Life cycle assessment comparison among different reuse intensities for industrial wooden containers

Goal, scope and background  The industrial packages sector has great importance for the transport sector in Europe. These containers, mainly wooden pallets and spools, are subject to European legislation, which promotes their reuse and recycling. This study uses life cycle assessment (LCA) to assess the environmental impact of the current management system in this sector and the benefits and drawbacks of different reuse intensities as a waste prevention strategy as opposed to the recycling option. Materials and methods  In this paper, four case studies located in Spain and representative of the wooden package sector in Europe are analysed: high reuse pallet, low reuse pallet, low reuse spool and null reuse spool. For the LCA study cases, the functional unit is that required to satisfy the transport necessity of 1,000 t by road. The impact and energy consumption assessment methods used are CML 2 Baseline 2000 and Cumulative Energy Demand. Data are mostly provided by the leading enterprises and organisations in this sector. Results  The paper provides, as a first result, a comprehensive inventory of the systems under study. Secondly, our assessment shows that the systems with higher reuse intensity show a reduction in energy and wood consumption and all the environmental impact categories except for the global warming potential from 34.0% to 81.0% in the pallet study cases and from 50.4% to 72.8% in the spool ones. This reduction is at the expense of the maintenance stage, which on the contrary increases its impact, although it is still relatively small—less than 7% in all the impact categories and flow indicators of the study cases. The highest impact stages are transport, raw material extraction and the process chain. The final disposal and maintenance stages are the lowest impact, contributing at most to less than 30% of the impact in the pallet study cases and 10% in the spool cases. Discussion  Wood consumption (WC), directly related to the number of containers needed to satisfy the functional unit, is the main factor in determining the impact of the stages, especially in the raw materials extraction and process chain stages, assuming that these are undertaken with the same technologies in all the case studies. Other variables, such as the management system, the maintenance index and the final disposal scenario, affect the impact of the remaining stages: transport, maintenance and final disposal. The global warming potential results obtained demonstrate the environmental benefits of using containers made of a renewable resource such as wood instead of using other materials, but these results are not expected to prioritise the lower reuse systems because of their better performance in this category. Conclusions  Reuse, a strategy capable of reducing the environmental impacts of the wooden container systems, is preferable to recycling, while the package maintenance tasks are still feasible. Therefore, reuse, combined with recycling as final disposal, should be encouraged to reduce the demand for natural resources and the waste generated. Recommendations  Based on these results, attention should be paid to the maintenance stage, which, being the lowest-impact one, could substantially reduce the impact of the remaining stages.     

Life Cycle Assessment of Advanced Industrial Wastewater Treatment Within an Urban Environment

A dissolved air flotation (DAF) system upgrade was proposed for an urban paper mill to recycle effluent. To understand the influence of operating variables on the environmental impacts of greenhouse gas (GHG) emissions and water consumption, a dynamic supply chain model was linked with life cycle assessment (LCA) to produce an environmental inventory. Water is a critical natural resource, and understanding the environmental impacts of recycling water is paramount in continued development of sustainable supply chains involving water. The methodology used in this study bridged the gap between detailed process models and static LCA modeling so that operating variables beyond discrete scenario analysis could be investigated without creating unnecessarily complex models. The model performed well in evaluating environmental impacts. It was found that there was no single optimum operating regime for all environmental impacts. For a mill discharging 80 cubic meters of effluent per hour (m³/hour), GHGs could be minimized with a DAF capacity of 17.5 m³/hour, while water consumption could be minimized with a DAF capacity of 25 m³/hour, which allowed insight into where environmental trade‐offs would occur. The study shows that more complexity can be achieved in supply chain modeling without requiring a full technical model. It also illustrates the need to consider multiple environmental impacts and highlights the trade‐off of GHG emissions with water consumption in water recycling. The supply chain model used in this water treatment case study was able to identify the environmental trade‐offs from the operating variables selected.     

