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1.
Nan Piao Xiao Ji Hong Xu Xiulin Fan Long Chen Sufu Liu Mounesha N. Garaga Steven G. Greenbaum Li Wang Chunsheng Wang Xiangming He 《Liver Transplantation》2020,10(10)
Development of electrolytes that simultaneously have high ionic conductivity, wide electrochemical window, and lithium dendrite suppression ability is urgently required for high‐energy lithium‐metal batteries (LMBs). Herein, an electrolyte is designed by adding a countersolvent into LiFSI/DMC (lithium bis(fluorosulfonyl)amide/dimethyl carbonate) electrolytes, forming countersolvent electrolytes, in which the countersolvent is immiscible with the salt but miscible with the carbonate solvents. The solvation structure and unique properties of the countersolvent electrolyte are investigated by combining electroanalytical technology with a Molecular Dynamics simulation. Introducing the countersolvent alters the coordination shell of Li+ cations and enhances the interaction between Li+ cations and FSI? anions, which leads to the formation of a LiF‐rich solid electrolyte interphase, arising from the preferential reduction of FSI? anions. Notably, the countersolvent electrolyte suppresses Li dendrites and enables stable cycling performance of a Li||NCM622 battery at a high cut‐off voltage of 4.6 V at both 25 and 60 °C. This study provides an avenue to understand and design electrolytes for high‐energy LMBs in the future. 相似文献
2.
Lithium Difluorophosphate‐Based Dual‐Salt Low Concentration Electrolytes for Lithium Metal Batteries
Hao Zheng Hongfa Xiang Fuyang Jiang Yongchao Liu Yi Sun Xin Liang Yuezhan Feng Yan Yu 《Liver Transplantation》2020,10(30)
The safety hazards and low Coulombic efficiency originating from the growth of lithium dendrites and decomposition of the electrolyte restrict the practical application of Li metal batteries (LMBs). Inspired by the low cost of low concentration electrolytes (LCEs) in industrial applications, dual‐salt LCEs employing 0.1 m Li difluorophosphate (LiDFP) and 0.4 m LiBOB/LiFSI/LiTFSI are proposed to construct a robust and conductive interphase on a Li metal anode. Compared with the conventional electrolyte using 1 m LiPF6, the ionic conductivity of LCEs is reduced but the conductivity decrement of the separator immersed in LCEs is moderate, especially for the LiDFP–LiFSI and LiDFP–LiTFSI electrolytes. The accurate Coulombic efficiency (CE) of the Li||Cu cells increases from 83.3% (electrolyte using 1 m LiPF6) to 97.6%, 94.5%, and 93.6% for LiDFP–LiBOB, LiDFP–LiFSI, and LiDFP–LiTFSI electrolytes, respectively. The capacity retention of Li||LiFePO4 cells using the LiDFP–LiBOB electrolyte reaches 95.4% along with a CE over 99.8% after 300 cycles at a current density of 2.0 mA cm?2 and the capacity reaches 103.7 mAh g?1 at a current density of up to 16.0 mA cm?2. This work provides a dual‐salt LCE for practical LMBs and presents a new perspective for the design of electrolytes for LMBs. 相似文献
3.
Correlating Electrode–Electrolyte Interface and Battery Performance in Hybrid Solid Polymer Electrolyte‐Based Lithium Metal Batteries
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Qiwei Pan Dmitri Barbash Derrick M. Smith Hao Qi Sarah E. Gleeson Christopher Y. Li 《Liver Transplantation》2017,7(22)
Solid polymer electrolytes (SPEs) are desirable in lithium metal batteries (LMBs) since they are nonflammable and show excellent lithium dendrite growth resistance. However, fabricating high performance polymer LMBs is still a grand challenge because of the complex battery system. In this work, a series of tailor‐designed hybrid SPEs are used to prepare LMBs with a LiFePO4‐based cathode. High performance LMBs with both excellent rate capability and long cycle life are obtained at 60 and 90 °C. The well‐controlled network structure in this series of hybrid SPEs offers a model system to study the relationship between the SPE properties and the LMB performance. It is shown that the cycle life of the polymer LMBs is closely correlated with the SPE–Li interface ionic conductivity, underscoring the importance of the solid electrolyte interface in LMB operation. LMB performance is further correlated with the molecular network structure. It is anticipated that results from this study will shed light on designing SPEs for high performance LMB applications. 相似文献
4.
