts among bottle components for both polymer and glass bottles. The polymer bottle exhibits lower impact in all impact categories considered regardless of the following: end-of-life treatment (using either cutoff or market-based allocation), bottle size, manufacturing electricity grid mix, glass recycled content, scrap rate, contrast media, distribution transport (air vs. ocean), and choice of impact assessment method. Secondary packaging can be a major contributor to impact. The polymer bottle has considerably lower impact compared to the glass bottle for all multi-pack configurations, but the comparison is less clear for single-pack configurations due to significantly higher packaging material used per functional dose, resulting in proportionally higher impacts in all impact categories.

Conclusions

The lower impacts of the polymer bottle for this packaging application can be attributed to lower material and manufacturing impacts, lower distribution impacts, and lower end-of-life disposal impacts. The results of this study suggest that using polymer rather than glass bottles provides a means by which to lower environmental impact of contrast media packaging.  相似文献   

5.

Purpose

The dairy sector covers multiple activities related to milk production and treatment for alimentary uses. Different dairy products are available in the markets, with yoghurt being the second most important in terms of production. The goal of this study was to analyse from a cradle-to-grave approach the environmental impacts and energy balance derived from the yoghurt (solid, stirred and drinking yoghurts) manufacture process in a specific dairy factory processing 100 % Portuguese raw milk.

Methods

The standard framework of life cycle assessment (LCA) was followed and inventory data were collected on site in the dairy factory and completed using the literature and databases. The following impact categories were evaluated adopting a CML method: abiotic depletion (ADP), acidification (AP), eutrophication (EP), global warming (GWP), ozone layer depletion (ODP), land competition (LC) and photochemical oxidants formation (POFP), with the energy analysis carried out based on the cumulative non-renewable fossil and nuclear energy demand (CED). A mass allocation approach was considered for the partitioning of the environmental burdens between the different products obtained since not only yoghurts are produced but also dairy fodder.

Results and discussion

The key processes from an environmental point of view were identified. Some of the potential results obtained were in line with other specific related studies where dairy systems were assessed from an LCA perspective. The production of the milk-based inputs (i.e. raw milk, concentrated and powdered milk) was the main factor responsible of the environmental loads and energy requirements, with remarkable contributions of 91 % of AP, 92 % of EP and 62 % of GWP. Other activities that have important environmental impacts include the production of the energy requirements in the dairy factory, packaging materials production and retailing. Potential alternatives were proposed in order to reduce the contributions to the environmental profile throughout the life cycle of the yoghurt. These alternatives were based on the minimisation of milk losses, reductions of distances travelled and energy consumption at retailing and household use, as well as changes to the formulation of the animal feed. All of these factors derived from light environmental reductions.

Conclusions

The main reductions of the environmental impact derived from yoghurt production can be primarily obtained at dairy farms, although important improvements could also be made at the dairy factory.  相似文献   

6.

Purpose

This paper performs a life cycle assessment study for a white wine produced in the northern part of Portugal, i.e. the white vinho verde. The purpose is to identify the environmental impacts occurring along the wine life cycle as well as the stages that mostly contribute to the environmental impact, as well as the associated causes. The stages considered include: (1) viticulture, (2) wine production (vinification to storage), (3) wine distribution and (4) bottles production.

Methods

The consumption of materials and energy, as well as the emissions to air, soil and water from the wine campaign of 2008/2009 were reported to the functional unit (0.75 l of white vinho verde). A Portuguese company that produces about 25 % of the current total production of white vinho verde supplied specific life cycle data for the stages of viticulture, wine production and distribution. SimaPro and the Ecoinvent database were used to perform the environmental assessment using CML 2001 impact methodology. A sensitivity analysis for a set of significant parameters was performed.

