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1.
Dual‐Confined Flexible Sulfur Cathodes Encapsulated in Nitrogen‐Doped Double‐Shelled Hollow Carbon Spheres and Wrapped with Graphene for Li–S Batteries
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Batteries with high energy and power densities along with long cycle life and acceptable safety at an affordable cost are critical for large‐scale applications such as electric vehicles and smart grids, but is challenging. Lithium–sulfur (Li‐S) batteries are attractive in this regard due to their high energy density and the abundance of sulfur, but several hurdles such as poor cycle life and inferior sulfur utilization need to be overcome for them to be commercially viable. Li–S cells with high capacity and long cycle life with a dual‐confined flexible cathode configuration by encapsulating sulfur in nitrogen‐doped double‐shelled hollow carbon spheres followed by graphene wrapping are presented here. Sulfur/polysulfides are effectively immobilized in the cathode through physical confinement by the hollow spheres with porous shells and graphene wrapping as well as chemical binding between heteronitrogen atoms and polysulfides. This rationally designed free‐standing nanostructured sulfur cathode provides a well‐built 3D carbon conductive network without requiring binders, enabling a high initial discharge capacity of 1360 mA h g?1 at a current rate of C/5, excellent rate capability of 600 mA h g?1 at 2 C rate, and sustainable cycling stability for 200 cycles with nearly 100% Coulombic efficiency, suggesting its great promise for advanced Li–S batteries. 相似文献
2.
Lithium‐sulfur (Li‐S) batteries are considered to be one of the promising next‐generation energy storage systems. Considerable progress has been achieved in sulfur composite cathodes, but high cycling stability and discharging capacity at the expense of volumetric capacity have offset their advantages. Herein, a functional separator is presented by coating cobalt‐embedded nitrogen‐doped porous carbon nanosheets and graphene on one surface of a commercial polypropylene separator. The coating layer not only suppresses the polysulfide shuttle effect through chemical affinity, but also functions as an electrocatalyst to propel catalytic conversion of intercepted polysulfides. The slurry‐bladed carbon nanotubes/sulfur cathode with 90 wt% sulfur deliver high reversible capacity of 1103 mA h g?1 and volumetric capacity of 1062 mA h cm?3 at 0.2 C, and the freestanding carbon nanofibers/sulfur cathode provides a high discharging capacity of 1190 mA h g?1 and volumetric capacity of 1136 mA h cm?3 at high sulfur content of 78 wt% and sulfur loading of 10.5 mg cm?2. The electrochemical performance is comparable with or even superior to those in the state‐of‐the‐art carbon‐based sulfur cathodes. The separator reported in this work holds great promise for the development of high‐energy‐density Li‐S batteries. 相似文献
3.
Fabrication of N‐doped Graphene–Carbon Nanotube Hybrids from Prussian Blue for Lithium–Sulfur Batteries
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Hybrid nanostructures containing 1D carbon nanotubes and 2D graphene sheets have many promising applications due to their unique physical and chemical properties. In this study, the authors find Prussian blue (dehydrated sodium ferrocyanide) can be converted to N‐doped graphene–carbon nanotube hybrid materials through a simple one‐step pyrolysis process. Through field emission scanning electron microscopy, transmission electron microscopy, X‐ray diffraction, Raman spectra, atomic force microscopy, and isothermal analyses, the authors identify that 2D graphene and 1D carbon nanotubes are bonded seamlessly during the growth stage. When used as the sulfur scaffold for lithium–sulfur batteries, it demonstrates outstanding electrochemical performance, including a high reversible capacity (1221 mA h g?1 at 0.2 C rate), excellent rate capability (458 and 220 mA h g?1 at 5 and 10 C rates, respectively), and excellent cycling stability (321 and 164 mA h g?1 at 5 and 10 C (1 C = 1673 mA g?1) after 1000 cycles). The enhancement of electrochemical performance can be attributed to the 3D architecture of the hybrid material, in which, additionally, the nitrogen doping generates defects and active sites for improved interfacial adsorption. Furthermore, the nitrogen doping enables the effective trapping of lithium polysulfides on electroactive sites within the cathode, leading to a much‐improved cycling performance. Therefore, the hybrid material functions as a redox shuttle to catenate and bind polysulfides, and convert them to insoluble lithium sulfide during reduction. The strategy reported in this paper could open a new avenue for low cost synthesis of N‐doped graphene–carbon nanotube hybrid materials for high performance lithium–sulfur batteries. 相似文献
4.
