共查询到20条相似文献,搜索用时 15 毫秒
1.
Kaiping Wang Lifeng Huang Naresh Eedugurala Song Zhang Md Abdus Sabuj Neeraj Rai Xiaodan Gu Jason D. Azoulay Tse Nga Ng 《Liver Transplantation》2019,9(47)
Supercapacitors have emerged as an important energy storage technology offering rapid power delivery, fast charging, and long cycle lifetimes. While extending the operational voltage is improving the overall energy and power densities, progress remains hindered by a lack of stable n‐type redox‐active materials. Here, a new Faradaic electrode material comprised of a narrow bandgap donor?acceptor conjugated polymer is demonstrated, which exhibits an open‐shell ground state, intrinsic electrical conductivity, and enhanced charge delocalization in the reduced state. These attributes afford very stable anodes with a coulombic efficiency of 99.6% and that retain 90% capacitance after 2000 charge–discharge cycles, exceeding other n‐dopable organic materials. Redox cycling processes are monitored in situ by optoelectronic measurements to separate chemical versus physical degradation mechanisms. Asymmetric supercapacitors fabricated using this polymer with p‐type PEDOT:PSS operate within a 3 V potential window, with a best‐in‐class energy density of 30.4 Wh kg?1 at a 1 A g?1 discharge rate, a power density of 14.4 kW kg?1 at a 10 A g?1 discharge rate, and a long cycle life critical to energy storage and management. This work demonstrates the application of a new class of stable and tunable redox‐active material for sustainable energy technologies. 相似文献
2.
Large‐Scale Conductive Yarns Based on Twistable Korean Traditional Paper (Hanji) for Supercapacitor Applications: Toward High‐Performance Paper Supercapacitors
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Young‐Jung Heo Ji Won Lee Yeong‐Rae Son Jong‐Hoon Lee Chang Su Yeo Tran Dai Lam Sang Yoon Park Soo‐Jin Park Le Hoang Sinh Min Kyoon Shin 《Liver Transplantation》2018,8(27)
A simple and scalable method to fabricate a yarn‐type supercapacitor with a large specific capacitance without the aid of traditional pseudocapacitive electrode materials such as conducting polymers and metal oxides is reported. The yarn‐type supercapacitors are made from twisting reduced graphene oxide (rGO) or/and single‐walled carbon nanotubes (SWNTs)‐coated Korean traditional paper (KTP). The yarn‐type paper supercapacitor displays surprisingly enhanced electrochemical capacitance values, showing synergistic effect between rGO and SWNTs (500 times larger than performance of yarn‐type rGO‐coated paper supercapacitors). Coating rGO or/and SWNTs on KTP gives good morphology to the composite film, in which porosity increases and mean pore diameter decreases. The yarn‐type rGO/SWNT paper supercapacitor shows good mechanical strength, high flexibility, excellent electrochemical performance, and long‐life operation. The yarn‐type supercapacitor has an excellent electrochemical performance with a specific capacitance of 366 F g?1 at scan rate of 25 mV s?1 and high stability without any degradation in electrical performance up to 10 000 charge–discharge cycles. The average capacitance of rGO/SWNT@KTP yarn‐type supercapacitors is seven times higher than that of sheet‐type supercapacitors at scan rate of 500 mV s?1. The lighting of a red light‐emitting diode (LED) is demonstrated by the yarn‐type paper supercapacitor without connecting supercapacitors in series. 相似文献
3.
