共查询到20条相似文献,搜索用时 15 毫秒
1.
Huan Li Ying Tao Chen Zhang Donghai Liu Jiayan Luo Weichao Fan Yue Xu Youzhi Li Conghui You Zheng‐Ze Pan Mingchun Ye Zhengyu Chen Zhang Dong Da‐Wei Wang Feiyu Kang Jun Lu Quan‐Hong Yang 《Liver Transplantation》2018,8(18)
Despite the outstanding gravimetric performance of lithium–sulfur (Li–S) batteries, their practical volumetric energy density is normally lower than that of lithium‐ion batteries, mainly due to the low density of nanostructured sulfur as well as the porous carbon hosts. Here, a novel approach is developed to fabricate high‐density graphene bulk materials with “ink‐bottle‐like” mesopores by phosphoric acid (H3PO4) activation. These pores can effectively confine the polysulfides due to their unique structure with a wide body and narrow neck, which shows only a 0.05% capacity fade per cycle for 500 cycles (75% capacity retention) for accommodating polysulfides. With a density of 1.16 g cm?3, a hybrid cathode containing 54 wt% sulfur delivers a high volumetric capacity of 653 mA h cm?3. As a result, a device‐level volumetric energy density as high as 408 W h L?1 is achieved with a cathode thickness of 100 µm. This is a periodic yet practical advance to improve the volumetric performance of Li–S batteries from a device perspective. This work suggests a design principle for the real use Li–S batteries although there is a long way ahead to bridge the gap between Li–S batteries and Li–ion batteries in volumetric performance. 相似文献
2.
Lithium‐sulfur (Li‐S) batteries are considered to be one of the promising next‐generation energy storage systems. Considerable progress has been achieved in sulfur composite cathodes, but high cycling stability and discharging capacity at the expense of volumetric capacity have offset their advantages. Herein, a functional separator is presented by coating cobalt‐embedded nitrogen‐doped porous carbon nanosheets and graphene on one surface of a commercial polypropylene separator. The coating layer not only suppresses the polysulfide shuttle effect through chemical affinity, but also functions as an electrocatalyst to propel catalytic conversion of intercepted polysulfides. The slurry‐bladed carbon nanotubes/sulfur cathode with 90 wt% sulfur deliver high reversible capacity of 1103 mA h g?1 and volumetric capacity of 1062 mA h cm?3 at 0.2 C, and the freestanding carbon nanofibers/sulfur cathode provides a high discharging capacity of 1190 mA h g?1 and volumetric capacity of 1136 mA h cm?3 at high sulfur content of 78 wt% and sulfur loading of 10.5 mg cm?2. The electrochemical performance is comparable with or even superior to those in the state‐of‐the‐art carbon‐based sulfur cathodes. The separator reported in this work holds great promise for the development of high‐energy‐density Li‐S batteries. 相似文献
3.
Selenium–sulfur solid solutions are a class of potential cathode materials for high energy batteries, since they have higher theoretical capacities than selenium and improved conductivity over sulfur. Here, a high‐performance cathode material by confining 70 wt% of SeS2 in a highly ordered mesoporous carbon (CMK‐3) framework with a polydopamine (PDA) protection sheath for novel Li–Se/S batteries is reported. With a relatively high SeS2 mass loading of 2.6–3 mg cm?2, the CMK‐3/SeS2@PDA cathode exhibits a high capacity of >1200 mA h g?1 at 0.2 A g?1, excellent C‐rate capability of 535 mA h g?1 at 5 A g?1, and prolonged life over 500 cycles. Benefitting from the unique advantages of SeS2 and the rationally designed host framework, this new cathode material demonstrates a feasible strategy to overcome the bottlenecks of current Li–S systems for high energy density rechargeable batteries. 相似文献
4.
