Molecular dynamics simulation of single discharge and dimensionless correlation with actual material removal in micro electrical discharge machining

Shorter time pulses and length scales in micro EDM (MEDM) makes it difficult to observe the material removal phenomena taking place at very small zone during discharge. Since numerical or analytical model considers material to be uniform/isotropic, it cannot predict the discrete effects viz. crystal structure distortion due to discharge. Also, little attention has been given to the mechanism of material removal in MEDM at the atomistic level. Therefore, to understand the behaviour of material removal and crystal structure distortion due to single spark in MEDM, MD simulations have been carried out. Based on MD simulations, it was found that the percentage of material removed by vaporisation (～40%) was higher at spark energies used in this model as compared to spark energies used by Wong et al. (20% at 23.50 µJ). Conversion from FCC crystal structure to amorphous was observed at the top surface of crater in both cases; the one with higher spark energy has marginally higher distortion indicating higher amorphisation. A new method is proposed based on which a dimensionless correlation was obtained between results of MDS and experiments which relates the ratio of specific material removal at higher spark energy to that at lower energy for both MDS and experiments.     

Material flow analysis (MFA) of an eco-economic system:a case study of Wujin District,Changzhou,China

The economic and ecological aspects of a social system are coherently linked and can be examined by its material and energy flows.In this study,we used the material flow analysis (MFA) to model the material input and output of the Wujin District of Changzhou City,Jiangsu Province in China.It was revealed that:(1) total material input and material input per capita increased with economic development,while the total material out-put and material output per capita decreased consistently;(2) except for water,the total material input continued to increase.Input of solid materials grew faster than that of gaseous materials,while the total material output declined.The gas output accounted for the largest pro-portion of the output resulting in primary environmental pollution as burned fossil fuel; (3) water use in agriculture continued with an increasing trend while that in industrial and residential sectors decreased per capita.The total wastewater discharge and wastewater discharge per capita decreased with a faster decreasing rate of residential was-tewater discharge followed by industrial wastewater dis-charge; (4) material input per unit GDP fluctuated and material output per unit GDP decreased.A decreasing trend in both water use and wastewater discharge per unit GDP was disclosed.These results suggest that the effi-ciency of resource use in the Wujin District has improved.This weakened the direct link between economic develop-ment and environmental deterioration.Additionally,we discussed the harmonic development between environ-ment and economy.Potential limitations of MFA's application were also discussed.It is suggested that effec-tive measures should be taken for the enforcement of cir-cular economic strategies and the construction of a resource-saving economy     

Material flow analysis (MFA) of an eco-economic system: a case study of Wujin District, Changzhou, China

The economic and ecological aspects of a social system are coherently linked and can be examined by its material and energy flows. In this study, we used the material flow analysis (MFA) to model the material input and output of the Wujin District of Changzhou City, Jiangsu Province in China. It was revealed that: (1) total material input and material input per capita increased with economic development, while the total material output and material output per capita decreased consistently; (2) except for water, the total material input continued to increase. Input of solid materials grew faster than that of gaseous materials, while the total material output declined. The gas output accounted for the largest proportion of the output resulting in primary environmental pollution as burned fossil fuel; (3) water use in agriculture continued with an increasing trend while that in industrial and residential sectors decreased per capita. The total wastewater discharge and wastewater discharge per capita decreased with a faster decreasing rate of residential wastewater discharge followed by industrial wastewater discharge; (4) material input per unit GDP fluctuated and material output per unit GDP decreased. A decreasing trend in both water use and wastewater discharge per unit GDP was disclosed. These results suggest that the efficiency of resource use in the Wujin District has improved. This weakened the direct link between economic development and environmental deterioration. Additionally, we discussed the harmonic development between environment and economy. Potential limitations of MFA’s application were also discussed. It is suggested that effective measures should be taken for the enforcement of circular economic strategies and the construction of a resource-saving economy __________ Translated from Acta Ecologica Sinica, 2006, (8): 2578–2586 [译自:生态学报]     

