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1.
  总被引:2,自引:0,他引:2  
Chlorine is an important industrial chemical. Not only is it a component of many important products, it is also needed for many chemical manufacturing processes, even where it does not appear in the final product. But a number of chlorine chemicals, especially organochlorines, are toxic, carcinogenic, tentogenic or otherwise potentially disturbing to the environment. For this reason, some environmentalists—notably Greenpeace-have advocated a ban, not just on some products but on all uses of elemental chlorine. The chemical industry is taking this threat seriously and mounting a vigorous defense. But the debate so far is not illuminating the issues effectively, because both sides are selectively using questionable and unverifiable data.
The scientific uncertainties are not really the problem. Rather, data in the public domain and accessible to environmentalists and even regulatory authorities are of very poor qualrty. Because of industry secrecy much crucial inforrnation is unavailable and some of what is available is misleading or wrong. The dual purposes of this article, and the ones that follow, are (I) to elucidate the information requirements for an adequate life-cycle analysis of chlorine and its uses and (2) to indicate how and where the use of massbalance methodology can help identify errors and fill in gaps.
The present article deals with electrolytic chlorine produdion and mercury flows arising from chlorine production. Subsequent articles deal with conversion processes and losses and further chemical industry uses of chlorine, major end uses of chlorine and chlorine chemicals, and persistent organochlorine pollutants.  相似文献   

2.
    
The debate over chlorine in industrialized economies has become extremely polarized in the last decade. Environmental pressure groups are striving for a virtual phaseout of chlorine and chlorinated hydrocarbons (CHCs), because they are convinced that the risks cannot be managed. Industry argues this is not necessary because environmental risks can be controlled, nor is it feasible, because at least 60% of all firms use CHCs, produds made with CHCs, or elemental chlorine. In an attempt to give this discussion a more factual basis, the Dutch minister of environment launched a strategic study on chlorine (see Kleijn et al. I997;Tukker et al. 1995). Using all available knowledge about emissions and contemporary evaluation methods, the study found only a limited number of environmental issues outstanding related to the chlorine chain: however, it also found important uncertainties. This article describes the outstanding uncertainties in more detail. It defines which uncertainties have to be regarded as chlorine-specific and the extent to which additional research can resolve them. For the remaining uncertainties the potential benefts of uncertainty reduction strategies are evaluted, relying mainly on the precautionary principle  相似文献   

3.
  总被引:1,自引:0,他引:1  
In the two previous articles in this series we reviewed the major processes of chlorine production (Part I) and its intermediate uses and waste products in the production of other chemicals (Part 11). In this article I consider some of the final applications of chlorine (e.g., for water treatment and pulp bleaching) and the uses of the most important chlorinated compounds such as solvents, chlorofluorocarbons, and the plastic polyvinyl chloride in the industrial economy. I summarize known evidence regarding their environmental fates. The special case of persistent long-lived toxic compounds (e.g., pesticides) will be discussed in a subsequent article.  相似文献   

4.
    
The major purpose of this article is to construct a plausible emissions profile for the European chemical industry from process data and mass balance considerations.' In it we describe this industry and its major conversion processes and emissions. Four major process chains, beginning with methane, ethylene, propylene, and benzene are analyzed, along with five important stand-alone processes. A self-consistent version of the industry is constructed for 1992, based on data from a variety of sources.
In 1992 Europe consumed 9,297 metric kilotons as measured by weight of chlorine (kMT[CI]) of salt and 2 I I kMT(CI) of recycled hydrochloric acid (HCI) to produce 86 I0 kMT of virgin elemental chlorine, plus 278 kMT(CI) of virgin by-product HCI. Total chlorine input to the industry was 8,689 kMT including I2 kMT(CI) of recycled chlorinated hydrocarbons (CHCs) and (net) 79 kMT(CI) of HCI. Shipments of chlorine and HCI to other sectors was 1,367 kMT(CI), while 7,322 kMT(CI) was embodied in products or lost within the sector: Of this subtotal, 350 kMT(CI) was used to manufacture identified inorganic chemicals, 5,694 kMT(CI) for identified organic chemicals, and 1,278 kMT(CI) for \"other unspecified\" chemicals.
We estimate that products account for 41.6% of inputs (measured at the \"fence\"), while wastes account for 24.7%  相似文献   