污水处理和回用技术的应用：中水回用在沈阳的发展前景和存在的问题

为了解决水资源供应严重短缺,缓解污水排放对环境造成的破坏,沈阳市在今后5～10年内将建成中水回用系统,使城市中水回用率达到50％.文中回顾了污水处理和回用技术的发展现状,总结了中水回用的常规技术和新工艺(包括土壤渗滤法、膜生物反应器工艺法、周期循环延时曝气工艺法),并指出土壤渗滤法(SAT)和膜生物反应器(MBR)因其独特的技术优势,在中水回用领域的光明前景.通过列举一些污水回用项目的实际例子,分析了中水回用技术应用所带来的经济和生态效应,并探讨了沈阳市中水回用存在的问题和解决方法.     

A Carbon Footprint of Textile Recycling: A Case Study in Sweden

Global population growth and rising living standards are increasing apparel consumption. Consequently, consumption of resources and generation of textile waste are increasing. According to the Swedish Environmental Protection Agency, textile consumption increased by 40% between the years 2000 and 2009 in Sweden. Given that there is currently no textile recycling plant in Sweden, the aim of this article is to explore the potential environmental benefits of various textile recycling techniques and thereby direct textile waste management strategies toward more sustainable options. Three different recycling techniques for a model waste consisting of 50% cotton and 50% polyester were identified and a life cycle assessment (LCA) was made to assess the environmental performance of them. The recycling processes are: material reuse of textile waste of adequate quality; separation of cellulose from polyester using N‐methylmorpholine‐N‐oxide as a solvent; and chemical recycling of polyester. These are compared to incineration, representing conventional textile waste treatment in Sweden. The results show that incineration has the highest global warming potential and primary energy usage. The material reuse process exhibits the best performance of the studied systems, with savings of 8 tonnes of carbon dioxide equivalents (CO₂‐eq) and 164 gigajoules (GJ) of primary energy per tonne of textile waste. Sensitivity analyses showed that results are particularly sensitive to the considered yields of the processes and to the choice of replaced products. An integration of these recycling technologies for optimal usage of their different features for treatment of 1 tonne of textile waste shows that 10 tonnes CO₂‐eq and 169 GJ of primary energy could be saved.     

Life Cycle Assessment of a Personal Computer and its Effective Recycling Rate (7 pp)

Background, Aims and Scope Telecommunication and information technology, dramatically emerged during the last decade, has generated environmental problems by accelerating mass production, mass consumption, and mass disposal of personal computers (PCs) in Korea. In addition, it has led the Korean new economy. The Korean government has encouraged researchers and industry to study the environmental impact, adequate disposal treatment, and the reasonable recycling rate of an end-of-life personal computer. The main purpose of this research is to investigate the life cycle environmental impact of PCs and to determine the desirable or feasible recycle rate of an end-of-life PC. An LCA on a PC was performed based on different recycling scenario. Target audiences are new product developers, designers, product recovery managers and environmental policy makers who are interested in the environmental impact of PCs and recycling of end-of-life products. Methods A target product is a Pentium IV personal computer made in Korea in 2001, excluding the monitor and peripheral equipment. The procedure of the LCA followed the ISO14040 series. System boundary includes the entire life cycle of the product, including pre-manufacturing (the electrical parts and components manufacturing), manufacturing, transportation, use, and disposal. The LCI and impact assessment database for a PC was constructed using SIMAPRO version 4.0 software and LCI information was compiled by site-specific data and the Korean national database. The LCA was performed on different recycling scenarios: one being that of the current recycling rate of 46%, and the other being the ideal condition of a 100% recycling rate. Results and Discussion Abiotic depletion, global warming, ecotoxicity, human toxicity, acidification, ozone layer depletion, photo-oxidant formation, and eutrophication are adopted as the impact categories. The pre-manufacturing stage was a significant stage for all of the environmental parameters, besides human toxicity potential. PC manufacturing consists of rather simple processes such as assembly and packaging. For improving the environmental performance of PCs, environmental management approaches of design for the environment and green procurement are recommended. The use stage had a significant potential due to the electricity consumption produced by burning fossil fuel. The disposal stage's contribution to environmental impact was largest in human toxicity, and second largest in ozone layer depletion potential. The PC recycling was shown to inhibit all environmental impacts with the exception of the ozone depletion and ecotoxicity potential. The increase of light oil, nitric acid, sulfuric acid, and deoxidating agent consumption during the recycling process contributes to the environmental impact of ozone and ecotoxicity parameters. Current recovery and recycling technologies should be taken into account for enhancing the benefits of recycling. Anyway, the effectiveness of recycling was highlighted by this study. PC recycling reduces the total environmental impact of the product. The PC recycling is recommended to be raised up to at least 63% in order to reduce the environmental burdens of a PC in other life cycle stages. Conclusion and Recommendation This study implies that design for the environment (DfE) in the product design stage and green procurement are recommended for improving the entire environmental performance of electronic equipment such as PCs. The recycling of waste PCs clearly reduces the environmental burden. There are, however, trade-offs among environmental parameters according to the PC recycling rate. Current recycling methods are not effective in reducing ozone depletion and ecotoxicity environmental impact. The product recovery is another key for efficient recycling. Efficient reverse logistics to collect and transport end-of-life PCs should be taken into account to enhance recycling effects. There were several electrical parts not included in this assessment, due to the unavailability of adequate data. Further studies with more detail and reliable inventories for electrical parts and sub-components are recommended. Furthermore, costs of recycling should also be treated in further research.     