Fanglin Wu Guk‐Tae Kim Matthias Kuenzel Huang Zhang Jakob Asenbauer Dorin Geiger Ute Kaiser Stefano Passerini 《Liver Transplantation》2019,9(43)
The eco‐friendly and low‐cost Co‐free Li1.2Mn0.585Ni0.185Fe0.03O2 is investigated as a positive material for Li‐ion batteries. The electrochemical performance of the 3 at% Fe‐doped material exhibits an optimal performance with a capacity and voltage retention of 70 and 95%, respectively, after 200 cycles at 1C. The effect of iron doping on the electrochemical properties of lithium‐rich layered materials is investigated by means of in situ X‐ray diffraction spectroscopy and galvanostatic intermittent titration technique during the first charge–discharge cycle while high‐resolution transmission electron microscopy is used to follow the structural and chemical change of the electrode material upon long‐term cycling. By means of these characterizations it is concluded that iron doping is a suitable approach for replacing cobalt while mitigating the voltage and capacity degradation of lithium‐rich layered materials. Finally, complete lithium‐ion cells employing Li1.2Mn0.585Ni0.185Fe0.03O2 and graphite show a specific energy of 361 Wh kg?1 at 0.1C rate and very stable performance upon cycling, retaining more than 80% of their initial capacity after 200 cycles at 1C rate. These results highlight the bright prospects of this material to meet the high energy density requirements for electric vehicles. 相似文献
4.
Lithiation‐Induced Dilation Mapping in a Lithium‐Ion Battery Electrode by 3D X‐Ray Microscopy and Digital Volume Correlation
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David S. Eastwood Vladimir Yufit Jeff Gelb Allen Gu Robert S. Bradley Stephen J. Harris Daniel J. L. Brett Nigel P. Brandon Peter D. Lee Philip J. Withers Paul R. Shearing 《Liver Transplantation》2014,4(4)
Recent advances in high‐resolution 3D X‐ray computed tomography (CT) allow detailed, non‐destructive 3D structural mapping of a complete lithium‐ion battery. By repeated 3D image acquisition (time lapse CT imaging) these investigations of material microstructure are extended into the fourth dimension (time) to study structural changes of the device in operando. By digital volume correlation (DVC) of successive 3D images the dimensional changes taking place during charge cycling are quantified at the electrode level and at the Mn2O4 particle scale. After battery discharging, the extent of lithiation of the manganese (III/IV) oxide grains in the electrode is found to be a function of the distance from the battery terminal with grains closest to the electrode/current collector interface having the greatest expansion (≈30%) and grains furthest from the current collector and closest to the counter electrode showing negligible dilation. This implies that the discharge is limited by electrical conductivity. This new CT+DVC technique is widely applicable to the 3D exploration of the microstructural degradation processes for a range of energy materials including fuel cells, capacitors, catalysts, and ceramics. 相似文献
5.
Andreas Wild Maria Strumpf Bernhard Häupler Martin D. Hager Ulrich S. Schubert 《Liver Transplantation》2017,7(5)
An all‐organic battery consisting of two redox‐polymers, namely poly(2‐vinylthianthrene) and poly(2‐methacrylamide‐TCAQ) is assembled. This all‐organic battery shows excellent performance characteristics, namely flat discharge plateaus, an output voltage exceeding 1.3 V, and theoretical capacities of both electrodes higher than 100 mA h g?1. Both organic electrode materials are synthesized in two respective three synthetic steps using the free‐radical polymerization technique. Li‐organic batteries manufactured from these polymers prove their suitability as organic electrode materials. The cathode material poly(2‐vinylthianthrene) (3) displays a discharging plateau at 3.95 V versus Li+/Li and a discharge capacity of 105 mA h g?1, corresponding to a specific energy of about 415 mW h g?1. The anode material poly(2‐methacrylamide‐TCAQ) (7) exhibits an initial discharge capacity of 130 mA h g?1, corresponding to 94% material activity. The combination of both materials results in an all‐organic battery with a discharge voltage of 1.35 V and an initial discharge capacity of 105 mA h g?1 (95% material activity). 相似文献
6.
The use of bio‐nanotechnology for the fabrication of diverse functional nanomaterials with precisely controlled morphologies and microstructures is attracting considerable attention due to its sustainability and renewability. As one of the key energy storage devices, supercapacitor (SC) requires the active electrode material to have high specific surface area, interconnected porous structure, excellent electronic conductivity, and appropriate heteroatom doping for promoting the transfer of electrons and electrolyte ions. The combination of bio‐technology and SC will open up a new avenue for the large‐scale fabrication of high performance functional energy storage devices. In this review, the most state‐of‐the‐art research progress in bio‐nanotechnological fabrication of different nanomaterials, including carbon materials, metal oxides, conducting polymers, and their corresponding composites are reviewed with the following three bio‐nanotechnical approaches covered: (1) biomass carbonization technologies; (2) bio‐template methods; and (3) bio‐complex technologies, while also highlighting their applications as functional SC electrodes. 相似文献
7.
