Interfacial Charge Field in Hierarchical Yolk–Shell Nanocapsule Enables Efficient Immobilization and Catalysis of Polysulfides Conversion

Inhibiting the shuttle effect of lithium polysulfides and accelerating their conversion kinetics are crucial for the development of high‐performance lithium–sulfur (Li–S) batteries. Herein, a modified template method is proposed to synthesize the robust yolk–shell sulfur host that is constructed by enveloping dispersive Fe₂O₃ nanoparticles within Mn₃O₄ nanosheet‐grafted hollow N‐doped porous carbon capsules (Fe₂O₃@N‐PC/Mn₃O₄‐S). When applied as a cathode for Li–S batteries, the as‐prepared Fe₂O₃@N‐PC/Mn₃O₄‐S can deliver capacities as high as 1122 mAh g^?1 after 200 cycles at 0.5 C and 639 mAh g^?1 after 1500 cycles at 10 C, respectively. Remarkably, even as the areal sulfur loading is increased to 5.1 mg cm^?2, the cathode can still maintain a high areal specific capacity of 5.08 mAh cm^?2 with a fading rate of only 0.076% per cycle over 100 cycles at 0.1 C. By a further combination analysis of electron holography and electron energy loss spectroscopy, the outstanding performance is revealed to be mainly traced to the oxygen‐vacancy‐induced interfacial charge field, which immobilizes and catalyzes the conversion of lithium polysulfides, assuring low polarization, fleet redox reaction kinetics, and sufficient utilization of sulfur. These new findings may shed light on the dependence of electrochemical performance on the heterostructure of sulfur hosts.     

化能自养硫氧化细菌Halothiobacillus sp.LS2介导的以乙炔为电子受体的硫氧化反应

【目的】探究化能自养硫氧化细菌Halothiobacillus sp. LS2介导的以乙炔为电子受体的厌氧硫氧化反应。【方法】稀释涂布法测定细胞生长情况,离子色谱仪测试硫氧化动力学中SO_4~(2–)和S_2O_3~(2–)以及基于相对荧光定量法的基因表达分析。【结果】尽管菌株LS2在以氧气为电子受体时的最大反应速率V_(max)更高,但在厌氧条件下且以乙炔为电子受体时,菌株LS2的生长量是氧气为电子受体时的2倍,且硫氧化酶基因soxB的表达量显著高于氧气作为电子受体时。【结论】菌株LS2不仅可以以乙炔为电子受体完成厌氧硫氧化反应,且这一代谢过程的产能效率较有氧硫氧化过程更高。本研究首次发现了微生物介导的以乙炔为电子受体的厌氧硫氧化反应,对丰富硫的生物地球化学循环理论有积极意义。     

Elastic Sandwich‐Type rGO–VS2/S Composites with High Tap Density: Structural and Chemical Cooperativity Enabling Lithium–Sulfur Batteries with High Energy Density

Driven by increasing demand for high‐energy‐density batteries for consumer electronics and electric vehicles, substantial progress is achieved in the development of long‐life lithium–sulfur (Li–S) batteries. Less attention is given to Li–S batteries with high volume energy density, which is crucial for applications in compact space. Here, a series of elastic sandwich‐structured cathode materials consisting of alternating VS₂‐attached reduced graphene oxide (rGO) sheets and active sulfur layers are reported. Due to the high polarity and conductivity of VS₂, a small amount of VS₂ can suppress the shuttle effect of polysulfides and improve the redox kinetics of sulfur species in the whole sulfur layer. Sandwich‐structured rGO–VS₂/S composites exhibit significantly improved electrochemical performance, with high discharge capacities, low polarization, and excellent cycling stability compared with their bare rGO/S counterparts. Impressively, the tap density of rGO–VS₂/S with 89 wt% sulfur loading is 1.84 g cm^?3, which is almost three times higher than that of rGO/S with the same sulfur content (0.63 g cm^?3), and the volumetric specific capacity of the whole cell is as high as 1182.1 mA h cm^?3, comparable with the state‐of‐the‐art reported for energy storage devices, demonstrating the potential for application of these composites in long‐life and high‐energy‐density Li–S batteries.     