Long Jiao Chen Zhang Chuannan Geng Shichao Wu Huan Li Wei Lv Ying Tao Zijin Chen Guangmin Zhou Jia Li Guowei Ling Ying Wan Quan‐Hong Yang 《Liver Transplantation》2019,9(19)
The detrimental shuttle effect in lithium–sulfur batteries mainly results from the mobility of soluble polysulfide intermediates and their sluggish conversion kinetics. Herein, presented is a multifunctional catalyst with the merits of strong polysulfides adsorption ability, superior polysulfides conversion activity, high specific surface area, and electron conductivity by in situ crafting of the TiO2‐MXene (Ti3C2Tx) heterostructures. The uniformly distributed TiO2 on MXene sheets act as capturing centers to immobilize polysulfides, the hetero‐interface ensures rapid diffusion of anchored polysulfides from TiO2 to MXene, and the oxygen‐terminated MXene surface is endowed with high catalytic activity toward polysulfide conversion. The improved lithium–sulfur batteries deliver 800 mAh g?1 at 2 C and an ultralow capacity decay of 0.028% per cycle over 1000 cycles at 2 C. Even with a high sulfur loading of 5.1 mg cm?2, the capacity retention of 93% after 200 cycles is still maintained. This work sheds new insights into the design of high‐performance catalysts with manipulated chemical components and tailored surface chemistry to regulate polysulfides in Li–S batteries. 相似文献
5.
Sulfur‐Embedded Activated Multichannel Carbon Nanofiber Composites for Long‐Life,High‐Rate Lithium–Sulfur Batteries
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Despite the 3–5 fold higher energy density than the conventional Li‐ion cells at a lower cost, commercialization of Li–S batteries is hindered by the insulating nature of sulfur and the dissolution of intermediate polysulfides (Li2S X , 4 < X ≤ 8) into the electrolyte. The authors demonstrate here multichannel carbon nanofibers that are composed of parallel mesoporous channels connected with micropores as sulfur containment. In addition, hydroxyl functional groups are formed on the carbon surface through a chemical activation to enhance the interaction between sulfur and carbon. In the sulfur embedded composite, the mesoporous multichannel enhances the active material utilization and sulfur loading, while the micropores act as a reaction chamber for sulfur component and trap site for polysulfide with the assistance of the functional groups. This sulfur–carbon composite electrode with 2.2 mg cm?2 sulfur displays excellent performance with high rate capability (initial capacity of 1351 mA h g?1 at C/5 rate and 847 mA h g?1 at 5C rate), maintaining 920 mA h g?1 even after 300 cycles (a decay of 0.07% per cycle). Furthermore, a stable reversible capacity of as high as ≈1100 mA h g?1 is realized with a higher sulfur loading of 4.6 mg cm?2. 相似文献
6.
Synergetic Protective Effect of the Ultralight MWCNTs/NCQDs Modified Separator for Highly Stable Lithium–Sulfur Batteries
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Lithium–sulfur (Li–S) batteries are highly attractive due to their high energy density, potentially low cost, and environmental compatibility. However, their commercialization has been greatly hindered by their poor cycle life and severe self‐discharge, which can be attributed to the polysulfides dissolution. To overcome these issues, much effort has been devoted to engineering the electrode structure and composition to improve the performance which is often expensive and laborious. In this study, an ultralight multiwall carbon nanotube/N‐doped carbon quantum dot (MWCNT/NCQD)‐coated separator is first designed, which is cost effective and facile. The MWCNTs/NCQDs‐coated separator is then applied in Li–S batteries. The MWCNTs/NCQDs coating provides a physical shield against polysulfide shuttling and chemical adsorption of polysulfides by MWCNTs and NCQDs. The synergetic effect of MWCNTs and NCQDs enables the production of Li–S cell with a relative high initial discharge capacity of 1330.8 mA h g?1 and excellent cyclic performance with a corresponding capacity fade rate of as low as 0.05% per cycle at 0.5 C over 1000 cycles. Excellent rate capability and anti‐self‐discharge behavior are also displayed. The design of MWCNTs/NCQDs‐coated separator is a viable approach for successfully developing practical Li–S batteries. 相似文献
7.
