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1.
Biwei Xiao Fernando A. Soto Meng Gu Kee Sung Han Junhua Song Hui Wang Mark H. Engelhard Vijayakumar Murugesan Karl T. Mueller David Reed Vincent L. Sprenkle Perla B. Balbuena Xiaolin Li 《Liver Transplantation》2018,8(24)
Hard carbon (HC) is the state‐of‐the‐art anode material for sodium‐ion batteries (SIBs). However, its performance has been plagued by the limited initial Coulombic efficiency (ICE) and mediocre rate performance. Here, experimental and theoretical studies are combined to demonstrate the application of lithium‐pretreated HC (LPHC) as high‐performance anode materials for SIBs by manipulating the solid electrolyte interphase in tetraglyme (TEGDME)‐based electrolyte. The LPHC in TEGDME can 1) deliver > 92% ICE and ≈220 mAh g?1 specific capacity, twice of the capacity (≈100 mAh g?1) in carbonate electrolyte; 2) achieve > 85% capacity retention over 1000 cycles at 1000 mA g?1 current density (4 C rate, 1 C = 250 mA g?1) with a specific capacity of ≈150 mAh g?1, ≈15 times of the capacity (10 mAh g?1) in carbonate. The full cell of Na3V2(PO4)3‐LPHC in TEGDME demonstrated close to theoretical specific capacity of ≈98 mAh g?1 based on Na3V2(PO4)3 cathode, ≈2.5 times of the value (≈40 mAh g?1) with nontreated HC. This work provides new perception on the anode development for SIBs. 相似文献
2.
Ji Qian Feng Wu Yusheng Ye Menglu Zhang Yongxin Huang Yi Xing Wei Qu Li Li Renjie Chen 《Liver Transplantation》2018,8(16)
Sodium‐ion batteries (SIBs) are considered to be a promising alternative for large‐scale electricity storage. However, it is urgent to develop new anode materials with superior ultralong cycle life performance at high current rates. Herein, a low‐cost and large‐scalable sulfur‐doped carbon anode material that exhibits the best high‐rate cycle performance and the longest cycle life ever reported for carbon anodes is developed. The material delivers a reversible capacity of 142 mA h g?1 at a current rate up to 10 A g?1. After 10 000 cycles the capacity is remained at 126.5 mA h g?1; 89.1% of the initial value. Density functional theory computations demonstrate that the sulfur‐doped carbon has a strong binding affinity for sodium which promotes sodium storage. Meanwhile, the kinetics analysis identifies the capacitive charge storage as a large contributor to sodium storage, which favors ultrafast storage of sodium ions. These results demonstrate a new way to design carbon‐based SIBs anodes for next‐generation large‐scale electricity storage. 相似文献
3.
Ji Ung Choi Jae Hyeon Jo Yun Ji Park Kug‐Seung Lee Seung‐Taek Myung 《Liver Transplantation》2020,10(27)
Herein, P′2‐type Na0.67[Ni0.1Fe0.1Mn0.8]O2 is introduced as a promising new cathode material for sodium‐ion batteries (SIBs) that exhibits remarkable structural stability during repetitive Na+ de/intercalation. The O? Ni? O? Mn? O? Fe? O bond in the octahedra of transition‐metal layers is used to suppress the elongation of the Mn? O bond and to improve the electrochemical activity, leading to the highly reversible Na storage mechanism. A high discharge capacity of ≈220 mAh g?1 (≈605 Wh kg?1) is delivered at 0.05 C (13 mAg?1) with a high reversible capacity of ≈140 mAh g?1 at 3 C and excellent capacity retention of 80% over 200 cycles. This performance is associated with the reversible P′2–OP4 phase transition and small volume change upon charge and discharge (≈3%). The nature of the sodium storage mechanism in a full cell paired with a hard carbon anode reveals an unexpectedly high energy density of ≈542 Wh kg?1 at 0.2 C and good capacity retention of ≈81% for 500 cycles at 1 C (260 mAg?1). 相似文献
4.
