A Super Lens System for Demagnification Imaging Beyond the Diffraction Limit

A super lens system is proposed to achieve subdiffraction limit demagnification imaging. The super lens system consists of a hyperlens with planar input and output surfaces, a metal superlens, and a plasmonic reflector. By employing the hyperlens to transform evanescent waves into propagating waves and employing the metal superlens and the plasmonic reflector to amplify evanescent waves, the super lens system can produce a subdiffraction limit image with relatively high electric field intensity. The reduction factor of the super lens system depends on the geometric parameters of the hyperlens. Simulation results show that an image with a half-pitch resolution of about one tenth the operating wavelength and a reduction factor of about 2.2 can be produced by the super lens system. The proposed super lens system has potential applications in nanolithography.     

Far-Field Super-Resolution Imaging of Nano-transparent Objects by Hyperlens with Plasmonic Resonant Cavity

A plasmonic resonant cavity-based hyperlens is theoretically proposed and demonstrated to achieve far-field phase contrast images of nano-transparent objects. The phase contrast super-resolution imaging is mainly contributed to the excited surface plasmons inside hyperlens and cavity structure surrounding nano-objects, which help to greatly enhance evanescent waves generated by nano-transparent objects and convert weak phase information to light intensity distribution with high contrast at the zoomed imaging plane of hyperlens. As examples, nano-dielectric object imaging is numerically demonstrated with half-pitch resolution about λ/10 and a minimum distinguishable refractive index difference down to 0.15.     

Improving Imaging Contrast of Non-Contacted Plasmonic Lens by Off-Axis Illumination with High Numerical Aperture

Off-axis illumination plasmonic lens (OAIPL) is proposed and demonstrated to improve the imaging contrast in non-contacted application manner. The spatial Fourier components of light transmitted through the nano-patterns are greatly enhanced in the imaging process by shifting the wave vectors with high numerical aperture off-axis illumination. On the other hand, a reflector in the image area helps to tailor the ratio between electric field components in the tangential and normal directions. These two effects resultantly deliver significant improvement of imaging performance, including enhanced resolution, imaging contrast, and elongation of air gap thickness. In comparison to the case of normal illumination, the air gap thickness for 30 and 60 nm half-pitch resolution is extended to 25 and 100 nm by OAIPL with numerical aperture (NA)?=?1.55, respectively.     

Off Axis Illumination Planar Hyperlens for Non-contacted Deep Subwavelength Demagnifying Lithography

Off axis illumination (OAI) technique combined with planar hyperlens is applied to achieve the non-contacted deep subwavelength demagnifying lithography. The designed OAI is confirmed to shift the spatial spectra of mask, leading to enhancement of the featured wavevectors components. On the other hand, the reflection effect of Ag cladding is necessary to obtain high contrast and high fidelity of nanopattern lithography. It is numerically demonstrated that the half-pitch resolution 32 nm with OAI (NA?=?1.37) is obtained under 80 nm air working distance, which is about six times than the case of the conventional configuration under normal illumination (NA?=?0). Further simulations show that the minimum half-pitch resolution of the planar hyperlens with OAI could reach 18 nm (～λ/20).     

Near-Field Optical Imaging of a Porous Au Film: Influences of Topographic Artifacts and Surface Plasmons

In this work, near-field scanning optical microscopy is employed to study a porous Au film and the direct observation of topographic artifacts and surface plasmon influences is revealed. Under tip illumination, topographic artifacts are found to be present in a reflection mode optical image but not in a transmission mode image. A simple algorithm is used for filtering the topographic artifacts and extracting a correct near-field optical image approximately. On the other hand, surface plasmon influences are present in both modes. By using three exciting wavelengths of 488, 647.1, and 520.8 nm, it is confirmed that a suitable wavelength should be chosen for avoiding the surface plasmon interference in a near-field optical investigation of morphological or material dielectric contrast. Finally, plasmonic or nonplasmonic regions on the porous Au film can be identified from the observed optical intensity variation in the optical images obtained at incident polarizations of 0°, 90°, and 45°.     