Supporting environmentally sound decisions for waste management with LCT and LCA

Introduction  

The amount of waste generated in Europe and, beyond, by our production and consumption patterns is significant. A proper waste management is essential in order to reduce detrimental environmental impacts. For the European Union, the general principles of good waste management are outlined in the Waste Framework Directive (2008/98/EC). This directive establishes a five-step hierarchy of waste management starting with the preferred option of waste prevention followed by preparing waste for reuse, recycling and other recovery with disposal (such as landfill) as the last resort.     

Decolorization of Pulp-Paper Mill Effluents by White-Rot Fungi

ABSTRACT:?

Phenolic effluents are waste products of pulp and paper, coal conversion, dying, textile, and olive oil industries. Such effluents impose coloration and toxicity problems in the receiving waters, causing serious environmental hazards. The pulp and paper mill effluent is highly colored, imparting black/brown color to the water body. The color is mainly due to lignin and its derivatives released during various stages in the paper-making process. The complex nature of such lignin compounds and their phenolic nature make them extremely resistant to microbial degradation. Conventional treatment methods such as aerated lagoons and activated sludge process are ineffective in removing color. However, physical and chemical treatment methods, including ultrafiltration, ion-exchange, and lime precipitation, are expensive and less efficient. Therefore, alternate low-cost biotreatment processes are now being considered, most of which are based on lignin-degrading fungi. Depending on the treatment process, the fungal inoculum for decolorization could be used in the form of mycelium, pellets, or in the immobilized state. The decomposition of lignin is an enzymatic process employing various ligninases being produced by the fungal species. Soluble and immobilized ligninolytic enzymes have also been employed for effluent decolorization. Therefore, the present review is an attempt to compile the scattered information on pulp-paper mill effluent decolorization employing microbes. The structure, distribution, physiology, and enzymology of lignin degradation is also briefly discussed.     

Economic Consequences of Increasing Polymer Content for the U.S. Automobile Recycling Infrastructure

Environmental awareness regarding resource use and emissions over the life cycle of the automobile has heightened the concerns for end-of-life (EOL) vehicle disposal. With increasing use of lighter materials to enhance fuel economythe steel dominated content of automobiles is changing to include a greater fraction of polymers. In light of impending regulations for vehicle disposal, various alternatives for remanufacturing and reuse of components and material disposal are under investigation. For example, if shredder operations are used to reclaim metallic materials, then the extent of disassembly will significantly affect proftability as well as the environment.
Using goal programming, we explore changes to the current US. vehicle recycling infrastructure for their effects on dismantler and shredder proftabilities. To investigate the effect of lightweighting on the profrtabilrty of the recycling infrastructure, two specific vehicle designs are compared: a steel unibody and a polymer-intensive vehicle. Other scenarios examine the outcomes for mandating removal of polymer materials during disassembly and for increasing the disposal cost of scrap polymer to that of hazardous waste. The results indicate that, if properly controlled, the current automobile recycling infrastructure in the United States can remain economically viable while it improves with respect to environmental considerations. Alternatively, implementation of certain policies that reduce profitability could cause disastrous consequences, resulting in the economic collapse of the infrastructure.     

