Sedimentary Residual Soil as a Waste Containment Barrier Material

Compacted soil liners are widely used as a waste containment barrier to control or restrict the migration of contaminant/leachate from the landfill into the environment because of their low hydraulic conductivity, attenuation capacity, resistance to damage or puncture, and cost effectiveness. Compacted soil liners are usually composed of natural inorganic clays or clayey soils. If natural clayey soils are not available, kaolinite or commercially available high swelling clay (bentonite) can be mixed with local soils or sand. This study examines the potential of a sedimentary residual soil as a waste containment barrier in landfills. The laboratory experiments conducted were: grain size distribution, Atterberg limits, swelling tests, compaction, volumetric shrinkage strain, unconfined compression, hydraulic conductivity and cation exchange capacity. The experimental results were compared with those recommended by various researchers for evaluation of its suitability. Test results showed that the soil compacted with modified Proctor compaction effort possesses low hydraulic conductivity (≤1 × 10^?7 cm/s) and adequate strength. In addition, compacted sedimentary residual soil exhibited little volumetric shrinkage strain of below 4% at this compaction effort. Thus, the sedimentary residual soil could be effectively used for the construction of a waste containment barrier in landfills.     

Effects of Light Crude Oil Contamination on the Physical and Mechanical Properties of Fine Sand

The use of oil-contaminated sand in building and construction is now being considered as an alternative and cost-effective way to minimize its adverse effect on the environment. To achieve this, the effect of oil contamination on the important mechanical properties of sand should be investigated first. This study investigated the effect of petroleum-derived contaminants on the water absorption, permeability, cohesion, friction angle, and shear strength of fine sand. Contaminated samples were prepared by mixing fine sand with different percentages of light crude oil (0 to 20%). The results indicated that the water absorption of fine sand decreases with an increase in crude oil. An increase in the cohesion was observed for sand with up to 1% of oil contamination, after which the cohesion began to decrease, which also results in the reduction in the permeability. A slight reduction in the friction angle was found for oil-contaminated fine sand. At a low normal stress of 50 kPa, as the percentage of light crude oil increased, the shear strength increased up to 1% of oil contamination and then it decreased. These results provided useful information on how oil-contaminated sand can be used safely and effectively in building and construction.     

Response of sulfate-reducing bacteria to an artificial oil-spill in a coastal marine sediment

In situ mesocosm experiments using a calcareous sand flat from a coastal area of the island of Mallorca in the Mediterranean Sea were performed in order to study the response of sulfate-reducing bacteria (SRB) to controlled crude oil contamination, or heavy contamination with naphthalene. Changes in the microbial community caused by the contamination were monitored by a combination of comparative sequence analysis of 16S rRNA genes, fluorescence in situ hybridization, cultivation approaches and metabolic activity rates. Our results showed that crude oil and naphthalene negatively influenced the total microbial community as the natural increase in cell numbers due to the seasonal dynamics was attenuated. However, both contaminants enhanced the sulfate reduction rates, as well as the culturability of SRB. Our results suggested the presence of autochthonous deltaproteobacterial SRBs that were able to degrade crude oil or polycyclic aromatic hydrocarbons such as naphthalene in anaerobic sediment layers.     

Further experimental investigations on the formation of plant compression fossils

Experimental work has been conducted on the formation of plant compression fossils using a simple compression apparatus in which actual plant material was compressed in wet sediment. Pressure was applied through a single perforated piston which only allowed the passage of water upwards out of the compacting sediment. Several lines of investigation were followed to establish the principal factors that dictate the form of a plant compression fossil. It is demonstrated that these include the grain size and the compressibility of the sediment, the degree of sediment fill of hollow structures within the plant organ prior to the compression, and finally the rigidity or degree of decay of the plant tissues before the deformation. The results of this work indicate that the horizontal dimensions of the plant organ change during compression. This is directly related to the compressibility of the sediment the plant was buried in; stems buried in clay matrices increased in horizontal dimensions, whereas stems buried in sand matrices underwent reductions in horizontal dimensions. This is associated with the difference in the response of these sediments to the hydrostatic stress that exists within the system during the initial stages of compaction. The results of this experimental study are used to interpret the structure and form of some plant compression fossils.     