Microemulsion Assisted Assembly of 3D Porous S/Graphene@g‐C3N4 Hybrid Sponge as Free‐Standing Cathodes for High Energy Density Li–S Batteries

A 3D porous sulfur/graphene@g‐C₃N₄ (S/GCN) hybrid sponge, which can be directly applied as a free‐standing cathode for Li–S batteries, is realized via a microemulsion assisted assembly approach. In this strategy, the interior oil emulsion droplets serve as soft templates to form pores to accommodate sulfur and the hydrophilic GCN stacks around oil droplets to assemble into a crosslinked 3D network. Through this microemulsion encapsulation route, S/GCN cathodes with a sulfur loading as high as 82 wt% can be achieved. Furthermore, the enriched N‐sites in GCN macropores offer numerous adhesion sites for polysulfides, realizing a “physical‐chemical” dual‐confinement for polysulfides from diffusion. Moreover, the robust and highly porous 3D graphene frameworks render efficient electron/Li⁺ transport pathways for fast kinetics as well as good structure integrity. Consequently, in comparison to the conventional G‐sponge/Li₂S_n catholyte system, S/GCN delivers a higher specific capacity, superior high‐rate capability (612 mA h g^?1 at 10 C), and alleviated anode corrosion issues. Particularly, an energy density as high as 1493 W h kg^?1 (calculated on the total weight of the cathode) and an extremely low capacity fading rate of 0.017% per cycle over 800 cycles at 0.3 C are achieved.     

High‐Performance All‐Solid‐State Lithium–Sulfur Batteries Enabled by Amorphous Sulfur‐Coated Reduced Graphene Oxide Cathodes

Safety and the polysulfide shuttle reaction are two major challenges for liquid electrolyte lithium–sulfur (Li–S) batteries. Although use of solid‐state electrolytes can overcome these two challenges, it also brings new challenges by increasing the interface resistance and stress/strain. In this work, the interface resistance and stress/strain of sulfur cathodes are significantly reduced by conformal coating ≈2 nm sulfur (S) onto reduced graphene oxide (rGO). An Li–S full cell consisting of an rGO@S‐Li₁₀GeP₂S₁₂‐acetylene black (AB) composite cathode is evaluated. At 60 °C, the all‐solid‐state Li–S cell demonstrates a similar electrochemical performance as in liquid organic electrolyte, with high rate capacities of 1525.6, 1384.5, 1336.3, 903.2, 502.6, and 204.7 mA h g^?1 at 0.05, 0.1, 0.5, 1.0, 2.0, and 5.0 C, respectively. It can maintain a high and reversible capacity of 830 mA h g^?1 at 1.0 C for 750 cycles. The uniform distribution of the rGO@S nanocomposite in the Li₁₀GeP₂S₁₂‐AB matrix generates uniform volume changes during lithiation/delithiation, significantly reducing the stress/strain, thus extending the cycle life. Minimization of the stress/strain of solid cells is the key for a long cycle life of all‐solid‐state Li–S batteries.     

Tethered Molecular Sorbents: Enabling Metal‐Sulfur Battery Cathodes

A rechargeable battery that uses sulfur at the cathode and a metal (e.g., Li, Na, Mg, or Al) at the anode provides perhaps the most promising path to a solid‐state, rechargeable electrochemical storage device capable of high charge storage capacity. It is understood that solubilization in the electrolyte and loss of sulfur in the form of long‐chain lithium polysulfides (Li₂S_x, 2 < x < 8) has hindered development of the most studied of these devices, the rechargeable Li‐S battery. Beginning with density‐functional calculations of the structure and interactions of a generic lithium polysulfide species with nitrile containing molecules, it is shown that it is possible to design nitrile‐rich molecular sorbents that anchor to other components in a sulfur cathode and which exert high‐enough binding affinity to Li₂S_x to limit its loss to the electrolyte. It is found that sorbents based on amines and imidazolium chloride present barriers to dissolution of long‐chain Li₂S_x and that introduction of as little as 2 wt% of these molecules to a physical sulfur‐carbon blend leads to Li‐S battery cathodes that exhibit stable long‐term cycling behaviors at high and low charge/discharge rates.     

Kinetics of sulfur oxidation by thiobacillus ferrooxidans

Abstract

Thiobacillus ferrooxidans ATCC 23270 was grown with elemental sulfur as the energy source. Substrate oxidation was measured using a Clark‐type oxygen electrode. Whole cells demonstrated a broad pH optimum for sulfur oxidation between pH 2.0 and 8.0. The V _max and K_sfor sulfur oxidation varied depending on pH. Sulfite was oxidized at 227 nmol O₂/min/mg protein. Thiosulfate oxidation was slow, and tetrathionate oxidation was not detected. At a concentration of 2 mM, sodium azide completely inhibited sulfur, sulfite, and thiosulfate oxidation. Inhibition by N‐ethylmaleimide, antimycin A, and 2‐heptyl‐4‐hydroxyquinoline N‐oxide varied with substrate.     

