Diagnostics of a nonequilibrium nitrogen plasma from the emission spectra of the second positive system of N2

A method is proposed for determining the electron density N _e and the electric field E in the non-equilibrium nitrogen plasma of a low-pressure discharge from the spectra of the second positive system of N₂. The method is based on measuring the specific energy deposition in the plasma and the distribution of nitrogen molecules over the vibrational levels of the C ³Π _u state, as well as on modeling this distribution for a given energy deposition. The fitting parameters of the model are the values of N _e and E. A kinetic model of the processes governing the steady-state density of the C ³Π _u nitrogen molecules is developed. The testing of this method showed it to be quite reliable. The method is of particular interest for diagnosing electrodeless discharges and provides detailed information on the processes occurring in the discharge plasma. Preliminary data are obtained on the plasma parameters in a cavity microwave discharge and an electrode microwave discharge. In particular, it is found that the electric field in an electrode microwave discharge in nitrogen is lower than that in a hydrogen discharge. This effect is shown to be produced by stepwise and associative processes with the participation of excited particles in nitrogen.     

Experimental Study of Heating of a Liquid Cathode and Transfer of Its Components into the Gas Phase under the Action of a DC Discharge

An atmospheric-pressure dc discharge in air (i = 10–50 mA) with metal and liquid electrolyte electrodes was studied experimentally. An aqueous solution of sodium chloride (0.5 mol/L) was used as the cathode or anode. The electric field strength in the plasma and the cathode (anode) voltage drops were obtained from the measured dependences of the discharge voltage on the electrode gap length. The gas temperature was deduced from the spectral distribution of nitrogen emission in the band N₂(C³Π _u → B³Π _g , 0–2). The time dependences of the temperatures of the liquid electrolyte electrodes during the discharge and in its afterglow, as well as the evaporation rate of the solution, were determined experimentally. The contributions of ion bombardment and heat flux from the plasma to the heating of the liquid electrode and transfer of solvent (water) into the gas phase are discussed using the experimental data obtained.     

A prototype of an electric-discharge gas flow oxygen−iodine laser: I. Modeling of the processes of singlet oxygen generation in a transverse cryogenic slab RF discharge

The existing kinetic model describing self-sustained and electroionization discharges in mixtures enriched with singlet oxygen has been modified to calculate the characteristics of a flow RF discharge in molecular oxygen and its mixtures with helium. The simulations were performed in the gas plug-flow approximation, i.e., the evolution of the plasma components during their motion along the channel was represented as their evolution in time. The calculations were carried out for the O₂: He = 1: 0, 1: 1, 1: 2, and 1: 3 mixtures at an oxygen partial pressure of 7.5 Torr. It is shown that, under these conditions, volumetric gas heating in a discharge in pure molecular oxygen prevails over gas cooling via heat conduction even at an electrode temperature as low as ~100 K. When molecular oxygen is diluted with helium, the behavior of the gas temperature changes substantially: heat removal begins to prevail over volumetric gas heating, and the gas temperature at the outlet of the discharge zone drops to ~220–230 K at room gas temperature at the inlet, which is very important in the context of achieving the generation threshold in an electric-discharge oxygen?iodine laser based on a slab cryogenic RF discharge.     

Plasma energy balance in the L-2M stellarator

Results are presented from studies of the effect of the discharge parameters (in particular, plasma density and heating power) and the characteristics of the magnetic configuration (e.g., rotational transform) on the confinement of a low-pressure plasma during electron-cyclotron resonance heating in the L-2M stellarator. An analysis shows that the plasma energy in the steady-state phase of a discharge is fairly well described by the product of power functions of the plasma density, heating power, and rotational transform: $W = W_0 n_e^{\alpha _n } P^{\alpha _p } \iota ^{\alpha _\iota } $ . The energy scalings constructed in terms of the parameters in the initial stage of free plasma decay and those in the steady-state phase are close to one another. The dynamic analysis of the plasma energy decay is now under way.     

Fast measurements of the limiter surface temperature and the heat flux onto the limiter in the T-11M tokamak by using an IR radiometer

The limiter surface temperature is measured with a high-speed IR radiometer (λ⋍3–6 μm) during a T-11M tokamak discharge. The IR radiometer was absolutely calibrated under steady-state operating conditions: the limiter was heated by a special inner heater, and the limiter temperature was measured with a thermocouple. Based on these measurements, the heat fluxes from the plasma onto the limiter surface during the discharge are determined. The measurement technique is discussed, and the data on the limiter surface temperature and the heat flux to the limiter for different regimes of the T-11M operation are presented. __________ Translated from Fizika Plazmy, Vol. 28, No. 10, 2002, pp. 872–876. Original Russian Text Copyright ? 2002 by Lazarev, Alekseev, Belov, Mirnov.     

