Uncovering the Fate of Critical Metals: Tracking Dissipative Losses along the Product Life Cycle

An increasing number of elements from the periodic table are being used in a growing number of products, enabling new material and product functionalities. Materials of high importance and high supply risks are usually referred to as critical materials. Many materials that are often considered critical are used in ways leading to their dissipative loss along the product life cycle. So far, the issue of material dissipation has been dealt with mainly on a rather aggregated level. Detailed knowledge on the occurrence and amount of dissipative losses in the life cycle of specific products is only scarcely available. Addressing this, a substance flow analysis of different critical metals along the life cycle of selected products is presented in this article. With regard to products used in Germany, the flows of indium and gallium used in copper‐indium‐gallium‐selenide (CIGS) photovoltaic cells, germanium used in polymerization catalysts, and yttrium used in thermal barrier coatings (TBCs) have been analyzed. The results comprise detailed knowledge about the life cycle stages in which dissipative losses occur and about the receiving media. In all case studies, a complete or almost complete dissipative loss can be observed, mainly to landfills and other material flows. In all case studies, material production can be identified as hotspots for dissipative losses. In two case studies fabrication and manufacturing (F&M for CIGS and TBCs) and in one case study end of life (polymerization catalysts) can be identified as further hotspots for dissipative losses. In addition, actions for reducing dissipation along the life cycle are discussed, targeting aspects such as the recovery of critical metals as by‐products, efficiency in F&M processes, and lack of recycling processes. Lack of economic incentives to apply more‐efficient technologies and processes already available is a key aspect in this regard.     

Estimation of Life Cycle Material Costs of Cadmium Telluride– and Copper Indium Gallium Diselenide–Photovoltaic Absorber Materials based on Life Cycle Material Flows

Chalcogenide and chalcopyrite photovoltaic (PV) technologies are highly suitable for solar energy conversion because of their high efficiency, long‐term stable performance, and low‐cost production. However, the absorber materials that are used, such as indium, gallium, and tellurium, are regarded as critical, and their limited availability can hinder market expansion. Therefore, we assess how material efficiency measures along the PV module's life cycle can reduce the net material demand of the absorber materials and thus the material costs. In order to estimate the material flows, we developed a closed‐loop model for the life cycle representing the phases module production, module collection, module recycling, and refinement. In order to reflect the variety and uncertainty in each phase, we compose three different efficiency scenarios by varying material efficiency measures on process and product levels. For each scenario, we compute the life cycle material costs based on the computed material flows. The results show that, in the long term, the material demand can be reduced down to one fourth of the required feedstock for module manufacturing; that is, three fourths of the absorber material stays in the life cycle in a very efficient scenario. Thus, total material costs along the life cycle could be significantly reduced, because the costs for material recycling are lower than the costs for “new” technical‐grade material. This reduction in life cycle material costs means that cadmium telluride– and copper indium gallium diselenide–PV can still be financially viable even if the price of the absorber materials increases significantly. Hence those technologies will still be competitive against crystalline silicon PV in the mid to long term.     

Urban Metabolism of Paris and Its Region

The article presents the results of a research project aimed at (1) examining the feasibility of material flow analysis (MFA) on a regional and urban scale in France, (2) selecting the most appropriate method, (3) identifying the available data, and (4) calculating the material balance for a specific case. Using the Eurostat method, the study was conducted for the year 2003 and for three regional levels: Paris, Paris and its suburbs, and the entire region. Applying the method on a local scale required two local indicators to be defined in order to take into account the impact of exported wastes on MFA: LEPO, local and exported flows to nature, and DMC_corr, a modified domestic material consumption (DMC) that excludes exported wastes (and imported ones if necessary). As the region extracts, produces, and transforms less material than the country as a whole, its direct material input (DMI) is lower than the national DMI. In all the areas, LEPO exceeds 50% of DMI; in contrast, recycling is very low. The multiscale approach reveals that urban metabolism is strongly impacted by density and the distribution of activities: the dense city center (Paris) exports all of its wastes to the other parts of the region and concentrates food consumption, whereas the agricultural and urban sprawl area consumes high levels of construction materials and fuel. This supports the use of MFA on an urban and regional scale as a basis for material flow management and dematerialization strategies and clearly reveals the important interactions between urban and regional planning and development, and material flows.     