Citrate‐Assisted Growth of NiCo2O4 Nanosheets on Reduced Graphene Oxide for Highly Reversible Lithium Storage

Hybrid nanostructures based on graphene and transition metal oxides hold great promise as high‐performance electrode materials for next‐generation lithium‐ion batteries. In this work, the rational design and fabrication of NiCo₂O₄ nanosheets supported on reduced graphene oxide (denoted as rGO/NiCo₂O₄) is presented as a novel anode material for highly efficient and reversible lithium storage. A solution method is applied to grow Ni‐Co precursor nanosheets on rGO, in which the addition of trisodium citrate is found crucial to guide the formation of uniform Ni‐Co precursor nanosheets. Subsequent thermal treatment results in formation of crystalline NiCo₂O₄ nanosheets on rGO without damaging the morphology. The interconnected NiCo₂O₄ nanosheets form hierarchically porous films on both sides of rGO. Such a hybrid nanostructure would effectively promote the charge transport and withstand volume variation upon prolonged charge/discharge cycling. As a result, the rGO/NiCo₂O₄ nanocomposite demonstrates high reversible capacities of 954.3 and 656.5 mAh g^–1 over 50 cycles at current densities of 200 and 500 mA g^–1 respectively, and remarkable capacity retention at increased current densities.     

Effects of different graphene-based nanomaterials as elicitors on growth and ganoderic acid production by Ganoderma lucidum

Graphene-based nanomaterials (GBNs) have attracted considerable interest nowadays due to their wide range of applications. However, very little attention has been paid to the application of nanomaterials as potential elicitors for production of valuable metabolites. Herein, aiming to earn insight into effects of nanomaterials on secondary metabolite biosynthesis by medicinal fungi, we evaluated the influence of GBNs on growth and production of ganoderic acid (GA) by Ganoderma lucidum in submerged culture. Graphene oxide (GO), reduced graphene oxide (rGO), and rGO/Fe₃O₄ nanocomposite were synthesized successfully and characterized by X-ray diffraction, Fourier transform infrared spectroscopy, and scanning electron microscopy analysis. The prepared nanomaterials were added to the culture of G. lucidum at final concentrations of 50, 100, and 150 mg/L on Day 5. The results showed that the elicitation of G. lucidum with GO and rGO decreased the cell dry weight and GA production slightly, especially in higher concentrations. However, rGO/Fe₃O₄ nanocomposite not negatively affected cell growth and improved GA production. G. lucidum growth rate responded to elicitation experiments differently and depended on the type of nanomaterials and their concentrations, but almost all GBNs caused an increase in GA content (mg/100 mg dry weight). Also, field emission scanning electron microscopy morphological study showed that under elicitation, mycelia were more condensed and tightly stacked together. The findings from this study may suggest that GBNs in low concentrations could be applied as elicitors to secondary metabolites production from higher fungus, but further environmental, physiological, and biological studies required.     

Layer‐by‐Layer Na3V2(PO4)3 Embedded in Reduced Graphene Oxide as Superior Rate and Ultralong‐Life Sodium‐Ion Battery Cathode

Na₃V₂(PO₄)₃ (NVP) is regarded as a promising cathode for advanced sodium‐ion batteries (SIBs) due to its high theoretical capacity and stable sodium (Na) super ion conductor (NASICON) structure. However, strongly impeded by its low electronic conductivity, the general NVP delivers undesirable rate capacity and fails to meet the demands for quick charge. Herein, a novel and facile synthesis of layer‐by‐layer NVP@reduced graphene oxide (rGO) nanocomposite is presented through modifying the surface charge of NVP gel precursor. The well‐designed layered NVP@rGO with confined NVP nanocrystal in between rGO layers offers high electronic and ionic conductivity as well as stable structure. The NVP@rGO nanocomposite with merely ≈3.0 wt% rGO and 0.5 wt% amorphous carbon, yet exhibits extraordinary electrochemical performance: a high capacity (118 mA h g^?1 at 0.5 C attaining the theoretical value), a superior rate capability (73 mA h g^?1 at 100 C and even up to 41 mA h g^?1 at 200 C), ultralong cyclability (70.0% capacity retention after 15 000 cycles at 50 C), and stable cycling performance and excellent rate capability at both low and high operating temperatures. The proposed method and designed layer‐by‐layer active nanocrystal@rGO strategy provide a new avenue to create nanostructures for advanced energy storage applications.     

