Particle Size Reduction during Harvesting of Crop Feedstock for Biogas Production I: Effects on Ensiling Process and Methane Yields

Shortening chopping length at harvest of biogas crops is a basic method of mechanical pretreatment that potentially affects subsequent conservation and biogas production processes. The objective of this study was to assess the influence of a wider range of particle size distributions achieved by laboratory chopping and of practice-oriented short and very short chopping lengths induced by forage harvesters, respectively, on ensiling parameters and methane formation. Shortening the cutting length enhanced lactic acid fermentation during ensiling and increased methane yield, although the effects of ensilage products on methane production partly overlaid the direct positive influence due to reduced particle size. A maximum increase in methane yield of 11?% to 13?% was obtained in the range of median particle lengths of 33 to 6?mm when taking storage losses into account. Thus, very short chopping lengths are beneficial for conservation and methane formation, yet full assessment necessitates further consideration of additional expenditures at harvest.     

Incorporating Uncertainty into a Life Cycle Assessment (LCA) Model of Short-Rotation Willow Biomass (Salix spp.) Crops

To estimate fossil fuel demand and greenhouse gas emissions associated with short-rotation willow (Salix spp.) crops in New York State, we constructed a life cycle assessment model capable of estimating point values and measures of variability for a number of key processes across eight management scenarios. The system used 445.0 to 1,052.4 MJ of fossil energy per oven-dry tonne (odt) of delivered willow biomass, resulting in a net energy balance of 18.3:1 to 43.4:1. The largest fraction of the energy demand across all scenarios was driven by the use of diesel fuels. The largest proportion of diesel fuel was associated with harvesting and delivery of willow chips seven times on 3-year rotations over the life of the crop. Similar patterns were found for greenhouse gas emissions across all scenarios, as fossil fuel use served as the biggest source of emissions in the system. Carbon sequestration in the belowground portion of the willow system provided a large carbon sink that more than compensated for carbon emissions across all scenarios, resulting in final greenhouse gas balances of ?138.4 to ?52.9 kg CO₂ eq. per odt biomass. The subsequent uncertainty analyses revealed that variability associated with data on willow yield, litterfall, and belowground biomass eliminated some of the differences between the tested scenarios. Even with the inclusion of uncertainty analysis, the willow system was still a carbon sequestration system after a single crop cycle (seven 3-year rotations) in all eight scenarios. A better understanding and quantification of factors that drive the variability in the biological portions of the system is necessary to produce more precise estimates of the emissions and energy performance of short-rotation woody crops.     

Impacts of Intensive Management and Landscape Structure on Timber and Energy Wood Production and net CO2 Emissions from Energy Wood Use of Norway Spruce

The aim of this study was to analyze the effects of intensive management and forest landscape structure (in terms of age class distribution) on timber and energy wood production (m³?ha^?1), net present value (NPV, ? ha^?1) with implications on net CO₂ emissions (kg CO₂ MWh^?1 per energy unit) from energy wood use of Norway spruce grown on medium to fertile sites. This study employed simulations using a forest ecosystem model and the Emission Calculation Tool, considering in its analyses: timber (saw logs, pulp) and energy wood (small-sized stem wood and/or logging residuals for top part of stem, branches, and needles) from the first thinning and harvesting residuals and stumps from the final felling. At the stand level, both fertilization and high pre-commercial stand density clearly increased timber production and the amount of energy wood. Short rotation length (40 and 60?years) outputted, on average, the highest annual stem wood production (most fertile and medium fertile sites), the 60?year rotation also outputted the highest average annual net present value (NPV with interest rates of 1?C4%). On the other hand, even longer rotation lengths, up to 80 and 100?years, were needed to output the lowest net CO₂ emissions per year in energy wood use. At the landscape level, the largest productivity (both for timber and energy wood) was obtained using rotation lengths of 60 and 80?years with an initial forest landscape structure dominated by older mature stands (a right-skewed age-class distribution). If the rotation length was 120?years, the initial forest landscape dominated by young stands (a left-skewed age-class distribution) provided the highest productivity. However, the NPV with interest rate of 2% was, on average, the highest with a right-skewed distribution regardless of the rotation length. If the rotation length was 120?years, normal age class distribution provided, on average, the highest NPV. On the other hand, the lowest emissions (kg CO₂ MWh^?1a^?1) were obtained with the left-skewed age-class distribution using the rotation lengths of 60 and 80?years, and with the normal age-class distribution using the rotation length of 120?years. Altogether, the management regimes integrating both timber and energy wood production and using fertilization provided, on average, the lowest emissions over all management alternatives considered.     

