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1.
Rational Design of Nickel Hydroxide‐Based Nanocrystals on Graphene for Ultrafast Energy Storage
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Bote Zhao Lei Zhang Qiaobao Zhang Dongchang Chen Yong Cheng Xiang Deng Yu Chen Ryan Murphy Xunhui Xiong Bo Song Ching‐Ping Wong Ming‐Sheng Wang Meilin Liu 《Liver Transplantation》2018,8(9)
Compact, light, and powerful energy storage devices are urgently needed for many emerging applications; however, the development of advanced power sources relies heavily on advances in materials innovation. Here, the findings in rational design, one‐pot synthesis, and characterization of a series of Ni hydroxide‐based electrode materials in alkaline media for fast energy storage are reported. Under the guidance of density functional theory calculations and experimental investigations, a composite electrode composed of Co‐/Mn‐substituted Ni hydroxides grown on reduced graphene oxide (rGO) is designed and prepared, demonstrating capacities of 665 and 427 C g?1 at current densities of 2 and 20 A g?1, respectively. The superior performance is attributed mainly to the low deprotonation energy and the facile electron transport, as elaborated by theoretical calculations. When coupled with an electrode based on organic molecular‐modified rGO, the resulting hybrid device demonstrates an energy density of 74.7 W h kg?1 at a power density of 1.68 kW kg?1 while maintaining capacity retention of 91% after 10,000 cycles (20 A g?1). The findings not only provide a promising electrode material for high‐performance hybrid capacitors but also open a new avenue toward knowledge‐based design of efficient electrode materials for other energy storage applications. 相似文献
2.
Geon‐Hyoung An John Hong Sangyeon Pak Yuljae Cho Sanghyo Lee Bo Hou SeungNam Cha 《Liver Transplantation》2020,10(3)
Recent supercapacitors show a high power density with long‐term cycle life time in energy‐powering applications. A supercapacitor based on a single metal electrode accompanying multivalent cations, multiple charging/discharging kinetics, and high electrical conductivity is a promising energy‐storing system that replaces conventionally used oxide and sulfide materials. Here, a hierarchically nanostructured 2D‐Zn metal electrode‐ion supercapacitor (ZIC) is reported which significantly enhances the ion diffusion ability and overall energy storage performance. Those nanostructures can also be successfully plated on various flat‐type and fiber‐type current collectors by a controlled electroplating method. The ZIC exhibits excellent pseudocapacitive performance with a high energy density of 208 W h kg?1 and a power density from 500 W kg?1, which are significantly higher than those of previously reported supercapacitors with oxide and sulfide materials. Furthermore, the fiber‐type ZIC also shows high energy‐storing performance, outstanding mechanical flexibility, and waterproof characteristics, without any significant capacitance degradation during bending tests. These results highlight the promising possibility of nanostructured 2D Zn metal electrodes with the controlled electroplating method for future energy storage applications. 相似文献
3.
Jiali Yu Jie Zhou Pingping Yao Hui Xie Meng Zhang Muwei Ji Huichao Liu Qian Liu Caizhen Zhu Jian Xu 《Liver Transplantation》2019,9(44)
Advanced 2D materials have spurred great interest as a new paradigm in pursuing improved energy storage performance. Herein, for the first time, antimonene is utilized as an effective active component for constructing highly deformable and editable freestanding film electrodes, as the basis of a supercapacitor with record‐breaking electrode performance. The insertion of antimonene is able to improve the environmental stability of the antimonene/MXene composite electrode and remarkably enhance the energy storage capability in both protic and neutral electrolytes. Notably, an ultrahigh specific volumetric capacitance of 4255 F cm?3 is achieved by the electrode tested in a1 m H2SO4 electrolyte, which represents the state‐of‐the‐art value reported to date for supercapacitor electrodes based on MXenes. The flexible supercapacitors constructed by the composite electrode, also demonstrate highly competitive energy and power densities: 459.75 mWh cm?3 and 3.12 W cm?3 for the asymmetrical one with a much widened potential window of 2 V in neutral electrolyte; 112.52 mWh cm?3 and 1 W cm?3 for the symmetrical configuration with an outstanding capacitance of 1265 F cm?3 in acidic media. This work sheds new light on the fabrication of high‐performance supercapacitor electrodes with functionalities in different electrolyte media and various device configurations. 相似文献
4.