Anaerobic Elemental Sulfur Reduction by Fungus Fusarium oxysporum

Reduction of inorganic sulfur compounds by the fungus Fusarium oxysporum was examined. When transferred from a normoxic to an anoxic environment, F. oxysporum reduced elemental sulfur to hydrogen sulfide (H₂S). This reaction accompanied fungal growth and oxidation of the carbon source (ethanol) to acetate. Over 2-fold more of H₂S than of acetate was produced, which is the theoretical correlation for the oxidation of ethanol to acetate. NADH-dependent sulfur reductase (SR) activity was detected in cell-free extracts of the H₂S-producing fungus, and was found to be up-regulated under the anaerobic conditions. On the other hands both O₂ consumption by the cells and cytochrome c oxidase activity by the crude mitochondrial fractions decreased. These results indicate that H₂S production involving SR was due to a novel dissimilation mechanism of F. oxysporum, and that the fungus adapts to anaerobic conditions by replacing the energy-producing mechanism of O₂ respiration with sulfur reduction.     

Raman microspectrometry sulfur detection and characterization in the marine ectosymbiotic nematode Eubostrichus dianae (Desmodoridae, Stilbonematidae)

Background information. Marine nematodes belonging to the Stilbonematidae (Desmodoridae) family are described as living in obligatory association with sulfur‐oxidizing chemoautotrophic ectosymbionts. The symbiotic bacteria carrying out this chemosynthesis should contain elemental sulfur in periplasmic granules as sulfur granules of chemoautotrophic endosymbionts described in various marine invertebrates. Results. Based on TEM (transmission electron microscopy) analyses, extracellular bacteria surrounding Eubostrichus dianae possess these spherical periplasmic granules. Few investigative techniques can be used to identify elemental sulfur, S₈, such as EDXS (energy dispersive X‐ray spectroscopy) and EELS (electron energy loss spectroscopy), which are associated with cryo‐fixation of the sample to avoid sulfur loss. These techniques are time consuming, expensive and require technical skills. Raman microspectrometry applied to the analysis of E. dianae allowed us to detect elemental sulfur, S₈, and confirmed the location of these sulfur clusters in the bacterial coat. In the same way, Raman spectrometry was positively applied to the endosymbiotic bivalve Codakia orbicularis, suggesting that this technique can be used to characterize sulfur in ecto‐ as well as in endo‐symbiotic sulfur‐oxidizing bacteria. Conclusions. As Raman spectrometry can be used on living organisms (without preliminary fixation) without sample damage and preserving the molecular structure of the sulfur (denatured during chemical fixation), it represents a very well‐adapted investigative tool for biologists. This technique therefore permits us to detect quickly and easily (in a few seconds and on entire living animals) the presence of sulfur compounds in the symbiotic nematode.     

Bioinspired Binders Actively Controlling Ion Migration and Accommodating Volume Change in High Sulfur Loading Lithium–Sulfur Batteries

High‐loading lithium–sulfur batteries have gained considerable fame for possessing high area capacity, but face a stern challenge from capacity fading because of serious issues, including “polysulfides shuttling,” insulating S/Li₂S, large volume changes, and the shedding of S/C particles during drying or the cell encapsulation process. Herein, a bioinspired water‐soluble binder framework is constructed via intermolecular physical cross‐linking of functional side chains hanging on the terpolymer binder. Experimental results and density‐functional theory (DFT) calculations reveal that this network binder featuring superior volume change accommodation can also capture lithium polysulfides (LiPSs) through strong anchoring of O, N⁺ actives to LiPSs by forming Li···O and N⁺···S_x^2? bonds. In addition, the abundant negative charged sulfonate coordination sites and good electrolyte uptake of the designed binder endow the assembled cells with high lithium ion conductivity and fast lithium ion diffusion. Consequently, a remarkable capacity retention of 98% after 350 cycles at 1 C and a high areal capacity of 12.8 mA h cm^?2 with high sulfur loading of 12.0 mg cm^?2 are achieved by applying the environmentally friendly binder.     