Results

Results show that for viticulture the contribution of each impact category is larger than 50 %. The production of bottles is the second contributor varying from about 4 % (to eutrophication) to 26 % (to acidification). Wine production and distribution are the subsequent contributors. The contribution of wine production varies between 0.6 % (to land competition) and about 13 % (from marine aquatic and sediment ecotoxicity 100a). The contribution of distribution is up to 14 % (to photochemical oxidation). Sensitivity analysis shows that significant changes are calculated for parameters as the nitrate leaching to groundwater, the emission of nitrous oxide from managed soil, and from runoff and leaching. Changes in these parameters are significant for only a few impact categories as eutrophication and global warming.

Conclusions

Viticulture is the stage with the largest relative contribution to the overall environmental impact and the bottle production is the subsequent stage. In order to improve the environmental performance of the supply chain for wine, it is necessary to optimise the dosage of fertilisers and phytosanitary products used during viticulture. The sensitivity analysis demonstrates that the most influential parameters relate with the emission of nitrogen compounds associated with the use of fertilisers.  相似文献   

7.

Purpose

Biofuels have received special research interest, driven by concerns over high fuel prices, security of energy supplies, global climate change as well as the search of opportunities for rural economic development. This work examines the production of biodiesel derived from the transesterification of crude rapeseed oil, one of the most important sources of biodiesel in Europe, paying special attention to the environmental profile-associated to the manufacture life cycle (i.e., cradle-to-gate perspective).

Methods

To do so, a Spanish company with an average annual biodiesel production of 300,000 t was assessed in detail. The Life Cycle Assessment (LCA) study covers the whole life cycle, from the production of the crude rapeseed oil to the biodiesel production and storage. The inventory data for the foreground system consisted of average annual data obtained by on-site measurements in the company, and background data were taken from databases. Seven impact categories have been assessed in detail: abiotic depletion, acidification, eutrophication, global warming, ozone layer depletion, land competition, and photochemical oxidant formation. An energy analysis was carried out based on the cumulative nonrenewable fossil and nuclear energy demand as an additional impact category. Furthermore, well-to-wheels environmental characterization results were estimated and compared per ton-kilometer for the biodiesel (B100) and the conventional diesel so as to point out the environmental drawbacks and strengths of using biodiesel as transport fuel in a 28 t lorry.

Results and discussion

The results showed that the cultivation of the rapeseed was the main key issue in environmental terms (68 %–100 % depending on the category) mainly because of fertilizer doses and intensive agricultural practices required. With regard to the biorefinery production process, pretreatment and transesterification sections considerably contribute to the environmental profile mostly due to electricity and chemical requirements. Concerning the well-to-wheels comparison, using B100 derived from rapeseed oil instead of petroleum-based diesel would reduce nonrenewable energy dependence (?20 %), GHG emissions (?74 %), and ozone layer depletion (?44 %) but would increase acidification (+59 %), eutrophication (+214 %), photochemical smog (+119 %), and land competition.

Conclusions

The information presented in this study could help to promote the use of renewable transport biofuels. However, the extensive implementation of biodiesel (particularly rapeseed oil-derived biodiesel) in our society is enormously complex with many issues involved not only from environmental but also economical and social points of view.  相似文献   

8.

Purpose

This life cycle assessment evaluates and quantifies the environmental impacts of renewable chemical production from forest residue via fast pyrolysis with hydrotreating/fluidized catalytic cracking (FCC) pathway.

Methods

The assessment input data are taken from Aspen Plus and greenhouse gases, regulated emissions, and energy use in transportation (GREET) model. The SimaPro 7.3 software is employed to evaluate the environmental impacts.

Results and discussion

The results indicate that the net fossil energy input is 34.8 MJ to produce 1 kg of chemicals, and the net global warming potential (GWP) is ?0.53 kg CO2 eq. per kg chemicals produced under the proposed chemical production pathway. Sensitivity analysis indicates that bio-oil yields and chemical yields play the most important roles in the greenhouse gas footprints.

Conclusions

Fossil energy consumption and greenhouse gas (GHG) emissions can be reduced if commodity chemicals are produced via forest residue fast pyrolysis with hydrotreating/FCC pathway in place of conventional petroleum-based production pathways.  相似文献   

9.