Aamir Razaq Leif Nyholm Martin Sjödin Maria Strømme Albert Mihranyan 《Liver Transplantation》2012,2(4):445-454
Composites of polypyrrole (PPy) and Cladophora nanocellulose, reinforced with 8 μm‐thick chopped carbon filaments, can be used as electrode materials to obtain paper‐based energy‐storage devices with unprecedented performance at high charge and discharge rates. Charge capacities of more than 200 C g?1 (PPy) are obtained for paper‐based electrodes at potential scan rates as high as 500 mV s?1, whereas cell capacitances of ~60–70 F g?1 (PPy) are reached for symmetric supercapacitor cells with capacitances up to 3.0 F (i.e.,0.48 F cm?2) when charged to 0.6 V using current densities as high as 31 A g?1 based on the PPy weight (i.e., 99 mA cm?2). Energy and power densities of 1.75 Wh kg?1 and 2.7 kW kg?1, respectively, are obtained when normalized with respect to twice the PPy weight of the smaller electrode. No loss in cell capacitance is seen during charging/discharging at 7.7 A g?1 (PPy) over 1500 cycles. It is proposed that the nonelectroactive carbon filaments decrease the contact resistances and the resistance of the reduced PPy composite. The present straightforward approach represents significant progress in the development of low‐cost and environmentally friendly paper‐based energy‐storage devices for high‐power applications. 相似文献
5.
Interconnected Frameworks with a Sandwiched Porous Carbon Layer/Graphene Hybrids for Supercapacitors with High Gravimetric and Volumetric Performances
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A facile approach to synthesize porous disordered carbon layers as energy storage units coating on graphene sheets to form interconnected frameworks by one‐step pyrolysis of the mixture of graphene oxide/polyaniline and KOH is presented. As effective energy storage units, these porous carbon layers play an important role in enhancing the electrochemical performances. The obtained porous carbon material exhibits a high specific surface area (2927 m2 g?1), hierarchical interconnected pores, moderate pore volume (1.78 cm3 g?1), short ion diffusion paths, and a high nitrogen level (6 at%). It displays both unparalleled gravimetric (481 F g?1) and outstanding volumetric capacitance (212 F cm?3) in an aqueous electrolyte. More importantly, the assembled symmetrical supercapacitor delivers not only high gravimetric (25.7 Wh kg?1 based on total mass of electroactive materials) but also high volumetric energy densities (11.3 Wh L?1) in an aqueous electrolyte. Furthermore, the assembled asymmetric supercapacitor yields a maximum energy density up to 88 Wh kg?1, which is, to the best of our knowledge, the highest value so far reported for carbon//MnO2 asymmetric supercapacitors in aqueous electrolytes. Therefore, this novel carbon material holds great promise for potential applications in energy‐related technological fields. 相似文献
6.
Huarong Peng Bin Yao Xijun Wei Tianyu Liu Tianyi Kou Peng Xiao Yunhuai Zhang Yat Li 《Liver Transplantation》2019,9(19)
Carbonaceous materials are attractive supercapacitor electrode materials due to their high electronic conductivity, large specific surface area, and low cost. Here, a unique hierarchical porous N,O,S‐enriched carbon foam (KNOSC) with high level of structural complexity for supercapacitors is reported. It is fabricated via a combination of a soft‐template method, freeze‐drying, and chemical etching. The carbon foam is a macroporous structure containing a network of mesoporous channels filled with micropores. It has an extremely large specific surface area of 2685 m2 g?1. The pore engineered carbon structure is also uniformly doped with N, O, and S. The KNOSC electrode achieves an outstanding capacitance of 402.5 F g?1 at 1 A g?1 and superior rate capability of 308.5 F g?1 at 100 A g?1. The KNOSC exhibits a Bode frequency at the phase angle of ?45° of 18.5 Hz, which corresponds to a time constant of 0.054 s only. A symmetric supercapacitor device using KNOSC as electrodes can be charged/discharged within 1.52 s to deliver a specific energy density of 15.2 W h kg?1 at a power density of 36 kW kg?1. These results suggest that the pore and heteroatom engineered structures are promising electrode materials for ultrafast charging. 相似文献
7.