Jin Zhao Yi‐Zhou Zhang Jianyu Chen Wenli Zhang Du Yuan Rodney Chua Husam N. Alshareef Yanwen Ma 《Liver Transplantation》2020,10(18)
The pursuit of more efficient carbon‐based anodes for sodium‐ion batteries (SIBs) prepared from facile and economical methods is a very important endeavor. Based on the crystallinity difference within carbon materials, herein, a low‐temperature selective burning method is developed for preparing oxygen and nitrogen codoped holey graphene aerogel as additive‐free anode for SIBs. By selective burning of a mixture of graphene and low‐crystallinity carbon at 450 °C in air, an elastic porous graphene monolith with abundant holes on graphene sheets and optimized crystallinity is obtained. These structural characteristics lead to an additive‐free electrode with fast charge (ions and electrons) transfer and more abundant Na+ storage active sites. Moreover, the heteroatom oxygen/nitrogen doping favors large interlayer distance for rapid Na+ insertion/extraction and provides more active sites for high capacitive contribution. The optimized sample exhibits superior sodium‐ion storage capability, i.e., high specific capacity (446 mAh g?1 at 0.1 A g?1), ultrahigh rate capability (189 mAh g?1 at 10 A g?1), and long cycle life (81.0% capacity retention after 2000 cycles at 5 A g?1). This facile and economic strategy might be extended to fabricating other superior carbon‐based energy storage materials. 相似文献
5.
3D Si/C Fiber Paper Electrodes Fabricated Using a Combined Electrospray/Electrospinning Technique for Li‐Ion Batteries
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Although the theoretical capacity of silicon is ten times higher than that of graphite, the overall electrode capacity of Si anodes is still low due to the low Si loading and heavy metal current collector. Here, a novel flexible 3D Si/C fiber paper electrode synthesized by simultaneously electrospraying nano‐Si‐PAN (polyacrylonitrile) clusters and electrospinning PAN fibers followed by carbonization is reported. The combined technology allows uniform incorporation of Si nanoparticles into a carbon textile matrix to form a nano‐Si/carbon composite fiber paper. The flexible 3D Si/C fiber paper electrode demonstrate a very high overall capacity of ≈1600 mAh g‐1 with capacity loss less than 0.079% per cycle for 600 cycles and excellent rate capability. The exceptional performance is attributed to the unique architecture of the flexible 3D Si/C fiber paper, i.e., the resilient and conductive carbon fiber network matrix, carbon‐coated Si nanoparticle clusters, strong adhesion between carbon fibers and Si nanoparticle clusters, and uniform distribution of Si/C clusters in the carbon fiber frame. The scalable and facile synthesis method, good mechanical properties, and excellent electrochemical performance at a high Si loading make the flexible 3D Si/C fiber paper batteries extremely attractive for plug‐in electric vehicles, flexible electronics, space exploration, and military applications. 相似文献
6.
Ran Yi Fang Dai Mikhail L. Gordin Hiesang Sohn Donghai Wang 《Liver Transplantation》2013,3(11):1507-1515
Silicon has been intensively pursued as the most promising anode material for Li‐ion batteries due to its high theoretical capacity of 3579 mAh/g. Micro‐sized Si–C composites composed of nanoscale primary building blocks are attractive Si‐based anodes for practical application because they not only achieve excellent cycling stability, but also offer both gravimetric and volumetric capacity. However, the effects of key parameters in designing such materials on their electrochemical performance are unknown and how to optimize them thus remains to be explored. Herein, the influence of Si nanoscale building block size and carbon coating on the electrochemical performance of the micro‐sized Si–C composites is investigated. It is found that the critical Si building block size is 15 nm, which enables a high capacity without compromising the cycling stability, and that carbon coating at higher temperature improves the first cycle coulombic efficiency (CE) and the rate capability. Corresponding reasons underlying electrochemical performance are revealed by various characterizations. Combining both optimized Si building block size and carbon coating temperature, the resultant composite can sustain 600 cycles at 1.2 A/g with a fixed lithiation capacity of 1200 mAh/g, the best cycling performance with such a high capacity for micro‐sized Si‐based anodes. 相似文献
7.