Plasmonically Tunable Blue-Shifted Emission from Coumarin 153 in Ag Nanostructure Random Media: A Demonstration of Fast Dynamic Surface-Enhanced Fluorescence

Enhancement of intensity and wavelength tunability of emission are desirable features for light-emitting device applications. We report on the large and tunable blue shift (60 nm) in emission from an environment-sensitive fluorophore (Coumarin153) embedded in Ag plasmonic random media. Coumarin 153 having emission at 555 nm, show a systematic blue shift (to 542, 503 and 495 nm) upon infiltration into random media fabricated by Ag nanowires of different aspect ratio (hence, surface plasmon resonances at 426, 445 and 464 nm). The blue shift is due to the fast dynamic surface-enhanced fluorescence mechanism and can be tuned by controlling the surface plasmon resonance and hotspot density in random media. Enhanced emission at desired wavelength is achieved by using nanostructures having higher extinction coefficient but same-surface plasmon resonance. Ag nanostructures of different aspect ratio used for fabricating the random media are synthesized by chemical route.     

Widefield fluorescence microscopy with extended resolution

Widefield fluorescence microscopy is seeing dramatic improvements in resolution, reaching today 100 nm in all three dimensions. This gain in resolution is achieved by dispensing with uniform Köhler illumination. Instead, non-uniform excitation light patterns with sinusoidal intensity variations in one, two, or three dimensions are applied combined with powerful image reconstruction techniques. Taking advantage of non-linear fluorophore response to the excitation field, the resolution can be further improved down to several 10 nm. In this review article, we describe the image formation in the microscope and computational reconstruction of the high-resolution dataset when exciting the specimen with a harmonic light pattern conveniently generated by interfering laser beams forming standing waves. We will also discuss extensions to total internal reflection microscopy, non-linear microscopy, and three-dimensional imaging.     

Near-Infrared Super Resolution Imaging with Metallic Nanoshell Particle Chain Array

We propose a near-infrared super resolution near field imaging system with an array of metallic nanoshell particle chain. The imaging array can plasmonically transfer the near field components of dipole sources and the super resolution images can be reconstructed in the output plane. By decreasing the metallic nanoshell’s thickness of the fixed size nanoparticle, the plasmon resonance wavelength of the isolate nanoshell particle is red-shifted to the near-infrared region. The operation wavelength of the imaging array is correspondingly red-shifted to the near-infrared region. In this paper, we study the incoherent and coherent super resolution imaging. The field intensity distributions at the different planes of imaging process are calculated using the finite element method. The simulation results demonstrate that the array has super resolution imaging capability at near-infrared wavelengths in the incoherent and coherent manners. The results also show that the image formation highly depends on the source coherence. In the same structural parameters, the reconstructed images under the illumination of incoherent light source reach to the higher image quality and spatial resolution than the images under the illumination of coherent light source of in phase. By reasonably designing parameters of the imaging array, the approximate spatial resolutions of λ/13 in incoherent case and λ/10 in coherent case are obtained at the near-infrared wavelength of 764 nm. Furthermore, the image–array distance and the chains’ spacing also affect the image reconstruction.     

Strong Fluorescence Enhancement with Silica-Coated Au Nanoshell Dimers

Fluorescence intensity is vital for fluorescence sensing and imaging because it determines the sensing sensitivity and imaging brightness. This study reports plasmon-enhanced fluorescence by engineering plasmonic nanostructures, that are SiO₂-coated Au nanoshell dimers with a high yield exceeding 60 %. With this elaborately designed nanostructure, we show that the thin SiO₂ shell can conveniently distance the fluorophore from the underneath metal, thereby effectively avoiding fluorescence quenching. Meanwhile, the inner Au nanoshell dimers create abundant hot spots at particle-particle junctions and enable near-infrared fluorescence enhancement. The largest fluorescence enhancement achieved is 69 times for the design with a 9 nm external SiO₂ shell, as is also confirmed by three-dimensional finite-difference time-domain simulations. This dramatically increased fluorescence has great significance in fluorescence-based sensing and imaging.     

