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1.
Heavy metals (Al, Cd, Co, Cr, Cu, Fe, Pb, Zn) in surface soil of Klang district were determined and multivariate analysis was used to understand their potential sources. The total and bioavailability of concentrations were used in identifying the potential risks to the ecology and human health. The means for the total heavy metal concentrations were found to be in the order of Fe > Al > Zn > Pb > Cu > Cr > Co > Cd, while the means for the bioavailability concentrations were found to be in the order of Al > Fe > Zn > Cu > Co > Cd > Pb > Cr. Principal Component Analysis showed Principal Component 1 as being of natural origin whereas Principal Components 2, 3, and 4 were associated with mixed anthropogenic sources, such as traffic and industrial emissions, organic matter, and granulometric fractions. Potential ecological risk assessment indicated an overall low ecological risk. Spatial assessment of non-carcinogenic risks showed that the Hazard Index values were more than one in Johan Setia, due to biomass burning of peat swamps exploited for agricultural development. While for spatial assessment of carcinogenic risks, the Lifetime Cancer Risk values were in the limit (1 × 10?5), indicating low cancer inducing risks. Nevertheless, with intense development pressure in the Klang district could overlap pollution inputs in the future.  相似文献   

2.
The objective of this study is the evaluation of health risk of heavy metals in soils of urban community gardens of Baghdad City in Iraq. The soil samples were collected from 14 community gardens and analyzed for Cd, Cr, Cu, Ni, Pb and Zn. The non-carcinogenic hazard index (HI) and carcinogenic risk index (RI) were utilized to evaluate human health risk of heavy metals. The health hazard evaluation showed that there is no non-carcinogenic hazard in light of the fact that the HI values were beneath the threshold value (HI < 1). The HI for children and adults has a descending order of Cd < Cr < Cu < Ni < Pb < Zn. The carcinogenic RI values for Cd, Cr and Ni were over the unacceptable threshold value (RI < 1 × 10?4), demonstrating that there is a serious carcinogenic risk for children and adults in the study area. The carcinogenic RI for children and adults has a descending order of Cr < Cd < Ni. These findings give environment administrators and leaders data on whether therapeutic activities are required to decrease exposure.  相似文献   

3.
To manage public health and make better use of groundwater resources, the concentration characteristics and a health risk assessment of eight heavy metals in shallow groundwater were studied. Besides this, this paper introduced triangular fuzzy numbers into the USEPA health risk assessment model to assess the health risk posed to local children and adults through different exposure pathways. The results showed that Mn levels exceeded the WHO’s guideline values of 100?µg/L with the proportion of 27.98% and Sr were over the health reference level (HRL) of 1500?µg/L with the proportion of 56.25%, while other heavy metals were below the corresponding standard. The results of the HRA showed that the non-carcinogenic risks from Sr and Mn in the district were relatively higher, while those from the remaining six heavy metals were relatively lower. All hazard index (HI) values did not exceed the safety level of 1 for either age group. The average carcinogenic risk from Cr was slightly higher than the acceptable level of 1?×?10?6 for adults. Sensitivity analyses conducted using Monte Carlo simulation indicated that Sr and Cr concentrations were the most influential variables contributing to the non-carcinogenic and carcinogenic risk values, respectively, while body weight had a minor contribution.  相似文献   

4.
Hazard evaluation of different heavy metal exposure on the crops cultivated around two abandoned metal mine sites was conducted. Bioconcentration Factor (BCF) of nine heavy metals including Cu, Cd, Hg, As, Cr, Zn, Pb, Mn, and Al in the samples of brown rice cultivated at exposed soil were measured. Soil-plant BCF was measured and compared with Korean and US EPA standards. BCF values of analyzed heavy metals except Hg and As were below the limits. BCF of Hg was over 5 times higher than the standard limit. Excess cancer risk (ECR) and hazard quotient (HQ) values of As was higher than the limit and suggested to have carcinogenic as well as non-carcinogenic threat to the public exposed to the sites. The data presented could be utilized in prioritizing abandoned metal mine sites for health effect survey.  相似文献   

