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1.
A total of 195 farmland soil samples were collected in Yanqi Basin, Xinjiang, northwest China, and the concentrations of As, Cd, Cr, Cu, Ni, Pb, and Zn were analyzed for their concentrations and pollution levels using the Nemerow comprehensive index. The health risk assessment model introduced by USEPA was utilized to evaluate the human health risks of heavy metals. Results indicated that the average concentrations of these seven metals were lower than the allowed soil environmental quality standards of China, while the average concentrations of Cd, Cr, Ni, Pb and Zn exceeded the background values of irrigation soils in Xinjiang. The average contamination factor (CF) for Pb indicated the heavy pollution, whereas the CF for Cd, Zn, Ni, Cu and Cr indicated the moderate pollution. The average PLI of heavy metals indicated the low pollution. The non-carcinogenic hazard index were below the threshold values, and the total carcinogenic risks due to As and Cr were within the acceptable range for both children and adults. As and Pb were the main non-carcinogenic factors, while As was the main carcinogenic factor in the study area. Special attentions should be paid to these priority control metals in order to target the lowest threats to human health.  相似文献   

2.
This study evaluated cancer risk and non-cancer human health hazard from exposure to the toxicants such as As, Cu, Pb, Zn, Mn, and CN in water from a southwestern river system in Ghana that drains through gold mining areas, using 108 water samples collected with random sampling techniques and analyzed in accordance with standard methods of chemical analysis outlined by the U.S. Environmental Protection Agency (USEPA). The concentrations of Cu and Zn were within World Health Organization and USEPA guideline values; Mn, free cyanide, As, and Pb values in most cases either exceeded USEPA and WHO values or both. The concentrations of the toxicants were used as input parameters in the cancer and non-cancer study that was conducted in line with USEPA risk assessment guidelines. The results of As cancer health risk revealed higher risk cases in two locations (Potroase and Dominase); non-cancer health risk for As was higher in 10 of the 14 locations, with other metals being of health concern at few locations in the study area. In conclusion, the findings of this study hold several policy implications as residents of mining communities still depend on these water bodies as their source of drinking water.  相似文献   

3.
The reclamation of subsidence area was regarded as a useful pathway to rebuild landscape and ecosystem. However, the elevated concentrations of heavy metals in the reclaimed area may lead to potential environmental and health risks. This study was aimed at investigating the accumulation of heavy metals in the soils and vegetables, and evaluate the potential health risks to human beings via consuming these vegetables. The concentrations of heavy metals (Cd, Cu, Pb, and Zn) were measured by using inductively coupled plasma mass spectrometry. The elevated concentrations of heavy metals were found in the soil from the reclaimed area when compared with the background value. The concentrations of heavy metals were various among the different vegetable species. The heavy metal tolerance could be found in all the selected vegetables. The elevated concentrations of Cu, Pb, and Zn in the edible part of the selected vegetables indicated that the consumption of these vegetables may lead to potential health risk. The intake of soybean, radish, sweet potato, and mugwort may lead to potential health risks due to the elevated target health quotients. Chinese cabbage and pepper were regarded as the suitable vegetables which may help in reducing the potential health risk.  相似文献   

4.
In this study, sediment samples were collected from Kabul River (Pakistan) and analyzed for heavy metals including zinc (Zn), cadmium (Cd), chromium (Cr), nickel (Ni) and lead (Pb). The physico-chemical characteristics were also determined which are known to influence the metal accumulation within the sediment matrix. Heavy metal concentrations (mg kg?1, dry weight basis) in the sediment were in the order of Zn > Cr > Ni > Pb > Cd. Heavy metal concentrations were found in moderately polluted category set by U. S. Environmental Protection Agency (USEPA). However, Cr and Ni concentrations exceeded the screening levels at the sites where a larger volume of industrial effluents enter into Kabul River. Higher concentrations of almost all the tested metals were detected at locations of greater industrial and sewage entry points. Sediment organic matter (OM) exhibited strong correlation with Pb (R2 = 0.80), Ni (R2 = 0.67) and Zn (R2 = 0.46), indicating that OM plays a significant role in metal retention and accumulation. The findings of this study showed that Kabul River is reasonably contaminated with selected heavy metals released from anthropogenic sources. In the study area, sewage discharge was the major source of heavy metals including Zn and Pb, which were observed at locations where sewage effluents enter into the river.  相似文献   