5.
  总被引:1,自引:0,他引:1  
\"Societal metabolism\" provides the appropriate conceptual basis for the rapidly growing development and analylical and policy interest in materials flow analysis (MFA). Following the review of the earlier intellectual background of societal metabolism in the first installment of this two-part article, this paper focuses on the current state of the art by examining more recent research referring t o societal metabolism in terms of material and substance flows. An operational classification of the literature according to frame of reference (socioeconomic system, ecosystem), system level (global, national, regional, functional, temporal), and types of flows under consideration (materials, energy, substances) highlights some of its characteristic features. There follows an integrated discussion of some of the major conceptual and methodological properties of MFA, with a particular focus on the field of bulk materials flows on a national level, comparing the major empirical results. Finally, the theoretical stringency research productivity, and political relevance of the MFA-related studies are assessed.  相似文献   

6.
    
This article, focusing on the flow of bulk construction minerals, establishes a mass balance framework for the North West of England, a region that imports more aggregate material than any other in the United Kingdom. The problems associated with construction minerals are of a different nature than most other resource flow issues: Depletion of resources and contamination are not considered major problems; rather it is the environmental impact resulting from life-cycle stages from extraction, transport, processing, through to final disposal that is most important. A mass balance framework can promote a better understanding of the regional flow of materials, and the impact of human activity on surrounding ecosystems, and hence underpin informed decision making. This is of particular relevance at the current time because increasing political emphasis is placed on sustainable resource management and resource productivity at the United Kingdom and European Union levels. Using a mass balance framework to analyze the sustainability impacts of construction and mineral flows in the North West of England, this study finds that flows resulting from construction activity account for 34,075 terajoules (TJ) of energy resulting in 2,701 gigagrams (Gg) of carbon dioxide emissions related to energy use, and 387 Gg of carbon dioxide emissions related to the transportation of the minerals. Against these impacts, the flow of bulk construction mineral salso supports 147,000 jobs within the region.  相似文献   

7.
    
This article is the second of a two-part series that describes and compares the essential features of nine \"physical economy\" approaches for mapping and quantifying the material demands of the human economy upon the natural environ-ment. These approaches are critical tools in the design and implementation of industrial ecology strategies for greater eco-efficiency and reduced environmental impacts of human economic activity. Part I of the series provided an overview, meth-odological classification, and comparison of a selected set of major materials flow analysis (MFA) and related techniques. This sequel includes a convenient reference and overview of the major metabolism measurement approaches in the form of a more detailed summary of the key specific analytical and other features of the approaches introduced in part I. The surveyed physical economy related environmental analysis ap-proaches include total material requirement and output mod-els, bulk MFA (IFF (Department of Social Ecology, Institute for Interdiscplinary Studies of Austrian Universities) material flow balance model variant), physical input-output tables, substance flow analysis, ecological footprint analysis, environmental space, material intensity per unit service, life-cycle assessment (LCA), the sustainable process index, and company-level MFA.  相似文献   

8.
物质流分析(SFA)方法及研究进展   总被引:2,自引:0,他引:2       下载免费PDF全文
张玲  袁增伟  毕军 《生态学报》2009,29(11):6189-6198
物质流分析(substance flow analysis,SFA)通过追踪经济-环境系统特定物质的输入、输出、贮存等过程,量化经济系统中物质流动与资源利用、环境效应之间的关系,为资源环境优化管理提供科学依据.系统阐述了SFA的内涵及发展历程,介绍了SFA方法体系,在此基础上对SFA研究现状进行了评述.分析表明,SFA是产业生态学领域内一种重要的产业代谢分析方法,它在污染物迁移路径追踪及环境影响分析、战略性资源生命周期代谢分析、物质社会存量分析等方面具有十分重要的应用价值.提出了SFA的未来应用领域和发展趋势.  相似文献   