Sulfidation of NiMn‐Layered Double Hydroxides/Graphene Oxide Composites toward Supercapacitor Electrodes with Enhanced Performance
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Supercapacitors can deliver high‐power density and long cycle stability, but the limited energy density due to poor electronic and ionic conductivity of the supercapacitor electrode has been a bottleneck in many applications. A strategy to prepare microflower‐like NiMn‐layered double hydroxides (LDH) with sulfidation is delineated to reduce the charge transfer resistance of supercapacitor electrode and realize faster reversible redox reactions with notably enhanced specific capacitance. The incorporation of graphite oxide (GO) in NiMn LDH during sulfidation leads to simultaneous reduction of GO with enhanced conductivity, lessened defects, and doping of S into the graphitic structure. Cycling stability of the sulfidized composite electrode is enhanced due to the alleviation of phase transformation during electrochemical cycling test. As a result, this sulfidation product of LDH/GO (or LDHGOS) can reach a high‐specific capacitance of 2246.63 F g?1 at a current density of 1 A g?1, and a capacitance of 1670.83 F g?1 is retained at a high‐current density of 10 A g?1, exhibiting an outstanding capacitance and rate performance. The cycling retention of the LDHGOS electrode is also extended to ≈ 67% after 1500 cycles compared to only ≈44% of the pristine NiMn LDH. 相似文献
8.
The collective redox activities of transition‐metal (TM) cations and oxygen anions have been shown to increase charge storage capacity in both Li‐rich layered and cation‐disordered rock‐salt cathodes. Repeated cycling involving anionic redox is known to trigger TM migration and phase transformation in layered Li‐ and Mn‐rich (LMR) oxides, however, detailed mechanistic understanding on the recently discovered Li‐rich rock‐salt cathodes is largely missing. The present study systematically investigates the effect of oxygen redox on a Li1.3Nb0.3Mn0.4O2 cathode and demonstrates that performance deterioration is directly correlated to the extent of oxygen redox. It is shown that voltage fade and hysteresis begin only after initiating anionic redox at high voltages, which grows progressively with either deeper oxidation of oxygen at higher potential or extended cycling. In contrast to what is reported on layered LMR oxides, extensive TM reduction is observed but phase transition is not detected in the cycled oxide. A densification/degradation mechanism is proposed accordingly which elucidates how a unique combination of extensive chemical reduction of TM and reduced quality of the Li percolation network in cation‐disordered rock‐salts can lead to performance degradation in these newer cathodes with 3D Li migration pathways. Design strategies to achieve balanced capacity and stability are also discussed. 相似文献
9.
A Novel Strategy to Suppress Capacity and Voltage Fading of Li‐ and Mn‐Rich Layered Oxide Cathode Material for Lithium‐Ion Batteries
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Shiming Zhang Haitao Gu Hongge Pan Suhui Yang Wubin Du Xiang Li Mingxia Gao Yongfeng Liu Min Zhu Liuzhang Ouyang Dechao Jian Feng Pan 《Liver Transplantation》2017,7(6)
Poor cycling stability is one of the key scientific issues needing to be solved for Li‐ and Mn‐rich layered oxide cathode. In this paper, sodium carboxymethyl cellulose (CMC) is first used as a novel binder in Li1.2Ni0.13Co0.13Mn0.54O2 cathode to enhance its cycling stability. Electrochemical performance is conducted by galvanostatic charge and discharge. Structure and morphology are characterized by X‐ray diffraction, scanning electronic microscopy, high‐resolution transmission electron microscopy, and X‐ray photoelectron spectroscopy. Results reveal that the CMC as binder can not only stabilize the electrode structure by preventing the electrode materials to detach from the current collector but also suppress the voltage fading of the Li1.2Ni0.13Co0.13Mn0.54O2 cathode due to Na+ ions doping. Most importantly, the dissolution of metal elements from the cathode materials into the electrolyte is also inhibited. 相似文献
10.
