不同土壤生境下斑茅对重金属的富集特征

为了筛选Cu、Zn、Pb、Cd多重金属离子的富集植物,对不同土壤生境(铜铁矿、钨矿、铅锌矿和无矿场污染)的优势种斑茅(Saccharum arundinaceum(Retz.)Jeswiet)对Cu、Zn、Pb、Cd离子富集情况进行了调查。结果表明,斑茅对Cu、Zn、Pb、Cd离子有富集优势并以Cu富集显著,斑茅根系土壤与斑茅地上部Cu含量存在相关性(P<0.05),斑茅对Pb和Cd的富集与转运存在极显相关性(P<0.01);在强酸、多金属污染弃耕农田土壤中,斑茅不仅符合Cu超富集植物的特征,而且其对Zn、Pb和Cd3种重金属的富集系数和转运系数均>1。在Cd、Cu、Pb和Zn均低于国家土壤环境质量二级标准(GB15618-1995)的弃耕农田中,斑茅对Cu、Zn和Cd的富集系数均>1。研究表明,斑茅可以作为Cu、Zn、Pb、Cd多金属污染土壤的富集植物进行人工修复。     

Heavy metal contamination and health risk assessment in soil-rice system near Xinqiao mine in Tongling city,Anhui province,China

In this study, paddy soil and rice grain samples were collected from the vicinity around the Xinqiao mine in Tongling, China to test for the presence of heavy metals (Cd, Ni, Cr, Cu, Zn, and Pb) in soil-rice system. Results indicated that the soil samples were primarily contaminated with Cd and Cu and followed with Zn and Pb. In rice grains, Cd, Cu, and Cr concentrations exceeded recommended guidelines. However, the regional distribution of heavy metals in rice grains and soil was inconsistent. The bioaccumulation factor of heavy metals in rice grains decreased in the order of Cd > Zn > Cu > Ni > Cr > Pb. The BAF was significantly positively correlated with TCLP-extractable metals and significantly negatively correlated with soil pH. However, the relationship between soil organic matter and the BAF in rice grains was complex. Health risk assessment through rice intake showed that hazard quotients of Cu and Cd were greater than 1 and could pose a considerable non-cancer health risk to adults and children; meanwhile, Cr, Ni, and Cd could pose an unacceptable cancer risk. The results indicated that the government must take measures to reduce heavy metal contents in paddy soil and rice.     

Five heavy metals accumulation and health risk in a traditional Chinese medicine Cortex Moutan collected from different sites in China

This study assessed the concentrations of five heavy metals Pb, Cd, Cr, Cu and Zn in both soil and a traditional Chinese medicine Cortex Moutan collected from 6 typical sites, growing this medicine, in China. The potential health risks associated with those heavy metals were also assessed. It is shown that Cd content in soils from five of the six sites was higher than the environmental Quality Standard for Soils of China (EQSS). The cortex from a copper tailings area in Tongling (marked as TLC) accumulated much higher amounts of heavy metals than the other sites. Calculated pollution index implied that the herbs in TLC were mildly contaminated by Pb, Cd, and Cu. Hazard quotient (HQ) indicated the intake of Pb, Cd, Cr, Cu, and Zn was safe by cortex consumption, but noncarcinogenic and carcinogenic risks of all metals in Cortex Moutan in hillside near the copper tailings (marked as TLB) and TLC were higher. The results suggested more attention should be paid to the planting area near the mining tailing, and in order to ensure the quality of the herbal medicines, the regions where this herb is grown should be at distance from the mining tailing area.     

Nutritional status and risks of potentially toxic elements in some paddy soils and rice tissues