5.
按离路基不同距离采集土壤、麦苗和籽粒样品, 在测定样品重金属 (Pb、Cd、Zn、Cr和Cu) 的基础上, 开展了路旁土壤-小麦系统重金属分布、积累和污染状况分析, 并对膳食小麦 (Triticumaestivum) 引起的健康风险进行了评价。结果表明:1) 土壤-小麦系统重金属含量随着离开路基距离的增加呈先增加后减少的趋势, 土壤重金属含量>麦苗重金属含量>籽粒重金属含量。2) 麦苗和小麦籽粒对土壤重金属富集能力的大小顺序均为Cu>Cd>Zn>Pb>Cr, 麦苗对重金属的富集能力大于小麦籽粒。3) 膳食小麦所致的Cd个人健康风险较大。  相似文献   

6.
Heavy metals enrichment in groundwater poses great ecological risks to human beings. In the present research work, a total of 59 groundwater samples from 12 sampling points in Dingji coal mine, Huainan coalfield, were collected and measured for Cu, Pb, Zn, Cd, Ni, Mn, Cr, and Fe by inductively coupled plasma mass spectrometry (ICP-MS). The human health risk caused by heavy metals through the pathway of drinking water was evaluated and analyzed using the US Environment Protection Agency (USEPA) evaluation model. It has been found that the carcinogenic risk values were between 1.05 × 10?5 and 3.5 × 10?4, all exceeding the maximum acceptable level recommended by the USEPA, and the carcinogenic risk of Cr accounted for 99.67% of the total carcinogenic risk. The non-carcinogenic health risk values were all lower than the negligible level given by the USEPA, and the contribution of non-carcinogenic health risk was in the order of Cr > Zn > Cu / Pb >Mn > Fe > Cd > Ni. Among them, Cr had the largest contribution, accounting for 36% of the total non-carcinogenic risk value. In this study, the carcinogenic risk constituted 99.99% of the total health risk, indicating that the total health risk essentially consisted of carcinogenic risk. The research results suggest that much more attention should be paid to the health risk caused by Cr in the groundwater.  相似文献   

7.
BackgroundThe presence of toxic toxic metals in lipstick can pose a health risk to many consumers of this type of cosmetics, especially for women. Thus, the aim of this study was to assess consequences attributed to dermal and oral exposure to toxic metals in lipsticks manufactured in China and Europe as determined by non-cancer and cancer risks assessment models from SCCS and USEPA, respectively.MethodThe treatment of the samples was carried out by calcination using muffle furnaces and the determination of Al, Cd and Pb were determined by inductively coupled plasma optical emission spectrometry (ICP-OES).ConcentrationsThe concentration of Cd and Pb in the study samples does not exceed the limits stablished for the FDA (00,228 mg kg−1·day−1 for Cd and 000,343 mg kg−1·day−1 for Pb, respectively) but they do not comply with the Regulation of the European Parliament, which prohibits the presence of these two metals in cosmetics. Neither European Union nor United States have established maximum levels for Al in cosmetics.ConclusionsThe cancer risk assessment of Cd and Pb metals resulted in a total cancer risk less than 1. The results of non-cancer oral risk assessment for Pb had a MoS result of 88 for China and 62 for Europe, suggesting that Pb poses a risk for the human health, especially in samples manufactured in Europe.  相似文献   