Cleanup of industrial effluents containing heavy metals: a new opportunity of valorising the biomass produced by brewing industry

Heavy metal pollution is a matter of concern in industrialised countries. Contrary to organic pollutants, heavy metals are not metabolically degraded. This fact has two main consequences: its bioremediation requires another strategy and heavy metals can be indefinitely recycled. Yeast cells of Saccharomyces cerevisiae are produced at high amounts as a by-product of brewing industry constituting a cheap raw material. In the present work, the possibility of valorising this type of biomass in the bioremediation of real industrial effluents containing heavy metals is reviewed. Given the auto-aggregation capacity (flocculation) of brewing yeast cells, a fast and off-cost yeast separation is achieved after the treatment of metal-laden effluent, which reduces the costs associated with the process. This is a critical issue when we are looking for an effective, eco-friendly, and low-cost technology. The possibility of the bioremediation of industrial effluents linked with the selective recovery of metals, in a strategy of simultaneous minimisation of environmental hazard of industrial wastes with financial benefits from reselling or recycling the metals, is discussed.     

Metal biosorption in lignocellulosic biofuel biorefinery effluent: an initial step towards sustainability of water resources

Biosorption of metals by microorganisms is a promising technology to remove accumulated non-process elements in highly recycled biorefinery process water. Removal of these elements would enable greater water reuse and reduce the environmental impact of effluent discharge. A model lignocellulosic ethanol biorefinery wastewater was created based on pulp mill effluent. This generated a wastewater with an environmentally realistic high loading of dissolved natural organic matter (900?mg/l), a potentially important factor influencing metal biosorption. Analysis of feedstock and pulp mill effluent indicated that Mn and Zn are likely to be problematic in highly recycled lignocellulosic ethanol biorefinery process water. Therefore, the growth of several bacteria and fungi from existing collections, and some isolated from pulp mill effluent were tested in the model wastewater spiked with Mn and Zn (0.2?mM). Wastewater isolates grew the best in the wastewater. Metal uptake varied by species and was much greater for Zn than Mn. A bacterium, Novosphingobium nitrogenifigens Y88(T), removed the most metal per unit biomass, 35 and 17?mg?Mn/g. No other organism tested decreased the Mn concentration. A yeast, Candida tropicalis, produced the most biomass and removed the most total metal (38?% of Zn), while uptake per unit biomass was 24?mg?Zn/g. These results indicate that microorganisms can remove significant amounts of metals in wastewater with high concentrations of dissolved natural organic matter. Metal sorption by autochthonous microorganisms in an anaerobic bioreactor may be able to extend water reuse and therefore lower the water consumption of future biorefineries.     