Aishuak Konarov Hee Jae Kim Jae‐Hyeon Jo Natalia Voronina Yongseok Lee Zhumabay Bakenov Jongsoon Kim Seung‐Taek Myung 《Liver Transplantation》2020,10(24)
Recently, anionic‐redox‐based materials have shown promising electrochemical performance as cathode materials for sodium‐ion batteries. However, one of the limiting factors in the development of oxygen‐redox‐based electrodes is their low operating voltage. In this study, the operating voltage of oxygen‐redox‐based electrodes is raised by incorporating nickel into P2‐type Na2/3[Zn0.3Mn0.7]O2 in such a way that the zinc is partially substituted by nickel. As designed, the resulting P2‐type Na2/3[(Ni0.5Zn0.5)0.3Mn0.7]O2 electrode exhibits an average operating voltage of 3.5 V and retains 95% of its initial capacity after 200 cycles in the voltage range of 2.3–4.6 V at 0.1C (26 mA g?1). Operando X‐ray diffraction analysis reveals the reversible phase transition: P2 to OP4 phase on charge and recovery to the P2 phase on discharge. Moreover, ex situ X‐ray absorption near edge structure and X‐ray photoelectron spectroscopy studies reveal that the capacity is generated by the combination of Ni2+/Ni4+ and O2?/O1? redox pairs, which is supported by first‐principles calculations. It is thought that this kind of high voltage redox species combined with oxygen redox could be an interesting approach to further increase energy density of cathode materials for not only sodium‐based rechargeable batteries, but other alkali‐ion battery systems. 相似文献
11.
Bing‐Qing Xiong Xinwei Zhou Gui‐Liang Xu Yuzi Liu Likun Zhu Youcheng Hu Shou‐Yu Shen Yu‐Hao Hong Si‐Cheng Wan Xiao‐Chen Liu Xiang Liu Shengli Chen Ling Huang Shi‐Gang Sun Khalil Amine Fu‐Sheng Ke 《Liver Transplantation》2020,10(4)
Alloy materials such as Si and Ge are attractive as high‐capacity anodes for rechargeable batteries, but such anodes undergo severe capacity degradation during discharge–charge processes. Compared to the over‐emphasized efforts on the electrode structure design to mitigate the volume changes, understanding and engineering of the solid‐electrolyte interphase (SEI) are significantly lacking. This work demonstrates that modifying the surface of alloy‐based anode materials by building an ultraconformal layer of Sb can significantly enhance their structural and interfacial stability during cycling. Combined experimental and theoretical studies consistently reveal that the ultraconformal Sb layer is dynamically converted to Li3Sb during cycling, which can selectively adsorb and catalytically decompose electrolyte additives to form a robust, thin, and dense LiF‐dominated SEI, and simultaneously restrain the decomposition of electrolyte solvents. Hence, the Sb‐coated porous Ge electrode delivers much higher initial Coulombic efficiency of 85% and higher reversible capacity of 1046 mAh g?1 after 200 cycles at 500 mA g?1, compared to only 72% and 170 mAh g?1 for bare porous Ge. The present finding has indicated that tailoring surface structures of electrode materials is an appealing approach to construct a robust SEI and achieve long‐term cycling stability for alloy‐based anode materials. 相似文献
12.
Lisa Åkerlund Rikard Emanuelsson Stéven Renault Hao Huang Daniel Brandell Maria Strømme Martin Sjödin 《Liver Transplantation》2017,7(20)
An organic cathode material based on a copolymer of poly(3,4‐ethylenedioxythiophene) containing pyridine and hydroquinone functionalities is described as a proton trap technology. Utilizing the quinone to hydroquinone redox conversion, this technology leads to electrode materials compatible with lithium and sodium cycling chemistries. These materials have high inherent potentials that in combination with lithium give a reversible output voltage of above 3.5 V (vs Li0/+) without relying on lithiation of the material, something that is not showed for quinones previously. Key to success stems from coupling an intrapolymeric proton transfer, realized by an incorporated pyridine proton donor/acceptor functionality, with the hydroquinone redox reactions. Trapping of protons in the cathode material effectively decouples the quinone redox chemistry from the cycling chemistry of the anode, which makes the material insensitive to the nature of the electrolyte cation and hence compatible with several anode materials. Furthermore, the conducting polymer backbone allows assembly without any additives for electronic conductivity. The concept is demonstrated by electrochemical characterization in several electrolytes and finally by employing the proton trap material as the cathode in lithium and sodium batteries. These findings represent a new concept for enabling high potential organic materials for the next generation of energy storage systems. 相似文献
13.