Purpose

Disposable beverage bottles made of polyethylene terephthalate (PET) stand in sharp contrast to many other disposable plastic packaging systems in the US for their high level of post-consumer recovery for recycling. This is due in part to container deposit programs in several US states, such as the California Redemption Value (CRV) program. We investigate the impacts of PET bottle recycling in the CRV program to evaluate its effectiveness at reducing environmental burdens.

Methods

We develop a life cycle model using standard process LCA techniques. We use the US LCI database to describe the energy production infrastructure and the production of primary materials. We describe the inventory and logistical requirements for materials recovery on the basis of state-maintained statistics and interviews with operators and industry representatives. We report inventory indicators describing energy, freight, and waste disposal requirements. We report several impact indicators based on CML and TRACI-2.0 techniques. We apply system expansion to compare post-consumer activities to produce secondary polymer against equivalent primary production.

Results and discussion

While bottle collection is distributed across the state, processing is more centralized and occurs primarily near urban centers. The average distance traveled by a bottle from discard to recovery is 145–175 km. Recycling requires 0.45–0.66 MJ of primary energy/L of beverage, versus 3.96 MJ during the pre-consumer phase. Post-consumer environmental impacts are significantly lower than pre-consumer impacts, with the exception of eutrophication. The results are robust to model sensitivity, with allocation of fuel for bottle collection being the most significant parameter. Curbside collection is slightly more energy efficient than consumer drop-off, and is subject to smaller parametric uncertainty. Recycling has the potential for net environmental benefits in five of seven impact categories, the exceptions being smog (marginal benefits) and eutrophication (increased impacts).

Conclusions

California’s decentralized program for collecting and processing PET bottles has produced a system which generates a large stream of post-consumer material with minimal environmental impact. The selection of a reclamation locale is the most significant factor influencing post-consumer impacts. If secondary PET displaces primary material, several environmental burdens can be reduced.

Recommendations and perspectives

Our results suggest that deposit programs on disposable packaging are an effective policy mechanism to increase material recovery and reduce environmental burdens. Deposit programs for other packaging systems should be considered.  相似文献   

10.

Purpose

As the debate on how to effectively link life cycle analysis (LCA) and negative externalities of the products or processes is still unsolved, an improved methodology that involves the private and social (environment) profitability to petrochemical projects in Mexico is presented. We incorporate both environmental impacts, identified through the LCA, using the eco-costs model, within a project appraisal analysis. The eco-costs are a single LCA-based indicator of environmental burden, based on the concept of marginal prevention costs, i.e. costs required to bring back the environmental degradation to a sustainable level.

Methods

The methodology was carried out in four steps. First, the potential environmental impacts (in physical units) were assessed through life-cycle assessment. Second, the marginal prevention costs of pollution (eco-costs) of impact categories were estimated. Third, since these monetary values are given for a European income level, eco-costs were adjusted to Mexican income levels (i.e., benefit transfer). Fourth, these adjusted values were used for assessing the financial viability of two petrochemical projects at two stages of installed capacity.

Results and discussion

The costs of marginal prevention (eco-costs) changed from 1.62 USD/kg of acrylonitrile in the old design to 0.926 USD/kg in the redesign. In case of vinyl chloride monomer (VCM), the eco-costs were from 16.08 USD/kg of VCM for the stage design to 1.62 USD/kg for the operational stage (ex post). The sensitivity analysis identified that only 15 % of these eco-costs, in the case of acrylonitrile, and 1.5 % for the VCM, could be incorporated to the costs of the project without affecting the profit on the investment.

Conclusions

The developed methodology was helpful to express potential environmental impacts in monetary units as financial indicators in a project appraisal. Thus, the methodology can be used to internalize the eco-costs into product prices, shifting the financial burden to firms and consumers, in order to offset the high costs of the green net national product.  相似文献   

11.