Life cycle assessment of printing and writing paper produced in Portugal

Goal, Scope and Background The environmental sustainability is one of the current priorities of the Portuguese pulp and paper industry. Life Cycle Assessment (LCA) was the methodology chosen to evaluate the sustainability of the printing and writing paper production activity. This paper grade represents about 60% of the total production of paper in Portugal and its production is expected to increase in the near future. The main goal of this study was to assess the potential environmental impacts associated with the entire life cycle of the printing and writing paper produced in Portugal from Eucalyptus globulus pulp and consumed in Germany, in order to identify the processes with the largest environmental impacts. Another goal of this study was to evaluate the effect on the potential environmental impacts of changing the market where the Portuguese printing and writing paper is consumed: German market vs. Portuguese market. Methods The main stages considered in this study were: forestry, pulp production, paper production, paper distribution, and paper final disposal. Transports and production of chemicals, fuels and energy in the grid were also included in these stages. Whenever possible and feasible, average or typical data from industry were collected. The remaining data were obtained from the literature and specialised databases. A quantitative impact assessment was performed for five impact categories: global warming over 100 years, acidification, eutrophication, non-renewable resource depletion and photochemical oxidant formation. Results In the German market scenario, the paper production stage was a remarkable hot spot for air emissions (non-renewable CO₂, NO_x and SO₂) and for non-renewable energy consumption, and, consequently, for the impact categories that consider these parameters: global warming, acidification and non-renewable resource depletion. These important environmental impacts are due to the energy requirements in the printing and writing paper production process, which are fulfilled by on-site fuel oil burning and consumption of electricity from the national grid, which is mostly based on the use of fossil fuels. The pulp production stage was identified as the largest contributor to water emissions (COD and AOX) and to eutrophication. Considering that energy consumed by the pulp production processes comes from renewable fuels, this stage was also the most contributing to renewable energy consumption. Discussion The paper distribution stage showed an important contribution to NO_x emissions, which, however, did not result in a major contribution to acidification or eutrophication. The final disposal stage was the main contributor to the photochemical oxidant formation potential due to CH₄ emissions from wastepaper landfilling. On the other hand, paper consumption in Portugal was environmentally more favourable than in Germany for the parameters/impact categories where the paper distribution stage has a significant contribution (non-renewable CO₂, NO_x, non-renewable energy consumption, acidification, eutrophication and non-renewable resource depletion) due to shorter distances needed to deliver paper to the consumers. For the remaining parameters/impact categories, the increase observed in the final disposal stage in the Portuguese market was preponderant, and resulted from the existence of significant differences in the final disposal alternatives in the analysed markets (recycling dominates in Germany, whereas landfilling dominates in Portugal). Conclusions The pulp and paper production stages were found to be of significance for almost all of the inventory parameters as well as for the impact assessment categories. The paper distribution and the final disposal stages were only of importance for some of the inventory parameters and some of the impact categories. The forestry stage played a minor role in the environmental impacts generated during the paper life cycle. The consumption of paper in Portugal led to a decrease in the environmental burdens of the paper distribution stage, but to an increase in the environmental burdens of the final disposal stage, when compared with the consumption of paper in Germany. Recommendations and Perspectives This study provides useful information that can assist the pulp and paper industry in the planning of future investments leading to an increase in its sustainability. The results of inventory analysis and impact assessment show the processes that play an important role in each impact category, which allow the industry to improve its environmental performance, making changes not only in the production process itself, but also in the treatment of flue gases and liquid effluents. Besides that concern regarding pollution prevention, other issues with relevance to the context of sustainability, such as the energy consumption, can also be dealt with.     

Assessment of Physical and Chemical Attributes of Sub-Tropical Soil to Predict Long Term Effluent Treatment Potential

On-site wastewater treatment systems aim to assimilate domestic effluent into the environment. Unfortunately failure of such systems is common and inadequate effluent treatment can have serious environmental implications. A research project was undertaken to determine the role of physical and chemical soil properties in the treatment performance of subsurface effluent disposal areas. Monitoring changes in these properties permits improved prediction of the treatment potential of a soil. The changes within soil properties of the disposal area due to effluent application were found to be directly related to the subsurface drainage characteristics, including permeability, clay content and clay type. The major controlling soil physical and chemical attributes were found to be moderate drainage, significant soil cation exchange capacity and dominance of exchangeable Ca or exchangeable Mg over exchangeable Na, low exchangeable Na, clay type and a minimum depth of 0.4 m of potential unsaturated soil before encountering a restrictive horizon. The study confirmed that both the physical properties and chemistry of the soil can be valuable predictive tools for evaluating the long term operation of sewage effluent disposal systems.     