Hezhe Lin Malin Li Xu Yang Dongxu Yu Yi Zeng Chunzhong Wang Gang Chen Fei Du 《Liver Transplantation》2019,9(20)
Thanks to low costs and the abundance of the resources, sodium‐ion (SIBs) and potassium‐ion batteries (PIBs) have emerged as leading candidates for next‐generation energy storage devices. So far, only few materials can serve as the host for both Na+ and K+ ions. Herein, a cubic phase CuSe with crystal‐pillar‐like morphology (CPL‐CuSe) assembled by the nanosheets are synthesized and its dual functionality in SIBs and PIBs is comprehensively studied. The electrochemical measurements demonstrate that CPL‐CuSe enables fast Na+ and K+ storage as well as the sufficiently long duration. Specifically, the anode delivers a specific capacity of 295 mA h g?1 at current density of 10 A g?1 in SIBs, while 280 mA h g?1 at 5 A g?1 in PIBs, as well as the high capacity retention of nearly 100% over 1200 cycles and 340 cycles, respectively. Remarkably, CPL‐CuSe exhibits a high initial coulombic efficiency of 91.0% (SIBs) and 92.4% (PIBs), superior to most existing selenide anodes. A combination of in situ X‐ray diffraction and ex situ transmission electron microscopy tests fundamentally reveal the structural transition and phase evolution of CuSe, which shows a reversible conversion reaction for both cells, while the intermediate products are different due to the sluggish K+ insertion reaction. 相似文献
8.
Wen Luo Feng Li Jean‐Jacques Gaumet Pierre Magri Sébastien Diliberto Liang Zhou Liqiang Mai 《Liver Transplantation》2018,8(19)
Antimony (Sb) has emerged as an attractive anode material for both lithium and sodium ion batteries due to its high theoretical capacity of 660 mA h g?1. In this work, a novel peapod‐like N‐doped carbon hollow nanotube encapsulated Sb nanorod composite, the so‐called nanorod‐in‐nanotube structured Sb@N‐C, via a bottom‐up confinement approach is designed and fabricated. The N‐doped‐carbon coating and thermal‐reduction process is monitored by in situ high‐temperature X‐ray diffraction characterization. Due to its advanced structural merits, such as sufficient N‐doping, 1D conductive carbon coating, and substantial inner void space, the Sb@N‐C demonstrates superior lithium/sodium storage performance. For lithium storage, the Sb@N‐C exhibits a high reversible capacity (650.8 mA h g?1 at 0.2 A g?1), excellent long‐term cycling stability (a capacity decay of only 0.022% per cycle for 3000 cycles at 2 A g?1), and ultrahigh rate capability (343.3 mA h g?1 at 20 A g?1). For sodium storage, the Sb@N‐C nanocomposite displays the best long‐term cycle performance among the reported Sb‐based anode materials (a capacity of 345.6 mA h g?1 after 3000 cycles at 2 A g?1) and an impressive rate capability of up to 10 A g?1. The results demonstrate that the Sb@N‐C nanocomposite is a promising anode material for high‐performance lithium/sodium storage. 相似文献
9.
Layer‐by‐Layer Na3V2(PO4)3 Embedded in Reduced Graphene Oxide as Superior Rate and Ultralong‐Life Sodium‐Ion Battery Cathode
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Yanan Xu Qiulong Wei Chang Xu Qidong Li Qinyou An Pengfei Zhang Jinzhi Sheng Liang Zhou Liqiang Mai 《Liver Transplantation》2016,6(14)
Na3V2(PO4)3 (NVP) is regarded as a promising cathode for advanced sodium‐ion batteries (SIBs) due to its high theoretical capacity and stable sodium (Na) super ion conductor (NASICON) structure. However, strongly impeded by its low electronic conductivity, the general NVP delivers undesirable rate capacity and fails to meet the demands for quick charge. Herein, a novel and facile synthesis of layer‐by‐layer NVP@reduced graphene oxide (rGO) nanocomposite is presented through modifying the surface charge of NVP gel precursor. The well‐designed layered NVP@rGO with confined NVP nanocrystal in between rGO layers offers high electronic and ionic conductivity as well as stable structure. The NVP@rGO nanocomposite with merely ≈3.0 wt% rGO and 0.5 wt% amorphous carbon, yet exhibits extraordinary electrochemical performance: a high capacity (118 mA h g?1 at 0.5 C attaining the theoretical value), a superior rate capability (73 mA h g?1 at 100 C and even up to 41 mA h g?1 at 200 C), ultralong cyclability (70.0% capacity retention after 15 000 cycles at 50 C), and stable cycling performance and excellent rate capability at both low and high operating temperatures. The proposed method and designed layer‐by‐layer active nanocrystal@rGO strategy provide a new avenue to create nanostructures for advanced energy storage applications. 相似文献
10.