Purpose

Although the funeral market is propagating new ‘green’ alternatives and exploring innovative techniques like resomation, very little is known about the environmental impact of funerals. This research aimed to develop a benchmark of funerals, by quantifying the environmental impacts of the most common funeral techniques, i.e. burial and cremation, by identifying where the main impacts originate from and by comparing these impacts to impacts of other activities during a person’s life.

Methods

The environmental impacts of funerals were analysed by means of a life cycle assessment (LCA), based on Dutch company information, literature and expert judgements. The results were analysed per impact category but also on an aggregated level by means of shadow prices. Two sensitivity analyses were performed: one examined the high impact of cotton in funeral coffins; the other checked the results by means of another weighting method.

Results and discussion

The results showed no significant difference between the two funeral techniques in five impact categories. Burial has the lowest impact in more than half of the categories, but its impact is many times higher in the two most differing categories than for cremation. The total shadow price of burial is about 30 % higher than the shadow price of cremation, but the main cause for this difference is a highly debated category, namely land use. If the results would be considered without the shadow prices of land impact categories, burial would score 25 % lower than cremation. These results are representing average practise and may deviate on certain aspects for other countries, but as a starting point for further studies, this benchmark is well applicable.

Conclusions and recommendations

This study delivered an environmental benchmark of funerals and insights in the impacts of the individual processes, which can be used in further assessment of ’green’ funeral options. The benchmark results show that the environmental impact of funerals is largely determined by secondary processes and that the total impact can be quite small in comparison to other human activities. Besides these environmental insights, it is important to take into account social, cultural, climatic, local, economical and ethical arguments before changing policies or giving recommendations.
  相似文献   

12.

Purpose

Since the construction sector is a considerable energy consumer and greenhouse gas (GHG) producer, the EU rules strive to build nearly zero-energy buildings, by reducing the operative energy and yearning for on-site energy production. This article underlines the necessity to go beyond the energy evaluations and move towards the environmental assessment in a life cycle perspective, by comparing the impacts due to building materials and energy production devices.

Methods

We compared the operational energy impacts and those of technologies and materials carrying out a life cycle assessment (LCA; ISO 14040, ISO 14044, EN 15643–2, EN 15978) on a nearly zero-energy building (ZEB), a residential complex with 61 apartments in four buildings, situated near Milan (Italy). We consider all life cycle phases, including production, transport, building site activities, use and maintenance; the materials inventory was filled out collecting data from invoices paid, building site reports, construction drawings and product data sheets. To make the assessment results comparable, we set a functional unit of 1 m2 of net floor area in 1 year (1 m2y), upon a lifespan of 100 years. The environmental data were acquired from Ecoinvent 2.2.

Results and discussion

The results highlight the important role of the pre-use and maintenance phases in building life so that in a nearly ZEB, the environmental impacts linked to the use are no longer the major proportion: the pre-use phase accounts for 56 %, while the operative energy is only 31 % of the total. For this reason, if the environmental assessment of the case study was shrunk to the operational consumption, only one third of the impacts would be considered. The consumption of non-renewable resources after 100 years are 193,950 GJ (133.5 kWh/m2y); the GHG emissions are 15,300 t (37.8 kg of CO2?eq/m2y). In the pre-use phase, structures have the major impacts (50 %) and the load of system components is unexpectedly high (12 %) due to the ambition of on-site energy production.

Conclusions

Paying attention to the operative energy consumption seems to address to only one third of the environmental impacts of buildings: the adoption of LCA as a tool to guide the design choices could help to identify the solution which ensures the lowest overall impact on the whole life, balancing the options of reducing the energy requirements, the on-site production from renewable sources and the limitation of the impacts due to building components (simpler and more durable).
  相似文献   

13.

Purpose

Health care infection control has led to increased utilization of disposable medical devices, which has subsequently led to adverse environmental effects attributed to health care and its supply chain. In dental practice, the dental bur is a commonly used instrument that can be either reused or used once and then disposed. To evaluate the disparities in environmental impacts of disposable and reusable dental burs, a comparative life cycle assessment (LCA) was performed.