High‐Performance and Low‐Temperature Lithium–Sulfur Batteries: Synergism of Thermodynamic and Kinetic Regulation
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Chao‐Ying Fan Yan‐Ping Zheng Xiao‐Hua Zhang Yan‐Hong Shi Si‐Yu Liu Han‐Chi Wang Xing‐Long Wu Hai‐Zhu Sun Jing‐Ping Zhang 《Liver Transplantation》2018,8(18)
The intrinsic polysulfides shuttle, resulting from not only concentration‐gradient diffusion but also slow conversion kinetics of polysulfides, bears the primary responsibility for the poor capacity and cycle stability of lithium–sulfur batteries (LSBs). Here, it is first presented that enriched edge sites derived from vertical standing and ultrathin 2D layered metal selenides (2DLMS) can simultaneously achieve the thermodynamic and kinetic regulation for polysulfides diffusion, which is systematically elucidated through theoretical calculation, electrochemical characterization, and spectroscopic/microscopic analysis. When employed to fabricate compact coating layer of separator, an ultrahigh capacity of 1338.7 mA h g?1 is delivered after 100 cycles at 0.2 C, which is the best among the reports. Over 1000 cycles, the cell still maintains the capacity of 546.8 mA h g?1 at 0.5 C. Moreover, the cell exhibits outstanding capacities of 1106.2 and 865.7 mA h g?1 after 100 cycles at stern temperature of 0 and ?25 °C. The superior low‐temperature performance is appealing for extended practical application of LSBs. Especially, in view of the economy, the 2DLMS is recycled as an anode of lithium‐ion and sodium‐ion batteries after finishing the test of LSBs. The low‐cost and scalable 2DLMS with enriched egde sites open a new avenue for the perfect regulation of the sulfur electrode. 相似文献
8.
3D Vertically Aligned and Interconnected Porous Carbon Nanosheets as Sulfur Immobilizers for High Performance Lithium‐Sulfur Batteries
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Sarish Rehman Xingxing Gu Kishwar Khan Nasir Mahmood Wenlong Yang Xiaoxiao Huang Shaojun Guo Yanglong Hou 《Liver Transplantation》2016,6(12)
A unique nanostructure of 3D and vertically aligned and interconnected porous carbon nanosheets (3D‐VCNs) is demonstrated by a simple carbonization of agar. The key feature of 3D‐VCNs is that they possess numerous 3D channels with macrovoids and mesopores, leading to high surface area of 1750 m2 g?1, which play an important role in loading large amount of sulfur, while vertically aligned microporous carbon nanosheets act as the multilayered physical barrier against polysulfides anions and prevent their dissolution in the electrolyte due to strong adsorption during cycling process. As a result, the 3D hybrid (3D‐S‐VCNs) infiltered with 68.3 wt% sulfur exhibits a high and stable reversible capacity of 844 mAh g?1 at the current density of 837 mA g?1 with excellent Coulombic efficiency ≈100%, capacity retention of ≈80.3% over 300 cycles, and good rate ability (the reversible capacity of 738 mAh g?1 at the high current density of 3340 mA g?1). The present work highlights the vital role of the introduction of 3D carbon nanosheets with macrovoids and mesopores in enhancing the performance of LSBs. 相似文献
9.
Highly Stable Lithium–Sulfur Batteries Based on Laponite Nanosheet‐Coated Celgard Separators
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Lithium–sulfur (Li–S) batteries are of great interest due to their high theoretical energy density. However, one of the key issues hindering their real world applications is polysulfide shuttle, which results in severe capacity decay and self‐discharge. Here, a laponite nanosheets/carbon black coated Celgard (LNS/CB‐Celgard) separator to inhibit polysulfide shuttle and to enhance the Li+ conductivity simultaneously is reported. The polysulfide shuttle is efficiently inhibited through strong interactions between the O active sites of the LNS and polysulfides by forming the Li···O and O? S bonds. Moreover, the separator features high Li+ conductivity, fast Li+ diffusion, excellent electrolyte wettability, and high thermal stability. Consequently, the Li–S batteries with the LNS/CB‐Celgard separator and the pure S cathode show a high initial reversible capacity of 1387 mA h g?1 at 0.1 C, high rate performance, superior cycling stability (with a capacity decay rate of 0.06% cycle?1 at 0.2 C and 0.028% cycle?1 at 1.0 C over 500 cycles), and ultralow self‐discharge. The separator could also enhance the performance of other batteries such as the LiFePO4/separator/Li battery. This work sheds a new light on the design and preparation of novel separators for highly stable Li–S batteries via a “green” and cost‐effective approach. 相似文献
10.