Stable Lithium Electrodeposition at Ultra‐High Current Densities Enabled by 3D PMF/Li Composite Anode
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Lei Fan Houlong L. Zhuang Weidong Zhang Yao Fu Zhihao Liao Yingying Lu 《Liver Transplantation》2018,8(15)
Lithium metal batteries (LMBs) are promising candidates for next‐generation energy storage due to their high energy densities on both weight and volume bases. However, LMBs usually undergo uncontrollable lithium deposition, unstable solid electrolyte interphase, and volume expansion, which easily lead to low Coulombic efficiency, poor cycling performance, and even safety hazards, hindering their practical applications for more than forty years. These issues can be further exacerbated if operated at high current densities. Here a stable lithium metal battery enabled by 3D porous poly‐melamine‐formaldehyde (PMF)/Li composite anode is reported. PMF with a large number of polar groups (amine and triazine) can effectively homogenize Li‐ion concentration when these ions approach to the anode surface and thus achieve uniform Li deposition. Moreover, the 3D structured anode can serve as a Li host to mitigate the volume change during Li stripping and plating process. Galvanostatic measurements demonstrate that the 3D composite electrode can achieve high‐lithium Coulombic efficiency of 94.7% at an ultrahigh current density of 10 mA cm?2 after 50 cycles with low hysteresis and smooth voltage plateaus. When coupled with Li4Ti5O12, half‐cells show enhanced rate capabilities and Coulombic efficiencies, opening great opportunities for high‐energy batteries. 相似文献
5.
Li‐Ping Wang Tai‐Shan Wang Ya‐Xia Yin Ji‐Lei Shi Chun‐Ru Wang Yu‐Guo Guo 《Liver Transplantation》2019,9(28)
Solid‐state lithium metal batteries (SSLMBs) may become one of the high‐energy density storage devices for the next generation of electric vehicles. High safety and energy density can be achieved by utilizing solid electrolytes and Li metal anodes. Therefore, developing cathode materials which can match with Li metal anode efficiently is indispensable. In SSLMBs, Li metal anodes can afford the majority of active lithium ions, then lithium‐depleted cathode materials can be a competitive candidate to achieve high gravimetric energy density as well as save lithium resources. Li0.33MnO2 lithium‐depleted material is chosen, which also has the advantages of low synthesis temperature and low cost (cobalt‐free). Notably, solid‐state electrolyte can greatly alleviate the problem of manganese dissolution in the electrolyte, which is beneficial to improve the cycling stability of the battery. Thus, SSLMBs enable practical applications of lithium‐depleted cathode materials. 相似文献
6.
Haiping Wu Yaobin Xu Xiaodi Ren Bin Liu Mark H. Engelhard Michael S. Ding Patrick Z. El‐Khoury Linchao Zhang Qiuyan Li Kang Xu Chongmin Wang Ji‐Guang Zhang Wu Xu 《Liver Transplantation》2019,9(41)
Due to the limited oxidation stability (<4 V) of ether oxygen in its polymer structure, polyethylene oxide (PEO)‐based polymer electrolytes are not compatible with high‐voltage (>4 V) cathodes, thus hinder further increases in the energy density of lithium (Li) metal batteries (LMBs). Here, a new type of polymer‐in‐“quasi‐ionic liquid” electrolyte is designed, which reduces the electron density on ethereal oxygens in PEO and ether solvent molecules, induces the formation of stable interfacial layers on both surfaces of the LiNi1/3Mn1/3Co1/3O2 (NMC) cathode and the Li metal anode in Li||NMC batteries, and results in a capacity retention of 88.4%, 86.7%, and 79.2% after 300 cycles with a charge cutoff voltage of 4.2, 4.3, and 4.4 V for the LMBs, respectively. Therefore, the use of “quasi‐ionic liquids” is a promising approach to design new polymer electrolytes for high‐voltage and high‐specific‐energy LMBs. 相似文献
7.