Metal–Organic Framework Derived Honeycomb Co9S8@C Composites for High‐Performance Supercapacitors
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Shixiong Sun Jiahuan Luo Yong Qian Yu Jin Yi Liu Yuegang Qiu Xiang Li Chun Fang Jiantao Han Yunhui Huang 《Liver Transplantation》2018,8(25)
Unique nanostructures always lead to extraordinary electrochemical energy storage performance. Here, the authors report a new strategy for using Metal‐organic frameworks (MOFs) derived cobalt sulfide in a carbon matrix with a 3D honeycombed porous structure, resulting in a high‐performance supercapacitor with unrivalled capacity of ≈1887 F g‐1 at the current density of 1 A g‐1. The honeycomb‐like structure of Co9S8@C composite is loosely adsorbed, with plentiful surface area and high conductivity, leading to improved Faradaic processes across the interface and enhanced redox reactions at active Co9S8 sites. Therefore, the heterostructure‐fabricated hybrid supercapacitor, using activated carbon as the counter electrode, demonstrates a high energy density of 58 Wh kg‐1 at the power density of 1000 W kg‐1. Even under an ultrahigh power density of 17 200 W kg‐1, its energy density maintains ≈38 Wh kg‐1. The hybrid supercapacitor also exhibits suitable cycling stability, with ≈90% capacity retention after 10 000 continuous cycles at the current density of 5 A g‐1. This work presents a practical method for using MOFs as sacrificial templates to synthesize metal‐sulfides for highly efficient electrochemical energy storage. 相似文献
8.
Kaiping Wang Lifeng Huang Naresh Eedugurala Song Zhang Md Abdus Sabuj Neeraj Rai Xiaodan Gu Jason D. Azoulay Tse Nga Ng 《Liver Transplantation》2019,9(47)
Supercapacitors have emerged as an important energy storage technology offering rapid power delivery, fast charging, and long cycle lifetimes. While extending the operational voltage is improving the overall energy and power densities, progress remains hindered by a lack of stable n‐type redox‐active materials. Here, a new Faradaic electrode material comprised of a narrow bandgap donor?acceptor conjugated polymer is demonstrated, which exhibits an open‐shell ground state, intrinsic electrical conductivity, and enhanced charge delocalization in the reduced state. These attributes afford very stable anodes with a coulombic efficiency of 99.6% and that retain 90% capacitance after 2000 charge–discharge cycles, exceeding other n‐dopable organic materials. Redox cycling processes are monitored in situ by optoelectronic measurements to separate chemical versus physical degradation mechanisms. Asymmetric supercapacitors fabricated using this polymer with p‐type PEDOT:PSS operate within a 3 V potential window, with a best‐in‐class energy density of 30.4 Wh kg?1 at a 1 A g?1 discharge rate, a power density of 14.4 kW kg?1 at a 10 A g?1 discharge rate, and a long cycle life critical to energy storage and management. This work demonstrates the application of a new class of stable and tunable redox‐active material for sustainable energy technologies. 相似文献
9.
NiCo2S4 Nanosheets Grown on Nitrogen‐Doped Carbon Foams as an Advanced Electrode for Supercapacitors
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To push the energy density limit of supercapacitors, a new class of electrode materials with favorable architectures is strongly needed. Binary metal sulfides hold great promise as an electrode material for high‐performance energy storage devices because they offer higher electrochemical activity and higher capacity than mono‐metal sulfides. Here, the rational design and fabrication of NiCo2S4 nanosheets supported on nitrogen‐doped carbon foams (NCF) is presented as a novel flexible electrode for supercapacitors. A facile two‐step method is developed for growth of NiCo2S4 nanosheets on NCF with robust adhesion, involving the growth of Ni‐Co precursor and subsequent conversion into NiCo2S4 nanosheets through sulfidation process. Benefiting from the compositional features and 3D electrode architectures, the NiCo2S4/NCF electrode exhibits greatly improved electrochemical performance with ultrahigh capacitance (877 F g?1 at 20 A g?1) and excellent cycling stability. Moreover, a binder‐free asymmetric supercapacitor device is also fabricated by using NiCo2S4/NCF as the positive electrode and ordered mesoporous carbon (OMC)/NCF as the negative electrode; this demonstrates high energy density (≈45.5 Wh kg?1 at 512 W kg?1). 相似文献
10.