This experiment was conducted to investigate the potential risk of toxic elements in paddy soils and rice straws, bran, and husked grains in Kuchesfahan, Gilan, Iran. The average content of total and DTPA-extractable of Cd, Cu, Fe, Mn, Ni, Pb, and Zn were 7.0, 26.3, 20728.8, 1516.7, 43.8, 16.6, and 211.8?mg kg^?1, and 0.32, 14.1, 97.3, 63.4, 1.7, 4.8, and 56.2?mg kg^?1, respectively. In addition, the average content of Cd, Cu, Fe, Mn, Ni, Pb, and Zn in rice grain was 0.16, 2.4, 135.5, 34.1, 2.0, 0.6, and 15.0?mg kg^?1, respectively. The average transfer factor for Cd, Cu, Fe, Mn, Ni, Pb, and Zn from soil to straw was 0.38, 0.16, 0.004, 0.13, 0.3, 0.04, and 0.09, respectively. The average values of estimated daily intake for Cd, Cu, Fe, Mn, Ni, Pb, and Zn through rice consumption for adult are respectively, estimated to be 0.0004, 0.005, 0.32, 0.08, 0.005, 0.0015, and 0.035?mg kg^?1 body weight per day. There was no health risk index (HRI) values for adult greater than 1 (except three samples for Fe, and one sample for Mn and Cd); indicated that intake of single metal through the consumption of rice was safe. The average of heath index (HI) value for rice consumption was 0.33 and 0.35 for adult and children, respectively. Therefore, combination of several potentially toxic elements may not cause risk to local residents. Spatial distributions of HRI were obtained for potentially toxic metals in husked grains.     

Potential health risk of heavy metals via consumption of rice and vegetables grown in the industrial areas of Bangladesh

Abstract

Heavy metals are toxic in nature, and their contamination in foodstuff is a matter of concern for human health. The present study was conducted to assess the concentrations of chromium, nickel, copper, arsenic, cadmium, and lead in rice and vegetables and their possible human health risks in Tangail district, Bangladesh. Metals were measured by inductively coupled plasma mass spectrometry (ICP-MS) after microwave digestion system. The average values of Cr, Ni, Cu, As, Cd, and Pb in rice and vegetables were 16.26, 16.11, 13.99, 2.28, 1.86, and 7.93?mg/kg, respectively. The average metal concentration in rice and vegetable species was in the decreasing order of okra?>?chili?>?bitter gourd?>?papaya?>?brinjal?>?bean?>?bottle gourd?>?rice?>?cucumber?>?sponge gourd?>?Indian spinach. The estimated daily intake (EDI) values of all the metals except Cu were higher than the maximum tolerable daily intake (MTDI). The target hazard quotients (THQs) values of Ni, Cu, As, Cd, and Pb exceeded the threshold value of 1 through consumption of rice and vegetables, indicating significant health risks to both adult and children. The target carcinogenic risk (TR) of As and Pb through consumption of rice and vegetables was higher than the USEPA threshold level (10^?4). From the health point of view, this study clearly revealed that consumption of these contaminated rice and vegetables definitely poses carcinogenic and non-carcinogenic risks.     

Human Exposure Pathways of Heavy Metals in a Lead-Zinc Mining Area,Jiangsu Province,China

Heavy metal pollution is becoming a serious issue in developing countries such as China, and the public is increasingly aware of its adverse health impacts in recent years. We assessed the potential health risks in a lead-zinc mining area and attempted to identify the key exposure pathways. We evaluated the spatial distributions of personal exposure using indigenous exposure factors and field monitoring results of water, soil, food, and indoor and outdoor air samples. The risks posed by 10 metals and the contribution of inhalation, ingestion and dermal contact pathways to these risks were estimated. Human hair samples were also analyzed to indicate the exposure level in the human body. Our results show that heavy metal pollution may pose high potential health risks to local residents, especially in the village closest to the mine (V1), mainly due to Pb, Cd and Hg. Correspondingly, the residents in V1 had higher Pb (8.14 mg/kg) levels in hair than those in the other two villages. Most of the estimated risks came from soil, the intake of self-produced vegetables and indoor air inhalation. This study highlights the importance of site-specific multipathway health risk assessments in studying heavy-metal exposures in China.     

郑汴路路旁土壤-小麦系统重金属积累及其健康风险评价

按离路基不同距离采集土壤、麦苗和籽粒样品, 在测定样品重金属 (Pb、Cd、Zn、Cr和Cu) 的基础上, 开展了路旁土壤-小麦系统重金属分布、积累和污染状况分析, 并对膳食小麦 (Triticumaestivum) 引起的健康风险进行了评价。结果表明:1) 土壤-小麦系统重金属含量随着离开路基距离的增加呈先增加后减少的趋势, 土壤重金属含量>麦苗重金属含量>籽粒重金属含量。2) 麦苗和小麦籽粒对土壤重金属富集能力的大小顺序均为Cu>Cd>Zn>Pb>Cr, 麦苗对重金属的富集能力大于小麦籽粒。3) 膳食小麦所致的Cd个人健康风险较大。     