Broadband Mid-Infrared Super-Resolution Imaging with Metallic Nanorod-Bridged Dimer Array

We propose a broadband mid-infrared super-resolution imaging system comprising a metallic nanorod-bridged dimer array. The imaging array enables super-resolution imaging of shaped dipole sources in the near field. A charge transfer plasmon (CTP) appears in a metallic nanorod-bridged dimer. By varying the radius of the junction, the plasmon resonance wavelength of CTP mode can be tuned into the mid-infrared region. Here, we investigate the broadband super-resolution imaging of the incoherent and coherent dipole sources at mid-infrared wavelengths. With the array pitch varying, we calculate the cross-sectional field intensity distributions at the source plane and the image plane by using the finite element method. The simulation results indicate that the broadband incoherent and coherent super-resolution imaging can be realized at mid-infrared wavelengths with the imaging array. The image quality is sensitively dependent on the source coherent, the array pitch, and the distance from the image plane to the array. In the same structural parameters, the image quality of coherent source of in-phase is lower than that of incoherent source. Increasing the array pitch improves the image quality but it also increases the size of the array. By reasonably choosing the array pitch of the array, the spatial resolution of ～λ/109 and ～λ/73 is obtained corresponding to the incoherent imaging case and coherent imaging case at the mid-infrared wavelength of 4390 nm. Moreover, the larger image-array distance results in the lower image quality.     

Mass spectrometry imaging with high resolution in mass and space

Mass spectrometry (MS) imaging links molecular information and the spatial distribution of analytes within a sample. In contrast to most histochemical techniques, mass spectrometry imaging can differentiate molecular modifications and does not require labeling of targeted compounds. We have recently introduced the first mass spectrometry imaging method that provides highly specific molecular information (high resolution and accuracy in mass) at cellular dimensions (high resolution in space). This method is based on a matrix-assisted laser desorption/ionization (MALDI) imaging source working at atmospheric pressure which is coupled to an orbital trapping mass spectrometer. Here, we present a number of application examples and demonstrate the benefit of ‘mass spectrometry imaging with high resolution in mass and space.’ Phospholipids, peptides and drug compounds were imaged in a number of tissue samples at a spatial resolution of 5–10 μm. Proteins were analyzed after on-tissue tryptic digestion at 50-μm resolution. Additional applications include the analysis of single cells and of human lung carcinoma tissue as well as the first MALDI imaging measurement of tissue at 3 μm pixel size. MS image analysis for all these experiments showed excellent correlation with histological staining evaluation. The high mass resolution (R = 30,000) and mass accuracy (typically 1 ppm) proved to be essential for specific image generation and reliable identification of analytes in tissue samples. The ability to combine the required high-quality mass analysis with spatial resolution in the range of single cells is a unique feature of our method. With that, it has the potential to supplement classical histochemical protocols and to provide new insights about molecular processes on the cellular level.     

Optimization on Plasmonic Lenses Based on Generation Efficiency of Surface Plasmon Polaritons at Metallic Nanoslit

The generation efficiency of surface plasmon polaritons at metallic nanoslit is theoretically analyzed, and a novel plasmonic lens with two semiannular nanoslits is proposed in this paper. Based on the analysis results, the focusing performance of the proposal is optimized with a maximum field intensity enhancement factor of 7.69 and the full width at half maximum is 132 nm (~0.2λ _i), far beyond theoretical diffraction limit. Meanwhile, some other classical plasmonic lenses are also optimized through improving generation efficiency of surface plasmon polaritons at nanoslit and the focusing performances are consequently greatly enhanced.     

Slab Thickness Dependence of Localized Surface Plasmon Resonance Behavior in Gold Nanorings

We present detailed experimental and numerical studies of plasmonic properties of gold nanoring (NR) arrays with different slab thicknesses from 15 to 125 nm. The hybrid plasmon resonances for the bonding and antibonding modes in gold NRs exhibit a high slab thickness dependence behavior in optical properties. For the thinner slab thickness below 50 nm, both hybrid modes show large spectral tunabilities by varying the slab thickness. Furthermore, for such hollow NR structure, the enhancements of electric field intensities at the inner and outer ring surfaces when reducing the slab thickness are investigated. We observe a significant transition of field distributions for the antibonding mode. All these features can be understood by surface charge distributions from our simulations. The results of this study offer a potential strategy to design a composite plasmonic nanostructure with large field enhancement for numerous applications.     