Long Cycle Life,Low Self‐Discharge Sodium–Selenium Batteries with High Selenium Loading and Suppressed Polyselenide Shuttling
下载免费PDF全文
![点击此处可从《Liver Transplantation》网站下载免费的PDF全文](/ch/ext_images/free.gif)
The use of selenium as a cathode in rechargeable sodium–selenium batteries is hampered by low Se loading, inferior electrode kinetics, and polyselenide shuttling between the cathode and anode. Here a high‐performance sodium–selenium cell is presented by coupling a binder‐free, self‐interwoven carbon nanofiber–selenium cathode with a light‐weight carbon‐coated bifunctional separator. With this strategy, electrodes with a high Se mass loading (4.4 mg cm?2) render high reversible capacities of 599 mA h g?1 at 0.1C rate and 382 mA h g?1 at 5C rate. In addition, this novel cell offers good shelf‐life with a low self‐discharge, retaining 93.4% of its initial capacity even after resting for six months. As evidenced by experimental and density functional theory analysis, the remarkable dynamic (cycle life) and static (shelf‐life) stabilities originate from the high electrical conductivity, improved Na‐ion accessibility through the 3D interconnected open channels, and highly restrained polyselenide shuttle. The results demonstrate the viability of high‐performance sodium–selenium batteries with high selenium loading. 相似文献
5.
Hierarchical Zn–Co–S Nanowires as Advanced Electrodes for All Solid State Asymmetric Supercapacitors
下载免费PDF全文
![点击此处可从《Liver Transplantation》网站下载免费的PDF全文](/ch/ext_images/free.gif)
A facile two‐step strategy is developed to design the large‐scale synthesis of hierarchical, unique porous architecture of ternary metal hydroxide nanowires grown on porous 3D Ni foam and subsequent effective sulfurization. The hierarchical Zn–Co–S nanowires (NWs) arrays are directly employed as an electrode for supercapacitors application. The as‐synthesized Zn–Co–S NWs deliver an ultrahigh areal capacity of 0.9 mA h cm?2 (specific capacity of 366.7 mA h g?1) at a current density of 3 mA cm?2, with an exceptional rate capability (≈227.6 mA h g?1 at a very high current density of 40 mA cm?2) and outstanding cycling stability (≈93.2% of capacity retention after 10 000 cycles). Most significantly, the assembled Zn–Co–S NWs//Fe2O3@reduced graphene oxide asymmetric supercapacitors with a wide operating potential window of ≈1.6 V yield an ultrahigh volumetric capacity of ≈1.98 mA h cm?3 at a current density of 3 mA cm?2, excellent energy density of ≈81.6 W h kg?1 at a power density of ≈559.2 W kg?1, and exceptional cycling performance (≈92.1% of capacity retention after 10 000 cycles). This general strategy provides an alternative to design the other ternary metal sulfides, making it facile, free‐standing, binder‐free, and cost‐effective ternary metal sulfide‐based electrodes for large‐scale applications in modern electronics. 相似文献
6.
Sulfur‐Embedded Activated Multichannel Carbon Nanofiber Composites for Long‐Life,High‐Rate Lithium–Sulfur Batteries
下载免费PDF全文
![点击此处可从《Liver Transplantation》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Despite the 3–5 fold higher energy density than the conventional Li‐ion cells at a lower cost, commercialization of Li–S batteries is hindered by the insulating nature of sulfur and the dissolution of intermediate polysulfides (Li2S X , 4 < X ≤ 8) into the electrolyte. The authors demonstrate here multichannel carbon nanofibers that are composed of parallel mesoporous channels connected with micropores as sulfur containment. In addition, hydroxyl functional groups are formed on the carbon surface through a chemical activation to enhance the interaction between sulfur and carbon. In the sulfur embedded composite, the mesoporous multichannel enhances the active material utilization and sulfur loading, while the micropores act as a reaction chamber for sulfur component and trap site for polysulfide with the assistance of the functional groups. This sulfur–carbon composite electrode with 2.2 mg cm?2 sulfur displays excellent performance with high rate capability (initial capacity of 1351 mA h g?1 at C/5 rate and 847 mA h g?1 at 5C rate), maintaining 920 mA h g?1 even after 300 cycles (a decay of 0.07% per cycle). Furthermore, a stable reversible capacity of as high as ≈1100 mA h g?1 is realized with a higher sulfur loading of 4.6 mg cm?2. 相似文献
7.