Xia Huang Jiayong Tang Bin Luo Ruth Knibbe Tongen Lin Han Hu Masud Rana Yuxiang Hu Xiaobo Zhu Qinfen Gu Dan Wang Lianzhou Wang 《Liver Transplantation》2019,9(32)
As the lightest member of transition metal dichalcogenides, 2D titanium disulfide (2D TiS2) nanosheets are attractive for energy storage and conversion. However, reliable and controllable synthesis of single‐ to few‐layered TiS2 nanosheets is challenging due to the strong tendency of stacking and oxidation of ultrathin TiS2 nanosheets. This study reports for the first time the successful conversion of Ti3C2Tx MXene to sandwich‐like ultrathin TiS2 nanosheets confined by N, S co‐doped porous carbon (TiS2@NSC) via an in situ polydopamine‐assisted sulfuration process. When used as a sulfur host in lithium–sulfur batteries, TiS2@NSC shows both high trapping capability for lithium polysulfides (LiPSs), and remarkable electrocatalytic activity for LiPSs reduction and lithium sulfide oxidation. A freestanding sulfur cathode integrating TiS2@NSC with cotton‐derived carbon fibers delivers a high areal capacity of 5.9 mAh cm?2 after 100 cycles at 0.1 C with a low electrolyte/sulfur ratio and a high sulfur loading of 7.7 mg cm?2, placing TiS2@NSC one of the best LiPSs adsorbents and sulfur conversion catalysts reported to date. The developed nanospace‐confined strategy will shed light on the rational design and structural engineering of metal sulfides based nanoarchitectures for diverse applications. 相似文献
11.
Functionalized Boron Nitride Nanosheets/Graphene Interlayer for Fast and Long‐Life Lithium–Sulfur Batteries
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Ye Fan Zhi Yang Wuxing Hua Dan Liu Tao Tao Md Mokhlesur Rahman Weiwei Lei Shaoming Huang Ying Chen 《Liver Transplantation》2017,7(13)
Lithium–sulfur (Li–S) batteries have a much higher energy density than Li ion batteries and thus are considered as next generation batteries for electric vehicle applications. However, the problem of rapid capacity fading due to the shuttling of soluble polysulfides between electrodes remains the main obstacle for practical applications. Here, a thin and selective interlayer structure has been designed and produced to decrease the charge transfer resistance and mitigate the shuttling problem, simply by coating the surface of cathode with a thin film of functionalized boron nitride nanosheets/graphene. Due to this thin and ultralight interlayer, the specific capacity and cycling stability of the Li–S batteries with a cathode of sulfur‐containing porous carbon nanotubes (≈60 wt% sulfur content) have been improved significantly with a life of over 1000 cycles, an initial specific capacity of 1100 mA h g?1 at 3 C, and a cycle decay as low as 0.0037% per cycle. This new interlayer provides a promising approach to significantly enhance the performance of Li–S batteries. 相似文献
12.