森林经营与管理下的温室气体排放、碳泄漏和净固碳量研究进展

森林在减缓全球气候变化和大气CO₂浓度升高上具有重要作用.森林经营与管理下的新造林和森林保护具有显著的固碳功能,其中,新造林和森林保护的固碳速率分别为0.04～7.52、0.33～5.20 t C·hm^-2·a^-1.同时,营造林过程中物资的生产和运输导致边界内产生温室气体排放;营造林导致的活动转移、市场效应和生态环境变化导致边界外产生碳泄漏.本文综述了国内外森林经营与管理活动边界内温室气体排放源的界定、计量方法、温室气体排放量与排放速率;边界外碳泄漏的类型、计量方法与碳泄漏量;净固碳量以及温室气体排放和碳泄漏对固碳的抵消强度.边界内温室气体排放对固碳的抵消强度为0.01%～19.3%,进一步考虑碳泄漏时可增至95%.若仅考虑森林经营与管理在边界内直接产生的温室气体排放与可测量的活动转移碳泄漏,森林经营与管理具有较好的净固碳效益,且相比于农田固碳措施在温室气体净减排方面具有更好的应用前景.随着我国各项重大生态工程新一期的开展和对工程固碳效益的关注,为增加重大生态工程对温室气体的净减排量,有必要在工程开展前进行合理规划、在工程开展过程中加强控制和监测以减少工程实施导致的边界内温室气体排放和边界外碳泄漏.     

Effects of Management on Economic Profitability of Forest Biomass Production and Carbon Neutrality of Bioenergy Use in Norway Spruce Stands Under the Changing Climate

We analyzed the effects of management on the economic profitability of forest biomass production and carbon neutrality of bioenergy use in Norway spruce (Picea abies L. Karst) stands under the changing climate. We employed a forest ecosystem model and life cycle assessment tool. In particular, we studied the effects of thinning, nitrogen fertilization, and rotation length on: (1) the production of timber and energy biomass, and its economic profitability (net present value), (2) carbon stock in the forest ecosystem and carbon balance in forestry, and (3) carbon dioxide (CO₂) emissions from the use of biomass in energy production. Results showed that the current Finnish baseline management with and without nitrogen fertilization resulted in the highest mean annual timber production and net present value (NPV) for long rotations (60 to 80 years), regardless of climate scenario. Mean annual production of energy biomass was enhanced by increasing stocking by 20–30 % compared to the baseline management, and/or use of nitrogen fertilization. Such management gave lower CO₂ emissions per unit of energy compared to the baseline management, as the carbon stock in the forest ecosystem and the carbon balance in forestry increased. Overall, the carbon neutrality and net present value were, on average, the highest in the baseline management or with a 20 % increase in stocking, with nitrogen fertilization and 60- to 80-year rotation lengths, regardless of the climate applied. However, it was not possible to simultaneously maximize the NPV of forest biomass production and the carbon neutrality of bioenergy use.     

The impact of landfilling and composting on greenhouse gas emissions – A review

Municipal solid waste is a significant contributor to greenhouse gas emissions through decomposition and life-cycle activities processes. The majority of these emissions are a result of landfilling, which remains the primary waste disposal strategy internationally. As a result, countries have been incorporating alternative forms of waste management strategies such as energy recovery from landfill gas capture, aerobic landfilling (aerox landfills), pre-composting of waste prior to landfilling, landfill capping and composting of the organic fraction of municipal solid waste. As the changing global climate has been one of the major environmental challenges facing the world today, there is an increasing need to understand the impact of waste management on greenhouse gas emissions. This review paper serves to provide an overview on the impact of landfilling (and its various alternatives) and composting on greenhouse gas emissions taking into account streamlined life cycle activities and the decomposition process. The review suggests greenhouse gas emissions from waste decomposition are considerably higher for landfills than composting. However, mixed results were found for greenhouse gas emissions for landfill and composting operational activities. Nonetheless, in general, net greenhouse gas emissions for landfills tend to be higher than that for composting facilities.     