The Life Cycle Assessment of an Energy‐Positive Peri‐Urban Residence in a Tropical Regime

Urban settlements are home to the greatest levels of greenhouse gas emissions and energy consumption globally, with unprecedented rates of urban expansion occurring today. With the majority of global urbanization occurring along the periphery of urban areas in developing countries, investigation of “green” building practices designed specifically for “peri‐urban” regions is critical for a low‐emitting future society. This study assesses a state‐of‐the‐art residence designed for a middle‐class family of four residing in the peri‐urban region of Bangkok, Thailand. The residence employs both demand‐side management strategies and low‐emitting energy supply technology to achieve energy‐positive status. To elucidate the influence that key design decisions have on the life cycle sustainability of the home, several variants of the residence are modeled. A process‐based life cycle assessment consistent with the International Organization for Standardization (ISO) 14044:2006 standard and following ReCiPe Midpoint life cycle impact assessment methodology is used to quantify the life cycle impacts per square meter of conditioned residence floor area for climate change (582 kilograms [kg] carbon dioxide equivalent), terrestrial acidification (4.01 kg sulfur dioxide equivalent), freshwater eutrophication (30.4 grams phosphorous equivalent), fossil depletion (362 kg iron equivalent), and metal depletion (186 kg oil equivalent) impacts. We model multiple scenarios in which varying proportions of Bangkok's peri‐urban detached housing demand are fulfilled by the energy‐positive residence variants. Under the best‐case replacement scenario (i.e., 100% replacement of future peri‐urban detached housing), significant reductions are achieved across the life cycle climate change (80%), terrestrial acidification (82%), and fossil depletion (81%) impact categories for the steel‐framed, energy‐positive residence.     

Evaluation of the Metals Industry's Position on Recycling and its Implications for Environmental Emissions

A healthy debate on the treatment of metals recycling in the life cycle assessment (LCA) community has persisted for more than a decade. While no clear consensus across stakeholder groups has emerged, the metals industry has endorsed a set of recycling “facts” that support a single approach, end‐of‐life recycling, for evaluating the environmental benefits of metals recycling. In this article we draw from research conducted in several disciplines and find that three key tenets of the metals industry capture the theoretical potential of metals recycling from a metallurgical standpoint rather than reflecting observed behavior. We then discuss the implications of these conclusions on environmental emissions from metals production and recycling. Evidence is provided that, contrary to the position of the metals industry, metals are not necessarily recycled at high rates, are recycled only a small number of times before final disposal, and are sometimes limited in recycling potential by the economics of contaminant removal. The analysis concludes that metal recycled from old scrap largely serves as an imperfect substitute for primary metal. As a result, large‐scale displacement of primary production and its associated environmental emissions is currently limited to a few specific instances.     

What Do We Know About Metal Recycling Rates?

The recycling of metals is widely viewed as a fruitful sustainability strategy, but little information is available on the degree to which recycling is actually taking place. This article provides an overview on the current knowledge of recycling rates for 60 metals. We propose various recycling metrics, discuss relevant aspects of recycling processes, and present current estimates on global end‐of‐life recycling rates (EOL‐RR; i.e., the percentage of a metal in discards that is actually recycled), recycled content (RC), and old scrap ratios (OSRs; i.e., the share of old scrap in the total scrap flow). Because of increases in metal use over time and long metal in‐use lifetimes, many RC values are low and will remain so for the foreseeable future. Because of relatively low efficiencies in the collection and processing of most discarded products, inherent limitations in recycling processes, and the fact that primary material is often relatively abundant and low‐cost (which thereby keeps down the price of scrap), many EOL‐RRs are very low: Only for 18 metals (silver, aluminum, gold, cobalt, chromium, copper, iron, manganese, niobium, nickel, lead, palladium, platinum, rhenium, rhodium, tin, titanium, and zinc) is the EOL‐RR above 50% at present. Only for niobium, lead, and ruthenium is the RC above 50%, although 16 metals are in the 25% to 50% range. Thirteen metals have an OSR greater than 50%. These estimates may be used in considerations of whether recycling efficiencies can be improved; which metric could best encourage improved effectiveness in recycling; and an improved understanding of the dependence of recycling on economics, technology, and other factors.     