Cleaning of inner vacuum surfaces in the Uragan-3M facility by radio-frequency discharges

A method for cleaning vacuum surfaces by a low-temperature (T _e ～ 10 eV) relatively dense (n _e ≈ 10¹² cm^?3) plasma of an RF discharge was developed and successfully applied at the Uragan-3M torsatron. The convenience of the method is that it can be implemented with the same antenna system and RF generators that are used to produce and heat the plasma in the operating mode and does not require retuning the frequencies of the antennas and RF generators. The RF discharge has a high efficiency from the standpoint of cleaning vacuum surfaces. After performing a series of cleanings by the low-temperature RF discharge plasma (about 20000 pulses), (i) the intensity of the CIII impurity line was substantially reduced, (ii) a quasi-steady operating mode with a duration of up to 50 ms, a plasma density of n _e ≈ 10¹² cm^?3, and an electron temperature of up to T _e ～ 1 keV was achieved, and (iii) mass spectrometric analysis of the residual gas in the chamber indicated a significant reduction in the impurity content.     

Analysis of cylindrical Langmuir probe using experiment and different theories

Cylindrical probe data have been analyzed using different theories in order to determine some plasma parameters (electron temperature and electron and ion densities). Langmuir probe data are obtained in a cylindrical DC glow discharge in the positive column plasma at argon gas pressures varied from 0.5 to 6 Torr and at constant discharge current equal to 10 mA. The electron density has calculated from the electron current at the space potential and from Orbital Motion Limited (OML) collisionless theory. Ion density has obtained from the OML analysis of the ion saturation currents. In addition, the electron temperature has measured by three different methods using probe and electrons currents. The electron temperature T _e , plasma density n _e , and space potential V _s , have been obtained from the measured single cylindrical probe I–V characteristic curves. The radial distribution of the electron temperature and plasma density along the glow discharge are measured and discussed. Using the collisionless theories by Langmuir cylindrical probe and up to several Torr argon gas pressures the differences between the values of electron temperature and electron and ion densities stay within reasonable error limits.     

Scanning calorimetry measurements of the energy parameters of a plasmochemical polymer oxidation reaction

The contributions of heat fluxes of different nature to the total heat flux from a weakly ionized oxygen plasma of a low-pressure (20–120 Pa) RF discharge onto the calorimeter surface, on which a chemical reaction between atomic oxygen and a polymer proceeds, are distinguished. The activation energy (ΔE≈0.37 eV), the reaction heat (H≈27 kJ/g), and the rate constant for heat release in a surface plasmochemical reaction are determined.     

The Direct Conversion of Heat to Electricity Using Multiferroic Alloys

We demonstrate a new method for the direct conversion of heat to electricity using the recently discovered multiferroic alloy, Ni₄₅Co₅Mn₄₀Sn₁₀ 1 . This alloy undergoes a low hysteresis, reversible martensitic phase transformation from a nonmagnetic martensite phase to a strongly ferromagnetic austenite phase upon heating. When biased by a suitably placed permanent magnet, heating through the phase transformation causes a sudden increase of the magnetic moment to a large value. As a consequence of Faraday’s law of induction, this drives a current in a surrounding circuit. Theory predicts that under optimal conditions the performance compares favorably with the best thermoelectrics. Because of the low hysteresis of the alloy, a promising area of application of this concept appears to be energy conversion at small ΔT, suggesting a possible route to the conversion of the vast amounts of energy stored on earth at small temperature difference. We postulate other new methods for the direct conversion of heat to electricity suggested by the underlying theory.     

Melting, glass transition, and apparent heat capacity of α-d-glucose by thermal analysis

The thermal behaviors of α-d-glucose in the melting and glass transition regions were examined utilizing the calorimetric methods of standard differential scanning calorimetry (DSC), standard temperature-modulated differential scanning calorimetry (TMDSC), quasi-isothermal temperature-modulated differential scanning calorimetry (quasi-TMDSC), and thermogravimetric analysis (TGA). The quantitative thermal analyses of experimental data of crystalline and amorphous α-d-glucose were performed based on heat capacities. The total, apparent and reversing heat capacities, and phase transitions were evaluated on heating and cooling. The melting temperature (T_m) of a crystalline carbohydrate such as α-d-glucose, shows a heating rate dependence, with the melting peak shifted to lower temperature for a lower heating rate, and with superheating of around 25 K. The superheating of crystalline α-d-glucose is observed as shifting the melting peak for higher heating rates, above the equilibrium melting temperature due to of the slow melting process. The equilibrium melting temperature and heat of fusion of crystalline α-d-glucose were estimated. Changes of reversing heat capacity evaluated by TMDSC at glass transition (T_g) of amorphous and melting process at T_m of fully crystalline α-d-glucose are similar. In both, the amorphous and crystalline phases, the same origin of heat capacity changes, in the T_g and T_m area, are attributable to molecular rotational motion. Degradation occurs simultaneously with the melting process of the crystalline phase. The stability of crystalline α-d-glucose was examined by TGA and TMDSC in the melting region, with the degradation shown to be resulting from changes of mass with temperature and time. The experimental heat capacities of fully crystalline and amorphous α-d-glucose were analyzed in reference to the solid, vibrational, and liquid heat capacities, which were approximated based on the ATHAS scheme and Data Bank.     