Analyzing Economic and Environmental Performance of Switchgrass Biofuel Supply Chains

This study optimized the net present value (NPV) of profit of various switchgrass-based ethanol supply chains and estimated associated greenhouse gas (GHG) emissions in west Tennessee. Three configurations of feedstock harvesting and storage, including a large round baler system, a large square baler system, and a chopping/densification system, were evaluated. A mixed-integer mathematical programming model incorporating high-resolution spatial data was used to determine the optimal locations and capacities of cellulosic ethanol plants and feedstock preprocessing facilities, and associated feedstock-draw areas by maximizing the NPV of profit over 20 years. The optimized outputs were then used to estimate the GHG emissions produced in the biofuel supply chain (BSC) per year. The study shows that BSC configurations have important implications for the economic and environmental performance of the system. The harvest and storage configurations affect the locations of conversion and preprocessing facilities, and associated feedstock-draw areas, hence impacting the cost and emissions of both feedstock and biofuels transportation. The findings suggest the BSC system that harvests feedstock with forage choppers and utilizes stretch-wrap balers to increase feedstock density has the highest NPV of profit. The BSC system that uses large square balers for harvest and storage emits the lowest amount of GHGs per year. In addition, the sensitivity analysis suggests that biofuel price and scaling factor of facility capital was influential to the economics of BSC systems. The breakeven price of biofuel for the three BSCs was around $0.97 L^?1.     

Impact of longevity on greenhouse gas emissions and profitability of individual dairy cows analysed with different system boundaries

Dairy production systems are often criticized as being major emitters of greenhouse gases (GHG). In this context, the extension of the length of the productive life of dairy cows is gaining interest as a potential GHG mitigation option. In the present study, we investigated cow and system GHG emission intensity and profitability based on data from 30 dairy cows of different productive lifetime fed either no or limited amounts of concentrate. Detailed information concerning productivity, feeding and individual enteric methane emissions of the individuals was available from a controlled experiment and herd book databases. A simplified GHG balance was calculated for each animal based on the milk produced at the time of the experiment and for their entire lifetime milk production. For the lifetime production, we also included the emissions arising from potential beef produced by fattening the offspring of the dairy cows. This accounted for the effect that changes in the length of productive life will affect the replacement rate and thus the number of calves that can be used for beef production. Profitability was assessed by calculating revenues and full economic costs for the cows in the data set. Both emission intensity and profitability were most favourable in cows with long productive life, whereas cows that had not finished their first lactation performed particularly unfavourably with regard to their emissions per unit of product and rearing costs were mostly not repaid. Including the potential beef production, GHG emissions in relation to total production of animal protein also decreased with age, but the overall variability was greater, as the individual cow history (lifetime milk yield, twin births, stillbirths, etc.) added further sources of variation. The present results show that increasing the length of productive life of dairy cows is a viable way to reduce the climate impact and to improve profitability of dairy production.     

The timber and energy biomass potential of intensively managed cloned Norway spruce stands

We used ecosystem model simulations to study the timber and energy biomass potential offered by intensively managed cloned Norway spruce stands. More specifically, we analysed how the use of cloned trees compared with non‐cloned trees, together with thinning, nitrogen (N) fertilisation and rotation length (from 60 to 100 years), affects the annual mean production of timber (i.e., saw logs, pulpwood) and energy biomass (i.e., stumps and harvesting residuals in the final felling) and its economic profitability [annual mean of net present value (NPV) with a 2% interest rate]. Furthermore, we employed a life cycle analysis/emission calculation tool to assess the total net CO₂ emissions per unit of energy (kg CO₂ MW h^?1) produced based on energy biomass. We found that both the annual mean production of timber and the NPV increased substantially, regardless of the management regime, if cloned trees with an annual growth increase of up to 30% compared with non‐cloned trees were used in regeneration. In general, the use of a short rotation with N fertilisation clearly increased the annual mean of the NPV. Consequently, the use of cloned trees also clearly increased the annual mean production of energy biomass and decreased the total net CO₂ emissions per unit of energy produced based on energy biomass. However, the total annual net CO₂ emissions were the lowest if a long rotation was used with N fertilisation. To conclude, the use of cloned trees together with intensive management could potentially be highly beneficial for the cost‐efficient and sustainable production of timber and energy biomass in an integrated way.     

