共查询到20条相似文献,搜索用时 15 毫秒
1.
Raymond Dennis 《Phytochemistry》1973,12(11):2705-2708
Utilizing GLC, IR, combined GC-MS, the following constituents were identified in the essential oil of Psiadia salviifolia; β-pinene, limonene, γ-terpinene, p-cymene, α-copaene, linalool, β-bourbonene, α-himachalene, γ-cadinene, δ-cadinene, -γ-elemene, and a hydroxy derivative of calamenene. A new monoterpene hydrocarbon was also isolated which from MS and IR evidence was named as 7-methyl-3-methylene-octa-1,4-diene. 相似文献
2.
Elsa Steinunn Halldorsdottir Ragnheidur Helga Palmadottir Nils T. Nyberg Elin Soffia Olafsdottir 《Phytochemistry letters》2013,6(3):355-359
8S-O-acetylepiclavolonine, a new Lycopodium alkaloid, was isolated from the Icelandic club moss Diphasiastrum alpinum and its structure and stereochemistry was determined using a combination of NMR spectroscopy and mass spectrometry. The previously described alkaloids 5R,8R-O-acetylfawcettiine, 5R,8S-O-acetyllofoline, lycodoline and anhydrolycodoline were found in D. alpinum for the first time together with previously reported lycopodine and clavolonine. The 1H NMR spectra of 8S-O-acetylepiclavolonine and 5R,8S-O-acetyllofoline, revealed a highly deshielded proton at ca. 12 ppm, which seems to be stabilized by an intramolecular hydrogen bond to the carbonyl oxygen of the 8S-O-acetyl group. The isolated alkaloids were tested toward acetylcholinesterase in vitro without showing significant inhibition. 相似文献
3.
Two new diterpenes, 3α-angeloyloxy-18-hydroxy-13-furyl-ent-labda-8(17)-ene and 3α-hydroxy-18-angeloyloxy- 13-furyl-ent-labda-8(17)-ene and an only recently reported third diterpene, 3α, 18-dihydroxy-13-furyl-ent-labda-8(17)-ene, were isolated from the leaves of Gutierrezia grandis. Their structures were determined by mass spectral, IR, 1H NMR and 13C NMR data was well as chemical evidence. 相似文献
4.
Six C31-secodammarane-type triterpenoid saponins, in addition to alnustic acid, were isolated from the male flowers of Alnus pendula. Two of these saponins were new and were shown to be the 12-O-(2′-O-acetyl)-β-d-xylopyranoside and the 12-O-(2′-O-acetyl)-β-d-glucopyranoside of alnustic acid, respectively, on the basis of their physico-chemical data. 相似文献
5.
《Phytochemistry》1986,25(11):2557-2561
8-O-Foliamenthoyleuphroside and 2′-O,8-O-difoliamenthoyleuphroside, new foliamenthic acid esters of euphroside, and the known iridoid euphroside have been isolated from the leaves and twigs of Clerodendrum incisum. From the roots of the same plant the known iridoid plantarenaloside has been isolated. The taxonomic significance of these findings is discussed. 相似文献
6.
《Phytochemistry》1987,26(4):1147-1152
Six phenolic glucoside gallates: D-threo-guaiacylglycerol 8-O-, L-threo-guaiacylglycerol 8-O-, 3-methoxy-4-hydroxyphenol 1-O-, gentisic acid 5-O-, 3,5- dimethoxy-4-hydroxyphenol 1-O- and cis-coniferyl alcohol 4-O-β-D-(6′-O-galloyl)glucopyranosides were isolated from Quercus mongolica and Q. acutissima. 相似文献
7.
Phytochemical investigation on the whole plant of Eryngium yuccifolium resulted in the isolation and identification of three phenolic compounds (1-3) and 12 polyhydroxylated triterpenoid saponins, named eryngiosides A-L (4-15), together with four known compounds kaempferol-3-O-(2,6-di-O-trans-p-coumaroyl)-β-d-glucopyranoside (16), caffeic acid (17), 21β-angeloyloxy-3β-[β-d-glucopyranosyl-(1→2)]-[β-d-xylopyranosyl-(1→3)]-β-d-glucuronopyranosyloxyolean-12-ene-15α,16α,22α,28-tetrol (18), and saniculasaponin III (19). This study reports the isolation of these compounds and their structural elucidation by extensive spectroscopic analyses and chemical degradation. 相似文献
8.