Effect of Bentonite on Compacted Clay Landfill Barriers

Compacted clay barriers (liner and cap) are one of the most important components of municipal waste landfills. On-site soils are generally used to construct the clay barriers as long as they can be compacted to standard specifications, including hydraulic conductivity. Wherever the available on-site soils are not suitable to be used for constructing clay barriers, soils amended with bentonite are commonly used. This article presents the results of an experimental study conducted on compacted clay-bentonite mixtures to develop data on the effects of bentonite on engineering properties of compacted clay-bentonite mixtures. Clay-bentonite mixtures with bentonite contents of up to 7% were tested to determine consistency using Atterberg limits, moisture-density relationships using standard Proctor compaction tests, shear strength using unconfined compression tests, hydraulic conductivity using triaxial flexible-wall hydraulic conductivity tests, and consolidation properties using one-dimensional consolidation tests. Unconfined compression tests were also performed with 11% bentonite content. The laboratory test results indicated that liquid limit, plastic limit, and plasticity index increased linearly with increased amount of bentonite. The addition of bentonite resulted in decreased maximum dry unit weight but the optimum moisture content increased slightly. Unconfined compression strength of compacted clay-bentonite mixtures increased linearly with an increase in the amount of bentonite. Hydraulic conductivity of compacted clay-bentonite mixtures decreased nonlinearly with increased amount of bentonite, but a linear relationship was observed between logarithm of hydraulic conductivity and bentonite content. The compression index increased slightly from 0 to 3% bentonite content but increased nonlinearly beyond 3% bentonite content, whereas the swelling index of clay-bentonite mixtures has been observed to increase approximately linearly with increase in the amount of bentonite.     

The 3-D model: Comparison of parameters obtained from and by simulating different tableting machines

The aim of this study is to apply 3-D modeling to data obtained from different tableting machines and for different compression wheels on a linear rotary tableting machine replicator. A new analysis technique to interpret these data by 3-D parameter plots is presented. Tablets were produced on an instrumented eccentric tableting machine and on a linear rotary tableting machine replicator. The materials used were dicalcium phosphate dihydrate (DCPD), spray-dried lactose, microcrystalline cellulose (MCC), hydroxypropyl methylcellulose (HPMC), and theophylline monohydrate. Tableting was performed to different maximum relative densities (ρ _{rel, max}). Force, time and displacement were recorded during compaction. The 3-D data plots were prepared using pressure, normalized time, and porosity according to Heckel. A twisted plane was fitted to these data according to the 3-D modeling technique. The resulting parameters were analyzed in a 3-D parameter plot. The results show that the 3-D modeling technique can be applied to compaction cycles from different tableting machines as different as eccentric and rotary tableting machines (simulated). The relation of the data to each other is the same even when the absolute values are different. This is also true for different compression wheels used on the linear rotary tableting machine replicator. By using compression wheels of different sizes on this simulator, mainly time plasticity changes. By using bigger compression wheels for simulation, the materials deform slower at lower densification and they deform faster at higher densification. For brittle materials, the stages of higher densification are influenced; for plastically deforming materials, the stages of lower and higher densification can be influenced.     