A High‐Energy Density Asymmetric Supercapacitor Based on Fe2O3 Nanoneedle Arrays and NiCo2O4/Ni(OH)2 Hybrid Nanosheet Arrays Grown on SiC Nanowire Networks as Free‐Standing Advanced Electrodes
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Jian Zhao Zhenjiang Li Xiangcheng Yuan Zhen Yang Meng Zhang Alan Meng Qingdang Li 《Liver Transplantation》2018,8(12)
In this paper, a novel freestanding core‐branch negative and positive electrode material through integrating trim aligned Fe2O3 nanoneedle arrays (Fe2O3 NNAs) is first proposed with typical mesoporous structures and NiCo2O4/Ni(OH)2 hybrid nanosheet arrays (NiCo2O4/Ni(OH)2 HNAs) on SiC nanowire (SiC NW) skeletons with outstanding resistance to oxidation and corrosion, good conductivity, and large‐specific surface area. The original built SiC NWs@Fe2O3 NNAs is validated to be a highly capacitive negative electrode (721 F g?1 at 2 A g?1, i.e., 1 F cm?2 at 2.8 mA cm?2), matching well with the similarly constructed SiC NWs@NiCo2O4/Ni(OH)2 HNAs positive electrode (2580 F g?1 at 4 A g?1, i.e., 3.12 F cm?2 at 4.8 mA cm?2). Contributed by the uniquely engineered electrodes, a high‐performance asymmetric supercapacitor (ASC) is developed, which can exhibit a maximum energy density of 103 W h kg?1 at a power density of 3.5 kW kg?1, even when charging the device within 6.5 s, the energy density can still maintain as high as 45 W h kg?1 at 26.1 kW kg?1, and the ASC manifests long cycling lifespan with 86.6% capacitance retention even after 5000 cycles. This pioneering work not only offers an attractive strategy for rational construction of high‐performance SiC NW‐based nanostructured electrodes materials, but also provides a fresh route for manufacturing next‐generation high‐energy storage and conversion systems. 相似文献
11.
Tremendous research efforts are devoted to developing wide potential window aqueous supercapacitors to resolve their low energy density concern. While the operational potential window is dictated by the intrinsic electrochemical stability of water (1.23 V), such a bottleneck may be surpassed by leveraging the additional overpotential of the oxygen evolution reaction and the hydrogen evolution reaction (HER). Herein, by employing an electroreduction technique, Na+ is adsorbed onto the carbon negative electrode which effectively acts as a physical barrier to hinder intermediate HER product formation, thereby reducing HER activity. To complement the wide potential carbon electrode, Na0.25MnO2 is employed as the positive electrode to take advantage of the extra energy (i.e., increased overpotential) required for Na+ insertion process into the structure. The asymmetric supercapacitor exhibits high energy density of 61.1 W h kg?1 at a power density of 982 W kg?1, and even at an ultrahigh power density of 42.9 kW kg?1, a respectable energy density of 16.3 W h kg?1 is attained. In addition, 93.7% capacitance retention is recorded after cycling for 10 000 cycles which further demonstrates its suitability as supercapacitor. The present success in fabricating a 2.7 V asymmetric supercapacitor will open a promising research route toward achieving high energy density and high power density. 相似文献
12.
