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Advanced Phosphorus‐Based Materials for Lithium/Sodium‐Ion Batteries: Recent Developments and Future Perspectives
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High‐performance and lost‐cost lithium‐ion and sodium‐ion batteries are highly desirable for a wide range of applications including portable electronic devices, transportation (e.g., electric vehicles, hybrid vehicles, etc.), and renewable energy storage systems. Great research efforts have been devoted to developing alternative anode materials with superior electrochemical properties since the anode materials used are closely related to the capacity and safety characteristics of the batteries. With the theoretical capacity of 2596 mA h g?1, phosphorus is considered to be the highest capacity anode material for sodium‐ion batteries and one of the most attractive anode materials for lithium‐ion batteries. This work provides a comprehensive study on the most recent advancements in the rational design of phosphorus‐based anode materials for both lithium‐ion and sodium‐ion batteries. The currently available approaches to phosphorus‐based composites along with their merits and challenges are summarized and discussed. Furthermore, some present underpinning issues and future prospects for the further development of advanced phosphorus‐based materials for energy storage/conversion systems are discussed. 相似文献
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Lithium‐ion batteries (LIBs) have dominated the portable electronics industry and solid‐state electrochemical research and development for the past two decades. In light of possible concerns over the cost and future availability of lithium, sodium‐ion batteries (SIBs) and other new technologies have emerged as candidates for large‐scale stationary energy storage. Research in these technologies has increased dramatically with a focus on the development of new materials for both the positive and negative electrodes that can enhance the cycling stability, rate capability, and energy density. Two‐dimensional (2D) materials are showing promise for many energy‐related applications and particularly for energy storage, because of the efficient ion transport between the layers and the large surface areas available for improved ion adsorption and faster surface redox reactions. Recent research highlights on the use of 2D materials in these future ‘beyond‐lithium‐ion’ battery systems are reviewed, and strategies to address challenges are discussed as well as their prospects. 相似文献
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Rechargeable ion batteries have contributed immensely to shaping the modern world and been seriously considered for the efficient storage and utilization of intermittent renewable energies. To fulfill their potential in the future market, superior battery performance of high capacity, great rate capability, and long lifespan is undoubtedly required. In the past decade, along with discovering new electrode materials, the focus has been shifting more and more toward rational electrode designs because the performance is intimately connected to the electrode architectures, particularly their designs at the nanoscale that can alleviate the reliance on the materials' intrinsic nature. The utilization of nanoarchitectured arrays in the design of electrodes has been proven to significantly improve the battery performance. A comprehensive summary of the structural features and fabrications of the nanoarchitectured array electrodes is provided, and some of the latest achievements in the area of both lithium‐ and sodium‐ion batteries are highlighted. Finally, future challenges and opportunities that would allow further development of such advanced electrode configuration are discussed. 相似文献
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Metal‐Ion Batteries: Open‐Structured V2O5·nH2O Nanoflakes as Highly Reversible Cathode Material for Monovalent and Multivalent Intercalation Batteries (Adv. Energy Mater. 14/2017)
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Huali Wang Xuanxuan Bi Ying Bai Chuan Wu Sichen Gu Shi Chen Feng Wu Khalil Amine Jun Lu 《Liver Transplantation》2017,7(14)
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Jingyang Wang Yan Wang Dong‐Hwa Seo Tan Shi Shouping Chen Yaosen Tian Haegyeom Kim Gerbrand Ceder 《Liver Transplantation》2020,10(10)