Emanation of water from underground plant parts

Summary A device was designed which used gypsum and electrical conductivity as a means of detecting and quantitizing the amount of water emanating from underground plant parts under natural conditions. Use of this device with the Common French Bean demonstrated that considerable amounts of moisture emanated from the underground part of the stem. The amount of water emanated was found to be influenced by environmental conditions, differences in soil type and degree of soil compaction. When plants were grown in an environment of approximately 100 per cent relative air humidity and at a temperature of 28 to 30°C, 115 to 125 µl of water emanated from an 11 mm length of stem in a 24-hour period, in contrast to 70 to 80 µl of water emanating from plants grown at 50 to 60 per cent relative air humidity and at a temperature of 18 to 20°C. Water emanation was more rapid in a compacted soil than loose soil and also appeared to be dependent on the amount of sand in a soil. Whereas 115 to 125 µl of water emanated in a silt loam soil, only 35 to 45 µl emanated in a loamy sand soil and less than 10 µl in washed sea sand during a 24-hour period. The sensitivity of the conductivity unit to changes in moisture and the utility of its design enables its employment under varied environmental conditions and offers a technique for plant pathologists to study the effect of both the below- and aboveground environments on moisture emanation from underground plant parts and the resultant effect on the associated microflora.Senior author was visiting Research Fellow and NATO Science Fellow, sponsored by the Netherlands Organization for the Advancement of Pure Research (ZWO), Sept. 16, 1964 to Sept. 15, 1965. Present address: Phytopathologisch Laboratorium W.C.S. Baarn, The Netherlands.     

Evaluating climatic and non-climatic influences on ion chemistry in natural and man-made lakes of Nebraska,USA

Conductivity and major ion chemistry data were analyzed for a suite of Nebraska (USA) natural lakes, reservoirs, sand pits, and barrow pits to evaluate the magnitude of climatic versus non-climatic influence on ionic concentration and composition. In both natural lakes and sand and barrow pits, conductivity is positively related to longitude and reflects decreasing effective moisture from east to west. Reservoirs showed no relationship between lake conductivity and location, probably because the reservoirs are very strongly influenced by groundwater and surface water inflow and have shorter residence times relative to the other lake types. At smaller spatial scales, conductivity among natural lakes is variable. Lakes that are at low elevation within a groundwater flow system were fresh, because of substantial input of fresh groundwater. In contrast, lakes at high elevation exhibited a wide range of conductivity, probably because of differences in the degree of connection to groundwater and surface to volume ratio impacts on evaporation rates. Differences also were evident among natural lakes in terms of their response to seasonal changes in precipitation. Sub-saline and saline lakes showed more seasonal variation in conductivity than freshwater lakes, and lakes in the more arid part of the state showed larger responses to precipitation change than those in areas to the east that receive higher precipitation.     

克隆整合和石油污染对芦苇湿地土壤理化性质的影响

克隆整合是克隆植物重要的性状之一。它不仅能够提高分株对环境胁迫的耐受能力,而且可能影响分株周围的土壤属性。为检验克隆整合对土壤属性的影响,在黄河三角洲芦苇湿地开展克隆整合和石油污染的两因子的野外实验。每年将0、5或10 mm厚的原油添加到直径为60 cm的圆形芦苇群落样方内来模拟无污染、轻度或重度石油污染,并通过保留或切断样方内外芦苇根状茎的连接来实现克隆整合的有或无。实验开始于2014年,并于2016年10月采集样方内土壤样品,测定土壤团聚体组成、pH值、电导率、总碳、总氮、总磷和有机碳含量。石油污染显著增加了土壤粗大团聚体(粒径:2 mm)、pH值、总氮和有机碳含量,降低了土壤微团聚体(粒径:0.053—0.25 mm)占比以及电导率。克隆整合显著降低了土壤pH值,提高了土壤电导率和氮磷比。克隆整合和石油污染的交互作用仅对电导率有显著效应。因此,石油污染和克隆整合都可以影响湿地土壤的理化性质,而克隆整合对分株周围土壤理化性质的影响可能进一步影响克隆植物的优势度。     

Distribution of cutin and suberin biomarkers under forest trees with different root systems

Background and aims

The rhizosphere, the soil immediately surrounding roots, provides a critical bridge for water and nutrient uptake. The rhizosphere is influenced by various forms of root–soil interactions of which mechanical deformation due to root growth and its effects on the hydraulics of the rhizosphere are the least studied. In this work, we focus on developing new experimental and numerical tools to assess these changes.

Methods

This study combines X-ray micro-tomography (XMT) with coupled numerical simulation of fluid and soil deformation in the rhizosphere. The study provides a new set of tools to mechanistically investigate root-induced rhizosphere compaction and its effect on root water uptake. The numerical simulator was tested on highly deformable soil to document its ability to handle a large degree of strain.