A Flexible Porous Carbon Nanofibers‐Selenium Cathode with Superior Electrochemical Performance for Both Li‐Se and Na‐Se Batteries
下载免费PDF全文
![点击此处可从《Liver Transplantation》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Linchao Zeng Wencong Zeng Yu Jiang Xiang Wei Weihan Li Chenglong Yang Yanwu Zhu Yan Yu 《Liver Transplantation》2015,5(4)
A flexible and free‐standing porous carbon nanofibers/selenium composite electrode (Se@PCNFs) is prepared by infiltrating Se into mesoporous carbon nanofibers (PCNFs). The porous carbon with optimized mesopores for accommodating Se can synergistically suppress the active material dissolution and provide mechanical stability needed for the film. The Se@PCNFs electrode exhibits exceptional electrochemical performance for both Li‐ion and Na‐ion storage. In the case of Li‐ion storage, it delivers a reversible capacity of 516 mAh g?1 after 900 cycles without any capacity loss at 0.5 A g?1. Se@PCNFs still delivers a reversible capacity of 306 mAh g?1 at 4 A g?1. While being used in Na‐Se batteries, the composite electrode maintains a reversible capacity of 520 mAh g?1 after 80 cycles at 0.05 A g?1 and a rate capability of 230 mAh g?1 at 1 A g?1. The high capacity, good cyclability, and rate capability are attributed to synergistic effects of the uniform distribution of Se in PCNFs and the 3D interconnected PCNFs framework, which could alleviate the shuttle reaction of polyselenides intermediates during cycling and maintain the perfect electrical conductivity throughout the electrode. By rational and delicate design, this type of self‐supported electrodes may hold great promise for the development of Li‐Se and Na‐Se batteries with high power and energy densities. 相似文献
8.
A cathode‐flow lithium‐iodine (Li–I) battery is proposed operating by the triiodide/iodide (I3?/I?) redox couple in aqueous solution. The aqueous Li–I battery has noticeably high energy density (≈0.28 kWh kg?1cell) because of the considerable solubility of LiI in aqueous solution (≈8.2 m ) and reasonably high power density (≈130 mW cm?2 at a current rate of 60 mA cm?2, 328 K). In the operation of cathode‐flow mode, the Li–I battery attains high storage capacity (≈90% of the theoretical capacity), Coulombic efficiency (100% ± 1% in 2–20 cycles) and cyclic performance (>99% capacity retention for 20 cycles) up to total capacity of 100 mAh. 相似文献
9.
Vertically Aligned MoS2 Nanosheets Patterned on Electrochemically Exfoliated Graphene for High‐Performance Lithium and Sodium Storage
下载免费PDF全文
![点击此处可从《Liver Transplantation》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Gang Wang Jian Zhang Sheng Yang Faxing Wang Xiaodong Zhuang Klaus Müllen Xinliang Feng 《Liver Transplantation》2018,8(8)
Molybdenum disulfide (MoS2) has been recognized as a promising anode material for high‐energy Li‐ion (LIBs) and Na‐ion batteries (SIBs) due to its apparently high capacity and intriguing 2D‐layered structure. The low conductivity, unsatisfied mechanical stability, and limited active material utilization are three key challenges associated with MoS2 electrodes especially at high current rates and mass active material loading. Here, vertical MoS2 nanosheets are controllably patterned onto electrochemically exfoliated graphene (EG). Within the achieved hierarchical architecture, the intimate contact between EG and MoS2 nanosheets, interconnected network, and effective exposure of active materials by vertical channels simultaneously overcomes the above three problems, enabling high mechanical integrity and fast charge transport kinetics. Serving as anode material for LIBs, EG‐MoS2 with 95 wt% MoS2 content delivered an ultrahigh‐specific capacity of 1250 mA h g?1 after 150 stable cycles at 1 A g?1, which is among the highest values in all reported MoS2 electrodes, and excellent rate performance (970 mA h g?1 at 5 A g?1). Moreover, impressive cycling stability (509 mA h g?1 at 1 A g?1 after 250 cycles) and rate capability (423 mA h g?1 at 2 A g?1) were also achieved for SIBs. The area capacities reached 1.27 and 0.49 mA h cm?2 at ≈1 mA cm?2 for LIBs and SIBs, respectively. This work may inspire the development of new 2D hierarchical structures for high efficiency energy storage and conversion. 相似文献
10.