8.
The aims of this article were to investigate heavy metals concentrations in urban street dust of Tianjin, to examine spatial variations of heavy metals pollution, and to assess their health risk to local populations. Urban street dust samples were collected from 144 typical crossroads in an urban area of Tianjin. Levels of heavy metals were determined by atomic absorption spectrophotometer analyzer. Given comprehensive consideration of the complexity and uncertainty of health risk assessment, trapezoidal fuzzy number was introduced to assess the health risk of heavy metals in the urban street dust of Tianjin. The results showed that the pollution of heavy metals in the urban street dust of Tianjin was serious. The relatively serious metal pollution tended to be located in the center, north, northeast, and southeast of the study area. The research indicated that heavy metals in street dust had caused non-cancer hazard to children but had not caused non-cancer or cancer hazard to adults. The direct ingestion of dust via hand-mouth contact behaviors was the major exposure pathway for health risk.  相似文献   

9.
In this study, paddy soil and rice grain samples were collected from the vicinity around the Xinqiao mine in Tongling, China to test for the presence of heavy metals (Cd, Ni, Cr, Cu, Zn, and Pb) in soil-rice system. Results indicated that the soil samples were primarily contaminated with Cd and Cu and followed with Zn and Pb. In rice grains, Cd, Cu, and Cr concentrations exceeded recommended guidelines. However, the regional distribution of heavy metals in rice grains and soil was inconsistent. The bioaccumulation factor of heavy metals in rice grains decreased in the order of Cd > Zn > Cu > Ni > Cr > Pb. The BAF was significantly positively correlated with TCLP-extractable metals and significantly negatively correlated with soil pH. However, the relationship between soil organic matter and the BAF in rice grains was complex. Health risk assessment through rice intake showed that hazard quotients of Cu and Cd were greater than 1 and could pose a considerable non-cancer health risk to adults and children; meanwhile, Cr, Ni, and Cd could pose an unacceptable cancer risk. The results indicated that the government must take measures to reduce heavy metal contents in paddy soil and rice.  相似文献   

10.
The present study was conducted to assess the suitability of sewage sludge amendment (SSA) in soil for Beta vulgaris var. saccharifera (sugar beet) by evaluating the heavy metal accumulation and physiological responses of plants grown at a 10%, 25%, and 50% sewage sludge amendment rate. The sewage sludge amendment was modified by the physicochemical properties of soil, thus increasing the availability of heavy metals in the soil and consequently increasing accumulation in plant parts. Cd, Pb, Ni, and Cu concentrations in roots were significantly higher in plants grown at 25% as compared to 50% SSA; however, Cr and Zn concentration was higher at 50% than 25% SSA. The concentrations of heavy metal showed a trend of Zn > Ni > Cu > Cr > Pb > Cd in roots and Zn > Cu > Ni > Cr > Pb > Cd in leaves. The only instance in which the chlorophyll content did not increase after the sewage sludge treatments was 50%. There were approximately 1.12-fold differences between the control and 50% sewage sludge application for chlorophyll content. The sewage sludge amendment led to a significant increase in Pb, Cr, Cd, Cu, Zn, and Ni concentrations of the soil. The heavy metal accumulation in the soil after the treatments did not exceed the limits for the land application of sewage sludge recommended by the US Environmental Protection Agency (US EPA). The increased concentration of heavy metals in the soil due to the sewage sludge amendment led to increases in heavy metal uptake and the leaf and root concentrations of Ni, Zn, Cd, Cu, Cr, Pb, and Zn in plants as compared to those grown on unamended soil. More accumulation occurred in roots and leaves than in shoots for most of the heavy metals. The concentrations of Cd, Cr, and Pb were more than the permissible limits of national standards in the edible portion of sugar beet grown on different sewage sludge amendment ratios. The study concludes that the sewage sludge amendment in the soil for growing sugar beet may not be a good option due to risk of contamination of Cr, Pb, and Cd.  相似文献   