Results

Our experimental results indicate that measured rhizosphere compaction by roots via localized soil compaction increased the simulated water flow to the roots by 27 % as compared to an uncompacted fine-textured soil of low bulk density characteristic of seed beds or forest topsoils. This increased water flow primarily occurred due to local deformation of the soil aggregates as seen in the XMT images, which increased hydraulic conductivity of the soil. Further simulated root growth and deformation beyond that observed in the XMT images led to water uptake enhancement of ~50 % beyond that due to root diameter increase alone and demonstrated the positive benefits of root compaction in low density soils.

Conclusions

The development of numerical models to quantify the coupling of root driven compaction and fluid flow provides new tools to improve the understanding of plant water uptake, nutrient availability and agricultural efficiency. This study demonstrated that plants, particularly during early growth in highly deformable low density soils, are involved in active mechanical management of their surroundings. These modeling approaches may now be used to quantify compaction and root growth impacts in a wide range of soils.     

The Influence of Hydraulic Gradient and Rate of Erosion on Hydraulic Conductivity of Sand-Bentonite Mixtures

The use of sand-bentonite mixtures as liner materials for waste disposal is very common. In the laboratory, this study investigated hydraulic conductivities of such mixtures at different hydraulic pressure (hydraulic gradient), dry unit weights, and bentonite contents. The bentonite content and the dry unit weight of the samples were both important factors, significantly affecting the hydraulic conductivity of the liner material. A bentonite content of 5% was found to be sufficient in reaching a hydraulic conductivity under 10^?9 m/s, when the liner material was compacted under near optimum moisture content. Nevertheless, hydraulic conductivity was found to increase with hydraulic pressures, especially for the 5% bentonite mixtures subjected to pressure above 40 kPa, suggesting some degree of internal erosion (washing out of particles).

Therefore, this paper discuses the influence of internal erosion of the mixtures under a given hydraulic gradient, on the final value of k. The internal erosion of the tested mixtures was found to be influenced mainly by porosity, which can be reduced by properly selecting the sand particle size distribution and the bentonite percentage. Furthermore, this study proposed an empirical expression to predict the risk of internal erosion in the sand-bentonite mixtures, and therefore of k being higher than planned. This expression can be used for designing bentonite content and compaction to achieve very low permeability.     

Environmental and centrifugal factors influencing the visco-elastic properties of oral biofilms in vitro

Centrifugal compaction causes changes in the surface properties of bacterial cells. It has been shown previously that the surface properties of planktonic cells change with increasing centrifugal compaction. This study aimed to analyze the influences of centrifugal compaction and environmental conditions on the visco-elastic properties of oral biofilms. Biofilms were grown out of a layer of initially adhering streptococci, actinomyces or a combination of these. Different uni-axial deformations were induced on the biofilms and the load relaxations were measured over time. Linear-Regression-Analysis demonstrated that both the centrifugation coefficient for streptococci and induced deformation influenced the percentage relaxation. Centrifugal compaction significantly influenced relaxation only upon compression of the outermost 20% of the biofilm (p < 0.05), whereas biofilm composition became influential when 50% deformation was induced, invoking re-arrangement of the bacteria in deeper biofilm structures. In summary, the effects of centrifugal compaction of initially adhering, centrifuged bacteria extend to the visco-elastic properties of biofilms, indicating that the initial bacterial layer influences the structure of the entire biofilm.     