Evaluation of Life Cycle Assessment Recycling Allocation Methods

Life cycle assessment practitioners struggle to accurately allocate environmental burdens of metals recycling, including the temporal dimension of environmental impacts. We analyze four approaches for calculating aluminum greenhouse gas emissions: the recycled content (RC) or cut‐off approach, which assumes that demand for recycled content displaces primary production; end‐of‐life recycling (EOLR), which assumes that postuse recycling displaces primary production; market‐based (MB) approaches, which estimate changes in supply and demand using price elasticities; and value‐corrected substitution (VCS), which allocates impact based on price differences between primary and recycled material. Our analysis suggests that applications of the VCS approach do not adequately account for the changing scrap to virgin material price ratio over time, whereas MB approaches do not address stock accumulation and depletion. The EOLR and RC approaches were analyzed using two case studies: U.S. aluminum beverage cans and vehicle engine blocks. These approaches produced similar results for beverage cans, which have a closed material loop system and a short product life. With longer product lifetimes, as noted with the engine blocks, the magnitude and timing of the emissions differs greatly between the RC and EOLR approaches. The EOLR approach indicates increased impacts at the time of production, offset by negative impacts in future years, whereas the RC approach assumes benefits to increased recycled content at the time of production. For vehicle engine blocks, emissions using EOLR are 140% higher than with RC. Results are highly sensitive to recycled content and future recycling rates, and the choice of allocation methods can have significant implications for life cycle studies.     

Location Optimization of Urban Mining Facilities with Maximal Covering Model in GIS: A Case of China

Urban mining offers an efficient supply of resources because of rich mines and low environmental impacts. Location selection and optimization for urban mining facilities is more complicated than for natural mines, given that it may vary according to the urban population, consumption habits, and economic development. China initiated the National Urban Mining Pilot Bases program in 2010 that targeted 50 national urban mining pilot bases, but unfortunately neglected the location planning issue. Twenty‐eight bases have already been selected, which are concentrated in the central and eastern areas of China. This article combines the use of analytic hierarchy process, maximal covering location model, and geographical information systems (GIS) software to optimize locations for China's urban mining pilot bases. Primary findings show that, theoretically, 40 urban mining pilot bases can sufficiently provide maximum gross domestic product (GDP) and population coverage service for China. Taking the current 28 bases as a precondition and 50 bases as the remaining policy target, our second optimization results in a list of 22 cities for the location selection of future urban mining pilot bases. In total, the optimized 22 cities, together with the selected 28 bases, can provide a maximum 97.5% of GDP and 95.1% of population coverage in China. This study illustrates the optimization process for urban mining recycling facilities in general and provides policy advice for China in a specific case.     

Assessment of Environmental Impacts of an Aging and Stagnating Water Supply Pipeline Network

Aging urban infrastructure is a common phenomenon in industrialized countries. The urban water supply pipeline network in the city of Oslo is an example. Even as it faces increasing operational, maintenance, and management challenges, it needs to better its environmental performance by reducing, for instance, the associated greenhouse gas emissions. In this article the authors examine the environmental life cycle performance of Oslo's water supply pipelines by analyzing annual resource consumption and emissions as well as life cycle assessment (LCA) impact potentials over a period of 16 years, taking into account the production/manufacture, installation, operation, maintenance, rehabilitation, and retirement of pipelines. It is seen that the water supply pipeline network of Oslo has already reached a state of saturation on a per capita basis, that is, it is not expanding any more relative to the population it serves, and the stock is now rapidly aging. This article is part of a total urban water cycle system analysis for Oslo, and analyzes more specifically the environmental impacts from the material flows in the water distribution network, examining six environmental impact categories using the SimaPro (version 7.1.8) software, Ecoinvent database, and the CML 2001 (version 2.04) methodology. The long‐term management of stocks calls for a strong focus on cost optimization, energy efficiency, and environmental friendliness. Global warming and abiotic depletion emerge as the major impact categories from the water pipeline system, and the largest contribution is from the production and installation phases and the medium‐size pipelines in the network.     

产业生态学最新研究进展及趋势展望

传统末端治理方式的弊端和清洁生产技术的局限性促使人们探求新的污染防治模式,生态学尤其是仿生学的发展激发了人们仿照自然生态系统来改造人类生产系统的想法,基于这种背景,产业生态学应运而生。分析了产业生态学诞生的背景及其形成过程,并全面系统论述了产业生态学领域的国内外进展,识别了目前我国该领域面临的问题与困境,并给出了对策建议。在此基础上,文章从学科发展的角度对产业生态学的发展趋势和前景作了展望。     