Environmental effects from a recycling rate increase of cardboard of aseptic packaging system for milk using life cycle approach

Goal, Scope and Background  Despite the well-known advantages of recycling materials to reduce solid waste or save natural resources, the recycling stage is an additional process within the life cycle that has its own energy and input requirements, as well as specific emissions. The objective of the present paper is to analyze the life cycle inventory associated with the increase in recycling rate (from 2% up to 22% at present) of the cardboard contained in the aseptic packaging for long-life milk. The main aspects of the manufacturing of the Tetra Pak aseptic package, including the filling of the product, the distribution of the conditioned product, up to the final disposal and recycling rates, were considered. Materials and Methods  This study was conducted in accordance with the general directives of the ISO 14040 series. The packaging material system was assessed using 1000 liters of milk as a functional unit, in a packaging system containing 12 units of 1 L cartons each, placed on a corrugated paperboard tray wrapped in polyethylene shrink film and arranged onto one-way wooden pallets. Brazilian inventories for energy, carton, corrugated paperboard and aluminum, based on site-collected data were employed. The final disposal of used packages was modeled using the Average Brazilian Municipal Solid Waste Management data collected for the purpose of the census of the year 2000. Results  Comparison of the total energy consumption throughout the whole life cycle of two recycling scenarios (i.e. different recycling rates) analyzed shows that the higher recycling rate led to a 6% reduction of the total energy requirement for the long-life milk package material system. The most significant reductions in the consumption of natural resources were: 8% water, 11% wood and 10% land use savings. Greenhouse gases were the main reduced air emissions and contributed with a reduction of 9.7% in GWP. Most water emissions were reduced: 10% COD, 9% BOD and 6% TSS. A unique drawback directly caused by the increase of the recycling rate was an increase of 14.4 g in TDS emissions (57%). Discussion  The reduction in energy requirements are related and limited to the proportionality among the different materials that make up the packaging system. Most emission reductions result from the replacement of virgin materials with recycled materials in the packaging system. Although the average balance of water emissions is positive, the need to improve wastewater treatment processes in the paper recycling plants to reduce TDS is highlighted as a key issue. Conclusions  It may be concluded that the increase in the recycling rate brings about a series of benefits in terms of reduction of energy and natural resource consumption, air pollutants and most water emissions. In this case, the increase of the recycling rate improved the overall environmental performance of the aseptic Tetra Pak system for milk. Recommendations and Perspectives  The authors are currently analyzing alternative recycling scenarios that will enable one to evaluate maximum reduction in GWP. Further studies could include the agriculture stages, livestock and consumer phase to broaden the environmental evaluation. ESS-Submission Editor: Dr. Andreas A. Detzel (andreas.detzel@ifeu.de)     

Integrated treatment of farm effluents in New Zealand’s dairy operations

Maintaining growth through intensification in the New Zealand dairy industry is a challenge for various reasons, in particular sustainably managing the large volumes of effluent. Dairy farm effluents have traditionally been treated using two-pond systems that are effective in the removal of carbon and suspended solids, however limited in their ability to remove nutrients. In the past these nutrient-rich two-pond treated effluents were disposed of in surface waters. Current environmental concerns associated with the direct discharge of these effluents to surface waters has prompted in developing technologies to either minimise the nutrient content of the effluent or apply effluents to land. Here, we discuss various approaches and methods of treatment that enable producers to sustainably manage farm effluents, including advanced pond treatment systems, stripping techniques to reduce nutrient concentration, land application strategies involving nutrient budgeting models to minimise environmental degradation and enhance fodder quality. We also discuss alternative uses of farm effluents to produce energy and animal feed.     