5.
Health Risk Assessment of Heavy Metals in Urban Soil of Karachi,Pakistan   总被引:1,自引:0,他引:1  
The potential health risk due to lifetime exposure to copper, lead, chromium, zinc, and iron in urban soil of Karachi, Pakistan, was evaluated. Mean concentrations of Cu, Pb, Cr, Zn, and Fe in topsoil samples were 33.3 ± 12.8, 42.1 ± 55.8, 9.6 ± 4.2, 99.5 ± 37.3, and 908.4 ± 57.8 mg kg?1, respectively. A U.S. Environmental Protection Agency model was adopted for the carcinogenic and non-carcinogenic risk assessment from different exposure pathways. Risk assessment indicated that the overall results for the carcinogenic risk were insignificant. However, the carcinogenic risk from Pb due to oral ingestion of soil exceeded the value of 1 × 10?6, in some areas of the city. It indicates that the exposure to Pb-contaminated soil may cause adverse health effects in humans, especially in children. The Hazard Quotient (HQ) for different metals through ingestion and dermal pathways was also found to be less than 1. The combined Hazard Index (HI) for children through different routes of exposure was 8.9 times greater than for adults. It indicates that the children are more susceptible to non-carcinogenic health effects of trace metals compared to adults. Particularly, non-carcinogenic risk of Pb to children via oral ingestion needs special attention.  相似文献   

6.
Access to safe and clean drinking water is an essential element of healthy life also known as the primary human needs. The present study was conducted to investigate heavy metal (HM) concentrations of drinking water. Excess health risk of HM (Cr, Pb, and Cd) intake is related to the drinking water consumption in local population. HMs concentrations were analyzed by using graphite furnace atomic absorption spectrometer and were compared with permissible limits regulated by country and World Health Organization (WHO). The hazard quotient (HQ) and Excess Lifetime Cancer Risk (ELCR) were determined to show the carcinogenic and non-carcinogenic effects of HMs, respectively. HQs were found in the order of Pb > Cd > Cr and subsequently HI index was also estimated for all HM in two age groups (children and adults). The comparisons indicate no possibility of non-carcinogenic effects to the local population. The values for ELCR were found in the order of Cr > Cd > Pb. The ELCR index was found above acceptable risk levels for chromium and cadmium in both children and adults groups. Furthermore, intermetal correlation results revealed that heavy metals have common sources resulting from geogenic and anthropogenic activities and these are major sources of water contamination in Sistan and Baluchestan province.  相似文献   

7.
To evaluate the potential health hazards caused by extensive vanadium–titanium magnetite mining, bioavailability and bioaccessibility of metals were assessed in the pluralistic mining–agriculture–residential city of Panzhihua, China. Intensive mining and related heavy traffic may have contributed to Ni, Cr, and Zn contamination and Mn and V accumulation in soils and road dusts. The metal bioavailability estimated by water extraction was significantly lower than metal bioaccessibility on the basis of the simple bioaccessibility extraction test. The bioaccessible metal concentrations were significantly and positively correlated with soil/dust total metal concentrations (p < .05). However, bioavailable metal concentrations exhibited no relationship with total metal concentrations except for V. The bioaccessibility of metals significantly varied and exhibited the following order: Pb > Zn > Mn > Ni > V > Cr. Health risk assessment indicated that the carcinogenic and non-carcinogenic risks posed by these metals were at an acceptable level, but Cr in soils of the mining area and V in surface soils along the Jinsha River were close to the safe level for children. Therefore, the potential health risk attributed to the exposure of children to metals in surface soils and road dusts in such areas should not be overlooked.  相似文献   

