共查询到20条相似文献,搜索用时 15 毫秒
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Wenchi Kong Shiwei Wang Feng Li Chen Zhao Jun Xing Yuting Zou Zhi Yu Chun‐Ho Lin Yuwei Shan Yu Hang Lai Qingfeng Dong Tom Wu Weili Yu Chunlei Guo 《Liver Transplantation》2020,10(34)
Grains and grain boundaries play key roles in determining halide perovskite‐based optoelectronic device performance. Halide perovskite monocrystalline solids with large grains, smaller grain boundaries, and uniform surface morphology improve charge transfer and collection, suppress recombination loss, and thus are highly favorable for developing efficient solar cells. To date, strategies of synthesizing high‐quality thin monocrystals (TMCs) for solar cell applications are still limited. Here, by combining the antisolvent vapor‐assisted crystallization and space‐confinement strategies, high‐quality millimeter sized TMCs of methylammonium lead iodide (MAPbI3) perovskites with controlled thickness from tens of nanometers to several micrometers have been fabricated. The solar cells based on these MAPbI3 TMCs show power conversion efficiency (PCE) of 20.1% which is significantly improved compared to their polycrystalline counterparts (PCE) of 17.3%. The MAPbI3 TMCs show large grain size, uniform surface morphology, high hole mobility (up to 142 cm2 V?1 s?1), as well as low trap (defect) densities. These properties suggest that TMCs can effectively suppress the radiative and nonradiative recombination loss, thus provide a promising way for maximizing the efficiency of perovskite solar cells. 相似文献
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Wenzhan Xu Luyao Zheng Xiaotao Zhang Yu Cao Tianyu Meng Dezhen Wu Lei Liu Wenping Hu Xiong Gong 《Liver Transplantation》2018,8(14)
In the past years, hybrid perovskite materials have attracted great attention due to their superior optoelectronic properties. In this study, the authors report the utilization of cobalt (Co2+) to partially substitute lead (Pb2+) for developing novel hybrid perovskite materials, CH3NH3Pb1‐xCoxI3 (where x is nominal ratio, x = 0, 0.1, 0.2 and 0.4). It is found that the novel perovskite thin films possess a cubic crystal structure with superior thin film morphology and larger grain size, which is significantly different from pristine thin film, which possesses the tetragonal crystal structure, with smaller grain size. Moreover, it is found that the 3d orbital of Co2+ ensures higher electron mobilities and electrical conductivities of the CH3NH3Pb1‐xCoxI3 thin films than those of pristine CH3NH3Pb4 thin film. As a result, a power conversion efficiency of 21.43% is observed from perovskite solar cells fabricated by the CH3NH3Pb0.9Co0.1I3 thin film. Thus, the utilization of Co, partially substituting for Pb to tune physical properties of hybrid perovskite materials provides a facile way to boost device performance of perovskite solar cells. 相似文献
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Niraj N. Lal Yasmina Dkhissi Wei Li Qicheng Hou Yi‐Bing Cheng Udo Bach 《Liver Transplantation》2017,7(18)
The meteoric rise of perovskite single‐junction solar cells has been accompanied by similar stunning developments in perovskite tandem solar cells. Debuting with efficiencies less than 14% in 2014, silicon–perovskite solar cells are now above 25% and will soon surpass record silicon single‐junction efficiencies. Unconstrained by the Shockley–Quiesser single‐junction limit, perovskite tandems suggest a real possibility of true third‐generation thin‐film photovoltaics; monolithic all‐perovskite tandems have reached 18% efficiency and will likely pass perovskite single‐junction efficiencies within the next 5 years. Inorganic–organic metal–halide perovskites are ideal candidates for inclusion in tandem solar cells due to their high radiative recombination efficiencies, excellent absorption, long‐range charge‐transport, and broad ability to tune the bandgap. In this progress report, the development of perovskite tandem cells is reviewed, with presentation of their key motivations and challenges. In detail, it presents an overview of recombination layer materials, bandgap‐tuneability, transparent contact architectures, and perovskite compounds for use in tandems. Theoretical estimates of efficiency for future tandem and triple‐junction perovskite cells are presented, outlining roadmaps for future focused research. 相似文献
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Azhar Fakharuddin Lukas Schmidt‐Mende Germà Garcia‐Belmonte Rajan Jose Ivan Mora‐Sero 《Liver Transplantation》2017,7(22)
Rapid improvement in photoconversion efficiency (PCE) of solution processable organometallic hybrid halide based perovskite solar cells (PSCs) have taken the photovoltaic (PV) community with a surprise and has extended their application in other electronic devices such as light emitting diodes, photo detectors and batteries. Together with efforts to push the PCE of PSCs to record values >22% – now at par with that of crystalline silicon solar cells – origin of their PV action and underlying physical processes are also deeply investigated worldwide in diverse device configurations. A typical PSC consists of a perovskite film sandwiched between an electron and a hole selective contact thereby creating ESC/perovskite and perovskite/HSC interfaces, respectively. The selective contacts and their interfaces determine properties of perovskite layer and also control the performance, origin of PV action, open circuit voltage, device stability, and hysteresis in PSCs. Herein, we define ideal charge selective contacts, and provide an overview on how the choice of interfacing materials impacts charge accumulation, transport, transfer/recombination, band‐alignment, and electrical stability in PSCs. We then discuss device related considerations such as morphology of the selective contacts (planar or mesoporous), energetics and electrical properties (insulating and conducting), and its chemical properties (organic vs inorganic). Finally, the outlook highlights key challenges and future directions for a commercially viable perovskite based PV technology. 相似文献
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Perovskite Solar Cells: Stable Formamidinium‐Based Perovskite Solar Cells via In Situ Grain Encapsulation (Adv. Energy Mater. 22/2018)
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Tanghao Liu Yuanyuan Zhou Zhen Li Lin Zhang Ming‐Gang Ju Deying Luo Ye Yang Mengjin Yang Dong Hoe Kim Wenqiang Yang Nitin P. Padture Matthew C. Beard Xiao Cheng Zeng Kai Zhu Qihuang Gong Rui Zhu 《Liver Transplantation》2018,8(22)
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Perovskite Solar Cells: Enhanced Light Harvesting in Perovskite Solar Cells by a Bioinspired Nanostructured Back Electrode (Adv. Energy Mater. 20/2017)
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Jian Wei Rui‐Peng Xu Yan‐Qing Li Chi Li Jing‐De Chen Xin‐Dong Zhao Zhong‐Zhi Xie Chun‐Sing Lee Wen‐Jun Zhang Jian‐Xin Tang 《Liver Transplantation》2017,7(20)
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