Methods

The functional unit was defined as one reusable dental bur, where the maximum instances reused was 30 (or in the case of a disposable, the equivalent functional unit would be 30 disposable dental burs). The system boundary included all cradle-to-grave aspects of both single-use and reused burs, including raw material extraction, manufacturing, packaging, distribution, reuse, and disposal. Primary data included the following: operating parameters for ultrasonic cleaning, manual cleaning, and autoclaving of the burs. The secondary data for raw material extraction and production of dental bur and packaging were obtained directly from life cycle inventory databases. Sensitivity analyses were also performed with respect to ultrasonic and autoclave loading.

Results and discussion

Findings from this research showed that when the ultrasonic and autoclave were loaded optimally, reusable burs had 40 % less of an environmental impact than burs used on a disposable basis. When the autoclave and ultrasonic were loaded to approximately two-third capacity, four environmental impact categories favored reusable burs (i.e., ozone depletion, smog, respiratory effects, exotoxicity), and four impact categories environmentally favored disposables (i.e., acidification, eutrophication, carcinogenics, and non-carcinogenics). When the autoclave and ultrasonic were loaded to approximately one-third capacity, reusable dental burs posed more negative environmental impacts in eight of nine environmental impact categories when compared to disposable burs.

Conclusions

Operational efficiency of ultrasonic and autoclave cleaning equipment should be emphasized to enhance the environmental performance of bur reuse. In fact, improper loading of the ultrasonic and autoclave can lead to greater adverse environmental impacts than if the burs were treated as disposables. The environmental and economic impacts associated with bur reuse are expected to be similar with other dental devices that are designated as disposable but are capable of being reused (e.g., scalpels, forceps).  相似文献   

14.

Purpose

This work has two major objectives: (1) to perform an attributional life cycle assessment (LCA) of a complex mean of production, the main Peruvian fishery targeting anchoveta (anchovy) and (2) to assess common assumptions regarding the exclusion of items from the life cycle inventory (LCI).

Methods

Data were compiled for 136 vessels of the 661 units in the fleet. The functional unit was 1 t of fresh fish delivered by a steel vessel. Our approach consisted of four steps: (1) a stratified sampling scheme based on a typology of the fleet, (2) a large and very detailed inventory on small representative samples with very limited exclusion based on conventional LCI approaches, (3) an impact assessment on this detailed LCI, followed by a boundary-refining process consisting of retention of items that contributed to the first 95 % of total impacts and (4) increasing the initial sample with a limited number of items, according to the results of (3). The life cycle impact assessment (LCIA) method mostly used was ReCiPe v1.07 associated to the ecoinvent database.

Results and discussion

Some items that are usually ignored in an LCI’s means of production have a significant impact. The use phase is the most important in terms of impacts (66 %), and within that phase, fuel consumption is the leading inventory item contributing to impacts (99 %). Provision of metals (with special attention to electric wiring which is often overlooked) during construction and maintenance, and of nylon for fishing nets, follows. The anchoveta fishery is shown to display the lowest fuel use intensity worldwide.

Conclusions

Boundary setting is crucial to avoid underestimation of environmental impacts of complex means of production. The construction, maintenance and EOL stages of the life cycle of fishing vessels have here a substantial environmental impact. Recommendations can be made to decrease the environmental impact of the fleet.  相似文献   

15.

Purpose

The aim of the present paper is to describe the development of a life cycle assessment study of the service of potable water supply in Sicily, Italy. The analysis considers the stages of collection, treatment and distribution of potable water through the regional network, whilst the use stage of water is not included.

Methods

The selection of a methodological pattern coherently with the requirements of an environmental label, such as the EPDs, aims at allowing comparability among different studies.