Porphyrin‐Derived Graphene‐Based Nanosheets Enabling Strong Polysulfide Chemisorption and Rapid Kinetics in Lithium–Sulfur Batteries
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Long Kong Bo‐Quan Li Hong‐Jie Peng Rui Zhang Jin Xie Jia‐Qi Huang Qiang Zhang 《Liver Transplantation》2018,8(20)
Lithium–sulfur (Li–S) batteries hold great promise as a next‐generation battery system because of their extremely high theoretical energy density and low cost. However, ready lithium polysulfide (LiPS) diffusion and sluggish redox kinetics hamper their cyclability and rate capability. Herein, porphyrin‐derived graphene‐based nanosheets (PNG) are proposed for Li–S batteries, which are achieved by pyrolyzing a conformal and thin layer of 2D porphyrin organic framework on graphene to form carbon nanosheets with a spatially engineered nitrogen‐dopant‐enriched skin and a highly conductive skeleton. The atomic skin is decorated with fully exposed lithiophilic sites to afford strong chemisorption to LiPSs and improve electrolyte wettability, while graphene substrate provides speedy electron transport to facilitate redox kinetics of sulfur species. The use of PNG as a lightweight interlayer enables efficient operation of Li–S batteries in terms of superb cycle stability (cyclic decay rate of 0.099% during 300 cycles at 0.5 C), good rate capability (988 mAh g?1 at 2.0 C), and impressive sulfur loading (areal capacity of 8.81 mAh cm?2 at a sulfur loading of 8.9 mg cm?2). The distinct interfacial strategy is expected to apply to other conversion reaction batteries relying on dissolution–precipitation mechanisms and requiring interfacial charge‐ and mass‐transport‐mediation concurrently. 相似文献
13.
Chemical Bonding and Physical Trapping of Sulfur in Mesoporous Magnéli Ti4O7 Microspheres for High‐Performance Li–S Battery
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Hao Wei Erwin F. Rodriguez Adam S. Best Anthony F. Hollenkamp Dehong Chen Rachel A. Caruso 《Liver Transplantation》2017,7(4)
Various host materials have been investigated to address the intrinsic drawbacks of lithium sulfur batteries, such as the low electronic conductivity of sulfur and inevitable decay in capacity during cycling. Besides the widely investigated carbonaceous materials, metal oxides have drawn much attention because they form strong chemical bonds with the soluble lithium polysulfides. Here, mesoporous Magnéli Ti4O7 microspheres are prepared via an in situ carbothermal reduction that exhibit interconnected mesopores (20.4 nm), large pore volume (0.39 cm3 g?1), and high surface area (197.2 m2 g?1). When the sulfur cathode is embedded in a matrix of mesoporous Magnéli Ti4O7 microspheres, it exhibits a superior reversible capacity of 1317.6 mA h g?1 at moderate current (C/10) and a low decay in capacity of 12% after 400 cycles at C/5. Strong chemical bonding of the lithium polysulfides to Ti4O7, as well as effective physical trapping in the mesopores and voids in the matrix are considered responsible for the improved electrochemical performance. A mechanism of the physical and chemical interactions between mesoporous Magnéli Ti4O7 microspheres and sulfur is proposed based on systematic investigations. 相似文献
14.
A Conductive Molecular Framework Derived Li2S/N,P‐Codoped Carbon Cathode for Advanced Lithium–Sulfur Batteries
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Li2S is one of the most promising cathode materials for Li‐ion batteries because of its high theoretical capacity and compatibility with Li‐metal‐free anode materials. However, the poor conductivity and electrochemical reactivity lead to low initial capacity and severe capacity decay. In this communication, a nitrogen and phosphorus codoped carbon (N,P–C) framework derived from phytic acid doped polyaniline hydrogel is designed to support Li2S nanoparticles as a binder‐free cathode for Li–S battery. The porous 3D architecture of N and P codoped carbon provides continuous electron pathways and hierarchically porous channels for Li ion transport. Phosphorus doping can also suppress the shuttle effect through strong interaction between sulfur and the carbon framework, resulting in high Coulombic efficiency. Meanwhile, P doping in the carbon framework plays an important role in improving the reaction kinetics, as it may help catalyze the redox reactions of sulfur species to reduce electrochemical polarization, and enhance the ionic conductivity of Li2S. As a result, the Li2S/N,P–C composite electrode delivers a stable capacity of 700 mA h g?1 with average Coulombic efficiency of 99.4% over 100 cycles at 0.1C and an areal capacity as high as 2 mA h cm?2 at 0.5C. 相似文献
15.