11.
In the present study, nine native plant species were collected to determine their potential to clean up nine heavy metals from soil of a sewage sludge dump site. Almost all nine plant species grown at sewage sludge dump site showed multifold higher concentrations of heavy metals as compared to plants grown at the reference site. All the investigated species were characterized by a bioaccumulation factor (BF) > 1.0 for some heavy metals. BF was generally higher for Cd, followed by Pb, Co, Cr, Cu, Ni, Mn, Zn, and Fe. The translocation factor (TF) varied among plant species, and among heavy metals. For most studied heavy metals, TFs were <1.0. The present study proved that the concentrations of all heavy metals (except Cd, Co, and Pb) in most studied species were positively correlated with those in soil. Such correlations indicate that these species reflect the cumulative effects of environmental pollution from soil, and thereby suggesting their potential use in the biomonitoring of most heavy metals examined. In conclusion, all tissues of nine plant species could act as bioindicators, biomonitors, and remediates of most examined heavy metals. Moreover, Bassia indica, Solanum nigrum, and Pluchea dioscoridis are considered hyperaccumulators of Fe; Amaranthus viridis and Bassia indica are considered hyperaccumulators of Pb; and Portulaca oleracea is considered hyperaccumulator of Mn.  相似文献   

12.
Due to increased anthropogenic activities, the aquatic environment is exposed to pollutants much more than ever. These pollutants go into the food chain and can pose a health risk to human. Correlatively, Borcka Dam Lake, Turkey has been affected by mining activities since decades. In the present study, therefore, Cu, Pb, As, Zn, Mn, Cd, Cr, and Se concentrations in water, sediment, and different tissues (muscle, gill, liver) of 11 fish species sampled from the lake were analyzed regarding metal(oid)s pollution and potential human health risk through fish consumption. The metal(oid) concentrations in the water were below the limit values recommended by USEPA for aquatic life criteria but sediments were heavily polluted by As, Cu, Pb, and Zn based on Sediment Quality Guideline. The lowest metal(oid) values among tissues for all fish species were determined in muscle (p < 0.05) which was lower than the limits for human consumption declared by European Union Regulation. Target Hazard Quotient and Hazard Index used non-cancer risk estimate which was lower than 1. In the view of these results, the consumption of fish caught from the Borcka Dam Lake may not pose a potential risk to human.  相似文献   

13.
Heavy-metal pollution in house dust is of great potential hazard to human health, as people spend more than half of their time at home. To investigate heavy-metal pollution in a heavily air-polluted area of the Xi'an western industrial area, house dust was collected from relatively large residential quarters and <63 μm fraction of dust was measured for heavy metals. The results show that concentrations of Cr, Mn, Co, and V in the house dust are close to that in the local natural soil, whereas that of Ni, Cu, Zn, and Pb are often significantly elevated—mainly caused by intensively industrial activities in this area. Total ecological risks of these eight metals are moderate to considerable in most (69%) dust samples, while they are considerable to high in the others, occurring at the southwest of the study area. Health risk assessments reveal that exposure of these eight metals in the house dust has no risks to adults but has significant non-cancer risks to children, predominantly caused by dust ingestion. The results of this study are helpful for environmental management in industrial areas.  相似文献   

14.
《农业工程》2020,40(1):64-71
Twenty five water samples were collected along the Taizihe River, the concentration and health risks of Zn, Cu, Pb, Cr and Cd were detected and evaluated, and the pollution sources was analyzed through principal components analyses. The results indicated that the order of average concentration of heavy metals was follows: Pb > Cr > Cu > Zn and Cd. Among that, the concentrations of Zn, Cu and Cr were at the permissible levels, but Pb and Cd exceeded grade V standard at some sites. The concentrations of Zn and Cu in the wet season were significant higher than that in the dry season (p < 0.05), but the average concentrations of Pb, Cr and Cd were not significantly different in the two seasons (p > 0.05). The annual average risks of human health caused by Cd and Cr were 10−3/a and 10−4/a, respectively, which were higher than the recommended maximum acceptable risk level. The human health risk values of Zn, Pb and Cu were all concentrated at 10−8/a or 10−9/a levels, which did not exceed the recommended standard. On the whole, Cd and Cr were the main health risk pollutants of Taizihe River. Pollution sources of Pb was different from other heavy metals in wet and dry season, Cd and Cr were similar in the wet and dry season. The mainly pollution source of heavy metals was industry, especially mining, metal smelting and electroplating industry.  相似文献   