Numerical simulation of a surface barrier discharge in air

The development of a surface barrier discharge in air at atmospheric pressure under the action of a constant voltage of different polarity is simulated numerically. When the polarity of the high-voltage electrode is negative, the discharge develops as an ionization wave that moves along the dielectric surface. When the polarity is positive, the discharge develops as a streamer that first moves above the dielectric surface and then comes into contact with and continues to develop along it. In the case of a high-voltage electrode of positive polarity, the discharge zone above the dielectric surface is approximately five times thicker than that in the case of negative polarity. The characteristic aspects of numerical simulation of the streamer phase of a surface barrier discharge are discussed. The numerical results on the density of the charge stored at the dielectric surface and on the length of the discharge zone agree with the experimental data.     

Reducing Life Cycle Environmental Impacts of Waste Electrical and Electronic Equipment Recycling

Collection and treatment of waste from electrical and electronic equipment (WEEE) is regulated in the European Union by the WEEE Directive. Producers are responsible for take‐back and recycling of discarded equipment. Valuable materials are, however, at risk of “getting lost” in current processes. Thus, strategies to minimize losses are sought after. The material hygiene (MH) concept was introduced to address this issue. Structural features, which are important for the outcome of reuse, recovery, and recycling, were investigated in an earlier field study of discarded dishwashers. It was proposed that a prestep, manual removal of copper prior to shredding could increase the purity of recovered material fractions. This article builds on the field study and theoretical reasoning underlying the MH concept. Dishwashers are assumed to be designed for disassembly when the prestep is introduced. A limited life cycle assessment was performed to determine whether the proposed prestep may be environmentally beneficial in a life cycle perspective. Two alternatives were analyzed: Case 1: the current shredding process. Case 2: prestep removal of copper before shredding. Targeted disassembly prior to shredding may reduce the abiotic depletion and global warming potential in a life cycle perspective. The prestep results in increased copper recovery, but, more important, copper contamination of the recovered steel fractions is reduced. The results also highlight the importance of minimizing energy consumption in all process stages.     

Study of the contributions of the electrode materials to the plasma of a high-current vacuum spark

The contribution of the electrode material to the formation of the plasma of a low-inductive high-current vacuum spark and its influence on the process of discharge micropinching were studied using X-ray spectroscopy and laser diagnostics. Electrode system configurations are determined in which the contributions of the materials of both electrodes to the plasma emitting X-rays are comparable and in which the contribution of one electrode is dominating. It is found that discharge pinching occurs primarily in the vapor of the pointed electrode independently of its polarity. The experimental results indicate the formation of a suprathermal electron beam in the micropinch region.     

基于物质流分析方法的生态海岛建设研究——以长海县为例

建设生态海岛是海岛生态经济系统实现可持续发展的重要途径。运用物质流分析方法对长海县的物质输入与输出状况进行计算,并用物质消耗强度、废物排放强度和环境负荷强度3个指标衡量了该海岛县生态效率的变化,分析了技术进步对海岛生态经济系统生态压力变化的贡献状况。结果表明,2003—2009年间,长海县物质输入总量、物质输出总量和环境负荷总量呈增长态势;生态效率明显提高;技术进步对减轻海岛生态经济系统生态压力的贡献没有抵消经济增长所产生的生态压力的增加量。为了减少物质输入和废物输出,减轻经济活动对海岛生态系统产生的压力,建立创新型管理机制有效促进技术进步,不断提高生态效率具有特别重要的作用。     

Biological nutrients removal from the supernatant originating from the anaerobic digestion of the organic fraction of municipal solid waste