Activation and ecological risk assessment of heavy metals in dumping sites of Dabaoshan mine,Guangdong province,China

In Dabaoshan mine, dumping sites were the largest pollution source to the local environment. This study analyzed the activation and ecological risk of heavy metals in waste materials from five dumping sites. Results indicated that the acidification of waste materials was severe at all dumping sites, and pH decreased below 3.0 at four of the five sites. There was a drastic variation in Cu, Zn, Pb, and Cd concentrations in different sites. Site A with 12915.3 mg kg^?1 Pb and 7.2 mg kg^?1 Cd and site C with 1936.2 mg kg^?1 Cu and 5069.0 mg kg^?1 Zn were severely polluted. Higher concentrations of water-soluble Cu were probably the critical constraint for local pioneer plants. A significant positive correlation was found between the concentrations of water-soluble and HOAc-extractable elements, and the regression analysis showed that, compared with Cu, Zn and Cd, Pb was more difficult to be transformed from HOAc extractable to water soluble. Concentration of water soluble metals should be an important index, same as concentration of HOAc extractable metals, in assessing ecological risks, availability, and toxicity of heavy metals. The modified ecological risk index indicated that all dumping sites had very high potential ecological risks. It is necessary to decrease the availability of heavy metals to reduce the impact of waste materials on environment.     

Source analysis and health risk of heavy metals in the different seasons from Taizihe River,China

Twenty five water samples were collected along the Taizihe River, the concentration and health risks of Zn, Cu, Pb, Cr and Cd were detected and evaluated, and the pollution sources was analyzed through principal components analyses. The results indicated that the order of average concentration of heavy metals was follows: Pb > Cr > Cu > Zn and Cd. Among that, the concentrations of Zn, Cu and Cr were at the permissible levels, but Pb and Cd exceeded grade V standard at some sites. The concentrations of Zn and Cu in the wet season were significant higher than that in the dry season (p < 0.05), but the average concentrations of Pb, Cr and Cd were not significantly different in the two seasons (p > 0.05). The annual average risks of human health caused by Cd and Cr were 10⁻³/a and 10⁻⁴/a, respectively, which were higher than the recommended maximum acceptable risk level. The human health risk values of Zn, Pb and Cu were all concentrated at 10⁻⁸/a or 10⁻⁹/a levels, which did not exceed the recommended standard. On the whole, Cd and Cr were the main health risk pollutants of Taizihe River. Pollution sources of Pb was different from other heavy metals in wet and dry season, Cd and Cr were similar in the wet and dry season. The mainly pollution source of heavy metals was industry, especially mining, metal smelting and electroplating industry.     

Heavy metal contamination in vegetables grown around peri-urban and urban-industrial clusters in Ghaziabad,India

Heavy metal contamination of agricultural soils resulting from rapid industrialization and urbanization is of great concern because of potential health risk due to dietary intake of contaminated vegetables. The present study aims to evaluate the status of heavy metals contamination of agricultural soils and food crops around an urban-industrial region in India. Transfer factor values of Cu, Cr, Pb, Cd, Zn, and Ni from soil to vegetable was estimated. The mean heavy metal concentrations (mg/kg) in agricultural soils (Cu: 17.8, Cr: 27.3, Pb: 29.8, Cd: 0.43, Zn: 87, Mn: 306.6, Fe: 16984, and Ni: 53.8) were within allowable concentrations for Indian agricultural soil. The concentrations of Pb, Cd, Zn, and Ni in crops/vegetables exceeded the World Health Organization/Food and Agriculture Organization safe limits. Relative orders of transfer of metals from soil to edible parts of the crops/vegetables were Cd > Pb > Ni > Zn > Cu > Cr. The enrichment factors of heavy metals in soil indicated minor to moderately severe enrichment for Pb, Cd, and Ni; minor to moderate enrichment for Zn; no enrichment to minor enrichment for Mn; and no enrichment to moderate enrichment for Cu at different sites. Ecological risk index of soil showed considerable contamination in one of the wastewater irrigated sites.     