Results and discussion

The analysis shows the shares of impacts along the life cycle chain, i.e. outputs by well fields and spring groups, purification and desalination plants, water losses in the waterworks, electrical consumption of waterworks systems and impacts of network maintenance. With regard to global warming potential (GWP), the impact of purification plants represents a 6–7 % share of the total, whilst desalination is at 74 %. Water losses in the waterworks show an impact of 15–17 %; the contribution owing to electrical consumption of waterworks systems and network maintenance results to be 3 %. Desalination plants represent the major contribution to all impact categories considered.

Conclusions

In respect to management issues, the most relevant impact categories resulted to be GWP, non-renewable energy resources and water consumption. Since the results for non-renewable energy resources are strictly connected to GWP emissions, carbon footprint and water footprint can be profitably used as single-issue indicators without the risk of burden shifting in studies aiming to evaluate the impact of potable water distribution.  相似文献   

16.

Purpose

Full life cycle assessment (LCA) impacts from decommissioning have rarely been assessed, largely because few sites have been decommissioned so that the impacts of decommissioning are currently uncertain. This paper presents the results of an LCA study of the ongoing decommissioning of the Magnox power plant at Trawsfynydd in the UK. These results have been used to estimate the potential environmental impacts for the whole UK Magnox fleet of 11 reactors that will have to be decommissioned during this century.

Methods

The functional unit is defined as ‘decommissioning one Magnox power plant’. The system boundary considers all stages in the life cycle of decommissioning, including site management, waste retrieval, plant deconstruction, packaging and storage of intermediate- and low-level wastes (ILW and LLW). High-level waste, i.e. waste fuel is excluded as it was being removed from the site to be reprocessed at Sellafield. The environmental impacts have been estimated using the CML 2001 methodology. Primary data have been sourced from the Trawsfynydd site and the background from Ecoinvent.

Results and discussion

Most impacts from decommissioning are due to the plant deconstruction (25–75 %) and ILW storage and disposal (25–70 %). For the example of global warming potential (GWP), estimated at 241 kt CO2 eq./functional unit, or 3.5 g CO2 eq./kWh of electricity generated during the lifetime of the plant, 55 % of the impact is from plant deconstruction and 30 % from ILW disposal. The results for the whole UK Magnox fleet indicate that the impacts vary greatly for different sites. For example, the GWP ranges from 0.89 to 7.14 g CO2 eq./kWh. If the impacts from storage of waste fuel at Sellafield are included in the estimates, the GWP increases on average by four times. Overall, decommissioning of the UK Magnox reactors would generate 2 Mt of CO2 eq. without and 11 Mt of CO2 eq. with the waste from Sellafield. This represents 0.4 and 2 % of the total UK annual emissions, respectively.

Conclusions

The impacts of decommissioning can vary greatly at different sites depending on the amount of waste and electricity generated by the plants. Delaying decommissioning to allow the energy system to decarbonise could reduce the environmental impacts, e.g. GWP could be reduced by 50 %. The impacts could also be reduced by reducing the volume of waste and increasing recycling of materials. For example, recycling 70 % of steel would reduce the impacts on average by 34 %.  相似文献   

17.

Purpose

A life cycle assessment was conducted to determine a baseline for environmental impacts of cheddar and mozzarella cheese consumption. Product loss/waste, as well as consumer transport and storage, is included. The study scope was from cradle-to-grave with particular emphasis on unit operations under the control of typical cheese-processing plants.

Methods

SimaPro© 7.3 (PRé Consultants, The Netherlands, 2013) was used as the primary modeling software. The ecoinvent life cycle inventory database was used for background unit processes (Frischknecht and Rebitzer, J Cleaner Prod 13(13–14):1337–1343, 2005), modified to incorporate US electricity (EarthShift 2012). Operational data was collected from 17 cheese-manufacturing plants representing 24 % of mozzarella production and 38 % of cheddar production in the USA. Incoming raw milk, cream, or dry milk solids were allocated to coproducts by mass of milk solids. Plant-level engineering assessments of allocation fractions were adopted for major inputs such as electricity, natural gas, and chemicals. Revenue-based allocation was applied for the remaining in-plant processes.