Kexin Liu Hui Cheng Zhuyi Wang Yin Zhao Yingying Lv Liyi Shi Xuesong Cai Zhongling Cheng Haijiao Zhang Shuai Yuan 《Liver Transplantation》2024,14(14):2303940
Ultrathin all-solid-state electrolytes with an excellent Li+ transport behavior are highly desirable for developing high-energy-density solid-state lithium metal batteries. However, how to balance the electrochemical performance and their mechanical properties remains a huge challenge. Herein, an ultrathin solid electrolyte membrane with a thickness of only 3 µm and a weight of 11.7 g m−2 is well constructed by integrating individual functionalized organic with inorganic modules. Impressively, the optimized hybrid electrolyte membrane shows a set of merits including a high room-temperature ionic conductivity of 1.77 × 10−4 S cm−1, large Li+ transference number of 0.65, and strong mechanical strength (strength of 29 MPa, elongation of 95%), as well as negligible thermal shrink at 180 °C. The analysis results reveal that the lithium sulfonate-functionalized mesoporous silica nanoparticles in the membrane play a crucial role in the selective transport of Li+ through anion trapping and cation exchange. The pouch full cell is further assembled with a high-voltage NCM cathode and thin lithium anode, which exhibits excellent long-term cycling stability, outstanding rate performance at room temperature, and high safety against abused conditions. The current work provides an innovative strategy for achieving lithium metal batteries with ultrathin all-solid-state electrolytes. 相似文献
8.
Safety‐Reinforced Poly(Propylene Carbonate)‐Based All‐Solid‐State Polymer Electrolyte for Ambient‐Temperature Solid Polymer Lithium Batteries
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Jianjun Zhang Jianghui Zhao Liping Yue Qingfu Wang Jingchao Chai Zhihong Liu Xinhong Zhou Hong Li Yuguo Guo Guanglei Cui Liquan Chen 《Liver Transplantation》2015,5(24)
An integrated preparation of safety‐reinforced poly(propylene carbonate)‐based all‐solid polymer electrolyte is shown to be applicable to ambient‐temperature solid polymer lithium batteries. In contrast to pristine poly(ethylene oxide) solid polymer electrolyte, this solid polymer electrolyte exhibits higher ionic conductivity, wider electrochemical window, better mechanical strength, and superior rate performance at 20 °C. Moreover, lithium iron phosphate/lithium cell using such solid polymer electrolyte can charge and discharge even at 120 °C. It is also noted that the solid‐state soft‐package lithium cells assembled with this solid polymer electrolyte can still power a red light‐emitting diode lamp without suffering from internal short‐circuit failures even after cutting off one part of the battery. Considering the aspects mentioned above, the solid polymer electrolyte is eligible for practical lithium battery applications with improved reliability and safety. Just as important, a new perspective that the degree of amorphous state of polymer is also as critical as its low glass transition temperature for the exploration of room temperature solid polymer electrolyte is illustrated. In all, this study opens up a kind of new avenue that could be a milestone to the development of high‐voltage and ambient‐temperature all‐solid‐state polymer electrolytes. 相似文献
9.
A Lithium Amide‐Borohydride Solid‐State Electrolyte with Lithium‐Ion Conductivities Comparable to Liquid Electrolytes
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Yigang Yan Ruben‐Simon Kühnel Arndt Remhof Léo Duchêne Eduardo Cuervo Reyes Daniel Rentsch Zbigniew Łodziana Corsin Battaglia 《Liver Transplantation》2017,7(19)
High ionic conductivity of up to 6.4 × 10?3 S cm?1 near room temperature (40 °C) in lithium amide‐borohydrides is reported, comparable to values of liquid organic electrolytes commonly employed in lithium‐ion batteries. Density functional theory is applied coupled with X‐ray diffraction, calorimetry, and nuclear magnetic resonance experiments to shed light on the conduction mechanism. A Li4Ti5O12 half‐cell battery incorporating the lithium amide‐borohydride electrolyte exhibits good rate performance up to 3.5 mA cm?2 (5 C) and stable cycling over 400 cycles at 1 C at 40 °C, indicating high bulk and interfacial stability. The results demonstrate the potential of lithium amide‐borohydrides as solid‐state electrolytes for high‐power lithium‐ion batteries. 相似文献
10.