Life Cycle–based Assessment of Energy Use and Greenhouse Gas Emissions in Almond Production,Part II: Uncertainty Analysis through Sensitivity Analysis and Scenario Testing

This is the second part of a two‐article series examining California almond production. The part I article describes development of the analytical framework and life cycle–based model and presents typical energy use and greenhouse gas (GHG) emissions for California almonds. This part II article builds on this by exploring uncertainty in the life cycle model through sensitivity and scenario analysis, and by examining temporary carbon storage in the orchard. Sensitivity analysis shows life cycle GHG emissions are most affected by biomass fate and utilization, followed by nitrous oxide emissions rates from orchard soils. Model sensitivity for net energy consumption is highest for irrigation system parameters, followed by biomass fate and utilization. Scenario analysis shows utilization of orchard biomass for electricity production has the greatest potential effect, assuming displacement methods are used for co‐product allocation. Results of the scenario analysis show that 1 kilogram (kg) of almond kernel and associated co‐products are estimated to cause between ?3.12 to 2.67 kg carbon dioxide equivalent (CO₂‐eq) emissions and consume between 27.6 to 52.5 megajoules (MJ) of energy. Co‐product displacement credits lead to avoided emissions of between ?1.33 to 2.45 kg CO₂‐eq and between ?0.08 to 13.7 MJ of avoided energy use, leading to net results of ?1.39 to 3.99 kg CO₂‐eq and 15.3 to 52.6 MJ per kg kernel (net results are calculated by subtracting co‐product credits from the results for almonds and co‐products). Temporary carbon storage in orchard biomass and soils is accounted for by using alternative global warming characterization factors and leads to a 14% to 18% reduction in CO₂‐eq emissions. Future studies of orchards and other perennial cropping systems should likely consider temporary carbon storage.     

The effect of lactation length on greenhouse gas emissions from the national dairy herd

Many governments have signed up to greenhouse gas emission (GHGE) reduction programmes under their national climate change obligations. Recently, it has been suggested that the use of extended lactations in dairy herds could result in reduced GHGE. Dairy GHGE were modelled on a national basis and the model was used to compare emissions from lactations of three different lengths (305, 370 and 440 days), and a current ‘base’ scenario on the basis of maintaining current milk production levels. In addition to comparing GHGE from the average ‘National Herd’ under these scenarios, results were used to investigate how accounting for lactations of different lengths might alter the estimation of emissions calculated from the National Inventory methodology currently recommended by Intergovernmental Panel on Climate Change. Data for the three lactation length scenarios were derived from nationally recorded dairy performance information and used in the GHGE model. Long lactations required fewer milking cows and replacements to maintain current milk yield levels than short ones, but GHGEs were found to rise from 1214 t of CO₂ equivalent (CE)/farm per year for lactations of 305 days to 1371 t CE/farm per year for 440-day lactations. This apparent anomaly can be explained by the less efficient milk production (kg milk produced per kg cow weight) found in later lactation, a more pronounced effect in longer lactations. The sensitivity of the model to changes in replacement rate, persistency and level of milk yield was investigated. Changes in the replacement rate from 25% to 20% and in persistency by −10% to +20% resulted in very small changes in GHGE. Differences in GHGE due to the level of milk yield were much more dramatic with animals in the top 10% for yield, producing about 25% less GHGE/year than the average animal. National Inventory results were investigated using a more realistic spread of lactation lengths than recommended for such calculations using emissions calculated in the first part of the study. Current UK emission calculations based on the National Inventory were 329 Gg of methane per year from the dairy herd. Using the national distribution of lactation lengths, this was found to be an underestimate by about 10%. This work showed that the current rise in lactation length or a move towards calving every 18 months would increase GHGE by 7% to 14% compared with the current scenario, assuming the same milk yield in all models. Increased milk yield would have a much greater effect on reducing GHGE than changes to lactation length, replacement rate or persistency. National Inventory methodology appears to underestimate GHGE when the distribution of lactation lengths is considered and may need revising to provide more realistic figures.     