Results and discussion

Greenhouse gas (GHG) emissions are of significant interest. For cheddar, as sold at retail (63.2 % milk solids), the carbon footprint using the IPCC 2007 factors is 8.60 kg CO2e/kg cheese consumed with a 95 % confidence interval (CI) of 5.86–12.2 kg CO2e/kg. For mozzarella, as sold at retail (51.4 % milk solids), the carbon footprint is 7.28 kg CO2e/kg mozzarella consumed, with a 95 % CI of 5.13–9.89 kg CO2e/kg. Normalization of the results based on the IMPACT 2002+ life cycle impact assessment (LCIA) framework suggests that nutrient emissions from both the farm and manufacturing facility wastewater treatment represent the most significant relative impacts across multiple environmental midpoint indicators. Raw milk is the major contributor to most impact categories; thus, efforts to reduce milk/cheese loss across the supply chain are important.

Conclusions

On-farm mitigation efforts around enteric methane, manure management, phosphorus and nitrogen runoff, and pesticides used on crops and livestock can also significantly reduce impacts. Water-related impacts such as depletion and eutrophication can be considered resource management issues—specifically of water quantity and nutrients. Thus, all opportunities for water conservation should be evaluated, and cheese manufacturers, while not having direct control over crop irrigation, the largest water consumption activity, can investigate the water use efficiency of the milk they procure. The regionalized normalization, based on annual US per capita cheese consumption, showed that eutrophication represents the largest relative impact driven by phosphorus runoff from agricultural fields and emissions associated with whey-processing wastewater. Therefore, incorporating best practices around phosphorous and nitrogen management could yield improvements.  相似文献   

18.

Purpose

Municipal solid waste (MSW) can be handled with several traditional management strategies, including landfilling, incineration, and recycling. Ethanol production from MSW is a novel strategy that has been proposed and researched for practical use; however, MSW ethanol plants are not widely applied in practice. Thus, this study has been conducted to analyze and compare the environmental and economic performance of incineration and ethanol production as alternatives to landfilling MSW.

Methods

The ISO 14040 life cycle assessment framework is employed to conduct the environmental impact assessment of three different scenarios for the two MSW management strategies based on processing 1 ton of MSW as the functional unit. The first scenario models the process of incinerating MSW and recovering energy in the form of process heat; the second scenario also includes the process of incinerating MSW but yields in the recovery of energy in the form of electricity; and the third scenario models the process of converting MSW into ethanol. The economic impacts of each scenario are then assessed by performing benefit-to-cost ratio (BCR) and net present value (NPV) analyses.

Results and discussion

The results from the environmental impact assessment of each scenario reveal that scenario 2 has the highest benefits for resource availability while scenario 3 is shown to be the best alternative to avoid human health and ecosystems diversity impacts. Scenario 1 has the worst environmental performance with respect to each of these environmental endpoint indicators and has net environmental impacts. The results of the economic analysis indicate that the third scenario is the best option with respect to BCR and NPV, followed by scenarios 2 and 1, respectively. Furthermore, environmental and economic analysis results are shown to be sensitive to MSW composition.

Conclusions

It appears municipalities should prefer MSW incineration with electricity generation or MSW-to-ethanol conversion over MSW incineration with heat recovery as an alternative to landfilling. The contradiction between the environmental impact assessment results and economic analysis results demonstrates that the decision-making process is sensitive to a broad set of variables. Decisions for a specific MSW management system are subject to facility location and size, MSW composition, energy prices, and governmental policies.  相似文献   

19.

Purpose

The purpose of this study was to update the average environmental impacts of global primary zinc production using a life cycle assessment (LCA) approach. This study represents the latest contribution from zinc producers, which historically established the first life cycle inventory for primary zinc production in 1998 (Western Europe) and the first global LCA-based cradle-to-gate study for zinc concentrate and special high-grade zinc (SHG; 99.99 %) in 2009. Improvements from the previous studies were realized through expanded geographical scope and range of production technologies.