Sechan Lee Kyunam Lee Kyojin Ku Jihyun Hong Soo Young Park Ji Eon Kwon Kisuk Kang 《Liver Transplantation》2020,10(32)
Organic electrode materials hold great potential due to their cost‐efficiency, eco‐friendliness, and possibly high theoretical capacity. Nevertheless, most organic cathode materials exhibit a trade‐off relationship between the specific capacity and the voltage, failing to deliver high energy density. Herein, it is shown that the trade‐off can be mitigated by utilizing the multi‐redox capability of p‐type electrodes, which can significantly increase the specific capacity within a high‐voltage region. The molecular structure of 5,10‐dihydro‐5,10‐dimethylphenazine is modified to yield a series of phenoxazine and phenothiazine derivatives with elevated redox potentials by substitutions. Subsequently, the feasibility of the multi‐redox capability is scrutinized for these high‐voltage p‐type organic cathodes, achieving one of the highest energy densities. It is revealed that the seemingly impractical second redox reaction is indeed dependent on the choice of the electrolyte and can be reversibly realized by tailoring the donor number and the salt concentration of the electrolyte, which places the voltage of the multi‐redox reaction within the electrochemical stability window. The results demonstrate that high‐energy‐density organic cathodes can be practically achieved by rational design of multi‐redox p‐type organic electrode materials and the compatibility consideration of the electrolyte, opening up a new avenue toward advanced organic rechargeable batteries. 相似文献
14.
Ultrahigh‐Energy‐Density Lithium‐Ion Batteries Based on a High‐Capacity Anode and a High‐Voltage Cathode with an Electroconductive Nanoparticle Shell
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The combination of high‐capacity anodes and high‐voltage cathodes has garnered a great deal of attention in the pursuit of high‐energy‐density lithium‐ion batteries. As a facile and scalable electrode‐architecture strategy to achieve this goal, a direct one‐pot decoration of high‐capacity silicon (Si) anode materials and of high‐voltage LiCoO2 (LCO) cathode materials is demonstrated with colloidal nanoparticles composed of electroconductive antimony‐doped tin oxide (ATO). The unusual ATO nanoparticle shells enhance electronic conduction in the LCO and Si electrode materials and mitigate unwanted interfacial side reactions between the electrode materials and liquid electrolytes. The ATO‐coated LCO materials (ATO‐LCO) enable the construction of a high‐mass‐loading cathode and suppress the dissolution of cobalt and the generation of by‐products during high‐voltage cycling. In addition, the ATO‐coated Si (ATO‐Si) anodes exhibit highly stable capacity retention upon cycling. Integration of the high‐voltage ATO‐LCO cathode and high‐capacity ATO‐Si anode into a full cell configuration brings unprecedented improvements in the volumetric energy density and in the cycling performance compared to a commercialized cell system composed of LCO/graphite. 相似文献
15.