9.
Human activity has quadrupled the mobilization of phosphorus (P), a nonrenewable resource that is not fully recycled biologically or industrially. P is accumulated in both water and solid waste due to fertilizer application and industrial, agricultural, and animal P consumption. This paper characterizes the industrial flows, which, although smaller than the agricultural and animal flows, are an important phosphorus source contributing to the pollution of surface waters. We present the quantification of the network of flows as constrained by mass balances of the global annual metabolism of phosphorus, based on global consumption for 2004, all of which eventually ends up as waste and in the soil and water systems. We find that on a yearly basis, 18.9 million metric tons (MMT) of P is produced, of which close to 75% goes to fertilizer and the rest to industrial and others uses. Phosphoric acid is the precursor for many of the intermediate and end uses of phosphate compounds described in this study and accounts for almost 80% of all P consumed. Eventually, all of the P goes to waste: 18.5 MMT ends up in the soil as solid waste, and 1.32 MMT is emissions to air and water. Besides quantifying P flows through our economy, we also consider some possible measures that could be taken to increase the degree of recovery and optimization of this resource and others that are closely related, such as the recovery of sulfur from gypsum and wastewater (sludge), and fluorine from wet phosphoric acid production.  相似文献   

10.
    
This article is the first of a two-part series that describes and compares the essential features of nine existing \"physical economy\" approaches for quantifying the material demands of the human economy upon the natural environment. A range of material flow analysis (MFA) and related techniques is assessed and compared in terms of several major dimensions. These include the system boundary identification for material flow sources, extents, and the key socioinstitutional entities containing relevant driving forces, as well as the nature and detailing of system components and flow interconnections, and the comprehensiveness and types of flows and materials covered.
Shared conceptual themes of a new wave of physical economy approaches are described with a brief overview of the potential applications of this broad family of methodologies. The evolving and somewhat controversial nature of the characteristics and role that define MFA is examined. This review suggests the need to specify whether MFA is a general metabolic flow measurement procedure that can be applied from micro to macrolevels of economic activity, or a more specific methodology aimed primarily at economy-wide analyses that \"map\" the material relations between society and nature. Some alternative options for classifying MFA are introduced for discussion before a more detailed comparative summary of the key methodological features of each approach in the second part of this two-part article.
The review is presented (1) as a reference and resource for the increasing number of policy makers and practitioners involved in industrial ecology and the evaluation of the material basis of economies and the formulation of eco-efficiency strategies, and (2) to provoke discussion and ongoing dialogue to clarify the many existing areas of discordance in environmental accounting related to material flows, and help consolidate the methodological basis and application of MFA.  相似文献   

11.
    
We have investigated the global warming potential (GWP) of CFC-I I, CFC-12, and their replacements, HCFC-I23 and HFC-I34a, based on a life-cycle methodology for refrigeration. We have extended the definition of the total equivalent warming impact (TEWI), which considers the GWP (direct) and GWP (indirect) warming potential of each chemical compound, by adding the GWP (chemical production), GWP (recycling), and GWP (atmospheric breakdown products) for each chemical. We call the new index \"life-cycle warming impact\" (LCWI).We find that the GWP (chemical production) contributes by no more than 1% to LCWI, and that the GWP (indirect) is highly dependent on refrigerator eficiency and the fuel mix of the electricity source used to operate the appliance. The GWP (atmospheric breakdown products) may also have a significant impact on LCWI.  相似文献   

12.
    
Fluorine is an essential element to human health and to the chemical industry. In spite of our dependence on fluorine and fluorine compounds, we have yet to learn to use them wisely. Our fluorine history, which spans about a hundred years, has had negative effects such as hydrofluoric acid pollution caused by aluminum smelters and ozone depletion due to chlorofluorocarbon (CFC) emissions. More recent concerns center on greenhouse effects from CFCs, hydrofluorocarbons (HFCs), and sulfur hexafluoride (SF6). In this article we note also that fluorine is a nonrenewable resource that is nonsubstitutable for many purposes. This article tracks fluorine from sources through conversion processes to end uses, most of which are dissipative. We present a stock‐flow model of the fluorine system. Based on this model we consider some possible measures that could be taken to increase the degree of recovery. To mention one example, a large percentage of the world demand for fluorspar could be supplied by the phosphate rock (fertilizer) industry, which currently dissipates a great deal of recoverable fluorine in waste phospho‐gypsum.  相似文献   