Ethylene Carbonate‐Free Electrolytes for High‐Nickel Layered Oxide Cathodes in Lithium‐Ion Batteries
Layered lithium nickel oxide (LiNiO2) can provide very high energy density among intercalation cathode materials for lithium‐ion batteries, but suffers from poor cycle life and thermal‐abuse tolerance with large lithium utilization. In addition to stabilization of the active cathode material, a concurrent development of electrolyte systems of better compatibility is critical to overcome these limitations for practical applications. Here, with nonaqueous electrolytes based on exclusively aprotic acyclic carbonates free of ethylene carbonate (EC), superior electrochemical and thermal characteristics are obtained with an ultrahigh‐nickel cathode (LiNi0.94Co0.06O2), capable of reaching a 235 mA h g?1 specific capacity. Pouch‐type graphite|LiNi0.94Co0.06O2 cells in EC‐free electrolytes withstand several hundred charge–discharge cycles with minor degradation at both ambient and elevated temperatures. In thermal‐abuse tests, the cathode at full charge, while reacting aggressively with EC‐based electrolytes below 200 °C, shows suppressed self‐heating without EC. Through 3D chemical and structural analyses, the intriguing impact of EC is visualized in aggravating unwanted surface parasitic reactions and irreversible bulk structural degradation of the cathode at high voltages. These results provide important insights in designing high‐energy electrodes for long‐lasting and reliable lithium‐ion batteries. 相似文献
11.
Aleksei Kolesnikov Martin Kolek Jan Frederik Dohmann Fabian Horsthemke Markus Brner Peter Bieker Martin Winter Marian Cristian Stan 《Liver Transplantation》2020,10(15)
Lithium metal is considered to be the most promising anode for the next generation of batteries if the issues related to safety and low coulombic efficiency can be overcome. It is known that the initial morphology of the lithium metal anode has a great influence on the cycling characteristics of a lithium metal battery (LMB). Lithium‐powder‐based electrodes (Lip‐electrodes) are reported to diminish the occurrence of high surface area lithium deposits. Usually, ultra‐thin lithium foils (<50 µm) and Lip‐electrodes are prepared on a copper substrate, thus a metal–metal contact area is generated. The combination of these two metals in the presence of an electrolyte, however, can lead to galvanic corrosion. Herein, the corrosion behavior of Lip‐electrodes is studied. The porosity of such electrodes leads to a high amount of accessible Cu surface in contact with electrolyte. As a consequence, Lip‐electrodes aged for 1 week in the electrolyte show spontaneous lithium dissolution near the junction to copper and void formation on the lithium‐powder particles. This corrosion process affects the delivered capacity of Lip‐electrodes and increases the overvoltage of the lithium electrodissolution process. The occurrence of corrosion at the Cu|Lip interface raises concerns about the practicality of multi‐metallic component systems for LMBs. 相似文献
12.