8.
Abstract

The purpose of the study was to acquire the source and evaluate the risk posed by heavy metals in road dust of steel industrial city (Anshan), Liaoning, Northeast China. Potential ecological risk index (RI), pollution index (PI) and geo-accumulation index (Igeo) were applied to evaluate the heavy metal pollution level, and the carcinogenic risk (RI) and hazard index (HI) were calculated to estimate the human health risk. The geographic information system maps clearly reveal the hot spots of heavy metal spatial distribution. Principle component analysis (PCA) and cluster analysis (CA) classified heavy metals into three groups. The metal Zn and Pb originate from the traffic emission, while Cd, Cr, Fe, Mn, Ni and Sb primarily come from industrial activities. These two pathways were the major source of heavy metals pollution by positive matrix factorization (PMF). The Igeo and PI values of heavy metals were decreased in the following order: Cd?>?Sb?>?Zn?>?Fe?>?Pb?>?Cu?>?Cr?>?Sn?>?Mn?>?Ni. The RI index showed the heavy metals were moderate to very high potential ecological risk. The HI values for children and adults presented a decreasing order of Cr?>?Pb?>?Ni?>?Cu?>?Cd?>?Zn. The HI also predicted a possibility of non-carcinogenic risk for children living in urban areas in comparison with adults.  相似文献   

9.
Heavy metals enrichment in groundwater poses great ecological risks to human beings. In the present research work, a total of 59 groundwater samples from 12 sampling points in Dingji coal mine, Huainan coalfield, were collected and measured for Cu, Pb, Zn, Cd, Ni, Mn, Cr, and Fe by inductively coupled plasma mass spectrometry (ICP-MS). The human health risk caused by heavy metals through the pathway of drinking water was evaluated and analyzed using the US Environment Protection Agency (USEPA) evaluation model. It has been found that the carcinogenic risk values were between 1.05 × 10?5 and 3.5 × 10?4, all exceeding the maximum acceptable level recommended by the USEPA, and the carcinogenic risk of Cr accounted for 99.67% of the total carcinogenic risk. The non-carcinogenic health risk values were all lower than the negligible level given by the USEPA, and the contribution of non-carcinogenic health risk was in the order of Cr > Zn > Cu / Pb >Mn > Fe > Cd > Ni. Among them, Cr had the largest contribution, accounting for 36% of the total non-carcinogenic risk value. In this study, the carcinogenic risk constituted 99.99% of the total health risk, indicating that the total health risk essentially consisted of carcinogenic risk. The research results suggest that much more attention should be paid to the health risk caused by Cr in the groundwater.  相似文献   

10.
A total of 195 farmland soil samples were collected in Yanqi Basin, Xinjiang, northwest China, and the concentrations of As, Cd, Cr, Cu, Ni, Pb, and Zn were analyzed for their concentrations and pollution levels using the Nemerow comprehensive index. The health risk assessment model introduced by USEPA was utilized to evaluate the human health risks of heavy metals. Results indicated that the average concentrations of these seven metals were lower than the allowed soil environmental quality standards of China, while the average concentrations of Cd, Cr, Ni, Pb and Zn exceeded the background values of irrigation soils in Xinjiang. The average contamination factor (CF) for Pb indicated the heavy pollution, whereas the CF for Cd, Zn, Ni, Cu and Cr indicated the moderate pollution. The average PLI of heavy metals indicated the low pollution. The non-carcinogenic hazard index were below the threshold values, and the total carcinogenic risks due to As and Cr were within the acceptable range for both children and adults. As and Pb were the main non-carcinogenic factors, while As was the main carcinogenic factor in the study area. Special attentions should be paid to these priority control metals in order to target the lowest threats to human health.  相似文献   

11.
Soil heavy metal contamination is a major environmental concern, and health risk associated with heavy metals is not fully explored. A combination of spatial analysis and Monte Carlo simulation was successfully used to identify the possible sources and health risk of cadmium (Cd), arsenic (As), mercury (Hg), lead (Pb), chromium (Cr), and copper (Cu) in soils collected from a rapidly developing region of China. It was found that mean concentrations of Cd (0.17 mg/kg ), As (8.74 mg/kg ), Hg (0.15 mg/kg ), Pb (27.28 mg/kg ), and Cu (33.32 mg/kg ) were greater than the soil background values. Accumulation and spatial variability of heavy metals were significantly affected by anthropogenic activities and soil properties. The risk assessment indicated that non-carcinogenic risk was not significant. However, 95% of the total cumulative carcinogenic risk of children was greater than 1E-05, implying high potential carcinogenic risk with As and Pb representing the major contributors. Ingestion of heavy metals in the soils was the main exposure pathway compared with the inhalation and the dermal exposure. Concentration of heavy metals in the soils, particulate emission factor, and dermal exposure ratio were the major parameters affecting health risk. This study highlights the importance of assessment of soil direct exposure health risk in studying heavy metal exposures.  相似文献   