Abstract

This study critically evaluates the biological processes and techniques applied to remove nitrogen and phosphorus from the anaerobic supernatant produced from the treatment of the organic fraction of municipal solid waste (OFMSW) and from its co-digestion with other biodegradable organic waste (BOW) streams. The wide application of anaerobic digestion for the treatment of several organic waste streams results in the production of high quantities of anaerobic effluents. Such effluents are characterized by high nutrient content, because organic and particulate nitrogen and phosphorus are hydrolyzed in the anaerobic digestion process. Consequently, adequate post-treatment is required in order to comply with the existing land application and discharge legislation in the European Union countries. This may include physicochemical and biological processes, with the latter being more advantageous due to their lower cost. Nitrogen removal is accomplished through the conventional nitrification/denitrification, nitritation/denitritation and the complete autotrophic nitrogen removal process; the latter is accomplished by nitritation coupled with the anoxic ammonium oxidation process. As anaerobic digestion effluents are characterized by low COD/TKN ratio, conventional denitrification/nitrification is not an attractive option; short-cut nitrogen removal processes are more promising. Both suspended and attached growth processes have been employed to treat the anaerobic supernatant. Specifically, the sequencing batch reactor, the membrane bioreactor, the conventional activated sludge and the moving bed biofilm reactor processes have been investigated. Physicochemical phosphorus removal via struvite precipitation has been extensively examined. Enhanced biological phosphorus removal from the anaerobic supernatant can take place through the sequencing anaerobic/aerobic process. More recently, denitrifying phosphorus removal via nitrite or nitrate has been explored. The removal of phosphorus from the anaerobic supernatant of OFMSW is an interesting research topic that has not yet been explored. At the moment, standardization in the design of facilities that treat anaerobic supernatant produced from the treatment of OFMSW is still under development. To move toward this direction, it is first necessary to assess the performance of alternative treatment options. It study concentrates existing data regarding the characteristics of the anaerobic supernatant produced from the treatment of OFMSW and from their co-digestion with other BOW. This provides data documenting the effect of the anaerobic digestion operating conditions on the supernatant quality and critically evaluates alternative options for the post-treatment of the liquid fraction produced from the anaerobic digestion process.     

季节性温度变化对CANON型潮汐流人工湿地脱氮的影响

探究了温度的季节性变化对基于亚硝化的全程自养脱氮(CANON)型潮汐流人工湿地(TFCW)脱氮性能及其微生物特性的影响。CANON型TFCW中的脱氮微生物群落在温度的季节性变化下会发生不同程度的改变,其脱氮途径及性能随之会出现周期性的波动。填料层温度在20.0 ℃以上时对TFCW脱氮性能及其中的优势脱氮菌群无显著影响,CANON作用是系统脱氮的主要途径。当填料层温度低于20.0 ℃时,厌氧氨氧化菌丰度与活性显著降低,在9.3~20.0 ℃时,亚硝酸盐氧化菌(NOB)的增殖及其活性的提高使TFCW中脱氮的主要途径由CANON作用演替为硝化/反硝化作用,系统对总氮(TN)的去除率仅为(34.8±13.0)%;在2.2~9.0 ℃时,TFCW中的厌氧氨氧化菌在受到抑制的同时仍保持着对NOB和反硝化菌群的相对竞争优势,系统脱氮重新依赖于CANON作用,其对TN的去除率为(54.8±4.8)%。该研究可为CANON型TFCW工艺的优化及工程化应用提供参考。     

Material Flow Indicators in the Czech Republic in Light of the Accession to the European Union

This article deals with the economy‐wide material flows in the Czech Republic in 1990–2006. It presents in brief the overall trends of the material flow indicators in 1990–2002. The major part of the article is focused on the years 2002–2006, which immediately preceded and followed the accession of the Czech Republic to the European Union in 2004. It is shown that this accession had quite a significant impact on the volume and character of the material flows of the Czech Republic. The accession was beneficial from an economic point of view, as it allowed for an increased supply of materials needed for economic growth. Furthermore, it was accompanied by an improvement in the efficiency of material transformation into economic output. From an environmental and broader sustainability point of view, however, this accession brought about some controversial outcomes. There was a significant increase in the net export of environmental pressure, on one hand, and an increase in net additions to the physical stock of the economy, on the other. Although the former is controversial from the viewpoint of equity in sharing area and resources, the latter places an additional burden on future generations because all physical stocks will turn into waste and emissions at some point, when their life span expires.     