Over the last decade, Na‐ion batteries have been extensively studied as low‐cost alternatives to Li‐ion batteries for large‐scale grid storage applications; however, the development of high‐energy positive electrodes remains a major challenge. Materials with a polyanionic framework, such as Na superionic conductor (NASICON)‐structured cathodes with formula NaxM2(PO4)3, have attracted considerable attention because of their stable 3D crystal structure and high operating potential. Herein, a novel NASICON‐type compound, Na4MnCr(PO4)3, is reported as a promising cathode material for Na‐ion batteries that deliver a high specific capacity of 130 mAh g?1 during discharge utilizing high‐voltage Mn2+/3+ (3.5 V), Mn3+/4+ (4.0 V), and Cr3+/4+ (4.35 V) transition metal redox. In addition, Na4MnCr(PO4)3 exhibits a high rate capability (97 mAh g?1 at 5 C) and excellent all‐temperature performance. In situ X‐ray diffraction and synchrotron X‐ray diffraction analyses reveal reversible structural evolution for both charge and discharge. 相似文献
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Supercapacitors: Design and Performance of Rechargeable Sodium Ion Batteries,and Symmetrical Li‐Ion Batteries with Supercapacitor‐Like Power Density Based upon Polyoxovanadates (Adv. Energy Mater. 6/2018)
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Jia‐Jia Chen Jian‐Chuan Ye Xia‐Guang Zhang Mark D. Symes Shao‐Cong Fan De‐Liang Long Ming‐Sen Zheng De‐Yin Wu Leroy Cronin Quan‐Feng Dong 《Liver Transplantation》2018,8(6)
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Yanjiao Ma Yuan Ma Gabriele Giuli Holger Euchner Axel Groß Giovanni Orazio Lepore Francesco d'Acapito Dorin Geiger Johannes Biskupek Ute Kaiser Hanno M. Schütz Anna Carlsson Thomas Diemant Rolf Jürgen Behm Matthias Kuenzel Stefano Passerini Dominic Bresser 《Liver Transplantation》2020,10(25)
The development of alternative anode materials with higher volumetric and gravimetric capacity allowing for fast delithiation and, even more important, lithiation is crucial for next‐generation lithium‐ion batteries. Herein, the development of a completely new active material is reported, which follows an insertion‐type lithiation mechanism, metal‐doped CeO2. Remarkably, the introduction of carefully selected dopants, herein exemplified for iron, results in an increase of the achievable capacity by more than 200%, originating from the reduction of the dopant to the metallic state and additional space for the lithium ion insertion due to a significant off‐centering of the dopant atoms in the crystal structure, away from the original Ce site. In addition to the outstanding performance of such materials in high‐power lithium‐ion full‐cells, the selective reduction of the iron dopant under preservation of the crystal structure of the host material is expected to open up a new field of research. 相似文献
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Lithium‐ion batteries (LIBs) with outstanding energy and power density have been extensively investigated in recent years, rendering them the most suitable energy storage technology for application in emerging markets such as electric vehicles and stationary storage. More recently, sodium, one of the most abundant elements on earth, exhibiting similar physicochemical properties as lithium, has been gaining increasing attention for the development of sodium‐ion batteries (SIBs) in order to address the concern about Li availability and cost—especially with regard to stationary applications for which size and volume of the battery are of less importance. Compared with traditional intercalation reactions, conversion reaction‐based transition metal oxides (TMOs) are prospective anode materials for rechargeable batteries thanks to their low cost and high gravimetric specific capacities. In this review, the recent progress and remaining challenges of conversion reactions for LIBs and SIBs are discussed, covering an overview about the different synthesis methods, morphological characteristics, as well as their electrochemical performance. Potential future research directions and a perspective toward the practical application of TMOs for electrochemical energy storage are also provided. 相似文献
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Songping Wu Rui Xu Mingjia Lu Rongyun Ge James Iocozzia Cuiping Han Beibei Jiang Zhiqun Lin 《Liver Transplantation》2015,5(21)
Graphene‐containing nanomaterials have emerged as important candidates for electrode materials in lithium‐ion batteries (LIBs) due to their unique physical properties. In this review, a brief introduction to recent developments in graphene‐containing nanocomposite electrodes and their derivatives is provided. Subsequently, synthetic routes to nanoparticle/graphene composites and their electrochemical performance in LIBs are highlighted, and the current state‐of‐the‐art and most recent advances in the area of graphene‐containing nanocomposite electrode materials are summarized. The limitations of graphene‐containing materials for energy storage applications are also discussed, with an emphasis on anode and cathode materials. Potential research directions for the future development of graphene‐containing nanocomposites are also presented, with an emphasis placed on practicality and scale‐up considerations for taking such materials from benchtop curiosities to commercial products. 相似文献