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The stem bark of Xylopia aethiopica has yielded four diterpenes, two of them novel. Three of the diterpenes were identified as (?)-kaur-16-en-19-oic acid and its 7-oxo and 7β-hydroxy derivatives. The fourth was the novel kolavane derivative 2-oxo-kolav-3,13-dien-15-oic acid, a type of compound not previously recorded in the Annonaceae. 相似文献
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Keisuke Watanabe Nobuo Ohno Hirosuke Yoshioka Jonathan Gershenzon Tom J. Mabry 《Phytochemistry》1982,21(3):709-713
Three germacranolide sesquitepene lactones (argophyllin-A and -B and eupatolide), three diterpenoids (ciliaric acid, (?)-16-α-hydroxy-kaur-11-en-19-oic acid and (?)-16-α-hydroxykaurane) and one flavonoid (nevadensin) were isolated and characterized from a chloroform extract of Helianthus argophyllus. Argophyllin-A and -B are both described here for the first time. Their structures were deduced by 1H NMR and 13C NMR. Argophyllin-A and -B were found to show anti-auxin effects while eupatolide exhibited weak insecticidal activity. 相似文献
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Four diterpenes were isolated from the stem bark of Xylopia acutiflora and characterized as (?)-kauran-16α-ol, 7,8-acetoxy-(?)-kaur-16-en-19-oic acid, 15-oxo-(?)-kaur-16-en-19-oic acid, and 16α- hydroxy-(?)-kauran-19-oic acid. 相似文献
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The aerial parts of Helianthus radula afforded a variety of known ent-kauranoic acids as well as two new substances, 11-oxotrachyloban-19-oic a 相似文献
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A new natural triterpenoid, 3β-hydroxylup-12-en-28-oic acid, has been isolated from the roots of Hyptis suaveolens in addition to α- and β-amyrin. 相似文献
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Twenty-seven mainly terpenoid constituents were identified in the essential oil of Mikania micrantha whole plant. Higher terpenoids present in the same plant included two kaurene derivatives and taraxasterol. 相似文献
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Guillermo Delgado Alfonso Romo de Vivar Alfredo Ortega Jorge Cárdenas Elmer O. Schlemper 《Phytochemistry》1983,22(5):1227-1230
The isolation of several known diterpenoids and one new diterpene diol from aerial parts of Viguiera insignis is reported. 相似文献
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Wickramasinghe M. Bandaranayake 《Phytochemistry》1980,19(2):255-257
The following terpenoids were identified in the oleoresin, bark and timber of Canarium zeylanicum: 3β-hydroxyurs-12-en-11-one, 3β-hydroxyolean-12-en-11-one, olean-12-en-3,11-dione, urs-12-en-3,11-dione, α- and β-amyrin, α- and β-amyrenone, taraxerol, sitosterol, canaric acid, elemene, elemol, α-pinene, α- and β-phellandrene, limonene, terpineol and carvone. 相似文献
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Paulo M. Imamura Anita J. Marsaioli Lauro E.S. Barata Edmundo A. Rúveda 《Phytochemistry》1977,16(11):1842-1844
The 13C NMR spectra of some eperuane diterpenes have been recorded and the signals assigned. The substituent shielding effects in these compounds, in comparison with those observed in other series of diterpenes, are also presented. 相似文献
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Four labdane-type diterpenoids have been isolated from the seed of Platycladus orientalis. Their structures have been elucidated by spectroscopic and chemical methods. 相似文献
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Ph. D. Ty M. Lischewski H.V. Phiet A. Preiss T.V. Sung J. Schmidt G. Adam 《Phytochemistry》1984,23(12):2889-2891
Two new triterpenoid carboxylic acids have been isolated from leaves of Acanthopanax trifoliatus and their structures elucidated as 3α, 11α-dihydroxylup-20(29)-en-28-oic acid and 30α, 11α,23-trihydroxylup-20(29)-en-28-oic acid by physical data and chemical transformations. 相似文献
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Anamaría Retana Ramos Eleazar M. Escamilla José Calderón Benjamín Rodríguez 《Phytochemistry》1984,23(6):1329-1330
A new diterpenoid has been isolated from the leaves and fruits of Taxodium mucronatum. Its structure, 8β-hydroxypimar-15-en- 19-oic acid, was established by chemical and spectroscopic means. 相似文献
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The structure of a new triterpene acid from the roots of Bryonia dioica is shown on the basis of chemical and spectroscopic evidence to be 3α-hydroxy-multiflora-7,9(11)-dien-29α-oic acid. This is the first report of a naturally occurring Δ7,9(11) -multiflorene compound. 相似文献
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Acid hydrolysis of the saponins from the stem bark of Guaiacum officinale yielded the new sapogenin 3β,20η-dihydroxy-30-norolean-12-en-28-oic acid and the artifacts 3β-hydroxy-30-norolean-12,19-dien-28-oic acid and its methyl ester. Larreagenin, sitosterol and oleanolic acid were also isolated. 相似文献
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Ferdinand Bohlmann Maniruddin Ahmed Harold Robinson Robert M. King 《Phytochemistry》1981,20(6):1439-1440
A new kolavane derivative, 18-acetoxy-kolav-3-en-15-oic acid, has been isolated from Liatris scariosa. 相似文献
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M. Lischewski P.D. Ty L. Kutschabsky D. Pfeiffer H.V. Phiet A. Preiss T.V. Sung G. Adam 《Phytochemistry》1985,24(10):2355-2357
From Acanthopanax trifoliatus the new nor-triterpenes 24-nor-3α, 11α-dihydroxy-lup-20(29)-en-28-oic acid and 24-nor-11α-hydroxy-3-oxo-lup-20(29)-en-28-oic acid were isolated. Their structures were determined on the basis of spectroscopic data, X-ray analysis and chemical transformations. 相似文献