Methods

The product system under study (SHG zinc) was characterized by collecting primary data for the relevant production processes, including zinc ore mining and concentration, transportation of the zinc concentrate, and zinc concentrate smelting. This data was modeled in GaBi 6 and complemented with background data from the GaBi 2013 databases to create the cradle-to-gate LCA model. Allocation was used to distribute the inputs and outputs among the various co-products produced during the production process, with mass of metal content being the preferred allocation approach, when applicable.

Results and discussion

In total, this global study includes primary data from 24 mines and 18 smelters, which cover 4.7?×?106 MT of zinc concentrate and 3.4?×?106 MT of SHG zinc, representing 36 and 27 % of global production, respectively. While the LCA model generated a full life cycle inventory, selected impact categories and indicators are reported in this article (global warming potential, acidification potential, eutrophication potential, photochemical ozone creation potential, ozone creation potential, and primary energy demand). The results show that SHG zinc has a primary energy demand of 37,500 MJ/t and a climate change impact of 2600 kg CO2-eq./t. Across all impact categories and indicators reported here, around 65 % of the burden are associated with smelting, 30 % with mining and concentration, and 5 % with transportation of the concentrate. Sensitivity analyses were carried out for the allocation method (total mass versus mass of metal content) and transportation of zinc concentrate.

Conclusions

This study generated updated LCA information for the global production of SHG zinc, in line with the metal industry’s current harmonization efforts. Through the provision of unit process information for zinc concentrate and SHG zinc production, greater transparency is achieved. Technological and temporal representativeness was deemed to be high. Geographical representativeness, however, was found to be moderate to low. Future studies should focus on increasing company participation from underrepresented regions.
  相似文献   

20.

Purpose

Manganese is a metal used extensively in everyday life, particularly in structural steel. Despite the importance of manganese as an essential alloying element in steel and stainless steel, the environmental profile of manganese alloys lacked globally representative, primary industry data. The International Manganese Institute (IMnI) and Hatch completed the first global life cycle assessment (LCA) of manganese alloy production, providing environmental benchmarks and a firm foundation of accurate data with which to inform other industry-led initiatives.

Methods

The study compiled primary data from 16 ore and alloy producers worldwide, covering 18 % of global ore production and 8 % of global alloy production for 2010. This peer-reviewed, ISO 14040 compliant LCA covers the cradle-to-gate life cycles of silicomanganese, ferromanganese, and refined ferromanganese. The study provides a comprehensive picture of global environmental performance, quantifying energy consumption, global warming potential (GWP), acidification potential (AP), photochemical ozone creation potential (POCP), primary water use, and primary waste generation. A novel model architecture was devised to generate process, site, and cradle-to-gate LCAs for single and multiple sites simultaneously, extracting greater value from the LCA process by facilitating environmental and operational benchmarking within the industry.

Results and discussion

The results of the study show that total GWP, AP, and POCP for 1 kg of average manganese alloy was 6.0 kg CO2e, 45 g SO2e, and 3 g C2H4e, respectively. Electricity demand and coal and coke consumption during smelting are the dominant operating parameters contributing to environmental performance. On-site air emission measures (GWP, POCP, NOX, and particulate matter (PM)) contributed 25 to 35 % of total life cycle emissions. Overburden and waste rock were the most significant primary solid waste flows by mass. The study provides a resource for improvement at the global industry and site scales by establishing benchmarks, identifying hotspots, and quantifying the benefits of efficiency savings through process optimization.

Conclusions

This LCA provides accurate primary data to improve steel and stainless steel product LCAs and communicate the environmental performance of the industry in quantitative terms. It facilitates dialogue between manganese producers and consumers through a shared understanding of the environmental profile of the industry. Through leveraging the study to identify hotspots within the manganese supply chain, producers can work both independently and collectively towards improving the environmental and economic performance of manganese alloys.
  相似文献   

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