Xuejie Gao Xiaofei Yang Keegan Adair Xiaona Li Jianwen Liang Qian Sun Yang Zhao Ruing Li Tsun‐Kong Sham Xueliang Sun 《Liver Transplantation》2020,10(7)
Although metallic lithium is regarded as the “Holy Grail” for next‐generation rechargeable batteries due to its high theoretical capacity and low overpotential, the uncontrollable Li dendrite growth, especially under high current densities and deep plating/striping, has inhibited its practical application. Herein, a 3D‐printed, vertically aligned Li anode (3DP‐VALi) is shown to efficiently guide Li deposition via a “nucleation within microchannel walls” process, enabling a high‐performance, dendrite‐free Li anode. Moreover, the microchannels within the microwalls are beneficial for promoting fast Li+ diffusion, supplying large space for the accommodation of Li during the plating/stripping process. The high‐surface‐area 3D anode design enables high operating current densities and high areal capacities. As a result, the Li–Li symmetric cells using 3DP‐VALi demonstrate excellent electrochemical performances as high as 10 mA cm?2/10 mAh cm?2 for 1500 h and 5 mA cm?2/20 mAh cm?2 for 400 h, respectively. Additionally, the Li–S and Li–LiFePO4 cells using 3DP‐VALi anodes present excellent cycling stability up to 250 and 800 cycles at a rate of 1 C, respectively. It is believed that these new findings could open a new window for dendrite‐free metal anode design and pave the way toward energy storage devices with high energy/power density. 相似文献
11.
Elastic Sandwich‐Type rGO–VS2/S Composites with High Tap Density: Structural and Chemical Cooperativity Enabling Lithium–Sulfur Batteries with High Energy Density
下载免费PDF全文
![点击此处可从《Liver Transplantation》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Driven by increasing demand for high‐energy‐density batteries for consumer electronics and electric vehicles, substantial progress is achieved in the development of long‐life lithium–sulfur (Li–S) batteries. Less attention is given to Li–S batteries with high volume energy density, which is crucial for applications in compact space. Here, a series of elastic sandwich‐structured cathode materials consisting of alternating VS2‐attached reduced graphene oxide (rGO) sheets and active sulfur layers are reported. Due to the high polarity and conductivity of VS2, a small amount of VS2 can suppress the shuttle effect of polysulfides and improve the redox kinetics of sulfur species in the whole sulfur layer. Sandwich‐structured rGO–VS2/S composites exhibit significantly improved electrochemical performance, with high discharge capacities, low polarization, and excellent cycling stability compared with their bare rGO/S counterparts. Impressively, the tap density of rGO–VS2/S with 89 wt% sulfur loading is 1.84 g cm?3, which is almost three times higher than that of rGO/S with the same sulfur content (0.63 g cm?3), and the volumetric specific capacity of the whole cell is as high as 1182.1 mA h cm?3, comparable with the state‐of‐the‐art reported for energy storage devices, demonstrating the potential for application of these composites in long‐life and high‐energy‐density Li–S batteries. 相似文献
12.
Lithium Difluorophosphate‐Based Dual‐Salt Low Concentration Electrolytes for Lithium Metal Batteries
Hao Zheng Hongfa Xiang Fuyang Jiang Yongchao Liu Yi Sun Xin Liang Yuezhan Feng Yan Yu 《Liver Transplantation》2020,10(30)
The safety hazards and low Coulombic efficiency originating from the growth of lithium dendrites and decomposition of the electrolyte restrict the practical application of Li metal batteries (LMBs). Inspired by the low cost of low concentration electrolytes (LCEs) in industrial applications, dual‐salt LCEs employing 0.1 m Li difluorophosphate (LiDFP) and 0.4 m LiBOB/LiFSI/LiTFSI are proposed to construct a robust and conductive interphase on a Li metal anode. Compared with the conventional electrolyte using 1 m LiPF6, the ionic conductivity of LCEs is reduced but the conductivity decrement of the separator immersed in LCEs is moderate, especially for the LiDFP–LiFSI and LiDFP–LiTFSI electrolytes. The accurate Coulombic efficiency (CE) of the Li||Cu cells increases from 83.3% (electrolyte using 1 m LiPF6) to 97.6%, 94.5%, and 93.6% for LiDFP–LiBOB, LiDFP–LiFSI, and LiDFP–LiTFSI electrolytes, respectively. The capacity retention of Li||LiFePO4 cells using the LiDFP–LiBOB electrolyte reaches 95.4% along with a CE over 99.8% after 300 cycles at a current density of 2.0 mA cm?2 and the capacity reaches 103.7 mAh g?1 at a current density of up to 16.0 mA cm?2. This work provides a dual‐salt LCE for practical LMBs and presents a new perspective for the design of electrolytes for LMBs. 相似文献
13.