Wei Chen Tianyu Lei Chunyang Wu Min Deng Chuanhui Gong Kai Hu Yinchang Ma Liping Dai Weiqiang Lv Weidong He Xuejun Liu Jie Xiong Chenglin Yan 《Liver Transplantation》2018,8(10)
Safety, nontoxicity, and durability directly determine the applicability of the essential characteristics of the lithium (Li)‐ion battery. Particularly, for the lithium–sulfur battery, due to the low ignition temperature of sulfur, metal lithium as the anode material, and the use of flammable organic electrolytes, addressing security problems is of increased difficulty. In the past few years, two basic electrolyte systems are studied extensively to solve the notorious safety issues. One system is the conventional organic liquid electrolyte, and the other is the inorganic solid‐state or quasi‐solid‐state composite electrolyte. Here, the recent development of engineered liquid electrolytes and design considerations for solid electrolytes in tackling these safety issues are reviewed to ensure the safety of electrolyte systems between sulfur cathode materials and the lithium‐metal anode. Specifically, strategies for designing and modifying liquid electrolytes including introducing gas evolution, flame, aqueous, and dendrite‐free electrolytes are proposed. Moreover, the considerations involving a high‐performance Li+ conductor, air‐stable Li+ conductors, and stable interface performance between the sulfur cathode and the lithium anode for developing all‐solid‐state electrolytes are discussed. In the end, an outlook for future directions to offer reliable electrolyte systems is presented for the development of commercially viable lithium–sulfur batteries. 相似文献
13.
Dong Xu Jianmeng Su Jun Jin Ce Sun Yadong Ruan Chunhua Chen Zhaoyin Wen 《Liver Transplantation》2019,9(25)
Poly(vinylidene fluoride‐co‐hexafluoropropylene) (PVDF‐HFP) based gel polymer electrolyte is regarded as a promising candidate to settle the safety issues of liquid electrolytes. However, the currently reported gel polymer electrolytes are still not safe enough owing to high amount of flammable liquid solvents contained in them. Herein, a fireproof PVDF‐HFP based gel polymer electrolyte is designed and synthesized through an in situ crosslinking method, with Li6.4Ga0.2La3Zr2O12 as initiator and ion‐conductive filler. The obtained gel polymer electrolyte demonstrates superior fire resisting properties. The optimized gel polymer electrolyte exhibits an ionic conductivity as high as 1.84 × 10?3 S cm?1 at 20 °C with an electrochemical window up to 4.75 V at room temperature. Moreover, the obtained gel polymer electrolyte shows excellent compatibility with lithium anodes. Therefore, the lithium anode is well protected. Lithium batteries assembled with the gel polymer electrolyte possess superb safety properties in cutting and burning tests. Furthermore, the batteries also show a discharge retention rate as high as 94.08% (in comparison with the initial discharge capacity) after cycling at 0.5 C for 360 cycles with an average columbic efficiency higher than 98%. The purpose of this report is to show the great potential of applying fire‐retardant gel polymer electrolyte to achieve high safety lithium batteries. 相似文献
14.
Hanyu Huo Yue Chen Jing Luo Xiaofei Yang Xiangxin Guo Xueliang Sun 《Liver Transplantation》2019,9(17)
Solid polymer electrolytes as one of the promising solid‐state electrolytes have received extensive attention due to their excellent flexibility. However, the issues of lithium (Li) dendrite growth still hinder their practical applications in solid‐state batteries (SSBs). Herein, composite electrolytes from “ceramic‐in‐polymer” (CIP) to “polymer‐in‐ceramic” (PIC) with different sizes of garnet particles are investigated for their effectiveness in dendrite suppression. While the CIP electrolyte with 20 vol% 200 nm Li6.4La3Zr1.4Ta0.6O12 (LLZTO) particles (CIP‐200 nm) exhibits the highest ionic conductivity of 1.6 × 10?4 S cm?1 at 30 °C and excellent flexibility, the PIC electrolyte with 80 vol% 5 µm LLZTO (PIC‐5 µm) shows the highest tensile strength of 12.7 MPa. A sandwich‐type composite electrolyte (SCE) with hierarchical garnet particles (a PIC‐5 µm interlayer sandwiched between two CIP‐200 nm thin layers) is constructed to simultaneously achieve dendrite suppression and excellent interfacial contact with Li metal. The SCE enables highly stable Li plating/stripping cycling for over 400 h at 0.2 mA cm?2 at 30 °C. The LiFePO4/SCE/Li cells also demonstrate excellent cycle performance at room temperature. Fabricating sandwich‐type composite electrolytes with hierarchical filler designs can be an effective strategy to achieve dendrite‐free SSBs with high performance and high safety at room temperature. 相似文献
15.