12.
Risk characterization of agricultural soils in the mining areas of Singhbhum copper belt was done by determining the total concentrations of metals using inductively coupled plasma-mass spectrometry and assessing the potential ecological and human health risks. The concentrations were above the average shale values for most of the metals. Principal component analysis showed anthropogenic contributions of Cu, Ni, Co, Mn, Pb, and Cr in the soils. Ecological risk assessment revealed that 50% of the soil samples were at moderate to very high ecological risk. Health risks for adults and children were calculated using hazard quotients (HQs), hazard index (HI), and Cancer risks for the oral, dermal, and inhalation pathways. The HQs for all the metals except As and Co were below 1, which suggested that non-carcinogenic risks due to metal exposure through soils were within the safe limit. However, considering all the metals and pathways, the HI for adults and children was 0.71 and 5.61, respectively, suggesting appreciable risk to local residents. The carcinogenic risks due to As and Cr in the soils were within the acceptable value of 1E–04. For both carcinogenic and non-carcinogenic risks, oral ingestion appeared to be the primary pathway followed by dermal and inhalation pathways.  相似文献   

13.
In recent years, heavy metal pollution accidents have occurred in many regions of China, and the public has become increasingly concerned about its health. Based on a U.S. Environmental Protection Agency model and using Monte Carlo simulation techniques, this article presents a procedure for health risk assessment of heavy metal pollution. A case study was conducted in the Qixia lead and zinc mining area. Based on the magnitude of heavy metal contamination in the mine factory, vicinal Qixia scenic site and village, the potential health risk calculated for a lifetime of exposure (through ingestion and dermal contact) was determined as the cumulative carcinogenic and non-carcinogenic risk for workers, tourists, and local residents (including children and adults), respectively. The risk assessment indicated that the carcinogenic risk is not significant. However, Pb poses a significant cumulative non-carcinogenic risk, which tends to be serious for workers. Additionally, local children are more vulnerable than adults to the risks associated with heavy metal contamination. Accordingly, risk alleviation and preventive measures should be taken, especially for children and workers.  相似文献   

14.
Abstract

Increasing levels of heavy metals in soil have become a serious concern for human health because they can be easily transferred into the human body through contaminated food web. It is imperative to evaluate pollution levels, origin and ecological risks of heavy metals. The geoaccumaualtion (Igeo), contamination factor (CF), pollution load index (PLI) and human health risk were estimated to determine the soil pollution in Faisalabad, a heavily-populated and industrialized city of Pakistan. The maximum CF (1.58) and PLI (1.22) values were estimated for Cd and Pb, respectively, and maximum Igeo (?0.19) value was observed for Cd. Correlation analysis and principal component analysis suggested that common industrial sources for Cd and Pb were identified in the study sites. It clearly indicates that the significant levels of heavy metals pollution arise from local industries, busy commercial centers and heavy traffic load in the last few decades in heavily-populated and industrialized city. Further, soil heavy metals concentration were used to evaluate the human health risk such as chronic or non-carcinogenic including hazard indexes HIexP (ingestion, inhalation and dermal and carcinogenic) and cancer risk (CR). The HIexP values of Pb (10.30) and Cd (4.56) were found above the permissible limit (HI = 1) for children. The CR due to carcinogenic metals (Co, Cr and Cd) are within the safe limit (1E-06 to 1E-04). However, CR was comparatively higher in adults as compared to children. The results from the current investigation can help to develop a sustainable strategy in the study region to minimize the entry of heavy metals in food chain through source identification and pollution abatement techniques.  相似文献   