Silicon Nanowires and Lithium Cobalt Oxide Nanowires in Graphene Nanoribbon Papers for Full Lithium Ion Battery
下载免费PDF全文
![点击此处可从《Liver Transplantation》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Rodrigo V. Salvatierra Abdul‐Rahman O. Raji Sung‐Ki Lee Yongsung Ji Lei Li James M. Tour 《Liver Transplantation》2016,6(24)
Described here is the production and characterization of a scalable method to produce 3D structured lithium ion battery anodes using free‐standing papers of porous silicon nanowires (Si‐NW) and graphene nanoribbons (GNRs). Using simple filtration methods, GNRs and Si‐NWs can be entangled into a mat thereby forming Si‐NW GNR papers. This produces anodes with high gravimetric capacity (up to 2500 mA h g?1) and high areal and volumetric capacities (up to 11 mA h cm?2 and 3960 mA h cm?3). The compact structure of the anode is possible since the GNR volume occupies a high proportion of empty space within the composite paper. These Si‐NW/GNR papers have been cycled for over 300 cycles, exhibiting a stable life cycle. Combined with LiCoO2 nanowires, a full battery is produced with high energy density (386 Wh kg?1), meeting requirements for high performance devices. 相似文献
14.
A Novel Graphene Oxide Wrapped Na2Fe2(SO4)3/C Cathode Composite for Long Life and High Energy Density Sodium‐Ion Batteries
下载免费PDF全文
![点击此处可从《Liver Transplantation》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Mingzhe Chen David Cortie Zhe Hu Huile Jin Shun Wang Qinfen Gu Weibo Hua Enhui Wang Weihong Lai Lingna Chen Shu‐Lei Chou Xiao‐Lin Wang Shi‐Xue Dou 《Liver Transplantation》2018,8(27)
The cathode materials in the Na‐ion battery system are always the key issue obstructing wider application because of their relatively low specific capacity and low energy density. A graphene oxide (GO) wrapped composite, Na2Fe2(SO4)3@C@GO, is fabricated via a simple freeze‐drying method. The as‐prepared material can deliver a 3.8 V platform with discharge capacity of 107.9 mAh g?1 at 0.1 C (1 C = 120 mA g?1) as well as offering capacity retention above 90% at a discharge rate of 0.2 C after 300 cycles. The well‐constructed carbon network provides fast electron transfer rates, and thus, higher power density also can be achieved (75.1 mAh g?1 at 10 C). The interface contribution of GO and Na2Fe2(SO4)3 is recognized and studied via density function theory calculation. The Na storage mechanism is also investigated through in situ synchrotron X‐ray diffraction, and pseudocapacitance contributions are also demonstrated. The diffusion coefficient of Na+ ions is around 10?12–10?10.8 cm2 s?1 during cycling. The higher working voltage of this composite is mainly ascribed to the larger electronegativity of the element S. The research indicates that this well‐constructed composite would be a competitive candidate as a cathode material for Na‐ion batteries. 相似文献
15.
Direct Growth of Flower‐Like δ‐MnO2 on Three‐Dimensional Graphene for High‐Performance Rechargeable Li‐O2 Batteries
下载免费PDF全文
![点击此处可从《Liver Transplantation》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Shuangyu Liu Yunguang Zhu Jian Xie Ying Huo Hui Ying Yang Tiejun Zhu Gaoshao Cao Xinbing Zhao Shichao Zhang 《Liver Transplantation》2014,4(9)
A challenge still remains to develop high‐performance and cost‐effective air electrode for Li‐O2 batteries with high capacity, enhanced rate capability and long cycle life (100 times or above) despite recent advances in this field. In this work, a new design of binder‐free air electrode composed of three‐dimensional (3D) graphene (G) and flower‐like δ‐MnO2 (3D‐G‐MnO2) has been proposed. In this design, graphene and δ‐MnO2 grow directly on the skeleton of Ni foam that inherits the interconnected 3D scaffold of Ni foam. Li‐O2 batteries with 3D‐G‐MnO2 electrode can yield a high discharge capacity of 3660 mAh g?1 at 0.083 mA cm?2. The battery can sustain 132 cycles at a capacity of 492 mAh g?1 (1000 mAh gcarbon ?1) with low overpotentials under a high current density of 0.333 mA cm?2. A high average energy density of 1350 Wh Kg?1 is maintained over 110 cycles at this high current density. The excellent catalytic activity of 3D‐G‐MnO2 makes it an attractive air electrode for high‐performance Li‐O2 batteries. 相似文献
16.