Atmospheric impact of bioenergy based on perennial crop (reed canary grass,Phalaris arundinaceae,L.) cultivation on a drained boreal organic soil

Marginal organic soils, abundant in the boreal region, are being increasingly used for bioenergy crop cultivation. Using long‐term field experimental data on greenhouse gas (GHG) balance from a perennial bioenergy crop [reed canary grass (RCG), Phalaris arundinaceae L.] cultivated on a drained organic soil as an example, we show here for the first time that, with a proper cultivation and land‐use practice, environmentally sound bioenergy production is possible on these problematic soil types. We performed a life cycle assessment (LCA) for RCG on this organic soil. We found that, on an average, this system produces 40% less CO₂‐equivalents per MWh of energy in comparison with a conventional energy source such as coal. Climatic conditions regulating the RCG carbon exchange processes have a high impact on the benefits from this bioenergy production system. Under appropriate hydrological conditions, this system can even be carbon‐negative. An LCA sensitivity analysis revealed that net ecosystem CO₂ exchange and crop yield are the major LCA components, while non‐CO₂ GHG emissions and costs associated with crop production are the minor ones. Net bioenergy GHG emissions resulting from restricted net CO₂ uptake and low crop yields, due to climatic and moisture stress during dry years, were comparable with coal emissions. However, net bioenergy emissions during wet years with high net uptake and crop yield were only a third of the coal emissions. As long‐term experimental data on GHG balance of bioenergy production are scarce, scientific data stemming from field experiments are needed in shaping renewable energy source policies.     

Improvements in Life Cycle Energy Efficiency and Greenhouse Gas Emissions of Corn-Ethanol

Corn-ethanol production is expanding rapidly with the adoption of improved technologies to increase energy efficiency and profitability in crop production, ethanol conversion, and coproduct use. Life cycle assessment can evaluate the impact of these changes on environmental performance metrics. To this end, we analyzed the life cycles of corn-ethanol systems accounting for the majority of U.S. capacity to estimate greenhouse gas (GHG) emissions and energy efficiencies on the basis of updated values for crop management and yields, biorefinery operation, and coproduct utilization. Direct-effect GHG emissions were estimated to be equivalent to a 48% to 59% reduction compared to gasoline, a twofold to threefold greater reduction than reported in previous studies. Ethanol-to-petroleum output/input ratios ranged from 10:1 to 13:1 but could be increased to 19:1 if farmers adopted high-yield progressive crop and soil management practices. An advanced closed-loop biorefinery with anaerobic digestion reduced GHG emissions by 67% and increased the net energy ratio to 2.2, from 1.5 to 1.8 for the most common systems. Such improved technologies have the potential to move corn-ethanol closer to the hypothetical performance of cellulosic biofuels. Likewise, the larger GHG reductions estimated in this study allow a greater buffer for inclusion of indirect-effect land-use change emissions while still meeting regulatory GHG reduction targets. These results suggest that corn-ethanol systems have substantially greater potential to mitigate GHG emissions and reduce dependence on imported petroleum for transportation fuels than reported previously.     

Life cycle assessment of commodity chemical production from forest residue via fast pyrolysis

Purpose

This life cycle assessment evaluates and quantifies the environmental impacts of renewable chemical production from forest residue via fast pyrolysis with hydrotreating/fluidized catalytic cracking (FCC) pathway.

Methods

The assessment input data are taken from Aspen Plus and greenhouse gases, regulated emissions, and energy use in transportation (GREET) model. The SimaPro 7.3 software is employed to evaluate the environmental impacts.