A Carbon Footprint of Textile Recycling: A Case Study in Sweden

Global population growth and rising living standards are increasing apparel consumption. Consequently, consumption of resources and generation of textile waste are increasing. According to the Swedish Environmental Protection Agency, textile consumption increased by 40% between the years 2000 and 2009 in Sweden. Given that there is currently no textile recycling plant in Sweden, the aim of this article is to explore the potential environmental benefits of various textile recycling techniques and thereby direct textile waste management strategies toward more sustainable options. Three different recycling techniques for a model waste consisting of 50% cotton and 50% polyester were identified and a life cycle assessment (LCA) was made to assess the environmental performance of them. The recycling processes are: material reuse of textile waste of adequate quality; separation of cellulose from polyester using N‐methylmorpholine‐N‐oxide as a solvent; and chemical recycling of polyester. These are compared to incineration, representing conventional textile waste treatment in Sweden. The results show that incineration has the highest global warming potential and primary energy usage. The material reuse process exhibits the best performance of the studied systems, with savings of 8 tonnes of carbon dioxide equivalents (CO₂‐eq) and 164 gigajoules (GJ) of primary energy per tonne of textile waste. Sensitivity analyses showed that results are particularly sensitive to the considered yields of the processes and to the choice of replaced products. An integration of these recycling technologies for optimal usage of their different features for treatment of 1 tonne of textile waste shows that 10 tonnes CO₂‐eq and 169 GJ of primary energy could be saved.     

Vehicles and Critical Raw Materials: A Sustainability Assessment Using Thermodynamic Rarity

The changing material composition of cars represents a challenge for future recycling of end‐of‐life vehicles (ELVs). Particularly, as current recycling targets are based solely on mass, critical metals increasingly used in cars might be lost during recycling processes, due to their small mass compared to bulk metals such as Fe and Al. We investigate a complementary indicator to material value in passenger vehicles based on exergy. The indicator is called thermodynamic rarity and represents the exergy cost (GJ) needed for producing a given material from bare rock to the market. According to our results, the thermodynamic rarity of critical metals used in cars, in most cases, supersedes that of the bulk metals that are the current focus of ELV recycling. While Fe, Al, and Cu account for more than 90% of the car's metal content, they only represent 60% of the total rarity of a car. In contrast, while Mo, Co, Nb, and Ni account for less than 1% of the car's metal content, their contribution to the car's rarity is larger than 7%. Rarity increases with the electrification level due to the greater amount of critical metals used; specifically, due to an increased use of (1) Al alloys are mainly used in the car's body‐in‐white of electric cars for light‐weighting purposes, (2) Cu in car electronics, and (3) Co, Li, Ni, and rare earth metals (La, Nd, and Pr) in Li‐ion and NiMH batteries.     

The Environmental Importance of Energy Use in Chemical Production

In many cases, policy makers and laymen perceive harmful emissions from chemical plants as the most important source of environmental impacts in chemical production. As a result, regulations and environmental efforts have tended to focus on this area. Concerns about energy use and greenhouse gas emissions, however, are increasing in all industrial sectors. Using a life cycle assessment (LCA) approach, we analyzed the full environmental impacts of producing 99 chemical products in Western Europe from cradle to factory gate. We applied several life cycle impact assessment (LCIA) methods to cover various impact areas. Our analysis shows that for both organic and inorganic chemical production in industrial countries, energy‐related impacts often represent more than half and sometimes up to 80% of the total impacts, according to a range of LCIA methods. Resource use for material feedstock is also important, whereas direct emissions from chemical plants may make up only 5% to 10% of the total environmental impacts. Additionally, the energy‐related impacts of organic chemical production increase with the complexity of the chemicals. The results of this study offer important information for policy makers and sustainability experts in the chemical industry striving to reduce environmental impacts. We identify more sustainable energy production and use as an important option for improvements in the environmental profile of chemical production in industrial countries, especially for the production of advanced organic and fine chemicals.     

Urban Mining's Potential to Relieve China's Coming Resource Crisis

China's mineral resource consumption has gone through multiple increases since 1980, resulting in the inadequacy of important strategic resources and a high level of external dependence. Some developed countries have already reduced primary resources consumption through urban mining. Can China also break through the bottleneck of the resource shortage and continue its economic and social development through strengthening of urban mining? This article selected copper (Cu), aluminum (Al), lead (Pb), and iron (Fe) as case studies and established predictive models for metal demand, recycling, and stock, based on stock analysis, material flow analysis, and a life distribution model, and then analyzed the metabolism of the four resources and compared the environmental effects of three scenarios. The study indicates that the urban mining potential of Cu, Fe, Al, and Pb will attain 8.1, 711.6, 37.0, and 12.1 million tonnes, respectively, in 2040. Compared with 2010, the substitution rate (secondary metals substituting primary metals) of Cu and Fe increase by 25.4% and 59.9%, whereas external dependence decreases by 30.8% and 25.7%. However, substitution is not obvious regarding Al and Pb. The low resource scenario decreases resources use, which will reduce external dependence in the short term, whereas the strengthened recovery scenario increases resource recovery and has a larger effect in reducing external dependence in the long term. So, in line with urban mining in the future, China should change its environment and resource strategy, further strengthen layout and construction of urban mining demonstration bases, and encourage the use of recyclable resources to provide a better foundation for urban mining.     