Andrea Paolella Wen Zhu Gui‐Liang Xu Andrea La Monaca Sylvio Savoie Gabriel Girard Ashok Vijh Hendrix Demers Alexis Perea Nicolas Delaporte Abdelbast Guerfi Xiang Liu Yang Ren Cheng‐Jun Sun Jun Lu Khalil Amine Karim Zaghib 《Liver Transplantation》2020,10(32)
The thickness of solid‐state electrolytes (SSEs) significantly affects the energy density and safety performance of all‐solid‐state lithium batteries. However, a sufficient understanding of the reactivity toward lithium metal of ultrathin SSEs (<100 µm) based on NASICON remains lacking. Herein, for the first time, a self‐standing and ultrathin (70 µm) NASICON‐type Li1.5Al0.5Ge1.5(PO4)3 (LAGP) electrolyte via a scalable solution process is developed, and X‐ray photoelectron spectroscopy reveals that changes in LAGP at the metastable Li–LAGP interface during battery operation is temperature dependent. Severe germanium reduction and decrease in LAGP particle size are detected at the Li–LAGP interface at elevated temperature. Oriented plating of lithium metal on its preferred (110) face occurs during in situ X‐ray diffraction cycling. 相似文献
16.
Lithium‐air (Li‐air) batteries have become attractive because of their extremely high theoretical energy density. However, conventional Li‐air cells operating with non‐aqueous electrolytes suffer from poor cycle life and low practical energy density due to the clogging of the porous air cathode by insoluble discharge products, contamination of the organic electrolyte and lithium metal anode by moist air, and decomposition of the electrolyte during cycling. These difficulties may be overcome by adopting a cell configuration that consists of a lithium‐metal anode protected from air by a Li+‐ion solid electrolyte and an air electrode in an aqueous catholyte. In this type of configuration, a Li+‐ion conducting “buffer” layer between the lithium‐metal anode and the solid electrolyte is often necessary due to the instability of many solid electrolytes in contact with lithium metal. Based on the type of buffer layer, two different battery configurations are possible: “hybrid” Li‐air batteries and “aqueous” Li‐air batteries. The hybrid and aqueous Li‐air batteries utilize the same battery chemistry and face similar challenges that limit the cell performance. Here, an overview of recent developments in hybrid and aqueous Li‐air batteries is provided and the factors that influence their performance and impede their practical applications, followed by future directions are discussed. 相似文献
17.
Hexagonal Boron Nitride‐Based Electrolyte Composite for Li‐Ion Battery Operation from Room Temperature to 150 °C
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Marco‐Tulio F. Rodrigues Kaushik Kalaga Hemtej Gullapalli Ganguli Babu Arava Leela Mohana Reddy Pulickel M. Ajayan 《Liver Transplantation》2016,6(12)
Batteries for high temperature applications capable of withstanding over 60 °C are still dominated by primary cells. Conventional rechargeable energy storage technologies which have exceptional performance at ambient temperatures employ volatile electrolytes and soft separators, resulting in catastrophic failure under heat. A composite electrolyte/separator is reported that holds the key to extend the capability of Li‐ion batteries to high temperatures. A stoichiometric mixture of hexagonal boron nitride, piperidinium‐based ionic liquid, and a lithium salt is formulated, with ionic conductivity reaching 3 mS cm?1, electrochemical stability up to 5 V and extended thermal stability. The composite is used in combination with conventional electrodes and demonstrates to be stable for over 600 cycles at 120 °C, with a total capacity fade of less than 3%. The ease of formulation along with superior thermal and electrochemical stability of this system extends the use of Li‐ion chemistries to applications beyond consumer electronics and electric vehicles. 相似文献
18.