A toxic diterpenoid diester and a monoester were isolated from the fruits of Aleurites fordii. The structure of the monoester was found to be 13-O-acetyl-16-hydroxyphorbol by transforming it into bisdehydrophorbol-(12,20)-diacetate. The structure of the toxic constituent was established as 12-O-palmityl-13-O-acetyl-16-hydroxyphorbol by partial synthesis from the monoester. 相似文献
9.
Cycloartane triterpenoids, 2′,24-O-diacetylisodahurinol-3-O-α-l-arabinopyranoside, 24-O-acetylisodahurinol-3-O-α-l-arabinopyranoside, 12β-hydroxy-25-anhydrocimigenol, cimigenol-12-one, 12β-hydroxy-15-deoxycimigenol, 2′-O-acetyl-24-epi-cimigenol-3-O-α-l-arabinopyranoside, 2′-O-acetylcimigenol-3-O-β-d-xylopyranoside, 25-anhydrocimigenol-3-O-α-l-arabinopyranoside, 2′,23-O-diacetylshengmanol-3-O-α-l-arabinopyranoside, and 2′,24-O-diacetyl-25-anhydrohydroshengmanol-3-O-α-l-arabinopyranoside, together with eight known compounds, were isolated from aerial parts of Cimicifuga foetida. Their structures were determined by application of spectroscopic analyses and chemical methods. Biological evaluation of the compounds against human HL-60, SMMC-7721, A549, SK-BR-3, and PANC-1 cell lines indicated that three of these compounds exhibited broad-spectrum and moderate cytotoxic activities, with IC50 values ranging from 6.20 to 22.74 μM. By comparing previous cytotoxic testing data and bioassay results from this study, preliminary structure–activity relationships of compounds with a cimigenol-skeleton can be proposed. 相似文献
10.
Huong Thuy Le Thien-Y Vu Tran-Van-Anh Nguyen Mai Dinh Tri Nguyen-Kim-Tuyen Pham Huy Truong Nguyen Ngoc-Hong Nguyen Huu-Hung Nguyen Thuc-Huy Duong 《化学与生物多样性》2023,20(6):e202300319
Sphaeranthus africanus L. is native in Vietnam. Little is known about α-glucosidase inhibition of Sphaeranthus africanus and its isolated compounds. A bioactive-guided isolation was applied to the Vietnamese Sphaeranthus africanus to find α-glucosidase inhibitory components. Eight compounds were detected and structurally elucidated. They are 3-angeloyloxy-5-[2′′,3′′-epoxy-2′′-methylbutanoyloxy]-7-hydroxycarvotacetone, 3-angeloyloxy-5-[3′′-chloro-2′′-hydroxy-2′′-methylbutanoyloxy]-7-hydroxycarvotacetone, 3-angeloyloxy-5-[2′′R,3′′R-dihydroxy-2′′-methyl-butanoyloxy]-7-hydroxycarvotacetone, 3-angeloyloxy-5-[2′′S,3′′R-dihydroxy-2′′-methylbutanoyloxy]-7-hydroxycarvotacetone, 3-angeloyloxy-5-[2′′S,3′′S-dihydroxy-2′′-methylbutanoyloxy]-7-hydroxycarvotacetone, 5-angeloyloxy-7-hydroxy-3-tigloyloxycarvotacetone, 3-O-methylquercetin, and chrysosplenol D. Their chemical structures were elucidated by extensive 1D and 2D NMR analysis and high-resolution mass spectroscopy as well as comparisons in literature. 3-Angeloyloxy-5-[2′′S,3′′S-dihydroxy-2′′-methylbutanoyloxy]-7-hydroxycarvotacetone is a new compound. Isolated compounds were evaluated for the α-glucosidase inhibition. Isolated compounds showed moderate activity with IC50 values ranging from 128.9–274.3 μM while others are weak. A molecular docking study was conducted, indicating that isolated compounds are potent α-glucosidase inhibitory compounds. 相似文献
11.