Shuilin Wu Yatu Chen Tianpeng Jiao Jun Zhou Junye Cheng Bin Liu Shaoran Yang Kaili Zhang Wenjun Zhang 《Liver Transplantation》2019,9(47)
Integrating a battery‐type electrode to build a hybrid supercapacitor is a promising approach to improve the overall energy density of a supercapacitor‐type energy storage device without sacrificing its power output. However, this strategy is usually achieved at the expense of cycling lifespan. In this work, a hybrid supercapacitor comprising Zn foil and porous carbon derived from chemical activated graphene (aMEGO) is developed, and the trade‐off between energy density and cycling life is well‐balanced by the utilization of 3 m Zn(CF3SO3)2 electrolyte with high Zn stripping/plating efficiency. Such a hybrid supercapacitor demonstrates an energy density of 106.3 Wh kg?1 and a power density of 31.4 kW kg?1, and significantly a wide operation voltage of 1.9 V is achieved in aqueous electrolyte. Benefitting from the high Zn stripping/plating efficiency, the Zn‐aMEGO hybrid‐supercapacitor also exhibits an ultralong cycling life up to 80 000 cycles with capacity retention of 93%, which is comparable to that of conventional electrochemical double‐layer capacitors. 相似文献
13.
Mulberry Paper‐Based Supercapacitor Exhibiting High Mechanical and Chemical Toughness for Large‐Scale Energy Storage Applications
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Tae Gwang Yun Donghyuk Kim Sang‐Min Kim Il‐Doo Kim Seungmin Hyun Seung Min Han 《Liver Transplantation》2018,8(21)
In response to the demand for flexible and sustainable energy storage devices that exhibit high electrochemical performance, a supercapacitor system is fabricated using mulberry tree‐derived paper as a substrate and Poly(3,4‐ethylenedioxythiophene)‐poly(styrenesulfonate) (PEDOT:PSS) and carbon black as the active material. The mulberry paper‐based supercapacitor system demonstrates high energy density of 29.8–39.8 Wh kg?1 and power density of 2.8–13.9 kW kg?1 with 90.7% retention of its initial capacity over 15 000 charge–discharge cycles. In addition, the mulberry tree fibers are known to have superior mechanical strength and toughness and the mulberry paper‐based supercapacitor; as a result, exhibit high mechanical and chemical toughness; 99% of its initial capacity is retained after 100 repeated applications of bending strains, and twisting. 94% capacity retention is observed even after exposure to HCl and H2SO4 acid solutions. The fabrication methodology of the mulberry‐based supercapacitor is highly scalable and could be stacked to increase the energy storage capacity, where operation of light‐emitting diode lights with a drive voltage of 12 V integrated in a wearable device is demonstrated. 相似文献
14.
Here, a simple active materials synthesis method is presented that boosts electrode performance and utilizes a facile screen‐printing technique to prepare scalable patterned flexible supercapacitors based on manganese hexacyanoferrate‐manganese oxide and electrochemically reduced graphene oxide electrode materials (MnHCF‐MnOx/ErGO). A very simple in situ self‐reaction method is developed to introduce MnOx pseudocapacitor material into the MnHCF system by using NH4F. This MnHCF‐MnOx electrode materials can deliver excellent capacitance of 467 F g?1 at a current density of 1 A g?1, which is a 2.4 times capacitance increase compared to MnHCF. In addition a printed, patterned, flexible MnHCF‐MnOx/ErGO supercapacitor is fabricated, showing a remarkable areal capacitance of 16.8 mF cm?2 and considerable energy and power density of 0.5 mWh cm?2 and 0.0023 mW cm?2, respectively. Furthermore, the printed patterned flexible supercapacitors also exhibit exceptional flexibility, and the capacitance remains stable, even while bending to various angles (60°, 90°, and 180°) and for 100 cycles. The flexible supercapacitor arrays integrated by multiple prepared single supercapacitors can power various LEDs even in the bent states. This approach offers promising opportunities for the development of printable energy storage materials and devices with high energy density, large scalability, and excellent flexibility. 相似文献
15.