以毒性鉴别评价法评价化工废水处理效果的研究

江苏省某化工厂废水处理设施进、出水经大型Sou（Daphnia magna）急性毒性试验的结果表明,废水在处理前、后均显示毒性。采用毒性鉴别评价的试验程序,对处理设施的进、出水进行了关键毒物的鉴别和评价。发现进水中存在的关键毒物为金属铜离子并共存多种金属和极性有机毒物,而出水中存在的毒物为酸性条件下易被氧化的有毒有机物。该废水处理工艺对废水毒性去除率为77.6%。由此可见,该处理工艺对金属离子有较好的去除,而对有毒有机化合物的去除效果不甚理想,因此,该厂生产工艺和废水处理工艺还有待进一步改进。     

Integration of aerobic granular sludge and membrane bioreactors for wastewater treatment

Environmental deterioration together with the need for water reuse and the increasingly restrictive legislation of water quality standards have led to a demand for compact, efficient and less energy consuming technologies for wastewater treatment. Aerobic granular sludge and membrane bioreactors (MBRs) are two technologies with several advantages, such as small footprint, high-microbial density and activity, ability to operate at high organic- and nitrogen-loading rates, and tolerance to toxicity. However, they also have some disadvantages. The aerobic granular sludge process generally requires post-treatment in order to fulfill effluent standards and MBRs suffer from fouling of the membranes. Integrating the two technologies could be a way of combining the advantages and addressing the main problems associated with both processes. The use of membranes to separate the aerobic granules from the treated water would ensure high-quality effluents suitable for reuse. Moreover, the use of granular sludge in MBRs has been shown to reduce fouling. Several recent studies have shown that the aerobic granular membrane bioreactor (AGMBR) is a promising hybrid process with many attractive features. However, major challenges that have to be addressed include how to achieve granulation and maintain granular stability during continuous operation of reactors. This paper aims to review the current state of research on AGMBR technology while drawing attention to relevant findings and highlight current limitations.     

Algal single cell protein from wastewater treatment and renovation process

A Source of high-quality protein for animal feed, based upon algae recovered in the process of upgrading waste oxidation pond effluents and promising to be particularly economical, is being developed at the Technion. Unlike other types of single cell protein(SCP), the algal protein does not have to return the full production cost but only that of concentration and final processing. The balance is shared by the value of waste disposal and the reclaimed water. Whereas such systems as activated sludge require considerable mechanical energy to supply the oxygen needed for aerobically degrading organics in wastewater, oxidation ponds utilize solar energy for that purpose. The sludge obtained when their effluents are clarified consists largely of algae, bacteria, fungi, and zooplankton in relative proportions varying with operating conditions, and contains 40–60%(dry basis) high-quality protein. The high rate oxidation pond (a particularly intensive type of pond) produces on the average 34 g/m²7sol;day solids, or over 100 tons/ha (hectare) annually. Two clarification routes have been found promising: centrifugation and alum flocculation followed by frothflotation. The latter route is less expensive in terms of both fixed and operating cost, and gives clarified effluent of higher quality, which can be seasonally stored with minimal eutrophication because the aluminum removes most of the phosphate from the effluent. A good product has been obtained by drum-drying the concentrate, and preliminary feeding tests have indicated that it can replace at least 1/4 of the soymeal in broiler rations and 2/3 of the fishmeal in carp feed. No ill effect of the aluminum in the product recovered by alum flocculation has been found so far a process for removing and recycling the aluminum has been developed nonetheless, in case ill effects do show up in further tests. The combined value of the benefits derived from a system centered around the high-rate oxidation pond with clarification by flocculation–flotation, in terms of waste treatment by alternative means, potable water saved, and soymeal replaced, significantly exceeds estimated cost.     

Remediation of dyes in textile effluent: a critical review on current treatment technologies with a proposed alternative

The control of water pollution has become of increasing importance in recent years. The release of dyes into the environment constitutes only a small proportion of water pollution, but dyes are visible in small quantities due to their brilliance. Tightening government legislation is forcing textile industries to treat their waste effluent to an increasingly high standard. Currently, removal of dyes from effluents is by physio-chemical means. Such methods are often very costly and although the dyes are removed, accumulation of concentrated sludge creates a disposal problem. There is a need to find alternative treatments that are effective in removing dyes from large volumes of effluents and are low in cost, such as biological or combination systems. This article reviews the current available technologies and suggests an effective, cheaper alternative for dye removal and decolourisation applicable on large scale.     