Mathematical modeling of gas-dynamic and radiative processes in experiments with the use of laser and heavy-ion beams

Results are presented from theoretical and experimental studies of gas-dynamic and radiative processes in the plasma that is planned to be used in future experiments on the stopping of fast heavy-ion beams. These experiments are aimed at measuring the enhanced (as compared to cold substance) plasma stopping power. To reliably interpret the experimental results, it is necessary to create a hydrodynamically stable homogeneous plasma with a uniform temperature and a lifetime exceeding the transit time of the heavy-ion beam (3–5 ns). The method for calculating plasma gas-dynamic characteristics with allowance for radiative heat transfer is described. The specific features of the so-called ion model of plasma, which is used to calculate plasma radiative characteristics, are discussed. The emission spectrum formed as a result of conversion of laser radiation into X-rays and the subsequent passing through a triacetate cellulose (C₁₂H₁₆O₈) target is calculated. The simulated spectrum of transmitted radiation satisfactorily agrees with experimental data.     

Alternatives for natural‐gas‐based heating systems: A quantitative GIS‐based analysis of climate impacts and financial feasibility

The heating of buildings currently produces 6% of global greenhouse gas emissions. Sustainable heating technologies can reduce heating‐related CO₂ emissions by up to 90%. We present a Python‐based GIS model to analyze the environmental and financial impact of strategies to reduce heating‐related CO₂ emissions of residential buildings. The city‐wide implementation of three alternatives to natural gas are evaluated: high‐temperature heating networks, low‐temperature heating networks, and heat pumps. We find that both lowering the demand for heat and providing more sustainable sources of heat will be necessary to achieve significant CO₂‐emission reductions. Of the studied alternatives, only low‐temperature heating networks and heat pumps have the potential to reduce CO₂ emissions by 90%. A CO₂ tax and an increase in tax on the use of natural gas are potent policy tools to accelerate the adoption of low‐carbon heating technologies.     

Effect of the radial electric field on lower hybrid plasma heating in the FT-2 tokamak

Conditions for efficient ion heating in the interaction of lower hybrid waves with plasma are experimentally determined. Experiments show that efficient lower hybrid heating stimulates a transition to the improved confinement mode. The formation of internal and external transport barriers is associated with strong central ion heating, which results in a change of the radial electric field E _r and an increase in the shear of the poloidal plasma velocity. The improved confinement mode in the central region of the discharge is attained under the combined action of lower hybrid heating and an additional rapid increase in the plasma current. A new mechanism for the generation of an additional field E _r is proposed to explain the formation of a transport barrier.     

Investigation of the electron energy distribution function in hollow-cathode glow discharges in nitrogen and oxygen

The mechanism for the formation of the inverse electron distribution function is proposed and realized experimentally in a nitrogen plasma of a hollow-cathode glow discharge. It is shown theoretically and experimentally that, for a broad range of the parameters of an N₂ discharge, it is possible to form a significant dip in the profile of the electron distribution function in the energy range ε=2–4 eV and, accordingly, to produce the inverse distribution with df(ε)/d?>0. The formation of a dip is associated with both the vibrational excitation of N₂ molecules and the characteristic features of a hollow-cathode glow discharge. In such a discharge, the applied voltage drops preferentially across a narrow cathode sheath. In the main discharge region, the electric field E is weak (E<0.1 V/cm at a pressure of about p～0.1 torr) and does not heat the discharge plasma. The gas is ionized and the ionization-produced electrons are heated by a beam of fast electrons (with an energy of about 400 eV) emitted from the cathode. A high-energy electron beam plays an important role in the formation of a dip in the profile of the electron distribution function in the energy range in which the cross section for the vibrational excitation of nitrogen molecules is maximum. A plasma with an inverted electron distribution function can be used to create a population inversion in which more impurity molecules and atoms will exist in electronically excited states.     

Experimental investigation of the shock wave in a fast discharge with cylindrical geometry

The work is devoted to the registration and the study of the properties of cylindrical shock waves generated in the fast discharge (dI/dt ～ 10¹² A/s) inside the ceramic tube (Al₂O₃) filled by argon at pressures of 100 and 300 Pa. The shock wave appears at the inner wall of the insulator and moves to the discharge axis with a velocity of about (3?4) × 10⁶ cm/s with subsequent cumulation. The plasma behind the front is heated enough to produce radiation in the vacuum ultraviolet (VUV) region, which makes it possible to study its structure by means of a pinhole camera with a microchannel plate detector. The time resolution of the registration system was 10 ns. The analysis of VUV spectra of the plasma shows that the electron temperature behind the shock wave front is about several eV; after the moment of cumulation, its temperature increases to 20–30 eV.     