Influence of Electrical Resistivity and Machining Parameters on Electrical Discharge Machining Performance of Engineering Ceramics

Engineering ceramics have been widely used in modern industry for their excellent physical and mechanical properties, and they are difficult to machine owing to their high hardness and brittleness. Electrical discharge machining (EDM) is the appropriate process for machining engineering ceramics provided they are electrically conducting. However, the electrical resistivity of the popular engineering ceramics is higher, and there has been no research on the relationship between the EDM parameters and the electrical resistivity of the engineering ceramics. This paper investigates the effects of the electrical resistivity and EDM parameters such as tool polarity, pulse interval, and electrode material, on the ZnO/Al₂O₃ ceramic''s EDM performance, in terms of the material removal rate (MRR), electrode wear ratio (EWR), and surface roughness (SR). The results show that the electrical resistivity and the EDM parameters have the great influence on the EDM performance. The ZnO/Al₂O₃ ceramic with the electrical resistivity up to 3410 Ω·cm can be effectively machined by EDM with the copper electrode, the negative tool polarity, and the shorter pulse interval. Under most machining conditions, the MRR increases, and the SR decreases with the decrease of electrical resistivity. Moreover, the tool polarity, and pulse interval affect the EWR, respectively, and the electrical resistivity and electrode material have a combined effect on the EWR. Furthermore, the EDM performance of ZnO/Al₂O₃ ceramic with the electrical resistivity higher than 687 Ω·cm is obviously different from that with the electrical resistivity lower than 687 Ω·cm, when the electrode material changes. The microstructure character analysis of the machined ZnO/Al₂O₃ ceramic surface shows that the ZnO/Al₂O₃ ceramic is removed by melting, evaporation and thermal spalling, and the material from the working fluid and the graphite electrode can transfer to the workpiece surface during electrical discharge machining ZnO/Al₂O₃ ceramic.     

A prototype of an electric-discharge gas flow oxygen−iodine laser: I. Modeling of the processes of singlet oxygen generation in a transverse cryogenic slab RF discharge

The existing kinetic model describing self-sustained and electroionization discharges in mixtures enriched with singlet oxygen has been modified to calculate the characteristics of a flow RF discharge in molecular oxygen and its mixtures with helium. The simulations were performed in the gas plug-flow approximation, i.e., the evolution of the plasma components during their motion along the channel was represented as their evolution in time. The calculations were carried out for the O₂: He = 1: 0, 1: 1, 1: 2, and 1: 3 mixtures at an oxygen partial pressure of 7.5 Torr. It is shown that, under these conditions, volumetric gas heating in a discharge in pure molecular oxygen prevails over gas cooling via heat conduction even at an electrode temperature as low as ~100 K. When molecular oxygen is diluted with helium, the behavior of the gas temperature changes substantially: heat removal begins to prevail over volumetric gas heating, and the gas temperature at the outlet of the discharge zone drops to ~220–230 K at room gas temperature at the inlet, which is very important in the context of achieving the generation threshold in an electric-discharge oxygen?iodine laser based on a slab cryogenic RF discharge.     

基于能值和物质流的吉林省生态效率研究

为探讨生态效率计算方法,结合能值分析和物质流分析构建了生态效率表达式,并对吉林省进行实证分析.结果表明:①生态效率在17a间提高了2.9倍;②生态效率的提高使环境压力降低了205.62%,对经济增长的贡献率达63.7%;③人口增长并非环境压力升高的主要原因,资源消耗对环境压力的影响比废弃物排放更大,但其脱钩现象却弱于废弃物排放;④2000年以后,生态效率对抑制环境压力升高、促进经济增长的作用都在下降,各指标的脱钩指数也均在减小,吉林省经济发展的不可持续性在增强.研究结果在理论上有助于深化生态效率研究方法,在实践上有助于深思我国环保政策存在的缺陷,对促进吉林省可持续发展也具有一定的借鉴意义.     