Yuxiang Hu Yang Bai Bin Luo Songcan Wang Han Hu Peng Chen Miaoqiang Lyu Joe Shapter Alan Rowan Lianzhou Wang 《Liver Transplantation》2019,9(28)
The solar‐rechargeable electric energy storage systems (SEESSs), which can simultaneously harvest and store solar energy, are considered a promising next‐generation renewable energy supply system. However, the difficulty in meeting the demands of higher overall photoelectric conversion and storage efficiency (PCSE) with both high power density and large energy density in the current SEESSs severely limit their practical application. Herein, a new class is demonstrated of portable and highly efficient SEESS that uniquely integrates a perovskite solar module (PSM) and an aluminum‐ion battery (AIB) directly on a bifunctional aluminum electrode without any external circuit. Such nanostructural design in the SEESS not only exhibits fast photo‐charge/discharge rate (less than one minute) with high power density (above 5000 W kg?1), but also delivers a high energy density (above 43 Wh kg?1). By rationally matching the maximum power point voltage of PSM with AIB charging voltage, an excellent solar‐charging efficiency of 15.2% and a high PCSE of 12.04% are achieved, which is among the best in all reported portable SEESSs. Moreover, enhanced PCSE is observed as the light intensity decreases, which makes such SEESS immune from the geographical location and climate limitations for diverse practical applications. 相似文献
16.
John B. Cook Hyung‐Seok Kim Terri C. Lin Chun‐Han Lai Bruce Dunn Sarah H. Tolbert 《Liver Transplantation》2017,7(2)
A synthesis methodology is demonstrated to produce MoS2 nanoparticles with an expanded atomic lamellar structure that are ideal for Faradaic‐based capacitive charge storage. While much of the work on MoS2 focuses on the high capacity conversion reaction, that process is prone to poor reversibility. The pseudocapacitive intercalation‐based charge storage reaction of MoS2 is investigated, which is extremely fast and highly reversible. A major challenge in the field of pseudocapacitive‐based energy storage is the development of thick electrodes from nanostructured materials that can sustain the fast inherent kinetics of the active nanocrystalline material. Here a composite electrode comprised of a poly(acrylic acid) binder, carbon fibers, and carbon black additives is utilized. These electrodes deliver a specific capacity of 90 mAh g?1 in less than 20 s and can be cycled 3000 times while retaining over 80% of the original capacity. Quantitative kinetic analysis indicates that over 80% of the charge storage in these MoS2 nanocrystals is pseudocapacitive. Asymmetric full cell devices utilizing a MoS2 nanocrystal‐based electrode and an activated carbon electrode achieve a maximum power density of 5.3 kW kg?1 (with 6 Wh kg?1 energy density) and a maximum energy density of 37 Wh kg?1 (with 74 W kg?1power density). 相似文献
17.
Xiaochuan Ren Zhiguo Ren Qingwei Li Wen Wen Xiaofang Li Ye Chen Lei Xie Liao Zhang Daming Zhu Biao Gao Paul K. Chu Kaifu Huo 《Liver Transplantation》2019,9(16)
Sodium‐ion capacitors (SICs) are emerging energy storage devices with high energy, high power, and durable life. Sn is a promising anode material for lithium storage, but the poor conductivity of the a‐NaSn phase upon sodaition hinders its implementation in SICs. Herein, a superior Sn‐based anode material consisting of plum pudding‐like Co2P/Sn yolk encapsulated with nitrogen‐doped carbon nanobox (Co2P/Sn@NC) for high‐performance SICs is reported. The 8–10 nm metallic nanoparticles produced in situ are uniformly dispersed in the amorphous Sn matrix serving as conductive fillers to facilitate electron transfer in spite of the formation of electrically resistive a‐NaSn phase during cycling. Meanwhile, the carbon shell buffers the large expansion of active Sn and provides a stable electrode–electrolyte interface. Owing to these merits, the yolk–shell Co2P/Sn@NC demonstrates a large capacity of 394 mA h g?1 at 100 mA g?1, high rate capability of 168 mA h g?1 at 5000 mA g?1, and excellent cyclability with 87% capacity retention after 10 000 cycles. By integrating the Co2P/Sn@NC anode with a peanut shell‐derived carbon cathode in the SIC, high energy densities of 112.3 and 43.7 Wh kg?1 at power densities of 100 and 10 000 W kg?1 are achieved. 相似文献
18.