Results and discussion

The results indicate that the net fossil energy input is 34.8 MJ to produce 1 kg of chemicals, and the net global warming potential (GWP) is ?0.53 kg CO₂ eq. per kg chemicals produced under the proposed chemical production pathway. Sensitivity analysis indicates that bio-oil yields and chemical yields play the most important roles in the greenhouse gas footprints.

Conclusions

Fossil energy consumption and greenhouse gas (GHG) emissions can be reduced if commodity chemicals are produced via forest residue fast pyrolysis with hydrotreating/FCC pathway in place of conventional petroleum-based production pathways.     

A global meta‐analysis of forest bioenergy greenhouse gas emission accounting studies

The potential greenhouse gas benefits of displacing fossil energy with biofuels are driving policy development in the absence of complete information. The potential carbon neutrality of forest biomass is a source of considerable scientific debate because of the complexity of dynamic forest ecosystems, varied feedstock types, and multiple energy production pathways. The lack of scientific consensus leaves decision makers struggling with contradicting technical advice. Analyzing previously published studies, our goal was to identify and prioritize those attributes of bioenergy greenhouse gas (GHG) emissions analysis that are most influential on length of carbon payback period. We investigated outcomes of 59 previously published forest biomass greenhouse gas emissions research studies published between 1991 and 2014. We identified attributes for each study and classified study cases by attributes. Using classification and regression tree analysis, we identified those attributes that are strong predictors of carbon payback period (e.g. the time required by the forest to recover through sequestration the carbon dioxide from biomass combusted for energy). The inclusion of wildfire dynamics proved to be the most influential in determining carbon payback period length compared to other factors such as feedstock type, baseline choice, and the incorporation of leakage calculations. Additionally, we demonstrate that evaluation criteria consistency is required to facilitate equitable comparison between projects. For carbon payback period calculations to provide operational insights to decision makers, future research should focus on creating common accounting principles for the most influential factors including temporal scale, natural disturbances, system boundaries, GHG emission metrics, and baselines.     

Warming effects on greenhouse gas fluxes in peatlands are modulated by vegetation composition

Understanding the effects of warming on greenhouse gas feedbacks to climate change represents a major global challenge. Most research has focused on direct effects of warming, without considering how concurrent changes in plant communities may alter such effects. Here, we combined vegetation manipulations with warming to investigate their interactive effects on greenhouse gas emissions from peatland. We found that although warming consistently increased respiration, the effect on net ecosystem CO₂ exchange depended on vegetation composition. The greatest increase in CO₂ sink strength after warming was when shrubs were present, and the greatest decrease when graminoids were present. CH₄ was more strongly controlled by vegetation composition than by warming, with largest emissions from graminoid communities. Our results show that plant community composition is a significant modulator of greenhouse gas emissions and their response to warming, and suggest that vegetation change could alter peatland carbon sink strength under future climate change.     

Life cycle assessment of the supply and use of bioenergy: impact of regional factors on biogas production

Purpose

This article evaluates the parameters that influence the results of a life cycle assessment (LCA) of biogas production from maize and the conversion of biogas into electricity. The environmental impacts of biogas vary according to regional farming procedures and, therefore, the soil, climate conditions, crop yield, and cultivation management. This study focuses on these regional parameters and the existing infrastructure, including the number of installed biogas plants and their share of used heat.

Materials and methods

To assess the regional impact, the LCAs of maize cultivation, on the one hand, and the production and use of biogas, on the other, were performed for three different areas. These areas were the administrative districts of Celle, Hildesheim, and Goettingen; all located in the south of Lower Saxony, Germany. The areas differed in geographic location conditions, crop yield, and the number of installed biogas plants. The necessary data for modeling the cultivation of maize were derived from the specific regional and local parameters of each area. The most important parameters were the soil characteristics and the climate conditions for cultivating maize. The share of used heat from combined heat and power unit (CHP) was another relevant factor for biogas production and use.