15.
This study investigated heavy metals concentration in groundwater in six coastal communities in Gokana, Rivers State, namely, Gbe, K-Dere, B-Dere, Mogho, Kpor and Bodo City and the human health risk posed to the local populace via ingestion and dermal contact using non-carcinogenic and carcinogenic health risk assessment. The mean values of the heavy metals ranged between 0.02–0.86, 0.16–0.19, 0.03–0.10, 0.02–0.03 and 0.01–0.17 for Mn, Ni, Pb, Cd and Cr, respectively. The heavy metals were above the drinking water quality recommended limits in all the study sites. Estimations of average daily dose (ADD) and dermal absorbed dose (DAD) health risk indicates that Mn, Ni and Pb posed human health risk via ingestion contact pathway. However, hazard index (HI) values of Cd and Cr for ingestion pathway were >1.0 and the estimated Lifetime of Carcinogenic Risks (LTCR) for Ni, Cd and Cr exceeded the predicted lifetime risk for carcinogens of 10?6 from ingestion pathway. Furthermore, there were more appreciable risk from Ni and Cr in the study sites as LTCR value in most sites were >10?4. This study indicates possible non-carcinogenic and carcinogenic human health hazard from groundwater consumption in Gokana via oral ingestion.  相似文献   

16.
This study presents the results of an analysis of combustion waste, namely fly ashes produced from the burning of solid fuels mixed with municipal waste. Heavy metal concentrations in the fly ashes examined fell within the following ranges (mg/kg): Cd 0.39–0.79, Cr 13.48–58.51, Ni 17.01–49.37 and Pb 14.95–59.74. As this type of waste does not exceed the limit values of pollutants for organic and organic-mineral fertilisers, it is often discarded on agricultural land or dumped in illegal landfills. Fine particles of fly ashes travel considerable distances and pose a risk to human health as they stick to people's hands during field works. The mean hazard quotient (HQ) values for non-carcinogenic forms of the elements analysed were 1.06E+00 for children and 1.47E-01 for adults. A HQ>1 indicates the probability of adverse health effects. The study has shown that the dominant exposure pathway was ingestion, which accounted for approx. 91% of total health risk, while the respective percentages for other pathways were less than 9% for dermal contact and 0.05% for inhalation. The highest health risk in the ingestion exposure pathway was observed for Cr (HQing = 4.50E-01 for children, HQing = 5.23E-02 for adults) and Pb (HQing = 4.31E-01 for children, HQing = 5.01E-02 for adults). Health risk associated with the presence of Ni and Cd in the material analysed was markedly lower. For carcinogenic forms, the Risk index was established at 6.13E-08 for children and 2.13E-07 for adults. As the exposure limit (10E-5) was not exceeded, the conditions in the area studied should be considered satisfactory.  相似文献   

17.
This study aimed to assess the drinking water quality and human potential health risk in Peshawar, which is the most populous district of Khyber Pakhtunkhwa Province, Pakistan. Water was randomly collected throughout Peshawar District (urban = 45 samples and rural = 29 samples). These samples were analyzed for heavy metal (As, Cd, Co, Cu, Cr, Hg, Ni, Pb, and Zn) concentrations using the atomic absorption spectrometer (Perkin Elmer, AAS-PEA-700). Heavy metal concentrations in drinking water revealed the highest pollution index (PI) values—17.80, 11.92, 7.50, and 5.70 for the Pb, Cr, Cd, and Ni, respectively. The contaminations of Cd and Pb were significantly higher (p < .05) than their maximum allowable limits set by the World Health Organization. Heavy metal contaminations in drinking water were evaluated for health risk assessment: the chronic risk or hazard quotient (HQ) and cancer risk. Results revealed that HQ values were >1 for the Cd and Pb, suggesting that the exposed human beings could be at chronic risk. Therefore, serious measures such as drinking water treatments and contamination controlling policies are needed to avoid the hazardous effects of toxic heavy metals.  相似文献   