Decomposition of tissue baits and termite density along a gradient of human land‐use intensification in Western Kenya

Termites are important decomposers and ‘ecosystem engineers’ in tropical ecosystems. Furthermore, termite assemblages are sensitive to human land‐use intensification and often termite density and the importance of soil‐feeding termites decrease with land‐use intensification. These changes in termite assemblages may also lead to a decrease in termite‐mediated ecosystem processes (e.g. soil formation, cellulose decomposition). We compared density and functional composition of termites with cellulose removal from undisturbed primary forests to farmlands (Kakamega Forest, Western Kenya). In contrast to the expectation, we found no response of termite abundance along the gradient of land‐use intensification. However, as expected, the relative abundance of soil‐feeders decreased from primary forests to farmlands. In contrast, frequency of attack on tissue paper baits and removal of tissue showed a clear hump‐shaped relationship to land‐use intensification with high values in secondary forests. These nonconcordant patterns of density and functional composition of termite assemblages with cellulose removal by termites suggest that it may be misleading to infer changes in a process by the characteristics of the assemblage of organisms that mediate that process.     

Transport of seston in the karstic hydrosystem of the Plitvice Lakes (Croatia)

Research into spatial and temporal variation in seston transport was carried out during the year 2000 on three reaches on the longitudinal profile of the karstic cascading system of the Plitvice Lakes in Croatia. The three investigated reaches were (i) a channel over a barrier with low gradient; (ii) flow through a deep lake; and (iii) a channel with cascades and a steep gradient. The aim of the study was to establish the influence of physiographical and hydrological differences of these reaches on the quality and quantity of seston transport and food resources in the seston. To calculate the seston transport, we measured: total suspended matter (TSM), particulate inorganic matter (PIM), particulate organic matter (POM), chlorophyll-a (chl-a), heterotrophic bacteria and discharge. The PIM contribution from TSM ranged between 60 and 90%, while the percentage of POM in TSM was the highest in summer and ranged from 33 to 46%. POM and discharge were significantly negatively correlated (r = −0.43, P < 0.05). For the transport of TSM, PIM, POM and chlorophyll-a statistically significant differences between the three reaches were established. In a principal component analysis, 86% of the variance was explained by the first two factors. The first factor corresponded well with net transport of TSM, PIM, POM and chl-a and distinguished investigated reaches in two groups: the 1^st group with increasing (reaches with low gradient and with high gradient), and the 2nd group with decreasing net seston transport (reach with flow through a deep lake). The second factor corresponded strongly with discharge and distinguished investigated reaches according to their temporal variability. Electronic Supplementary Material Supplementary material is available in the online version of this article at and is accessible for authorized users Handling editor: J. Padisak     

Evaluation of the Tire Industry of China based on Physical Input–Output Analysis

With the rapid development of the rubber industry and its downstream sectors in China, the resulting sharp increase in the number of scrap tires is creating great environmental pressure. By considering the tire production, consumption, collection, and reuse processes as a whole system of tire material flows, and based on physical input–output analysis (IOA), this article analyzes the status quo of China's tire industry and performs a comparative study between China and Europe. The study shows that the tire industry of China in 2005 and that of Europe in 1996 are similar in material‐flow characteristics. To make the best use of materials, it is necessary to strengthen the reuse of scrap tires in China. A scenario analysis is presented to show the effects of improving the reuse process from the viewpoint of IOA.     