Amorphous MoS3 Infiltrated with Carbon Nanotubes as an Advanced Anode Material of Sodium‐Ion Batteries with Large Gravimetric,Areal, and Volumetric Capacities
下载免费PDF全文
![点击此处可从《Liver Transplantation》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Hualin Ye Lu Wang Shuo Deng Xiaoqiao Zeng Kaiqi Nie Paul N. Duchesne Bo Wang Simon Liu Junhua Zhou Feipeng Zhao Na Han Peng Zhang Jun Zhong Xuhui Sun Youyong Li Yanguang Li Jun Lu 《Liver Transplantation》2017,7(5)
The search for earth‐abundant and high‐performance electrode materials for sodium‐ion batteries represents an important challenge to current battery research. 2D transition metal dichalcogenides, particularly MoS2, have attracted increasing attention recently, but few of them so far have been able to meet expectations. In this study, it is demonstrated that another phase of molybdenum sulfide—amorphous chain‐like MoS3—can be a better choice as the anode material of sodium‐ion batteries. Highly compact MoS3 particles infiltrated with carbon nanotubes are prepared via the facile acid precipitation method in ethylene glycol. Compared to crystalline MoS2, the resultant amorphous MoS3 not only exhibits impressive gravimetric performance—featuring excellent specific capacity (≈615 mA h g?1), rate capability (235 mA h g?1 at 20 A g?1), and cycling stability but also shows exceptional volumetric capacity of ≈1000 mA h cm?3 and an areal capacity of >6.0 mA h cm?2 at very high areal loadings of active materials (up to 12 mg cm?2). The experimental results are supported by density functional theory simulations showing that the 1D chains of MoS3 can facilitate the adsorption and diffusion of Na+ ions. At last, it is demonstrated that the MoS3 anode can be paired with an Na3V2(PO4)3 cathode to afford full cells with great capacity and cycling performance. 相似文献
17.
Yijun Chen Yunsong Wang Zhipeng Wang Mingchu Zou Hui Zhang Wenqi Zhao Muhammad Yousaf Liusi Yang Anyuan Cao Ray P. S. Han 《Liver Transplantation》2018,8(19)
Achieving a high areal capacity is essential for the transfer of outstanding laboratory electrode results to commercial applications and also to ensure there exists a capacity matched cathode and anode for a properly tuned battery. Despite intensive efforts, most electrode materials exhibit areal capacities lower than that of the graphite anodes (4 mA h cm?2). An effective and low‐cost approach is reported to attain a high areal capacity via an intense densification by compacting a porous carbon nanotube sponge grafted with Co3O4 nanoparticles. The hybrid sponge can be compacted to a large degree (up to a tenfold densification) while still keeping its structural integrity and the 3D porous network. This method allows achieving a mass loading of up ?to 14.3 mg cm?2 and an areal capacity of 12 mA h cm?2 (at a current density of 200 mA g?1) together with a gravimetric capacity of >800 mA h g?1. This densification by compaction approach offers an effective and low‐cost strategy to develop high mass loading and areal capacity electrodes for practical energy storage systems. 相似文献
18.