15.
Soil heavy metal pollution from mining activities is potentially harmful to human health through the food chain. In this study, a total of 43 soil samples were collected from a depth of 0–20 cm from fields close to a Pb and Zn smelter. The samples were used to: 1) analyze the pollution level of heavy metals (Pb, Zn, Cr, and Cu) and spatial distribution pattern; 2) evaluate the degree of accumulation and enrichment, potential ecological risk, and human health risk; and 3) perform source apportionment in Fengxiang County, Shaanxi Province of China. The results showed that the concentration ranged from 43.67 to 189.55, 131.43 to 239.53, 74.77 to 112.25, and 24.69 to 37.71 mg·kg?1 for Pb, Zn, Cr, and Cu, respectively, and the mean concentration for Pb, Zn, Cr, and Cu was 129.46, 192.85, 91.98 and 31.67 mg·kg?1, respectively. The concentrations were greater than the Shaanxi Province background values, while they were lower than the second-level limits of Environmental Quality Standard for Soils of China (EQSS). The spatial distribution of heavy metal contents showed a banded in soil except Cu. The spatial distribution pattern and pollution assessment indexes (Igeo, EF) indicated that the investigated metals had been accumulated in the study areas, and implied significant influences from anthropogenic activities, local meteorological situation, and soil properties. The ecological risk assessment showed that the risks were relatively low (RI<150). Compared with the exposure risk for adults, that for children was significantly greater. The ingestion of heavy metals in the soils by humans was the main exposure pathway compared with the dermal exposure. There may be a risk of noncarcinogenic adverse health effects (HQ < 1, 0.377 ≤ HI≤1.553) on children, but the adults were unlikely to experience obvious adverse health effects (HQ < 1, HI < 1). The carcinogenic risk of Cr for adults and children was at an unacceptable level. The carcinogenic and noncarcinogenic risks were in the order of children > adults. The correlation analysis showed that Pb, Cr, and Cu have identical anthropogenic and natural sources, while Zn has another identical source. This study could provide a basis for the sustainable management of this region by reducing metal inputs and to protect soils from long-term heavy metal accumulation.  相似文献   

16.
为了明确调水调沙工程长期影响下黄河口近岸沉积物中重金属含量的分布特征及其生态风险,基于2012年黄河口近岸27个站位的表层沉积物样品,通过ICP-MS测定重金属(Zn、Cr、Ni、Pb、Cu、Cd)和砷(As)含量,并运用潜在生态风险指数法(RI)对其进行生态风险评估。结果表明:近岸沉积物中重金属和As的平均含量表现为AsZnCrNiPbCuCd。Cr、Ni、Cu和Pb四种元素的分布规律较为一致,整体呈现出近岸和近黄河口高而远离河口和岸线低的空间分异特征。Ni、Cu、Pb、Zn与粘土均呈极显著或显著正相关(P0.01或P0.05),而Cd、Cr和As与其相关性均未达到显著水平(P0.05)。近岸沉积物中6种重金属和As的平均单项潜在生态风险指数大小顺序整体表现为CdAsNiPbCuCrZn。就潜在生态风险(RI)而言,研究区域18.52%的站位属轻微生态危害,70.07%的站位属中等生态危害,7.41%的站位属强生态危害,Cd和As是造成危害的两种主要元素。近岸沉积物中重金属和As的来源复杂且多样,主要是由于农业化肥使用、海上石油开采和泄漏、化石燃料燃烧以及河口污染物输入所致。对比研究发现,随着调水调沙工程的长期实施,除Cd和As外沉积物中其他重金属含量均呈下降趋势,说明二者的生态风险将会随调水调沙的长期实施呈增加趋势,而其他重金属的生态风险将呈降低趋势,故未来应重点关注近岸沉积物中Cd和As的生态毒理风险。  相似文献   