Bench-Scale Production of Biosurfactants and their Potential in Ex-Situ MEOR Application

The fermentative production of biosurfactants by five Bacillus strains in a bench-scale bioreactor and evaluation of biosurfactant-based enhanced oil recovery using sand pack columns were investigated. Adjusting the initial dissolved oxygen to 100% saturation, without any further control and with collection of foam and recycling of biomass, gave higher biosurfactant production. The microorganisms were able to produce biosurfactants, thus reducing the surface tension and interfacial tension to 28 mN/m and 5.8–0.5 mN/m, respectively, in less than 10 hours. The crude surfactant concentration of 0.08–1.1 g/L, and critical micelle concentration (CMC) values of 19.4–39 mg/L, corresponding to the biosurfactants produced by the different Bacillus strains, were observed. The efficiency of crude biosurfactant preparation obtained from Bacillus strains for enhanced oil recovery, by sand pack column studies, revealed it to vary from 30.22–34.19% of the water flood residual oil saturation. The results are indicative of the potential of the strains for the development of ex-situ, microbial-enhanced, oil recovery processes.     

Some physical properties of pot plant composts and their effect on plant growth

Summary The effect of compaction of the substrate on the growth of tomato varied with both the substrate and the degree of compaction. With most substrates, and in particular the fine-sand series which had a poor structure, any degree of compaction gave adverse effects, whilst with the brickearth series, which had a good structure, a moderate amount of compaction gave a significant increase in growth when peat was included in the substrate.Peat was a more effective physical conditioner than grit in reducing the adverse effects of compression.Compaction decreased the fresh weight and internode length of tomatoes and increased the period from pricking out to anthesis. The lower rate of nitrification found in compacted substrates was not responsible for the lower growth rate. Supplementary oxygen applied either as calcium peroxide or hydrogen peroxide had no effect at high substrate densities. It is tentatively suggested that the higher water tensions and mechanical impedance of the high density substrate were the cause of the slower growth.     

Microbial challenges for domestic heating oil storage tanks

Microbial growth on hydrocarbons is common in nature and used in bioremediation of contaminated sites, whereas in fuel storage tanks this phenomenon can affect the stability of the fuel and the tank. The impact of microbial growth and produced metabolites on materials, which are used in the construction of storage tanks, were analyzed. In contrast to metal tank components, polymeric materials did not affect or were influenced by microorganisms. Zinc was highly corroded by microbial growth, most likely due to the formation of organic acids that were produced during microbial growth on hydrocarbons. A contaminated water phase in a storage tank of a heating system was simulated with a self‐constructed pump test bench. Microbial growth began in the water phase of the storage tank and microbes were distributed throughout the tank system, through water‐in‐oil microemulsions. No microbial growth was observed in oil that was previously contaminated, indicating that essential nutrients had been depleted. The identification and removal of these essential nutrients from fuels could minimize or prevent microbial contamination. The results are discussed with regard to developing recommendations for the design and operation of domestic heating oil storage tanks to lower the risk of technical failure due to microbial contamination.     

Fuzzy Logic Modeling of Contamination Degree of Ni and V Metal Species in Sediments from the Crude Oil Prospecting Area of the Ondo Coast,Nigeria

There are numerous statistical models for evaluating the degree of pollution in an environment. This study presents a fuzzy logic–based model—simple fuzzy classification (SFC)—for evaluating contamination of Ni and V species in the sediments of Nigeria's Ondo coastal area. Concentrations of five species of these metals were obtained from 10 sampling sites following sequential extractions from sediments. The results were formulated into a fuzzy membership function matrix based on three classifications relative to regulatory standards and sediments’ degree of contamination. The results of the SFC show that the estuary is moderately enriched by Ni species in a range of 61–84% and further introduction of Ni may shift its contamination level into the highly polluted category. The SFC results also show that the estuary is clean of V species contamination in a range of 77–99%. The Ni and V were associated with the organic specie notably at the crude oil exploration site and at the coastal discharge point. Crude oil exploration and domestic wastes discharges are notable sources of metal contaminations into the estuary. However, the salinity incursion from the coastal ocean and prevailing biogeochemistry affect the species in which the metals exist.     