Potassium ion hybrid capacitors have great potential for large‐scale energy devices, because of the high power density and low cost. However, their practical applications are hindered by their low energy density, as well as electrolyte decomposition and collector corrosion at high potential in potassium bis(fluoro‐sulfonyl)imide‐based electrolyte. Therefore, anode materials with high capacity, a suitable voltage platform, and stability become a key factor. Here, N‐doping carbon‐coated FeSe2 clusters are demonstrated as the anode material for a hybrid capacitor, delivering a reversible capacity of 295 mAh g?1 at 100 mA g?1 over 100 cycles and a high rate capability of 158 mAh g?1 at 2000 mA g?1 over 2000 cycles. Meanwhile, through density functional theory calculations, in situ X‐ray diffraction, and ex situ transmission electron microscopy, the evolution of FeSe2 to Fe3Se4 for the electrochemical reaction mechanism is successfully revealed. The battery‐supercapacitor hybrid using commercial activated carbon as the cathode and FeSe2/N‐C as the anode is obtained. It delivers a high energy density of 230 Wh kg?1 and a power density of 920 W kg?1 (the energy density and power density are calculated based on the total mass of active materials in the anode and cathode). 相似文献
19.
A Novel Sustainable Flour Derived Hierarchical Nitrogen‐Doped Porous Carbon/Polyaniline Electrode for Advanced Asymmetric Supercapacitors
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Pingping Yu Zhiming Zhang Lingxia Zheng Feng Teng Linfeng Hu Xiaosheng Fang 《Liver Transplantation》2016,6(20)
Hierarchically porous nitrogen‐doped carbon (HPC)/polyaniline (PANI) nanowire arrays nanocomposites are synthesized by a facile in situ polymerization. 3D interconnected honeycomb‐like HPC was prepared by a cost‐effective route via one‐step carbonization using urea and alkali‐treated wheat flour as carbon precursor with a high specific surface area (1294 m2 g?1). The specific capacitances of HPC and HPC/PANI (with a surface area of 923 m2 g?1) electrode are 383 and 1080 F g?1 in 1 m H2SO4, respectively. Furthermore, an asymmetric supercapacitor based on HPC/PANI as positive electrode and HPC as negative electrode is successfully assembled with a voltage window of 0–1.8 V in 1 m Na2SO4 aqueous electrolyte, exhibiting high specific capacitance (134 F g?1), high energy density (60.3 Wh kg?1) and power density (18 kW kg?1), and excellent cycling stability (91.6% capacitance retention after 5000 cycles). 相似文献
20.
Design and Performance of Rechargeable Sodium Ion Batteries,and Symmetrical Li‐Ion Batteries with Supercapacitor‐Like Power Density Based upon Polyoxovanadates
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Jia‐Jia Chen Jian‐Chuan Ye Xia‐Guang Zhang Mark D. Symes Shao‐Cong Fan De‐Liang Long Ming‐Sen Zheng De‐Yin Wu Leroy Cronin Quan‐Feng Dong 《Liver Transplantation》2018,8(6)
The polyanion Li7V15O36(CO3) is a nanosized molecular cluster (≈1 nm in size), that has the potential to form an open host framework with a higher surface‐to‐bulk ratio than conventional transition metal oxide electrode materials. Herein, practical rechargeable Na‐ion batteries and symmetric Li‐ion batteries are demonstrated based on the polyoxovanadate Li7V15O36(CO3). The vanadium centers in {V15O36(CO3)} do not all have the same VIV/V redox potentials, which permits symmetric devices to be created from this material that exhibit battery‐like energy density and supercapacitor‐like power density. An ultrahigh specific power of 51.5 kW kg?1 at 100 A g?1 and a specific energy of 125 W h kg?1 can be achieved, along with a long cycling life (>500 cycles). Moreover, electrochemical and theoretical studies reveal that {V15O36(CO3)} also allows the transport of large cations, like Na+, and that it can serve as the cathode material for rechargeable Na‐ion batteries with a high specific capacity of 240 mA h g?1 and a specific energy of 390 W h kg?1 for the full Na‐ion battery. Finally, the polyoxometalate material from these electrochemical energy storage devices can be easily extracted from spent electrodes by simple treatment with water, providing a potential route to recycling of the redox active material. 相似文献