Biyu Jin Lifeng Yang Jiawen Zhang Yongjie Cai Juan Zhu Jianguo Lu Yang Hou Qinggang He Huabin Xing Xiaoli Zhan Fengqiu Chen Qinghua Zhang 《Liver Transplantation》2019,9(48)
High‐loading lithium–sulfur batteries have gained considerable fame for possessing high area capacity, but face a stern challenge from capacity fading because of serious issues, including “polysulfides shuttling,” insulating S/Li2S, large volume changes, and the shedding of S/C particles during drying or the cell encapsulation process. Herein, a bioinspired water‐soluble binder framework is constructed via intermolecular physical cross‐linking of functional side chains hanging on the terpolymer binder. Experimental results and density‐functional theory (DFT) calculations reveal that this network binder featuring superior volume change accommodation can also capture lithium polysulfides (LiPSs) through strong anchoring of O, N+ actives to LiPSs by forming Li···O and N+···Sx2? bonds. In addition, the abundant negative charged sulfonate coordination sites and good electrolyte uptake of the designed binder endow the assembled cells with high lithium ion conductivity and fast lithium ion diffusion. Consequently, a remarkable capacity retention of 98% after 350 cycles at 1 C and a high areal capacity of 12.8 mA h cm?2 with high sulfur loading of 12.0 mg cm?2 are achieved by applying the environmentally friendly binder. 相似文献
16.
Nitrogen Doped/Carbon Tuning Yolk‐Like TiO2 and Its Remarkable Impact on Sodium Storage Performances
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Yolk‐like TiO2 are prepared through an asymmetric Ostwald ripening, which is simultaneously doped by nitrogen and wrapped by carbon from core to shell. It presents a high specific surface area (144.9 m2 g?1), well‐defined yolk‐like structure (600–700 nm), covered with interweaved nanosheets (3–5 nm) and tailored porosity (5–10 nm) configuration. When first utilized as anode material for sodium‐ion batteries (SIBs), it delivers a high reversible specific capacity of 242.7 mA h g?1 at 0.5 C and maintains a considerable capacity of 115.9 mA h g?1 especially at rate 20 C. Moreover, the reversible capacity can still reach 200.7 mA h g?1 after 550 cycles with full capacity retention at 1 C. Even cycled at extremely high rate 25 C, the capacity retention of 95.5% after 3000 cycles is acquired. Notably, an ultrahigh initial coulombic efficiency of 59.1% is achieved. The incorporation of nitrogen with narrowing the band gap accompanied with carbon uniformly coating from core to shell make the NC TiO2‐Y favor a bulk type conductor, resulting in fast electron transfer, which is beneficial to long‐term cycling stability and remarkable rate capability. It is of great significance to improve the energy‐storage properties through development of the bulk type conductor as anode materials in SIBs. 相似文献
17.
In Situ Assembly of 2D Conductive Vanadium Disulfide with Graphene as a High‐Sulfur‐Loading Host for Lithium–Sulfur Batteries
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Xingyu Zhu Wen Zhao Yingze Song Qiucheng Li Feng Ding Jingyu Sun Li Zhang Zhongfan Liu 《Liver Transplantation》2018,8(20)
Lithium–sulfur (Li–S) batteries are deemed to be one of the most promising energy storage technologies because of their high energy density, low cost, and environmental benignancy. However, existing drawbacks including the shuttling of intermediate polysulfides, the insulating nature of sulfur, and the considerable volume change of sulfur cathode would otherwise result in the capacity fading and unstable cycling. To overcome these challenges, herein an in situ assembly route is presented to fabricate VS2/reduced graphene oxide nanosheets (G–VS2) as a sulfur host. Benefiting from the 2D conductive and polar VS2 interlayered within a graphene framework, the obtained G–VS2 hybrids can effectively suppress the polysulfide shuttling, facilitate the charge transport, and cushion the volume expansion throughout the synergistic effect of structural confinement and chemical anchoring. With these advantageous features, the obtained sulfur cathode (G–VS2/S) can deliver an outstanding rate capability (≈950 and 800 mAh g?1 at 1 and 2 C, respectively) and an impressive cycling stability at high rates (retaining ≈532 mAh g?1 after 300 cycles at 5 C). More significantly, it enables superior cycling performance of high‐sulfur‐loading cathodes (achieving an areal capacity of 5.1 mAh cm?2 at 0.2 C with a sulfur loading of 5 mg cm?2) even at high current densities. 相似文献
18.