18.
The investigation revealed the adverse health threats on human beings from toxic metals via ingestion of seafood from two contaminated sites in Odisha. Bioaccumulation through food chain was presented as tissue metal concentrations. The non-carcinogenic and carcinogenic health hazards were estimated by Target Hazard Quotient (THQ) and Target Cancer Risk (TCR) following USEPA referred safe metal intake limit. THQ of Metals like Mn, Ni, Cd, Pb in both sites showed >1, indicating a severe non carcinogenic health threat to humans from the investigated metals. THQ of Cu, Zn, Fe, Cr and Hg showed < 1, implying the least possible deleterious health effects. Cr was the most significant carcinogenic pollutant in both sites. The marine fish consumption of Dhamra site might cause extra 7 cases of cancer per 10000 populations due to higher Cr level (cancer risk 6.7 × 10?3). Carcinogenic risk of Ni and Pb were below the tolerable range of 10E-4. The presence of Cd in sea foods elevated cancer risks in both sites. The metal pollution index (MPI) indicated, the highest toxic metal bio accumulation was contributed by Arius arius species. Ilisha megaloptera and Lates calcarifer from Dhamra and Puri showed highest hazard index (HI) suggesting unaccountable non-carcinogenic health threat.  相似文献   

19.
The purpose of this study was to determine the contamination level, distribution, health risk and potential sources of Cr, Cd, Pb, Zn, Cu, Ni and As in 66 topsoil samples from industrial areas in Bandar Abbas County. The geoaccumulation index, pollution index and pollution load index were calculated to assess the pollution level in the industrial soils. The hazard index and carcinogenic risk were used to assess human health risk of heavy metals. Results showed that the contamination levels of heavy metals were in the descending order of Cu> Cd> Pb> Zn> As> Ni> Cr. Moreover, based on principal component analysis, Cd, Zn, Cu, and Pb originated mainly from anthropogenic sources, including power plants, oil and gas refinery, steel and zinc production factories and municipal waste landfills. For non-carcinogenic effects, hazard index of studied metals decreased in the order of Cr> As> Cd> Pb> Ni > Cu> Zn. Arsenic, chromium and cadmium were regarded as the priority pollutants. Carcinogenic risks due to Cd and As in suburban soils were within tolerable risk to human health; however, children faced more health risk in their daily life than adults via their unconscious ingestion and dermal contact pathway.  相似文献   

20.
Soil heavy metal pollution from mining activities is potentially harmful to human health through the food chain. In this study, a total of 43 soil samples were collected from a depth of 0–20 cm from fields close to a Pb and Zn smelter. The samples were used to: 1) analyze the pollution level of heavy metals (Pb, Zn, Cr, and Cu) and spatial distribution pattern; 2) evaluate the degree of accumulation and enrichment, potential ecological risk, and human health risk; and 3) perform source apportionment in Fengxiang County, Shaanxi Province of China. The results showed that the concentration ranged from 43.67 to 189.55, 131.43 to 239.53, 74.77 to 112.25, and 24.69 to 37.71 mg·kg?1 for Pb, Zn, Cr, and Cu, respectively, and the mean concentration for Pb, Zn, Cr, and Cu was 129.46, 192.85, 91.98 and 31.67 mg·kg?1, respectively. The concentrations were greater than the Shaanxi Province background values, while they were lower than the second-level limits of Environmental Quality Standard for Soils of China (EQSS). The spatial distribution of heavy metal contents showed a banded in soil except Cu. The spatial distribution pattern and pollution assessment indexes (Igeo, EF) indicated that the investigated metals had been accumulated in the study areas, and implied significant influences from anthropogenic activities, local meteorological situation, and soil properties. The ecological risk assessment showed that the risks were relatively low (RI<150). Compared with the exposure risk for adults, that for children was significantly greater. The ingestion of heavy metals in the soils by humans was the main exposure pathway compared with the dermal exposure. There may be a risk of noncarcinogenic adverse health effects (HQ < 1, 0.377 ≤ HI≤1.553) on children, but the adults were unlikely to experience obvious adverse health effects (HQ < 1, HI < 1). The carcinogenic risk of Cr for adults and children was at an unacceptable level. The carcinogenic and noncarcinogenic risks were in the order of children > adults. The correlation analysis showed that Pb, Cr, and Cu have identical anthropogenic and natural sources, while Zn has another identical source. This study could provide a basis for the sustainable management of this region by reducing metal inputs and to protect soils from long-term heavy metal accumulation.  相似文献   

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