Dynamics of the water molecule density in a discharge chamber filled with a low-pressure humid gas

The dynamics of the H₂O molecule density in a metal gas-discharge chamber filled with low-pressure water vapor or its mixtures with noble gases was investigated by manometric and spectral methods. Regimes both with and without discharge excitation were studied. In the absence of a discharge, the molecule density dynamics is governed by the heterogeneous interaction of molecules with the chamber walls. In the presence of a discharge, in addition to the heterogeneous interaction, fast plasmachemical molecule dissociation also contributes to the initial stage of H₂O molecule loss. The role of heating of the chamber walls is discussed.     

Controlling the characteristics of a repetitive volume discharge in CFC-12 and its mixtures with argon

The parameters of a repetitive volume discharge in CF₂Cl₂ (CFC-12) and its mixtures with argon at pressures of P(CF₂Cl₂)≤0.4 kPa and P(Ar)≤1.2 kPa are studied. The discharge was ignited in an electrode system consisting of a spherical anode and a plane cathode by applying a dc voltage U_ch≤1 kV to the anode. The electrical and optical characteristics of a volume discharge (such as the current-voltage characteristics; the plasma emission spectra; and the waveforms of the discharge voltage, the discharge current, and the total intensity of plasma emission) are investigated. It is found that, by shunting the discharge gap with a pulsed capacitor with a capacitance of C₀≤3.5 nF, it is possible to control the amplitude and duration of the discharge current pulses, as well as the characteristics of the pulsed plasma emission. The increase in the capacitance C₀ from 20 to 3500 pF leads to a significant increase in the amplitude and duration of the discharge current pulses, whereas the pulse repetition rate decreases from 70 to 3 kHz. The glow discharge exists in the form of a domain with a height of up to 3 cm and diameter of 0.5–3.0 cm. The results obtained can be used to design an untriggered repetitive germicidal lamp emitting in the Cl₂(257/200 nm) and ArCl (175 nm) molecular bands and to develop plasmachemical methods for depositing amorphous fluorocarbon and chlorocarbon films.     

Formation of an internal transport barrier in the ohmic H-mode in the TUMAN-3M tokamak

In experiments on studying the ohmic H-mode in the TUMAN-3M tokamak, it is found that, in high-current (I _p～120–170 kA) discharges, a region with high electron-temperature and density gradients is formed in the plasma core. In this case, the energy confinement time τ _E attains 9–18 ms, which is nearly twice as large as that predicted by the ELM-free ITER-93H scaling. This is evidence that the internal transport barrier in a plasma can exist without auxiliary heating. Calculations of the effective thermal diffusivity by the ASTRA transport code demonstrate a strong suppression of heat transport in the region where the temperature and density gradients are high.     

Characteristic properties of the frame-antenna-produced RF discharge evolution in the Uragan-3M torsatron

In the ? = 3 Uragan-3M torsatron, hydrogen plasma is produced and heated by RF fields in the Alfvén range of frequencies (ω ? ω _ci ). To this end, a frame antenna with a broad spectrum of generated parallel wavenumbers is used. The RF discharge evolution is studied experimentally at different values of the RF power fed to the antenna (the anode voltage of the oscillator and the antenna current) and the initial pressure of the fueling gas. It is shown that, depending on the antenna current and hydrogen pressure, the discharge can operate in two regimes differing in the plasma density, temperature, and particle loss. The change in the discharge regime with increasing anode voltage is steplike in character. The particular values of the anode voltage and pressure at which the change occurs are affected by RF preionization or breakdown stabilization by a microwave discharge. The obtained results will be used in future experiments to choose the optimal regimes of the frame-antenna-produced RF discharge as a target for the production and heating of a denser plasma by another, shorter wavelength three-half-turn antenna.     

Analysis of the separation of gadolinium isotopes by the ICR method

The problem of separating gadolinium isotopes is discussed. The parameters of isotope separation in a plasma by the ICR method are estimated for a device with given operating parameters. The mean transverse energy 〈E_⊥〉 of the heated ions of the ¹⁵⁷Gd isotope and the heating efficiency η are calculated as functions of the frequency of the RF electric field in the plasma. The dependence of the heating efficiency η on the longitudinal temperature of the plasma flow is investigated. The issue of how the concentration of the target isotope ions at the collector plate depends on the longitudinal coordinate measured from the front edge of the plate is analyzed for different values of the frequency detuning parameter. The extraction coefficient Г for the target isotope is calculated as a function of the distance b between the collector plates for different frequency detunings.