Phytochemical research of Pteris multifida Poir. led to the isolation of fifteen compounds, including six flavonoids (1–6) and nine sesquiterpenoids (7–15). Their structures were characterized by NMR, MS, ORD and CD data. Compounds kaempferol 3-O-α-L-rhamnoside-7-O-β-D-glucoside (1), myricetin 3-O-β-D-glucoside (2), kaempferol 3-O-β-D-glucoside (4), luteolin-7-O-β-D-rutinoside (5), quercetin-3-O-α-L-rhamnopyranoside (6), (2S,3S)-12-hydroxypterosin Q (7), (2S,3S)-pterosin Q (8), 2-hydroxypterosin C (9) and (2S)-12-hydroxypterosin A (10) were first isolated from P. multifida, and compounds 1–2 and 10 were first isolated from the family Pteridaceae. Furthermore, the chemotaxonomic significance of the isolates was discussed. 相似文献
12.
From an ether extract of the twigs and leaves of Sapium insigne four new diterpene esters were isolated. They were identified as 12-O-(2′E, 4′E-decadienoyl)-4-deoxy-16-hydroxyphorbol-13-acetate, 12-O-hexanoyl-4α-deoxy-phorbol-13-acetate, 12-O-hexanoyl-4α-deoxy-16-hydroxyphorbo-1-13-acetate and 12-O-dodecanoyl-4α-deoxy-16-hydroxyphorbol-13-acetate by spectroscopic and chemical methods. 相似文献
13.
Two hydrolysable tannins were isolated from green tea, and their structures were characterized by chemical and spectral means as 1,4,6-tri-O -galloyl-β-d-glucose and 1-O-galloyl-4,6-(?)-hexahydroxydiphenoyl-β-d-glucose. In addition, a new proanthocyanidin gallate was isolated, together with the known procyanidins B-2, B-4 and C-1. The structure of the proanthocyanidin was established as epigallocatechin-(4β → 8)-3-O-galloylepicatechin. 相似文献
14.
Blue flowers of six Bhutani Meconopsis species, M. bhutanica, M. bella, M. horridula, M. simplicifolia, M. primulina and M. polygonoides, were surveyed for anthocyanins and other flavonoids. Four anthocyanins were isolated and identified as cyanidin 3-O-sambubioside-7-O-glucoside (1), cyanidin 3-O-[xylosyl-(1 → 2)-(6″-malonylglucoside)]-7-O-glucoside (2), cyanidin 3-O-sambubioside (4) and cyanidin 3-O-[xylosyl-(1 → 2)-(6″-malonylglucoside)] (5). On the other hand, 12 flavonols were isolated from their Meconopsis species with various combination and characterized as kaempferol 3-O-glycosides (8–12), kaempferol 3,7-O-glycosides (13–16), quercetin 3-O-glycosides (17 and 18) and isorhamnetin 3-O-glycoside (19). Of six Meconopsis species which were surveyed in this experiment, anthocyanin and flavonol composition of five species except for M. horridula was clarified for the first time. Their Meconopsis species showed the different flavonoid profiles, respectively, and flavonoid diversity within the glycosylation level of Meconopsis flowers were indicated. 相似文献
15.
Matteo Adinolfi Gaspare Barone Margherita Belardini Rosa Lanzetta Guglielmo Laonigro Michelangelo Parrilli 《Phytochemistry》1984,23(9):2091-2093
From the bulbs of Muscari comosum two novel 3-benzyl-4-chromanones, 7-O-methyl-3,9-dihydropunctatin and 8-O-demethyl-7-O-methyl-3,9-didropunctatin, were isolated. 相似文献
16.
Maeda H Kakoki N Ayabe M Koga Y Oribe T Matsuo Y Tanaka T Kouno I 《Phytochemistry》2011,72(8):796-803
ent-Eudesmane sesquiterpenoids, 8,11-dihydroxy-2,4-cycloeudesmane, 11-hydroxy-2,4-cycloeudesman-8-one and 2,4-cyclo-7(11)-eudesmen-8-one, were isolated from the wood of Platycarya strobilacea, which has been used as an aromatic tree since at least the 18th century. On charring the wood, 2,4-cyclo-7(11)-eudesmen-8-one was detected in the smoke. In the charred wood, the concentrations of ellagitannins, such as galloyl pedunculagin, dramatically decreased, whereas concentrations of pentagalloyl glucose, and other gallotannins were relatively stable. In addition, two other compounds, the 6′-O-m- and p-digalloyl oak lactone precursor and the 3-O-methylellagic acid 4′-O-(4″-O-galloyl)-xylopyranoside, were isolated from the charred wood along with m- and p-digallic acid. 相似文献
17.