Results

Our results demonstrate significant differences among the investigated areas. The smallest environmental impact of all the considered categories occurs in Goettingen and the largest in Celle. The net greenhouse gas emissions vary from 0.179?kg CO₂ eq./kWh_el in Celle to 0.058?kg CO₂ eq./kWh_el in Goettingen. This result is due to the maize cultivation system and the different credits for using heat from the CHP. Variances in energy crop cultivation result from different nitrogen and irrigation demands. In addition, despite higher applications of nitrogen fertilizer and irrigation, the maize yield is lower in Celle. The impact category of total fossil energy shows similar results to that of the greenhouse gas (GHG) emissions. The results range from ?0.274 to 0.175 kWh/kWh_el. The results of acidification and eutrophication vary from 1.62 in Goettingen to 1.94?g SO₂ eq./kWh_el in Celle and respectively 0.330 to 0.397?g PO ₄ ^3? eq./kWh_el. These differences are primarily caused by maize cultivation, especially irrigation.

Conclusions and perspectives

Cultivating maize and using waste heat from the CHP were identified as the most influential parameters for the GHG emissions and total fossil energy demand. Regarding acidification and eutrophication, the most relevant factors are the application of digester output and the emissions from the CHP. Our results show the need to consider regional parameters in the LCA of bioenergies, particularly biogas production and use, especially if the LCA studies are used for generalized evaluations such as statements on the climate protection potential of biogas.     

Time series analysis models for estimation of greenhouse gas emitted by different sectors in Turkey

Due to the increasing global warming in the world, analyzing greenhouse gas emissions is a crucial issue. This study has examined greenhouse gas emissions in Turkey according to energy sector, industrial processes sector, agriculture sector and waste sector. Then, time series analysis models are used to estimate greenhouse gas emissions based on sectors. Models' performances are tested using mean error, mean absolute error and root mean square error. The results show that forecasting models have a good potential to estimate the national greenhouse gas emissions for different sector within a reasonable error. The study results will help organize and estimate the national greenhouse gas emissions inventory.     

Elevated CO<Subscript>2</Subscript> and nitrogen addition accelerate net carbon gain in a brackish marsh

Wetlands have an inordinate influence on the global greenhouse gas budget, but how global changes may alter wetland contribution to future greenhouse gas fluxes is poorly understood. We determined the greenhouse gas balance of a tidal marsh exposed to nine years of experimental carbon dioxide (CO₂) and nitrogen (N) manipulation. We estimated net carbon (C) gain rates by measuring changes in plant and soil C pools over nine years. In wetland soils that accrete primarily through organic matter inputs, long-term measurements of soil elevation, along with soil C density, provide a robust estimate of net soil C gain. We used net soil C gain along with methane and nitrous oxide fluxes to determine the radiative forcing of the marsh under elevated CO₂ and N addition. Nearly all plots exhibited a net gain of C over the study period (up to 203 g C m^?2 year^?1), and C gain rates were greater with N and CO₂ addition. Treatment effects on C gain and methane emissions dominated trends in radiative forcing while nitrous oxide fluxes in all treatments were negligible. Though these soils experience salinities that typically suppress methane emissions, our results suggest that elevated CO₂ can stimulate methane emissions, overcoming positive effects of elevated CO₂ on C gain, converting brackish marshes that are typically net greenhouse gas sinks into sources. Adding resources, either CO₂ or N, will likely increase “blue carbon” accumulation rates in tidal marshes, but importantly, each resource can have distinct influences on the direction of total greenhouse forcing.     

The Consequences of Substituting Sand with Used Copper Slag in Construction

Using waste copper slag (CS) as a replacement for sand in concrete mixture is becoming popular in Singapore and around the world. What are the consequences of this material substitution? Will this result in lower environmental impact? This work used attributional and consequential life cycle assessments to evaluate the net results of replacing sand with CS. Impacts were assessed with respect to embodied energy and greenhouse gas emissions (global warming potential; GWP). It was found that embodied energy and GWP of using a combination of 0.13 kilograms (kg) of CS and 0.9 kg of sand are higher than those of 1 kg of sand. If CS replaces sand and the leftover sand replaces crushed rock sand, the net embodied energy and GWP may also increase. Landfilling the waste CS is similar to recycling it as a building material, in terms of embodied energy incurred and GWPs. Finally, four lessons from these findings were used to suggest a few integrated sustainable resource management policies for the building material and shipping industries.