Heavy metal contamination and health risks of indoor dust around Xinqiao Mining Area,Tongling, China

Abstract

In this study, the concentrations and health risks of heavy metals (Cu, Pb, Zn, Ni, Co, Cd, and Cr) in indoor dust are investigated in the vicinity of the Xinqiao mining area, Tongling, China. Results indicate that heavy metals except Co were clearly enriched in indoor dust. Especially Cd was extremely enriched, followed by Zn, Cu, and Pb. However, no significant regional differences (p?>?0.05) were found in other elemental contents aside from Cu. Statistical analysis revealed that metal elements except Co were presumed to originate primarily from mining activities. Health risk assessment indicated that the hazard quotients and hazard indices of all studied metal elements were less than 1 and thus posed no potential noncancer health risks to adults and children. Moreover, the cancer risks of Ni, Cr, Cd, and Co were within acceptable ranges, implying no cancer risk to local residents; however, the noncarcinogenic risk of Pb and the carcinogenic risk of Cr and Cd warrant close attention.     

Health risks of heavy metals to the general public in Hengyang,China, via consumption of rice

This investigation was conducted to survey the levels of cadmium (Cd), lead (Pb), chromium (Cr), copper (Cu), zinc (Zn), and manganese (Mn) in polished rice collected at supermarkets located in Hengyang, China. The surveyed rice samples were grouped according to their production areas into four different groups—Hunan, Jiangxi, Jilin, and Thailand. The data showed that the highest means of Cd, Pb, Cr, Cu, Zn, and Mn contents were in rice samples produced from Hunan (0.215 mg/kg), Thailand (0.537 mg/kg), Hunan (0.348 mg/kg), Jiangxi (2.472 mg/kg), Thailand (17.259 mg/kg), and Jinlin (9.326 mg/kg), respectively. Average daily intake dose for the six elements through consumption of rice was lower than the oral reference dose. Although the hazard quotient values for all six elements were <1.0, hazard index values in all the production areas (except Thailand) were >1.0, and cancer risk (CR) and total CR values were >10^?4, respectively. Certainly, there are inherent limitations for these health risk values, including actual ingestion rate, exposure duration, and bioavailability of heavy metals. These results indicate that long-term heavy metal exposure by consumption of rice in Hengyang could pose both potential non-carcinogenic and carcinogenic health risks to the local residents.     

Concentrations of heavy metals in vegetables between 2004 and 2018, and its impacts on human health in China

Abstract

Heavy metals in vegetables are of great concern worldwide due to their potential bioaccumulation in human. This review-based study researched the concentrations of heavy metals in vegetables from all provinces of China between 2004 and 2018, and assessed the health risk for the residents. The results displayed the highest Pb, Cd, Cu, and Zn concentrations in vegetables were 0.192?mg/kg (west area), 0.071?mg/kg (central area), 3.961?mg/kg (central area), and 10.545?mg/kg (central area), which were lower than the maximum allowable concentration. In the national scale, the weighted average level of heavy metals in vegetables was found to be in the order of Zn?>?Cu?>?Pb?>?Cd. The hazard index (HI) of each province showed that beside Anhui and Hunan province, residents in other provinces of China faced a low high risk of Pb, Cd, Cu, and Zn. However, people consuming vegetables faced a high risk of Pb, Cd, Cu, and Zn in Anhui and Hunan provinces. This research may provide insight into heavy metal accumulation in vegetables and forecast to residents to cope with these problems for improved human health.     

Risk assessment of population exposure to toxic trace elements via consumption of vegetables and fruits grown in some mining areas of Armenia

Consumption of unsafe food is one of the most important public health concerns. Trace elements’ contamination caused by direct or indirect activities of mining industries is of importance in this respect. The present study was conducted to assess the chronic dietary exposure and related health risks of trace elements through the intake of selected vegetables and fruits grown under the impact of mining industry in Syunik region (Armenia). Consumption data were obtained via food frequency questionnaire and the concentrations of Cu, Mo, Ni, Cr, Pb, Zn, Hg, and Cd in different fruits and vegetables were determined. Moreover, by combining concentration data with consumption data, estimated daily intake, and target hazard quotient were assessed for each element. The results obtained showed that mean concentrations for Pb and Hg in some vegetables exceeded maximum acceptable levels set by international organizations. Hazard indexes > 1 have been obtained in some cases indicating that for some vegetables (particularly for potato, carrot, maize, onion leaf, grape, bean, beet, sweet pepper, eggplant, and tomato) habitual consumption has a potential to pose adverse health effect to the local population.     