Al Doping for Mitigating the Capacity Fading and Voltage Decay of Layered Li and Mn‐Rich Cathodes for Li‐Ion Batteries
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Prasant Kumar Nayak Judith Grinblat Mikhael Levi Elena Levi Sangryun Kim Jang Wook Choi Doron Aurbach 《Liver Transplantation》2016,6(8)
Li and Mn‐rich layered cathodes, despite their high specific capacity, suffer from capacity fading and discharge voltage decay upon cycling. Both specific capacity and discharge voltage of Li and Mn‐rich cathodes are stabilized upon cycling by optimized Al doping. Doping Li and Mn‐rich cathode materials Li1.2Ni0.16Mn0.56Co0.08O2 by Al on the account of manganese (as reflected by their stoichiometry) results in a decrease in their specific capacity but increases pronouncedly their stability upon cycling. Li1.2Ni0.16Mn0.51Al0.05Co0.08O2 exhibits 96% capacity retention as compared to 68% capacity retention for Li1.2Ni0.16Mn0.56Co0.08O2 after 100 cycles. This doping also reduces the decrease in the average discharge voltage upon cycling, which is the longstanding fatal drawback of these Li and Mn‐rich cathode materials. The electrochemical impedance study indicates that doping by Al has a surface stabilization effect on these cathode materials. The structural analysis of cycled electrodes by Raman spectroscopy suggests that Al doping also has a bulk stabilizing effect on the layered LiMO2 phase resulting in the better electrochemical performance of Al doped cathode materials as compared to the undoped counterpart. Results from a prolonged systematic work on these cathode materials are presented and the best results that have ever been obtained are reported. 相似文献
16.
Jun Wang Xin He Elie Paillard Nina Laszczynski Jie Li Stefano Passerini 《Liver Transplantation》2016,6(21)
Layered lithium‐ and manganese‐rich oxides (LMROs), described as xLi2MnO3·(1–x)LiMO2 or Li1+yM1–yO2 (M = Mn, Ni, Co, etc., 0 < x <1, 0 < y ≤ 0.33), have attracted much attention as cathode materials for lithium ion batteries in recent years. They exhibit very promising capacities, up to above 300 mA h g?1, due to transition metal redox reactions and unconventional oxygen anion redox reaction. However, they suffer from structural degradation and severe voltage fade (i.e., decreasing energy storage) upon cycling, which are plaguing their practical application. Thus, this review will aim to describe the pristine structure, high‐capacity mechanisms and structure evolutions of LMROs. Also, recent progress associated with understanding and mitigating the voltage decay of LMROs will be discussed. Several approaches to solve this problem, such as adjusting cycling voltage window and chemical composition, optimizing synthesis strategy, controlling morphology, doping, surface modification, constructing core‐shell and layered‐spinel hetero structures, are described in detail. 相似文献
17.
Longtao Ma Shengmei Chen Changbai Long Xinliang Li Yuwei Zhao Zhuoxin Liu Zhaodong Huang Binbin Dong Juan Antonio Zapien Chunyi Zhi 《Liver Transplantation》2019,9(45)
Herein, a two‐species redox reaction of Co(II)/Co(III) and Fe(II)/Fe(III) incorporated in cobalt hexacyanoferrate (CoFe(CN)6) is proposed as a breakthrough to achieve jointly high‐capacity and high‐voltage aqueous Zn‐ion battery. The Zn/CoFe(CN)6 battery provides a highly operational voltage plateau of 1.75 V (vs metallic Zn) and a high capacity of 173.4 mAh g?1 at current density of 0.3 A g?1, taking advantage of the two‐species redox reaction of Co(II)/Co(III) and Fe(II)/Fe(III) couples. Even under extremely fast charge/discharge rate of 6 A g?1, the battery delivers a sufficiently high discharge capacity of 109.5 mAh g?1 with its 3D opened structure framework. This is the highest capacity delivered among all the batteries using Prussian blue analogs (PBAs) cathode up to now. Furthermore, Zn/CoFe(CN)6 battery achieves an excellent cycling performance of 2200 cycles without any capacity decay at coulombic efficiency of nearly 100%. One further step, a sol–gel transition strategy for hydrogel electrolyte is developed to construct high‐performance flexible cable‐type battery. With the strategy, the active materials can adequately contact with electrolyte, resulting in improved electrochemical performance (≈18.73% capacity increase) and mechanical robustness of the solid‐state device. It is believed that this study optimizes electrodes by incorporating multi redox reaction species for high‐voltage and high‐capacity batteries. 相似文献
18.