Weight under Steel Wheels: Material Stock and Flow Analysis of High‐Speed Rail in China

The construction of a nation‐wide high‐speed rail (HSR) network has emerged as a hugely expensive and ambitious infrastructure project in China. As of December 2012, some 8,800 kilometers (km) of double‐track HSR lines came into service in the country, accounting for 40% of the total HSR length in the world. The network is expected to expand to 34,000 km or longer in around two decades. As the first HSR system specially built and operated in an economically developing country, it helps integrate the sprawling economy and lift the quality of life of the increasing urban population. China's experiences in HSR are expected to be of value to other countries aiming to adopt bullet train systems, especially those at a similar level of industrialization and urbanization. This work specifically examines material stocks and flows associated with the HSR infrastructure construction in China. A major distinction from the construction of HSR tracks in Europe is that nearly 70% of the HSR tracks in China are laid upon bridges or inside tunnels, which are structures that demand great amounts of raw materials. The entire network, once completed by 2030, will cumulatively require 83 to 137 million tonnes (Mt) of steel and 560 to 920 Mt of cement. This is still a small share of China's use of material resources. Nonetheless, the massive application of the steel‐ and cement‐intensive structures deserves consideration when assessing the environmental performance of HSR over its entire life cycle.     

Urban Mining in Times of Raw Material Shortage

The present article investigates to what extent and level of success urban mining—the recovery of resources from anthropogenic stock—has been applied in the past during shortages of primary resources. As a case study, the Austrian economy during World War I—when raw materials indeed had to be substituted from secondary sources—is analyzed here. By means of material flow analysis, the management of copper, an important and relatively scarce metal that is difficult to substitute, is examined. The combination of increased demand for copper (for ammunition) and constraints on supply from sources other than the domestic anthroposphere highlights the importance of planning for and surveying urban mining activities. The results also indicate limitations to extracting a large share of copper from the anthroposphere, even in the face of a critical shortage. Although extreme measures, such as confiscation, were taken, only 1.7 kilograms of copper per capita (kg Cu/cap), amounting to perhaps as little as 10% of the anthropogenic stock, could be made available through the end of the war.     

Global Life Cycle Paper Flows,Recycling Metrics,and Material Efficiency

Despite major improvements in recycling over the last decades, the pulp and paper sector is a significant contributor to global greenhouse gas emissions and other environmental pressures. Further reduction of virgin material requirements and environmental impacts requires a detailed understanding of the global material flows in paper production and consumption. This study constructs a Sankey diagram of global material flows in the paper life cycle, from primary inputs to end‐of‐life waste treatment, based on a review of publicly available data. It then analyzes potential improvements in material flows and discusses recycling and material efficiency metrics. The article argues that the use of the collection rate as a recycling metric does not directly stimulate avoidance of virgin inputs and associated impacts. An alternative metric compares paper for recycling (recovered paper) with total fibrous inputs and indicates that the current rate is at just over half of the technical potential. Material efficiency metrics are found to be more useful if they relate to the reuse potential of wastes. The material balance developed in this research provides a solid basis for further study of global sustainable production and consumption of paper. The conclusions on recycling and efficiency should be considered for improving environmental assessment and stimulating a shift toward resource efficiency and the circular economy.     

Use of Industrial By‐Products in Urban Roadway Infrastructure

Incorporating the beneficial use of industrial by‐products into the industrial ecology of an urban region as a substitute or supplement for natural aggregate can potentially reduce life cycle impacts. This article specifically looks at the utilization of industrial by‐products (IBPs) (coal ash, foundry sand, and foundry slag) as aggregate for roadway sub‐base construction for the Pittsburgh, Pennsylvania, urban region. The scenarios compare the use of virgin aggregate with the use of a combination of both virgin and IBP aggregate, where the aggregate material is selected based on proximity to the construction site and allows for minimization of transportation impacts. The results indicate that the use of IBPs to supplement virgin aggregate on a regional level has the potential of reducing impacts related to energy use, global warming potential, and emissions of nitrogen oxides (NO_x), sulfur dioxide (SO₂), carbon monoxide (CO), PM₁₀ (particulate matter—10 microns), mercury (Hg), and lead (Pb). Regional management of industrial by‐products would allow for the incorporation of these materials into the industrial ecology of a region and reduce impacts from the disposal of the IBP materials and the extraction of virgin materials and minimize the impacts from transportation. The combination of reduced economic and environmental costs provides a strong argument for state transportation agencies to develop symbiotic relationships with large IBP producers in their regions to minimize impacts associated with roadway construction and maintenance—with the additional benefit of improved management of these materials.