Yan Zhang Vesna Srot Igor Moudrakovski Yuezhan Feng Peter A. van Aken Joachim Maier Yan Yu 《Liver Transplantation》2019,9(27)
Sodium‐ion batteries (SIBs) are considered to be promising energy storage devices for large‐scale grid storage application due to the vast earth‐abundance and low cost of sodium‐containing precursors. Designing and fabricating a highly efficient anode is one of the keys to improve the electrochemical performance of SIBs. Recently, fluoride‐based materials are found to show an exceptional anode function with high theoretical specific capacity, based on open‐framework structure enabling Na insertion and also exhibiting improved safety. However, fluoride‐based materials suffer from sluggish kinetics and poor capacity retention essentially due to low electric conductivity. Here, an efficient mixed‐conducting network offering fast pathways is proposed to address these issues. This network relies on titanium fluoride?carbon (TiF3?C) core/sheath nanofibers that are prepared via electrospinning. Such highly interconnected electrodes exhibit an enhanced and faster sodium storage performance. Carbon sheath nanofibers are key to an efficient ion‐ and electron‐conducting network that enable Na+/e? transfer to reach the nanosized TiF3. In addition, in‐situ‐converted Ti and NaF particles embedded in the carbon matrix allow high reversible interfacial storage. As a result, the TiF3?C core/sheath electrode exhibits a high capacity of 161 mAh g?1 at a high current density of 1000 mA g?1 over 2000 cycles. 相似文献
11.
Yao Xiao Peng‐Fei Wang Ya‐Xia Yin Yan‐Fang Zhu Xinan Yang Xu‐Dong Zhang Yuesheng Wang Xiao‐Dong Guo Ben‐He Zhong Yu‐Guo Guo 《Liver Transplantation》2018,8(22)
Delivery of high‐energy density with long cycle life is facing a severe challenge in developing cathode materials for rechargeable sodium‐ion batteries (SIBs). Here a composite Na0.6MnO2 with layered–tunnel structure combining intergrowth morphology of nanoplates and nanorods for SIBs, which is clearly confirmed by micro scanning electron microscopy, high‐resolution transmission electron microscopy as well as scanning transmission electron microscopy with atomic resolution is presented. Owing to the integrated advantages of P2 layered structure with high capacity and that of the tunnel structure with excellent cycling stability and superior rate performance, the composite electrode delivers a reversible discharge capacity of 198.2 mAh g?1 at 0.2C rate, leading to a high‐energy density of 520.4 Wh kg?1. This intergrowth integration engineering strategy may modulate the physical and chemical properties in oxide cathodes and provide new perspectives on the optimal design of high‐energy density and high‐stable materials for SIBs. 相似文献
12.
Dan Sun Xiaobo Zhu Bin Luo Yu Zhang Yougen Tang Haiyan Wang Lianzhou Wang 《Liver Transplantation》2018,8(26)
Metal phosphides are promising anode candidates for sodium‐ion batteries (SIBs) due to their high specific capacity and low operating potential but suffer from poor cycling stability caused by huge volume expansion and poor solid‐state ion transfer rate. Herein, a new strategy to grow a new class of mesoporous metal phosphide nanoarrays on carbon felt (CF) as binder‐free anodes for SIBs is reported. The resultant integrated electrodes demonstrate excellent cycling life up to 1000 times (>90% retention rate) and high rate capability of 535 mAh g?1 at a current density of 4 A g?1. Detailed characterization reveals that the synergistic effect of unique mesoporous structure for accommodating huge volume expansion during sodiation/desodiation process, ultrasmall primary particle size (≈10 nm) for providing larger electrode/electrolyte contact area and shorter ion diffusion distance, and 3D conductive networks for facilitating the electrochemical reaction, leads to the extraordinary battery performance. Remarkably, a full SIB using the new CoP4/CF anode and a Na3V2(PO4)2F3 cathode delivers an average operating voltage of ≈3.0 V, a reversible capacity of 553 mAh g?1, and very high energy density of ≈280 Wh kg?1 for SIBs. A flexible SIB with outstanding mechanical strength based on this binder‐free new anode is also demonstrated. 相似文献
13.