13.
Dynamic material flow analysis (dMFA) is widely used to model stock-flow dynamics. To appropriately represent material lifetimes, recycling potentials, and service provision, dMFA requires data about the allocation of economy-wide material consumption to different end-use products or sectors, that is, the different product stocks, in which material consumption accumulates. Previous estimates of this allocation only cover few years, countries, and product groups. Recently, several new methods for estimating end-use product allocation in dMFA were proposed, which so far lack systematic comparison. We review and systematize five methods for tracing material consumption into end-use products in inflow-driven dMFA and discuss their strengths and limitations. Widely used data on industry shipments in physical units have low spatio-temporal coverage, which limits their applicability across countries and years. Monetary input–output tables (MIOTs) are widely available and their economy-wide coverage makes them a valuable source to approximate material end-uses. We find four distinct MIOT-based methods: consumption-based, waste input–output MFA (WIO-MFA), Ghosh absorbing Markov chain, and partial Ghosh. We show that when applied to a given MIOT, the methods’ underlying input–output models yield the same results, with the exception of the partial Ghosh method, which involves simplifications. For practical applications, the MIOT system boundary must be aligned to those of dMFA, which involves the removal of service flows, sector (dis)aggregation, and re-defining specific intermediate outputs as final demand. Theoretically, WIO-MFA, applied to a modified MIOT, produces the most accurate results as it excludes massless and waste transactions. In part 2 of this work, we compare methods empirically and suggest improvements for aligning MIOT-dMFA system boundaries.  相似文献   

14.
    
The concept of sustainable development concerns not only the natural environment but also human societies and economies. The method of economy‐wide materials flow accounting and analysis (EW‐MFA) is internationally recognized as a valuable tool for studying the physical dimensions of economies. EW‐MFA has been carried out in many industrialized countries, but very little work has been done for developing China; this article can be regarded as one of the first attempts to study China's economy in terms of materials flows. In this article we have compiled materials flow accounts for China during the time series 1990 to 2002 and derived indicators associated with international comparison. Results show that the annual material consumption of China's economy continuously increased except for a slump around 1998, whereas the material efficiency exhibited a three‐phase trend reflecting different macropolicies of the Eighth, Ninth, and Tenth Five‐Year Plans implemented by the central government. Based on this experience with EW‐MFA for China, suggestions for methodology development and further research are given for improving EW‐MFA as a more effective tool for environmental management.  相似文献   

15.
    
Phosphorus (P) is a key factor in aquatic eutrophication, and P contamination has become a common issue worldwide. Many developing countries, including China, have made great efforts in the anti‐P contamination battle. In this article we mainly discuss the P flow in Wuwei, a typical county in China with insufficient wastewater treatment, using the method of static substance flow analysis. We show that characterizing P metabolic pathways and flows at the county level can provide useful information about P pollution. Through complex calculations, we found that Wuwei County released 3,552 metric tons (t) of P into the local aquatic environment in 2008 and that its P load (3.35 kilograms P per capita per year [kg P/cap/yr] or 19.43 kilograms P per hectare per year [kg‐P/ha/yr]) was greater than both the adjoining counties’ and Chaohu City's average levels combined. The agricultural subsystem discharged the largest quantity of P (2,572 t) and had a relatively low production conversion efficiency (32%) and P waste recycling rate (36%). The rural residential and small‐scale livestock breeding systems also accounted for substantial portions of P discharge. Anti‐P contamination efforts should consequently focus on those three subsystems. Based on the results of this case study, we also discuss the feasibility of potential efforts to reduce P contamination.  相似文献   

16.
    
Several tools exist for the analysis of the environmental impacts of chains or networks of processes. These relatively simple tools include materials flow accounting (MFA), substance flow analysis (SFA), life-cycle assessment (LCA), energy analysis, and environmentally extended input-output analysis (IOA), all based on fixed input-output relations. They are characterized by the nature of their flow objects, such as products, materials, energy, substances, or money flows, and by their spatial and temporal characteristics. These characteristics are insufficient for their methodological characterization, and sometimes lead to inappropriate use. More clarity is desirable, both for clearer guidance of applications and for a more consistent methodology development. In addition to the nature of the flow object and to spatial and temporal characteristics, another key feature concerns the way in which processes are included in a system to be analyzed.
The inclusion of processes can be done in two fundamentally different ways: according to a full mode of analysis, with the inclusion of all flows and related processes to their full extent as present in a region in a specific period of time; and according to an attribution mode, taking processes into account insofar as these are required for a given social demand, function, or activity, in principle whenever and wherever these processes take place. This distinction, which cuts across families of tools that traditionally belong together, appears to have significant methodological and practical implications. Thus the distinction between the two modes of analysis, however crucial it may be, strengthens the idea of one coherent family of tools for environmental systems analysis.  相似文献   