Dry granulation and compression of spray-dried plant extracts

The purpose of this research was to evaluate the influence of dry granulation parameters on granule and tablet properties of spray-dried extract (SDE) fromMaytenus ilicifolia, which is widely used in Brazil in the treatment of gastric disorders. The compressional behavior of the SDE and granules of the SDE was characterized by Heckel plots. The tablet properties of powders, granules, and formulations containing a high extract dose were compared. The SDE was blended with 2% magnesium stearate and 1% colloidal silicon dioxide and compacted to produce granules after slugging or roll compaction. The influences of the granulation process and the roll compaction force on the technological properties of the granules were studied. The flowability and density of spray-dried particles were improved after granulation. Tablets produced by direct compression of granules showed lower crushing strength than the ones obtained from nongranulated material. The compressional analysis by Heckel plots revealed that the SDE undergoes plastic deformation with a very low tendency to rearrangement at an early stage of compression. On the other hand, the granules showed an intensive rearrangement as a consequence of fragmentation and rebounding. However, when the compaction pressure was increased, the granules showed plastic deformation. The mean yield pressure values showed that both granulation techniques and the roll compaction force were able to reduce the material's ability to undergo plastic deformation. Finally, the tablet containing a high dose of granules showed a close dependence between crushing strength and the densification degree of the granules (ie, roll compaction force). Published: October 14, 2005     

An ellipsometry study on the effect of aluminium chloride and ferric chloride formulations on mucin layers adsorbed at hydrophobic surfaces

Ellipsometry was used to investigate the effect of polyaluminium chloride (PAC) formulations of different degrees of hydrolysation on an adsorbed mucin film. The results were compared to the effect of aluminium chloride (AlCl₃) and ferric chloride. A compaction of the mucin film took place upon addition of the formulations and this occurred to different extents and at different concentrations for the different formulations. The compaction of PAC of a low degree of hydrolysis behaved similarly to AlCl₃. PAC of a high degree of hydrolysis showed a greater compaction effect than the other aluminium formulations. The initial compaction concentration was found to be 0.001 mM which is less than previously found for aluminium–mucin complex formation in bulk. The reversibility of the compaction was also investigated. The compaction of the mucin film was found to be partly reversible for AlCl₃ and PAC of low degree of hydrolysis. No reversibility was observed for the formulations of PAC of high hydrolysis grade or for ferric chloride. The results are consistent with previously observed effects of PAC of a low degree of hydrolysis on bacterial surfaces where a compaction of surface polymers was indicated by the reduced range of repulsive steric interactions.     

Population differentiation and the effects of herbivory and sand compaction on the subterranean growth of a desert lily

Differences in level of herbivory can select for local adaptation and genetic differentiation of plant populations in different environments. Mean bulb depth of the desert lily Pancratium sickenbergeri, differs considerably among populations differing in the level of herbivory by the dorcas gazelle. The gazelle digs in the sand to remove most of the bulb of the lily. Deeper bulbs have less material removed by herbivory than shallow bulbs and have higher fitness. A possible confounding factor is the degree of sand compaction, which may retard the downward growth of the bulb. We conducted a common garden experiment with 2 sand types with seeds from source populations with different levels of herbivory. There was a large genetic difference among populations. Two of 3 analyses indicated that there was an interaction between population and sand type, indicating that there is a heritable component of plasticity.     

Growth of yeast on n-alkanes. I. Stochastic model

In a system where yeast cells grow on n-alkanes dissolved in oil drops suspended in water, the dispersed oil phase will, in most cases, be fully segregated. This means that each drop has its own history that depends on its degree of saturation with yeast cells. This degree of saturation with yeast cells is determined by a stochastic process depending on adsorption, desorption, and cell production. Although many authors mention segregation as a phenomenon likely to occur, so far this segregation has hardly been taken into account. In this paper the interaction of the population of completely segregated oil drops with the population of yeast cells, which results in growth, is described. The consequences of the model are elucidated by the discussion of some extreme cases. The batch fermentation of hydrocarbons by yeast cell is simulated by means of a Monte Carlo procedure. Adsorption, desorption, and production of yeast cells are considered as chance processes. The history of all individual drops is recorder. The influence of the chance of desorption appears to be much larger than that of the chance of adsorption (at the investigated range). Also the size of the inoculum at the start of the process appears to have a strong influence on the course of fermentation.