Benoit Mortemard de Boisse Shin‐ichi Nishimura Eriko Watanabe Laura Lander Akihisa Tsuchimoto Jun Kikkawa Eiichi Kobayashi Daisuke Asakura Masashi Okubo Atsuo Yamada 《Liver Transplantation》2018,8(20)
Increasing the energy density of rechargeable batteries is of paramount importance toward achieving a sustainable society. The present limitation of the energy density is owing to the small capacity of cathode materials, in which the (de)intercalation of ions is charge‐compensated by transition‐metal redox reactions. Although additional oxygen‐redox reactions of oxide cathodes have been recognized as an effective way to overcome this capacity limit, irreversible structural changes that occur during charge/discharge cause voltage drops and cycle degradation. Here, a highly reversible oxygen‐redox capacity of Na2Mn3O7 that possesses inherent Mn vacancies in a layered structure is found. The cross validation of theoretical predictions and experimental observations demonstrates that the nonbonding 2p orbitals of oxygens neighboring the Mn vacancies contribute to the oxygen‐redox capacity without making the Mn?O bond labile, highlighting the critical role of transition‐metal vacancies for the design of reversible oxygen‐redox cathodes. 相似文献
19.
Jian Yan Liping Yang Mengqi Cui Xu Wang Kenji Jianzhi Chee Viet Cuong Nguyen Vipin Kumar Afriyanti Sumboja Ming Wang Pooi See Lee 《Liver Transplantation》2014,4(18)
Polyaniline (PANI), a promising conducting polymer for supercapacitor, exhibits high specific capacitance and good rate capability. However, it suffers from low cycling stability due to the breakage or scission of polymer chains and loss of contact caused by the volume change during the charge–discharge, as well as the irreversible oxidation and reduction. Here, a strategy for using aniline tetramers loaded on graphene oxide (AT‐GO) is developed to prevent chain breaking and increase the tolerance of volume change. The potential window is also controlled to reduce the irreversible reactions. In a three electrode test, AT‐GO exhibits a good cycling stability with specific capacitance remaining more than 93 to 96% after 2000 cycles. In a two electrode test, the specific capacitance remains 97.7% of its initial specific capacitance after 2000 cycles by suppressing the side reactions. AT‐GO also shows a high specific capacitance of more than 769 F g?1 at 1 A g?1 and it remains 581 F g?1 at 60 A g?1, suggesting a good rate capability. These results suggest that AT‐GO is a promising electrode material for practical applications. 相似文献
20.
Review on Challenges and Recent Advances in the Electrochemical Performance of High Capacity Li‐ and Mn‐Rich Cathode Materials for Li‐Ion Batteries
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Prasant Kumar Nayak Evan M. Erickson Florian Schipper Tirupathi Rao Penki Nookala Munichandraiah Philipp Adelhelm Hadar Sclar Francis Amalraj Boris Markovsky Doron Aurbach 《Liver Transplantation》2018,8(8)
Li and Mn‐rich layered oxides, xLi2MnO3·(1–x)LiMO2 (M=Ni, Mn, Co), are promising cathode materials for Li‐ion batteries because of their high specific capacity that can exceed 250 mA h g?1. However, these materials suffer from high 1st cycle irreversible capacity, gradual capacity fading, low rate capability, a substantial charge‐discharge voltage hysteresis, and a large average discharge voltage decay during cycling. The latter detrimental phenomenon is ascribed to irreversible structural transformations upon cycling of these cathodes related to potentials ≥4.5 V required for their charging. Transition metal inactivation along with impedance increase and partial layered‐to‐spinel transformation during cycling are possible reasons for the detrimental voltage fade. Doping of Li, Mn‐rich materials by Na, Mg, Al, Fe, Co, Ru, etc. is useful for stabilizing capacity and mitigating the discharge‐voltage decay of xLi2MnO3·(1–x)LiMO2 electrodes. Surface modifications by thin coatings of Al2O3, V2O5, AlF3, AlPO4, etc. or by gas treatment (for instance, by NH3) can also enhance voltage and capacity stability during cycling. This paper describes the recent literature results and ongoing efforts from our groups to improve the performance of Li, Mn‐rich materials. Focus is also on preparation of cobalt‐free cathodes, which are integrated layered‐spinel materials with high reversible capacity and stable performance. 相似文献