Rechargeable Iron–Sulfur Battery without Polysulfide Shuttling

Sulfur represents one of the most promising cathode materials for next‐generation batteries; however, the widely observed polysulfide dissolution/shuttling phenomenon in metal–sulfur redox chemistries has severely restricted their applications. Here it is demonstrated that when pairing the sulfur electrode with the iron metal anode, the inherent insolubility of iron sulfides renders the shuttling‐free nature of the Fe–S electrochemical reactions. Consequently, the sulfur electrode exhibits promising performance for Fe²⁺ storage, where a high capacity of ≈1050 mAh g^?1, low polarization of ≈0.16 V as well as stable cycling of 150 cycles are realized. The Fe–S redox mechanism is further revealed as an intriguing stepwise conversion of S₈ ? FeS₂ ? Fe₃S₄ ? FeS, where a low volume expansion of ≈32.6% and all‐solid‐state phase transitions facilitate the reaction reversibility. This study suggests an alternative direction to exploit sulfur electrodes in rechargeable transition metal–sulfur batteries.     

Freestanding and Sandwich‐Structured Electrode Material with High Areal Mass Loading for Long‐Life Lithium–Sulfur Batteries

Freestanding cathode materials with sandwich‐structured characteristic are synthesized for high‐performance lithium–sulfur battery. Sulfur is impregnated in nitrogen‐doped graphene and constructed as primary active material, which is further welded in the carbon nanotube/nanofibrillated cellulose (CNT/NFC) framework. Interconnected CNT/NFC layers on both sides of active layer are uniquely synthesized to entrap polysulfide species and supply efficient electron transport. The 3D composite network creates a hierarchical architecture with outstanding electrical and mechanical properties. Synergistic effects generated from physical and chemical interaction could effectively alleviate the dissolution and shuttling of the polysulfide ions. Theoretical calculations reveal the hydroxyl functionization exhibits a strong chemical binding with the discharge product (i.e., Li₂S). Electrochemical measurements suggest that the rationally designed structure endows the electrode with high specific capacity and excellent rate performance. Specifically, the electrode with high areal sulfur loading of 8.1 mg cm^?2 exhibits an areal capacity of ≈8 mA h cm^?2 and an ultralow capacity fading of 0.067% per cycle over 1000 discharge/charge cycles at C/2 rate, while the average coulombic efficiency is around 97.3%, indicating good electrochemical reversibility. This novel and low‐cost fabrication procedure is readily scalable and provides a promising avenue for potential industrial applications.     

Sulfur Species Investigation in Extra- and Intracellular Sulfur Globules of Acidithiobacillus ferrooxidans and Acidithiobacillus caldus

The sulfur chemical speciation in extracellular and intracellular sulfur globules of Acidithiobacillus ferrooxidans and Acidithiobacillus caldus were investigated with an integrated approach including scanning electron microscopy, transmission electron microscopy, energy dispersive spectroscopy and sulfur K-edge X-ray absorption near edge structure spectroscopy (XANES). The results indicated that both strains can accumulate extracellular sulfur globules when grown on thiosulfate, and the major sulfur chemical speciation of which were S₈ for A. ferrooxidans and mixture of ring sulfur and polythionate for A. caldus, respectively. In contrast, A. ferrooxidans can accumulate both linear sulfur and S₈ internally when grown with sulfur powder and thiosulfate, whereas A. caldus did not accumulate intracellular sulfur globules. In addition, the fitted results of sulfur K-edge XANES spectra indicated that the reduced glutathione (containing thiols groups) were involved in sulfur bio-oxidation of both strains and the tetrathionate were the intermediate products during thiosulfate metabolism by two strains.     

3D Porous γ‐Fe2O3@C Nanocomposite as High‐Performance Anode Material of Na‐Ion Batteries

A simple and template‐free method for preparing three‐dimensional (3D) porous γ‐Fe₂O₃@C nanocomposite is reported using an aerosol spray pyrolysis technology. The nanocomposite contains inner‐connected nanochannels and γ‐Fe₂O₃ nanoparticles (5 nm) uniformly embedded in a porous carbon matrix. The size of γ‐Fe₂O₃ nanograins and carbon content can be controlled by the concentration of the precursor solution. The unique structure of the 3D porous γ‐Fe₂O₃@C nanocomposite offers a synergistic effect to alleviate stress, accommodate large volume change, prevent nanoparticles aggregation, and facilitate the transfer of electrons and electrolyte during prolonged cycling. Consequently, the nanocomposite shows high‐rate capability and long‐term cyclability when applied as an anode material for Na‐ion batteries (SIBs). Due to the simple one‐pot synthesis technique and high electrochemical performance, 3D porous γ‐Fe₂O₃@C nanocomposites have a great potential as anode materials for rechargeable SIBs.     