Ya‐Tao Liu Dian‐Dian Han Lu Wang Guo‐Ran Li Sheng Liu Xue‐Ping Gao 《Liver Transplantation》2019,9(11)
Both the energy density and cycle stability are still challenges for lithium–sulfur (Li–S) batteries in future practical applications. Usually, light‐weight and nonpolar carbon materials are used as the hosts of sulfur, however they struggle on the cycle stability and undermine the volumetric energy density of Li–S batteries. Here, heavy NiCo2O4 nanofibers as carbon‐free sulfur immobilizers are introduced to fabricate sulfur‐based composites. NiCo2O4 can accelerate the catalytic conversion kinetics of soluble intermediate polysulfides by strong chemical interaction, leading to a good cycle stability of sulfur cathodes. Specifically, the S/NiCo2O4 composite presents a high gravimetric capacity of 1125 mAh g?1 at 0.1 C rate with the composite as active material, and a low fading rate of 0.039% per cycle over 1500 cycles at 1 C rate. In particular, the S/NiCo2O4 composite with the high tap density of 1.66 g cm?3 delivers large volumetric capacity of 1867 mAh cm?3, almost twice that of the conventional S/carbon composites. 相似文献
19.
3D Hyperbranched Hollow Carbon Nanorod Architectures for High‐Performance Lithium‐Sulfur Batteries
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Shuangqiang Chen Xiaodan Huang Hao Liu Bing Sun Waikong Yeoh Kefei Li Jinqiang Zhang Guoxiu Wang 《Liver Transplantation》2014,4(8)
Lithium‐sulfur batteries have been plagued for a long time by low Coulombic efficiency, fast capacity loss, and poor high rate performance. Here, the synthesis of 3D hyperbranched hollow carbon nanorod encapsulated sulfur nanocomposites as cathode materials for lithium‐sulfur batteries is reported. The sulfur nanocomposite cathodes deliver a high specific capacity of 1378 mAh g‐1 at a 0.1C current rate and exhibit stable cycling performance. The as‐prepared sulfur nanocomposites also achieve excellent high rate capacities and cyclability, such as 990 mAh g‐1 at 1C, 861 mAh g‐1 at 5C, and 663 mAh g‐1 at 10C, extending to more than 500 cycles. The superior electrochemical performance are ascribed to the unique 3D hyperbranched hollow carbon nanorod architectures and high length/radius aspect ratio of the carbon nanorods, which can effectively prevent the dissolution of polysulfides, decrease self‐discharge, and confine the volume expansion on cycling. High capacity, excellent high‐rate performance, and long cycle life render the as‐developed sulfur/carbon nanorod nanocomposites a promising cathode material for lithium‐sulfur batteries. 相似文献
20.
Fengping Xiao Xuming Yang Hongkang Wang Jun Xu Yulong Liu Denis Y. W. Yu Andrey L. Rogach 《Liver Transplantation》2020,10(23)
Practical applications of room temperature sodium–sulfur batteries are still inhibited by the poor conductivity and slow reaction kinetics of sulfur, and dissolution of intermediate polysulfides in the commonly used electrolytes. To address these issues, starting from a novel 3D Zn‐based metal–organic framework with 2,5‐thiophenedicarboxylic acid and 1,4‐bis(pyrid‐4‐yl) benzene as ligands, a S, N‐doped porous carbon host with 3D tubular holes for sulfur storage is fabricated. In contrast to the commonly used melt‐diffusion method to confine sulfur physically, a vapor‐infiltration method is utilized to achieve sulfur/carbon composite with covalent bonds, which can join electrochemical reaction without low voltage activation. A polydopamine derived N‐doped carbon layer is further coated on the composite to confine the high‐temperature‐induced gas‐phase sulfur inside the host. S and N dopants increase the polarity of the carbon host to restrict diffusion of sulfur, and its 3D porous structure provides a large storage area for sulfur. As a result, the obtained composite shows outstanding electrochemical performance with 467 mAh g?1 (1262 mAh g?1(sulfur)) at 0.1 A g?1, 270 mAh g?1 (730 mAh g?1(sulfur)) after 1000 cycles at 1 A g?1 and 201 mAh g?1 (543 mAh g?1(sulfur)) at 5.0 A g?1. 相似文献