17.
武娟妮  石磊 《生态学报》2010,30(22):6208-6217
以江苏宜兴经济开发区为例,基于物质流分析构建了工业园区的氮代谢网络和分析方法,解析了工业园区中产业系统和污水处理系统的氮代谢途径和通量。研究表明,氮物质流系统的源和汇比磷物质流系统多,流通量大且较为集中;氮肥生产、纺织印染和食品加工行业是宜兴经济开发区的主要氮排放源;企业自备处理设施除氮效果较好,去除率约79%,而污水处理厂由于设计和运行等原因氮去除率较低,约57%;生活污水氮去除率低;直接排入水体的降水造成的水体负荷约28%。由此,建议企业继续完善企业内处理设施,对集中污水处理厂进行脱氮除磷提标改造,同时加强对园区内生活污水、生活垃圾和企业固体排放物的管理。  相似文献   

18.
    
Modeling pathways toward sustainable production and consumption requires improved spatio-temporal and material coverage of end-use product stocks. Momentarily, studies on inflow-driven, dynamic material flow analysis (dMFA) extrapolate scarce information on material end-use shares (i.e., ratios that split economy-wide material consumption to different end-use products) for single countries and years across longer time periods and global regions. Therefore, in part 1 of this work, we reviewed five methods to derive material end-use shares which use industry shipment data in physical units and monetary input–output tables (MIOTs). Herein, we comparatively apply these methods to the United States, drawing on detailed national data, as well as the multi-regional input–output model EXIOBASE3. To better match MIOT and dMFA system definitions, we propose the end-use transfer method, which re-routes specific intermediate outputs to final demand in MIOTs. In closing, we conclude on 12 points for improved end-use shares. We find mixed results regarding the fit between end-use shares derived from industry shipments and MIOTs: for detailed national data, we find good fit for some materials (e.g., aluminum), while others deviate strongly (e.g., steel). In many cases, the temporal trend of MIOT-derived end-use shares roughly agrees with industry shipments. For EXIOBASE3, we find good fit for some countries and materials, but substantial mismatches for others. Despite mixed results, combining MIOT-based end-use shares with industry shipments and auxiliary country-level data could enable improved temporal, geographical, and end-use resolution. However, the scarcity, documentation, and quality of input data are key limitations for more accurate and detailed end-use shares. This article met the requirements for a gold-gold data openness badge described at http://jie.click/badges .   相似文献   

19.
The United States is not only the world's largest economy, but it is also one of the world's largest consumers of natural resources. The country, which is inhabited by some 5% of the world's population, uses roughly one‐fifth of the global primary energy supply and 15% of all extracted materials. This article explores long‐term trends and patterns of material use in the United States. Based on a material flow account (MFA) that is fully consistent with current standards of economy‐wide MFAs and covers domestic extraction, imports, and exports of materials for a 135‐year period, we investigated the evolution of the U.S. industrial metabolism. This process was characterized by an 18‐fold increase in material consumption, a multiplication of material use per capita, and a shift from renewable biomass toward mineral and fossil resources. In spite of considerable improvements in material intensity, no dematerialization has happened so far; in contrast to other high‐income countries, material use has not stabilized since the 1970s, but has continued to grow. This article compares patterns and trends of material use in the United States with those in Japan and the United Kingdom and discusses the factors underlying the disproportionately high level of U.S. per capita resource consumption.  相似文献   

20.
    
Changes in food consumption and related processes have a significant impact on the flow of nitrogen in the environment. This study identifies both flows within the system and emissions to the hydrosphere and atmosphere. A case study of an average inhabitant of the city of Linköping, Sweden, covers the years 1870, 1900, 1950, and 2000 and includes changes in food consumption and processing, agricultural production, and organic waste handling practices. Emissions to the hydrosphere from organic waste handling increased from 0.57 kilograms of nitrogen per capita per year (kg N/cap per year) to 3.1 kg N/cap per year, whereas the total flow of nitrogen to waste deposits grew from a negligible amount to 1.7 kg N/cap per year. The largest flow of nitrogen during the entire period came from fodder. The input of chemical fertilizer rose gradually to a high level of 15 kg N/cap per year in the year 2000. The total load per capita disposed of to the environment decreased during these 130 years by about 30%.  相似文献   

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