Seasonal Variation of Metals in Seawater, Sediment, and Manila Clam Ruditapes philippinarum from China

Concentrations of trace metals (Cu, Pb, Zn, Cd, Cr, Hg, and As) were determined for the first time in seawater, sediment, and Manila clam from Deer Island, Liaoning Province, China. The seawater, sediment, and clam samples were collected seasonally at three clam farming sites around Deer Island during 2010–2011. The average concentrations of Cu, Pb, Zn, Cd, Cr, Hg, and As in the seawater samples were 4.16, 0.72, 5.88, 0.45, 2.51, 0.03, and 1.02 μg/l, respectively. The seasonal variations of trace metals in seawater showed a significant difference in the concentrations of Cu, Pb, Zn, Hg, and As among seasons. The average concentrations of Cu, Pb, Zn, Cd, Cr, Hg, and As in the sediment samples were 6.43, 13.80, 53.08, 1.10, 36.40, 0.05, and 4.78 mg/kg dry weight, respectively. Trace metal concentrations in sediment seasonally varied significantly except for Cd and Hg. The average concentrations of Cu, Pb, Zn, Cd, Cr, Hg, and As in the clam samples were 11.28, 0.61, 92.50, 0.58, 3.98, 0.03, and 1.98 mg/kg dry weight, respectively. Concentrations of Cu, Zn, Cd, Cr, and As in Manila clam showed marked seasonal fluctuations with significant difference. Cu and Zn were the metals with the highest mean biosediment accumulation factor values in Manila clam. Besides, significant correlations for the concentrations of Cu and Zn relative to their concentrations in sediment were also found. Such differences in regression analyzes may be explained by differential bioaccumulation of essential and xenobiotic metals. Concentrations of trace metals in Manila clam did not exceed the maximum established regulatory concentrations for human consumption. Moreover, the calculations revealed that the estimated daily intake values for the examined clam samples were below the internationally accepted dietary guidelines and the calculated hazard quotient values were well less than 1, thus strongly indicating that health risk associated with the intake studied metals through the consumption of Manila clam from Deer Island was absent.     

Cadmium and lead in rice grains and wheat breads in Isfahan (Iran) and human health risk assessment

This study was conducted to survey the levels of cadmium (Cd) and lead (Pb) in the main foods of Isfahan province (central Iran). The rice grains and wheat breads were collected from Isfahan city and villages around the Isfahan and Mobarakeh Steel companies. The food samples were wet-ashed by heating in the presence of concentrated nitric acid and hydrogen peroxide. The concentrations of Cd and Pb were determined by inductively coupled plasma-optical emission spectrometer (ICP-OES). The potential exposure risks were then estimated. Levels of Cd in the rice grains and Pb in the investigated foods (except Sangak beard) were above the maximum levels as set by the Codex Alimentarius and National standards of Iran. The wheat bread samples in Isfahan city and Mobarakeh Steel regions presented higher estimated weekly intake (EWI) of Pb (40.93 and 35.35 µg kg^–1 body weight, respectively) compared to other foods. The EWI for Cd and Pb in most samples was considerably above than the provisional tolerable weekly intake. In most cases, the target hazard quotients values were above one and consequently the consumption of foods in the investigated regions was a potentially serious health risk caused by exposure to the crops contaminated with Cd and Pb.     

Dietary Exposure Assessment of Potentially Toxic Trace Elements in Fruits and Vegetables Sold in Town of Kapan,Armenia

Fruits and vegetables grown under the impact of Armenia’s mining industry are widely sold in markets of adjacent towns. As the share of fruits and vegetables in Armenians’ diet is significant, the present study aims to assess the dietary exposure of potentially toxic trace elements through the intake of fruits and vegetables sold in Kapan town, located in the biggest mining region of Armenia. The concentrations of Cu, Mo, Ni, Cr, Pb, Zn, Hg, As, and Cd in 15 types of fruits and vegetables were determined. Non-carcinogenic and carcinogenic risks were assessed. Although the estimated daily intakes of trace elements for each studied food item did not exceed health-based guidelines values, in case of the combined consumption of fruits and vegetables estimated cumulative daily intakes exceeded reference doses for Cu and Mo. Moreover, carcinogenic risk for the majority of fruits and vegetables exceeded the EPA recommended risk level of 10⁻⁶, indicating adverse health effect to local population. The outcomes of this study can serve as a basis for further research that will consider many other exposure pathways (i.e., inhalation or dermal pathways) in order to ensure the safety of the residents living under the impact of mining industry.