Open‐Structured V2O5·nH2O Nanoflakes as Highly Reversible Cathode Material for Monovalent and Multivalent Intercalation Batteries
下载免费PDF全文
![点击此处可从《Liver Transplantation》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Huali Wang Xuanxuan Bi Ying Bai Chuan Wu Sichen Gu Shi Chen Feng Wu Khalil Amine Jun Lu 《Liver Transplantation》2017,7(14)
The high‐capacity cathode material V2O5·n H2O has attracted considerable attention for metal ion batteries due to the multielectron redox reaction during electrochemical processes. It has an expanded layer structure, which can host large ions or multivalent ions. However, structural instability and poor electronic and ionic conductivities greatly handicap its application. Here, in cell tests, self‐assembly V2O5·n H2O nanoflakes shows excellent electrochemical performance with either monovalent or multivalent cation intercalation. They are directly grown on a 3D conductive stainless steel mesh substrate via a simple and green hydrothermal method. Well‐layered nanoflakes are obtained after heat treatment at 300 °C (V2O5·0.3H2O). Nanoflakes with ultrathin flower petals deliver a stable capacity of 250 mA h g?1 in a Li‐ion cell, 110 mA h g?1 in a Na‐ion cell, and 80 mA h g?1 in an Al‐ion cell in their respective potential ranges (2.0–4.0 V for Li and Na‐ion batteries and 0.1–2.5 V for Al‐ion battery) after 100 cycles. 相似文献
19.
An Air‐Stable Densely Packed Phosphorene–Graphene Composite Toward Advanced Lithium Storage Properties
下载免费PDF全文
![点击此处可从《Liver Transplantation》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Yu Zhang Huanwen Wang Zhongzhen Luo Hui Teng Tan Bing Li Shengnan Sun Zhong Li Yun Zong Zhichuan J. Xu Yanhui Yang Khiam Aik Khor Qingyu Yan 《Liver Transplantation》2016,6(12)
Phosphorene, monolayer or few‐layer black phosphorus (BP), has recently triggered strong scientific interest for lithium/sodium ion batteries (LIBs/SIBs) applications. However, there are still challenges regarding large‐scale fabrication, poor air stability. Herein, we report the high‐yield synthesis of phosphorene with good crystallinity and tunable size distributions via liquid‐phase exfoliation of bulk BP in formamide. Afterwards, a densely packed phosphorene–graphene composite (PG‐SPS, a packing density of 0.6 g cm?3) is prepared by a simple and easily up‐scalable spark plasma sintering (SPS) process. When working as anode materials of LIBs, PG‐SPS exhibit much improved first‐cycle Coloumbic efficiency (60.2%) compared to phosphorene (11.5%) and loosely stacked phosphorene–graphene composite (34.3%), high specific capacity (1306.7 mAh g?1) and volumetric capacity (256.4 mAh cm?3), good rate capabilities (e.g., 415.0 mAh g?1 at 10 A g?1) as well as outstanding long‐term cycling life (91.9% retention after 800 cycles at 10 A g?1). Importantly, excellent air stability of PG‐SPS over the 60 days observation in maintaining its high Li storage properties can be achieved. On the contrary, 95.2% of BP in PG sample was oxidized after only 10 days exposure to ambience, leading to severe degradation of electrochemical properties. 相似文献
20.
Xinxin Cao Anqiang Pan Sainan Liu Jiang Zhou Site Li Guozhong Cao Jun Liu Shuquan Liang 《Liver Transplantation》2017,7(20)
Sodium (Na) super ion conductor structured Na3V2(PO4)3 (NVP) is extensively explored as cathode material for sodium‐ion batteries (SIBs) due to its large interstitial channels for Na+ migration. The synthesis of 3D graphene‐like structure coated on NVP nanoflakes arrays via a one‐pot, solid‐state reaction in molten hydrocarbon is reported. The NVP nanoflakes are uniformly coated by the in situ generated 3D graphene‐like layers with the thickness of 3 nm. As a cathode material, graphene covered NVP nanoflakes exhibit excellent electrochemical performances, including close to theoretical reversible capacity (115.2 mA h g?1 at 1 C), superior rate capability (75.9 mA h g?1 at 200 C), and excellent cyclic stability (62.5% of capacity retention over 30000 cycles at 50 C). Furthermore, the 3D graphene‐like cages after removing NVP also serve as a good anode material and deliver a specific capacity of 242.5 mA h g?1 at 0.1 A g?1. The full SIB using these two cathode and anode materials delivers a high specific capacity (109.2 mA h g?1 at 0.1 A g?1) and good cycling stability (77.1% capacity retention over 200 cycles at 0.1 A g?1). 相似文献