Coupling of Whispering-Gallery Modes in the Graphene Nanodisk Plasmonic Dimers

In this paper, we proposed plasmonic dimers consisted of two evanescent field coupled graphene monolayer nanodisks. The electromagnetic properties including the split modes with non-degenerate wavelengths, enhancement of the quality factors (Q factors) and mode areas, and the coupling between the fundamental and the first-order whispering-gallery modes are numerically predicted and analyzed systematically. Compared with the single graphene nanodisk, the Q factor of TM_4,1 reaches 356 in a dimer with a radius of 5 nm of each nanodisk and an inter-disk gap of 0.4 nm, where the corresponding mode area is as small as 6.88?×?10^‐?5(λ ₀)². In addition, the enhanced performances of size-mismatched coupled graphene plasmonic dimers are investigated. This graphene monolayer plasmonic dimer could be one of the fundamental components in the future ultra-high density plasmonic circuit technique, on-chip plasmonic interconnect, and transformation plasmonics. It also could be used as the test-beds for added explorations of cavity quantum electrodynamic experiments.     

Search of Extremely Sensitive Near-Infrared Plasmonic Interfaces: A Theoretical Study

The sensitivity of the wavelength position of localized surface plasmon resonance (LSPR) in metal nanostructures to local changes in the refractive index has been widely used for label-free detection strategies. Tuning the optical properties of the nanostructures from the visible to the infrared region is expected to have a drastic effect on the refractive index sensitivity. Here, we theoretically investigate the optical response of a newly designed plasmonic interface to changes in the bulk refractive index by the finite difference time domain method. It consists of a structured interface, where the planar interface is superposed with dielectric pillars 30 nm in height and 125 nm in length with a separation distance of 15 nm. The pillars are covered with U-shaped gold nanostructures of 50 nm in height, 125 nm in length, and 5 nm of gold base thickness. The whole structure is finally covered with a 5-nm thick dielectric layer of n ₂?=?2.63. This plasmonic structure shows bulk refractive index sensitivities up to 1750 nm/RIU (RIU : refractive index unit) in the near infrared (λ?=?2621 nm). The enhanced sensitivity is a consequence of the extremely enhanced electrical field between the gold nanopillars of the plasmonic interface.     

A Facile Strategy for All-Optical Controlling Platform by Using Plasmonic Perfect Absorbers

Dual-band light absorption with the maximal absorptivity up to 99.7% and the minimal spectral bandwidth down to 3 nm is obtained in the plasmonic absorbers consisting of triple-layer plasmonic crystal-nonlinear medium cavity-metal substrate structure, where the intercalated dielectric material is chosen to be a Kerr medium cavity. Efficient all-optical controlling with high spectral intensity change ratios and detecting signal-to-noise is achieved for the system after a slight increase of pumping intensity. These impressive results mainly result from the strong plasmonic resonant field confinement in the middle nonlinear Kerr medium cavity and the near-perfect relative intensity change response by the ultra-sharp anti-reflection spectrum. This work can lay a foundation for advanced all-optical devices by exploiting light perfect absorption behavior and resonant optical field enhancement.     

Analysis of a Surface Plasmon Resonance Probe Based on Photonic Crystal Fibers for Low Refractive Index Detection

A photonic crystal fiber (PCF)-based surface plasmon resonance (SPR) probe with gold nanowires as the plasmonic material is proposed in this work. The coupling characteristics and sensing properties of the probe are numerically investigated by the finite element method. The probe is designed to detect low refractive indices between 1.27 and 1.36. The maximum spectral sensitivity and amplitude sensitivity are 6 × 10³ nm/RIU and 600 RIU^?1, respectively, corresponding to a resolution of 2.8 × 10^?5 RIU for the overall refractive index range. Our analysis shows that the PCF-SPR probe can be used for lower refractive index detection.     