     

Metal residues in flesh of edible blue crab,Callinectes amnicola,from a tropical coastal lagoon: Health implications

Metals such as cadmium (Cd), lead (Pb), zinc (Zn), and copper (Cu) were estimated in the flesh of the edible blue crab Callinectes amnicola from selected areas of the Lagos Lagoon, Nigeria (i.e., Makoko, Iddo, Okababa, Ikoyi, and Ajah) for 18 months between March 2011 and August 2012. Estimated average daily intake (EADI) and target hazard quotient (THQ) were used to determine the risk implications for adult and child consumer populations. Range of Cd, Pb, Zn, and Cu across sites was 0.16–0.46, 1.48–3.17, 2.21–3.65, and 9.48–12.76 mg kg^?1 crab flesh wet weight, respectively. Lead concentrations in crab flesh from Makoko (3.16 ± 1.44 mg kg^?1) and Iddo (5.17 ± 1.26 mg kg^?1) exceeded the maximum accepted limits recommended by the Food and Agriculture Organization/World Health Organization for food fisheries. The EADI across sites for the adult consumer population exceeded the reference dose (RfD) recommended by the U.S. Environmental Protection Agency for most metals with magnitude of ≤7-fold while EADI of Pb among child consumer population across sites exceeded RfD by a maximum of 4.5-fold. THQs for adult population were >1 for all metals across all sites, and >1 for Pb and Cd for selected sites for the child consumer population. Findings from this study indicate higher health risks of metal toxicity to adult consumer populations, and risks of lead toxicity to child consumer populations around the Lagos Lagoon, Nigeria.     

Soil Heavy Metal Pollution Assessment Near the Largest Landfill of China

To assess the extent and potential hazards of heavy metal pollution at Shanghai Laogang Landfill, the largest landfill in China, surface soil samples were collected near the landfill and concentrations of Cu, Zn, Cd, Pb, and Cr were determined. The results revealed that the concentrations of heavy metals, except Pb, were higher in the surface soil near the landfill than in the background soil. Principal component analysis and hierarchical cluster analysis suggested that the enrichment of Cu in soil was probably related to agricultural activities and Cd and Pb to landfill leachates, whereas Zn and Cr concentrations were probably controlled by soil matrix characteristics. The pollution indices (PIs) of the metals were: Cd > Cu > Cr > Zn > Pb. Among the five measured metals, Cd showed the largest toxic response and might cause higher ecological hazards than other metals. The integrated potential eco-risk index (RI) of the five metals ranged from 26.0 to 104.9, suggesting a low-level eco-risk potential. This study indicated the accumulations of Cu, Zn, Cd, Pb, and Cr did not reach high pollution levels, and therefore posed a low eco-risk potential in surface soil near the landfill.     

Effects of Variations in Cadmium and Lead Levels in River Sediments on Local Foods and Body Burden of Local Residents in Non-Polluted Areas in Japan

This study was initiated to examine if variations in the concentrations of cadmium (Cd) and lead (Pb) in water environment may affect metal levels in local foods and body burden of local residents in non-polluted areas in Japan. Two nationwide databases have been made available on concentrations of Cd in locally harvested brown rice and of Cd and Pb in sediments in local river beds. These data were combined with published data on metal concentrations in polished rice, food duplicates, and blood and urine from the residents. Cd in river sediments correlated significantly with those in brown rice, food duplicates, blood, and urine. Cd in food duplicates correlated with Cd in rice. In contrast, Pb concentrations in the river sediments either did not correlate or correlated only weakly with Pb in biological materials or food duplicates. Possible implication of the different behavior between Cd and Pb regarding the intensity of correlation was discussed with reference to the different routes of exposure to the elements. In conclusions, the Cd body burden on local residents in Japan is significantly influenced by Cd levels in water in the general environment, whereas water-borne Pb did not show clear correlation with the Pb body burden.