17.
This study was done to evaluate heavy metal concentrations in street dust samples, to compare measured concentrations in samples to background concentrations in order to make evaluations for pollution indices, and to describe the quality of street dust in the studied area in relation to pollution. A total of 30 cumulative samples were collected from the streets of Eslamshahr City. Concentrations of heavy metals were determined using an Inductively Coupled Plasma-Optical Emission Spectrometry (ICP-OES). Results determined mean concentrations (mg/kg) of the heavy metals Cd, Cr, Cu, Ni, Pb, and Zn, in collected samples of street dust as 0.34, 35.1, 239, 42.4, 71.3, and 573, respectively. Igeo values for Cd and Cr, Cu, Ni, Pb, and Zn showed level of moderately polluted, unpolluted, moderately to strongly polluted, unpolluted, moderately polluted and moderately to strongly polluted, respectively. The pattern of total metal concentrations in the studied area was ranked as follows: Zn and Cu>Pb>Cd>Ni>Cr. The highest values for the monomial potential ecological risk (Er) were observed for Cd (114). The mean level of RI for the studied soil samples was 192 (91.3–244), which is classed as presenting a strong potential ecological risk.  相似文献   

18.
The objective of this study is to assess the spatial distribution and uncertainty of the potential ecological risks of heavy metals in soil using sequential Gaussian simulation (SGS) and the Hakanson potential ecological risk index (PERI). We collected 130 soil samples in an area of 150 km2 in the High-Tech Park of Wuhan, China, and measured the concentrations of five heavy metals in soil (i.e., Cd, Cr, Cu, Pb, and Zn). We then simulated the spatial distribution of each heavy metal using SGS, and calculated Hakanson PERIs for individual metals and multiple metals based on the simulated realizations. The spatial uncertainty of the Cd PERI and its occurrence probabilities in different risk grades were further assessed. Results show that the potential ecological risks of Cr, Cu, Pb, and Zn are relatively low in the study area, but Cd indeed reaches a serious level that deserves much attention and essential treatment. The total PERI of multiple heavy metals indicates a moderate grade in most of the study area. In general, combining SGS and the Hakanson PERI appears to be an effective method for evaluating the potential ecological risks of heavy metals in soil and the priority areas for remediation.  相似文献   

19.
Trace heavy metals such as Cr(III), Ni(II), Cd(II), Zn(II), Pb(II), and Cu(II) are hazardous pollutants and are rich in areas with high anthropogenic activities. Their concentrations were analyzed using atomic absorption spectroscopy, and it was found that their concentrations were several fold higher in downstream Swan River water samples of the Kahuta Industrial Triangle as compared to upstream. Heavy metal soil concentrations taken from the downstream site were 149% for Cr, 131% for Ni, 176% for Cd, 139% for Zn, 224% for Pb, and 182% for Cu when compared to samples from the upstream site. Quantitative analysis concluded that these metals were higher in milk samples collected from downstream as compared to the samples from upstream water-irrigated sites. The order of metal in milk was as Zn > Cr > Cu > Cd > Pb = Ni. Heavy metal contaminations may affect the drinking water quality, food chain, and ecological environment. It was also suggested that the toxicity due to such polluted water, soil, and milk are seriously dangerous to human health in future.  相似文献   

20.
The quality of water sources and its potential health implications to adults and children populations of respective major communities in Northern Cross-River was assessed. Water samples (n = 10/water source/site) were collected from three (Okpoma, Okuku and Ugaga) communities and heavy metal concentrations (Lead (Pb), Cadmium (Cd), Chromium (Cr), Manganese (Mn), Nickel (Ni), Copper (Cu), Cobalt (Co), and Zinc (Zn)) were evaluated using Atomic Absorption Spectrometer (AAS). Overall, Pb, Cd, Ni, and Co were higher than drinking water guidelines, while only Cr, Mn, Cu, and Zn were within the permissible limits. The estimated average daily intake (EADI) and target hazard quotient (THQ) were used to determine risk implications for adult and children consumer populations. The EADI for Pb in adults for borehole water, Pb and Cr by child consumer population for borehole and shallow well water exceeded the reference dose (RfD) by USEPA. The THQ for adult population were >1 for Pb in borehole water and >1 for Pb and Cr across all sites for the child consumer population. Overall, our findings indicate toxicity and higher hazard risk for both adult (Pb) and children (Pb and Cr) populations that source drinking water from borehole and shallow well water in these communities.  相似文献   

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