Inhibitory factors affecting the process of enhanced biological phosphorus removal (EBPR) – A mini-review

Enhanced biological phosphorus removal (EBPR) technology has been widely considered as a key strategy in preventing eutrophication and recognized as the advancing front of research in wastewater treatment. The key to keep its high efficiency in biological phosphorus removal is to optimize the operation and management of the system. Previous research in this field has undoubtedly improved understanding of the factors hindered overall efficiency of EBPR. However, it is obvious that much remains to be learnt. This paper attempts to review the fundamental understanding in factors inhibiting the stability and reliability of the EBPR systems in the state-of-the-art research. In view of modeling the EBPR systems, an appropriate extension of the current mechanistic models with these inhibitory factors is recommended in order to better simulate and predict the behavior of full-scale and lab-scale EBPR plants. From the perspectives of the further mechanistic and multi-factors study, the direction of denitrifying dephosphatation and granules/biofilms are also discussed. This comprehensive overview will not only help us to understand the overall mechanism of the EBPR process, but also benefit the researchers and engineers to consider all the possible factors affecting the process in the urban sewage treatment plants.     

不同流态中长江江豚的栖息活动比较

长江江豚(Neophocaena asiaeorientalis)呈斑块状分布在长江干流,对栖息地有明确的选择性.流态是栖息地水文环境的核心内容.为研究长江江豚对不同流态的选择性,本文根据1993-2021年对长江下游15次样线考察记录到的412次,合计1 117头江豚个体的栖息活动进行了统计分析.结果表明:全年长江江...     

Relocalization of the calcium gradient and a dihydropyridine receptor is involved in upward bending by bulging of Chara protonemata, but not in downward bending by bowing of Chara rhizoids

The localization of cytoplasmic free calcium and a dihydropyridine (DHP) receptor, a putative calcium channel, was recorded during the opposite graviresponses of tip-growing Chara rhizoids and Chara protonemata by using the calcium indicator Calcium Crimson and a fluorescently labeled dihydropyridine (FL-DHP). In upward (negatively gravitropically) growing protonemata and downward (positively gravitropically) growing rhizoids, a steep Ca²⁺ gradient and DHP receptors were found to be symmetrically localized in the tip. However, the localization of the Ca²⁺ gradient and DHP receptors differed considerably during the gravitropic responses upon horizontal positioning of the two cell types. During the graviresponse of rhizoids, a continuous bowing downward by differential flank growth, the Ca²⁺ gradient and DHP receptors remained symmetrically localized in the tip at the centre of growth. However, after tilting protonemata into a horizontal position, there was a drastic displacement of the Ca²⁺ gradient and FL-DHP to the upper flank of the apical dome. This displacement occurred after the apical intrusion and sedimentation of the statoliths but clearly before the change in the growth direction became evident. In protonemata, the reorientation of the growth direction started with the appearence of a bulge on that site of the upper flank which was predicted by the asymmetrically displaced Ca²⁺ gradient. With the upward shift of the cell tip, which is suggested to result from a statolith-induced displacement of the growth centre, the Ca²⁺ gradient and DHP receptors became symmetrically relocalized in the apical dome. No major asymmetrical rearrangement was observed during the following phase of gravitropic curvature which is characterized by slower rates of bending. Labeling with FL-DHP was completely inhibited by a non-fluorescently labeled dihydropyridine. From these results it is suggested that FL-DHP labels calcium channels in rhizoids and protonemata. In rhizoids, positive gravitropic curvature is caused by differential growth limited to the opposite subapical flanks of the apical dome, a process which does not involve displacement of the growth centre, the calcium gradient or calcium channels. In protonemata, however, it is proposed that a statolith-induced asymmetrical relocalization of calcium channels and the Ca²⁺ gradient precedes, and might mediate, the rearrangement of the centre of growth, most likely by the displacement of the Spitzenk?rper, to the upper flank, which results in the negative gravitropic reorientation of the growth direction. Received: 13 February 1999 / Accepted: 25 June 1999