Recycling of aluminum can in terms of Life Cycle Inventory (LCI)

Background, Aims and Scope  Life Cycle Assessment is a technique for evaluating the environmental performance of a given product by: identifying and quantifying the energy and raw materials used in its manufacturing process, as well as the emissions of pollutants to water, soil, and air inherent in this production, use and disposal, and evaluating the environmental impact associated with the use of energy and materials and the emissions of pollutants, thus identifying opportunities to improve the system in order to optimize the environmental performance of the product. CETEA (Packaging Technology Center) has conducted a Life Cycle Assessment — LCA study of aluminum can with emphasis in life cycle inventory, collecting data for the reference years 2000–2002. The goal of this paper is to present part of this complete study, focusing the influence of aluminium recycling rate on the Life Cycle Inventory (LCI) of aluminum beverage cans in Brazil. Methods  The adopted methodology was based on the recommendations of SETAC — Society of Environmental Toxicology and Chemistry and the ISO 14040 Standard, approved by the Sub-Committee 05 of the Environmental Administration Technical Committee, TC-207, from ISO — INTERNATIONAL ORGANIZATION FOR STANDARDIZATION [1,2]. Data storage and modeling were performed by employing the PIRA Environmental Management System — PEMS [3]. Results  Taking into account the impact categories adopted in this study, it has been shown that recycling helps to improve the aluminium can environmental profile measured as LCI data. Discussion  For the transformed aluminium products, the recycling rate affects the values of the environmental parameters inventoried, but not in the same proportion, since the contribution of other stages of the product system life cycle and the recycling process remain unchanged, including the yield of this process. In general, the recycling balance is always positive due to the importance of the stages that precede the packaging production and the problem of increasing the municipal waste volume. Conclusions  The advantages of the recycling are obviously concentrated on the inventoried parameters related to the primary aluminum production and to the package disposal. The verified benefits of the recycling increase with the recycling rate enhancement. However, the effects on the inventory do not have the same magnitude of the recycling rate. This happens due to the relative contributions of the other life cycle stages, such as the transportation and sheet or can production. In agreement with the presented results, it is possible to conclude that the aluminum can recycling reduces part of the consumption of natural resources and the emissions associated to the stages previous to the production of the packaging. The parameters specifically related to the stage of aluminum production suffer reduction directly proportional to the increase of the recycling rate. In this way, all of the efforts made to increase the recycling rate will have a positive contribution to the LCI of the aluminum can. Recommendations  It is worth pointing out that LCA studies are iterative and dynamic. The data can always be refined, substituted or complemented with updated information in order to improve the representativeness of the analyzed sector. Perspectives  From this study, the aluminum sector in Brazil is able to quantify the benefits of future actions for environmental improvement of the Brazilian aluminum industry, as well as to contribute technically to Environmental Labeling initiatives regarding aluminum products. ESS-Submission Editor: Alain Dubreuil (dubreuil@nrcan.gc.ca)     

Ethanolic fermentation of acid pre-treated starch industry effluents by recombinant Saccharomyces cerevisiae strains

Two industrial effluents, a pre-fermentation effluent and a post-fermentation effluent from a wheat starch production plant, were used as substrates for fuel ethanol production in anaerobic batch cultures using minimal nutritional amendment. The performances of three metabolically engineered xylose-utilizing Saccharomyces cerevisiae strains: TMB 3001 expressing XYL1, XYL2 and XKS1, redox metabolism modulated CPB.CR1 and glucose de-repressed CPB.CR2, as well as a reference strain CEN.PK 113-7D not fermenting xylose, were evaluated. For the recombinant strains a glucose consumption phase preceded the xylose consumption phase. In both effluents, biomass and ethanol production occurred predominantly during the glucose consumption phase, whereas xylitol and glycerol formation were predominant in the xylose consumption phase. Total specific ethanol productivities on glucose were 6-fold higher than on xylose in the pre-fermentation effluent and 15-fold higher than on xylose in the post-fermentation effluent. CPB.CR1 showed impaired growth compared to the two other xylose-utilizing strains, but displayed 18% increased ethanol yield in the post-fermentation effluent.