Gülcemal D Alankuş-Çalışkan O Karaalp C Ors AU Ballar P Bedir E 《Carbohydrate research》2010,345(17):2529-2533
A new flavanone glycoside, naringenin-7-O-β-d-glucuronopyranoside, and a new flavonol glycoside, 6-hydroxykaempferol-7-O-β-d-glucuronopyranoside were isolated together with 12 known compounds, 5 flavone glycoside; hispidulin-7-O-β-d-glucuronopyranoside, apigenin-7-O-β-d-methylglucuronopyranoside, hispidulin-7-O-β-d-methylglucuronopyranoside, hispidulin-7-O-β-d-glucopyranoside, apigenin-7-O-β-d-glucopyranoside, a flavonol; kaempferol, two flavone; apigenin, and luteolin, a flavanone glycoside; eriodictyol-7-O-β-d-glucuronopyranoside, and three phenol glycoside; arbutin, salidroside, and 3,5-dihydroxyphenethyl alcohol-3-O-β-d-glucopyranoside from Centaurea urvillei subsp. urvillei. The structure elucidation of the new compounds was achieved by a combination of one- (1H and 13C) and two-dimensional NMR techniques (G-COSY, G-HMQC, and G-HMBC) and LC-ESI-MS. The isolated compounds were tested for their antiproteasomal activity. The results indicated that kaempferol, a well known and widely distributed flavonoid in the plant kingdom, was the most active antiproteasomal agent, followed by apigenin, eriodictyol-7-O-β-d-glucuronopyranoside, 3,5-dihydroxyphenethyl alcohol-3-O-β-d-glucopyranoside, and salidroside, respectively. 相似文献
18.
A new flavonol glycoside, gossypetin 8-O-rhamnoside, was isolated from flower petals of Gossypium arboreum along with quercetin 7-O-glucoside, quercetin 3-O-glucoside and quercetin 3′-O-glucoside. These compounds showed antibacterial activity against Pseudomonas maltophilia and Enterobacter cloacae. 相似文献
19.
Ryo Nakabayashi Makoto Kobayashi Keiko Yonekura-Sakakibara Mami Yamazaki Mariko Kitajima Hiromitsu Takayama 《Phytochemistry》2009,70(8):1017-1029
In order to conduct metabolomic studies in a model plant for genome research, such as Arabidopsis thaliana (Arabidopsis), it is a prerequisite to obtain structural information for the isolated metabolites from the plant of interest. In this study, we isolated metabolites of Arabidopsis in a relatively non-targeted way, aiming at the construction of metabolite standards and chemotaxonomic comparison. Anthocyanins (5 and 7) called A8 and A10 were isolated and their structures were elucidated as cyanidin 3-O-[2-O-(β-d-xylopyranosyl)-6-O-(4-O-(β-d-glucopyranosyl)-E-p-coumaroyl)-β-d-glucopyranoside]-5-O-[6-O-(malonyl)-β-d-glucopyranoside] and cyanidin 3-O-[2-O-(2-O-(E-sinapoyl)-β-d-xylopyranosyl)-6-O-(4-O-(β-d-glucopyranosyl)-E-p-coumaroyl)-β-d-glucopyranoside]-5-O-[β-d-glucopyranoside] from analyses of 1D NMR, 2D NMR (1H NMR, NOE, 13C NMR, HMBC and HMQC), HRFABMS, FT-ESI-MS and GC-TOF-MS data. In addition, 35 known compounds, including six anthocyanins, eight flavonols, one nucleoside, one indole glucosinolate, four phenylpropanoids and a derivative, together with three indoles, one carotenoid, one apocarotenoid, three galactolipids, two chlorophyll derivatives, one steroid, one hydrocarbon, and two dicarboxylic acids, were also isolated and identified from their spectroscopic data. 相似文献
20.
A new polyhydroxy-1-ketosteroid, flavescin, was isolated from Marsdenia flavescens A. Cunn. Its structure was elucidated as 12-O-acetyl-3β,8β,12β,14β-20-pentahydroxy-Δ5- pregnene-1-one. 相似文献