Investigating the Characteristics of a Double Circular Ring Resonators Slow Light Device Based on the Plasmonics-Induced Transparency Coupled with Metal-Dielectric-Metal Waveguide System

We have numerically investigated an analog of electromagnetically induced transparency (EIT) in a metal-dielectric-metal (MDM) waveguide bend. The geometry consists of two asymmetrical stubs extending parallel to an arm of a straight MDM waveguide bend. Finite-difference time-domain simulations show that a transparent window is located at 1550 nm, which is the phenomenon of plasmonic-induced transparency (PIT). Signal wavelength is assumed to be 820 nm. The velocity of the plasmonic mode can be largely slowed down while propagating along the MDM bends. Multiple-peak plasmon-induced transparency can be realized by cascading multiple cavities with different lengths and suitable cavity-cavity separations. Large group index up to 73 can be obtained at the PIT window. Our proposed configuration may thus be applied to storing and stopping light in plasmonic waveguide bends. In addition, the relationship between the transmission characteristics and the geometric parameters including the radius of the nano-ring, the coupling distance, and the deviation length between the stub and the nano-ring is studied in a step further. The velocity of the plasmonic mode can be largely slowed down while propagating along the MDM bends. For indirect coupling, formation of transparency window is determined by resonance detuning, but, evolution of transparency is mainly attributed to the change of the coupling distance. Theoretical results may provide a guideline for control of light in highly integrated optical circuits. The characteristics of our plasmonic system indicate a significant potential application in integrated optical circuits such as optical storage, ultrafast plasmonic switch, highly performance filter, and slow light devices.     

1064‐nm‐resonant gold nanorods for photoacoustic theranostics within permissible exposure limits

Therapeutic and diagnostic methods based on photomechanical effects are attracting much current attention in contexts as oncology, cardiology and vascular surgery, for such applications as photoacoustic imaging or microsurgery. Their underlying mechanism is the generation of ultrasound or cavitation from the interaction of short optical pulses with endogenous dyes or targeted contrast agents. Among the latter, gold nanorods are outstanding candidates, but their use has mainly been reported for photoacoustic imaging and photothermal treatments. Conversely, much less is still known about their value as a precision tool for photomechanical manipulations, such as to impart local damage with high spatial resolution through the expansion and collapse of microbubbles. Here, we address the feasibility of gold nanorods exhibiting a distribution of surface plasmon resonances between about 900 to above 1100 nm as a contrast agent for photoacoustic theranostics. After testing their cytotoxicity and cellular uptake, we discuss their photostability and use to mediate cavitation and the photomechanical destruction of targeted cells. We find that the choice of a plasmonic band peaking around 1064 nm is key to enhance the translational potential of this approach. With respect to the standard alternative of 800 nm, at 1064 nm, relevant regulations on optical exposure are less restrictive and the photonic technology is more mature.      

Study of Broadband Tunable Properties of Surface Plasmon Resonances of Noble Metal Nanoparticles Using Mie Scattering Theory: Plasmonic Perovskite Interaction

We suggest semi-analytical approach to study the optical properties of noble metal nanoparticles and their interaction to the perovskite material (methyl ammonia lead halide: CH₃NH₃PbI₃). Metal nanoparticles embedded in perovskite matrix exhibits broadband surface plasmon resonances, and the tunability of these plasmonic resonances is highly sensitive to particle size. The calculation of optical cross section have been done using Mie scattering theory which is applicable to arbitrary size and spherical-shape metal nanoparticles. We have taken five different radii ranging from 15 to 100 nm to understand the plasmonic resonances and its spectral width in the wavelength range 300 to 800 nm. Out of these noble metal nanoparticles, silver have highest scattering efficiency nearly of the order of 18 for the case of 15 nm radii at resonance wavelength 613 nm. Our finding reveals a new concept to understand the applications of plasmonic resonances in order to enhance the photon absorption inside the thin film of perovskite.