Covalent Encapsulation of Sulfur in a MOF‐Derived S,N‐Doped Porous Carbon Host Realized via the Vapor‐Infiltration Method Results in Enhanced Sodium–Sulfur Battery Performance

Practical applications of room temperature sodium–sulfur batteries are still inhibited by the poor conductivity and slow reaction kinetics of sulfur, and dissolution of intermediate polysulfides in the commonly used electrolytes. To address these issues, starting from a novel 3D Zn‐based metal–organic framework with 2,5‐thiophenedicarboxylic acid and 1,4‐bis(pyrid‐4‐yl) benzene as ligands, a S, N‐doped porous carbon host with 3D tubular holes for sulfur storage is fabricated. In contrast to the commonly used melt‐diffusion method to confine sulfur physically, a vapor‐infiltration method is utilized to achieve sulfur/carbon composite with covalent bonds, which can join electrochemical reaction without low voltage activation. A polydopamine derived N‐doped carbon layer is further coated on the composite to confine the high‐temperature‐induced gas‐phase sulfur inside the host. S and N dopants increase the polarity of the carbon host to restrict diffusion of sulfur, and its 3D porous structure provides a large storage area for sulfur. As a result, the obtained composite shows outstanding electrochemical performance with 467 mAh g^?1 (1262 mAh g^?1_(sulfur)) at 0.1 A g^?1, 270 mAh g^?1 (730 mAh g^?1_(sulfur)) after 1000 cycles at 1 A g^?1 and 201 mAh g^?1 (543 mAh g^?1_(sulfur)) at 5.0 A g^?1.     

3D Hyperbranched Hollow Carbon Nanorod Architectures for High‐Performance Lithium‐Sulfur Batteries

Lithium‐sulfur batteries have been plagued for a long time by low Coulombic efficiency, fast capacity loss, and poor high rate performance. Here, the synthesis of 3D hyperbranched hollow carbon nanorod encapsulated sulfur nanocomposites as cathode materials for lithium‐sulfur batteries is reported. The sulfur nanocomposite cathodes deliver a high specific capacity of 1378 mAh g^‐1 at a 0.1C current rate and exhibit stable cycling performance. The as‐prepared sulfur nanocomposites also achieve excellent high rate capacities and cyclability, such as 990 mAh g^‐1 at 1C, 861 mAh g^‐1 at 5C, and 663 mAh g^‐1 at 10C, extending to more than 500 cycles. The superior electrochemical performance are ascribed to the unique 3D hyperbranched hollow carbon nanorod architectures and high length/radius aspect ratio of the carbon nanorods, which can effectively prevent the dissolution of polysulfides, decrease self‐discharge, and confine the volume expansion on cycling. High capacity, excellent high‐rate performance, and long cycle life render the as‐developed sulfur/carbon nanorod nanocomposites a promising cathode material for lithium‐sulfur batteries.     

An Efficient Separator with Low Li‐Ion Diffusion Energy Barrier Resolving Feeble Conductivity for Practical Lithium–Sulfur Batteries

Due to unprecedented features including high‐energy density, low cost, and light weight, lithium–sulfur batteries have been proposed as a promising successor of lithium‐ion batteries. However, unresolved detrimental low Li‐ion transport rates in traditional carbon materials lead to large energy barrier in high sulfur loading batteries, which prevents the lithium–sulfur batteries from commercialization. In this report, to overcome the challenge of increasing both the cycling stability and areal capacity, a metallic oxide composite (NiCo₂O₄@rGO) is designed to enable a robust separator with low energy barrier for Li‐ion diffusion and simultaneously provide abundant active sites for the catalytic conversion of the polar polysulfides. With a high sulfur‐loading of 6 mg cm^?2 and low sulfur/electrolyte ratio of 10, the assembled batteries deliver an initial capacity of 5.04 mAh cm^?2 as well as capacity retention of 92% after 400 cycles. The metallic oxide composite NiCo₂O₄@rGO/PP separator with low Li‐ion diffusion energy barrier opens up the opportunity for lithium–sulfur batteries to achieve long‐cycle, cost‐effective operation toward wide applications in electric vehicles and electronic devices.