Qiang Ma Xian‐Xiang Zeng Junpei Yue Ya‐Xia Yin Tong‐Tong Zuo Jia‐Yan Liang Qi Deng Xiong‐Wei Wu Yu‐Guo Guo 《Liver Transplantation》2019,9(13)
Herein, a composite polymer electrolyte with a viscoelastic and nonflammable interface is designed to handle the contact issue and preclude Li dendrite formation. The composite polymer electrolyte (cellulose acetate/polyethylene glycol/Li1.4Al0.4Ti1.6P3O12) exhibits a wide electrochemical window of 5 V (vs Li+/Li), a high Li+ transference number of 0.61, and an excellent ionic conductivity of above 10?4 S cm?1 at 60 °C. In particular, the intimate contact, low interfacial impedance, and fast ion‐transport process between the electrodes and solid electrolytes can be simultaneously achieved by the viscoelastic and nonflammable layer. Benefiting from this novel design, solid lithium metal batteries with either LiFePO4 or LiCoO2 as cathode exhibit superior cyclability and rate capability, such as a discharge capacity of 157 mA h g?1 after 100 cycles at C/2 and 97 mA h g?1 at 5C for LiFePO4 cathode. Moreover, the smooth and uniform Li surface after long‐term cycling confirms the successful suppression of dendrite formation. The viscoelastic and nonflammable interface modification of solid electrolytes provides a promising and general strategy to handle the interfacial issues and improves the operative safety of solid lithium metal batteries. 相似文献
19.
Advanced Electrolytes for Fast‐Charging High‐Voltage Lithium‐Ion Batteries in Wide‐Temperature Range
Xianhui Zhang Lianfeng Zou Yaobin Xu Xia Cao Mark H. Engelhard Bethany E. Matthews Lirong Zhong Haiping Wu Hao Jia Xiaodi Ren Peiyuan Gao Zonghai Chen Yan Qin Christopher Kompella Bruce W. Arey Jun Li Deyu Wang Chongmin Wang Ji‐Guang Zhang Wu Xu 《Liver Transplantation》2020,10(22)
LiNixMnyCo1?x?yO2 (NMC) cathode materials with Ni ≥ 0.8 have attracted great interest for high energy‐density lithium‐ion batteries (LIBs) but their practical applications under high charge voltages (e.g., 4.4 V and above) still face significant challenges due to severe capacity fading by the unstable cathode/electrolyte interface. Here, an advanced electrolyte is developed that has a high oxidation potential over 4.9 V and enables NMC811‐based LIBs to achieve excellent cycling stability in 2.5–4.4 V at room temperature and 60 °C, good rate capabilities under fast charging and discharging up to 3C rate (1C = 2.8 mA cm?2), and superior low‐temperature discharge performance down to ?30 °C with a capacity retention of 85.6% at C/5 rate. It is also demonstrated that the electrode/electrolyte interfaces, not the electrolyte conductivity and viscosity, govern the LIB performance. This work sheds light on a very promising strategy to develop new electrolytes for fast‐charging high‐energy LIBs in a wide‐temperature range. 相似文献
20.
High‐Performance Aqueous Rechargeable Li‐Ni Battery Based on Ni(OH)2/NiOOH Redox Couple with High Voltage
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Ming Zhang Zheng Huang Zhongrong Shen Yingpeng Gong Bo Chi Jian Pu Jian Li 《Liver Transplantation》2017,7(17)
New energy storage and conversion systems require large‐scale, cost‐effective, good safety, high reliability, and high energy density. This study demonstrates a low‐cost and safe aqueous rechargeable lithium‐nickel (Li‐Ni) battery with solid state Ni(OH)2/NiOOH redox couple as cathode and hybrid electrolytes separated by a Li‐ion‐conductive solid electrolyte layer. The proposed aqueous rechargeable Li‐Ni battery exhibits an approximately open‐circuit potential of 3.5 V, outperforming the theoretic stable window of water 1.23 V, and its energy density can be 912.6 W h kg‐1, which is much higher than that of state‐of‐the‐art lithium ion batteries. The use of a solid‐state redox couple as cathode with a metallic lithium anode provides another postlithium chemistry for practical energy storage and conversion. 相似文献