Since their commercialization by Sony in 1991, graphite anodes in combination with various cathodes have enabled the widespread success of lithium‐ion batteries (LIBs), providing over 10 billion rechargeable batteries to the global population. Next‐generation nonaqueous alkali metal‐ion batteries, namely sodium‐ion batteries (SIBs) and potassium‐ion batteries (PIBs), are projected to utilize intercalation‐based carbon anodes as well, due to their favorable electrochemical properties. While traditionally graphite anodes have dominated the market share of LIBs, other carbon materials have been investigated, including graphene, carbon nanotubes, and disordered carbons. The relationship between carbon material properties, electrochemical performance, and charge storage mechanisms is clarified for these alkali metal‐ion batteries, elucidating possible strategies for obtaining enhanced cycling stability, specific capacity, rate capability, and safety aspects. As a key component in determining cell performance, the solid electrolyte interphase layer is described in detail, particularly for its dependence on the carbon anode. Finally, battery safety at extreme temperatures is discussed, where carbon anodes are susceptible to dendrite formation, accelerated aging, and eventual thermal runaway. As society pushes toward higher energy density LIBs, this review aims to provide guidance toward the development of sustainable next‐generation SIBs and PIBs. 相似文献
14.
Ning Sun Zhaoruxin Guan Yuwen Liu Yuliang Cao Qizhen Zhu Huan Liu Zhaoxiang Wang Peng Zhang Bin Xu 《Liver Transplantation》2019,9(32)
Hard carbons (HCs) are promising anodes of sodium‐ion batteries (SIBs) due to their high capacity, abundance, and low cost. However, the sodium storage mechanism of HCs remains unclear with no consensus in the literature. Here, based on the correlation between the microstructure and Na storage behavior of HCs synthesized over a wide pyrolysis temperature range of 600–2500 °C, an extended “adsorption–insertion” sodium storage mechanism is proposed. The microstructure of HCs can be divided into three types with different sodium storage mechanisms. The highly disordered carbon, with d002 (above 0.40 nm) large enough for sodium ions to freely transfer in, has a “pseudo‐adsorption” sodium storage mechanism, contributing to sloping capacity above 0.1 V, together with other conventional “defects” (pores, edges, heteroatoms, etc.). The pseudo‐graphitic carbon (d‐spacing in 0.36–0.40 nm) contributes to the low‐potential (<0.1 V) plateau capacity through “interlayer insertion” mechanism, with a theoretical capacity of 279 mAh g?1 for NaC8 formation. The graphite‐like carbon with d002 below 0.36 nm is inaccessible for sodium ion insertion. The extended “adsorption–insertion” model can accurately explain the dependence of the sodium storage behavior of HCs with different microstructures on the pyrolysis temperature and provides new insight into the design of HC anodes for SIBs. 相似文献
15.
Hard Carbon Anodes and Novel Electrolytes for Long‐Cycle‐Life Room Temperature Sodium‐Sulfur Full Cell Batteries
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A novel combination of hard carbon anode sodium pre‐loading and a tailored electrolyte is used to prepare room temperature sodium‐sulfur full cell batteries. The electrochemical loading with sodium ions is realized in a specific mixture of diethyl carbonate, ethylene carbonate, and fluoroethylene carbonate electrolyte in order to create a first solid electrolyte interface (SEI) on the anode surface. Combining such anodes with a porous carbon/sulfur composite cathode results in full cells with a significantly decreased polysulfide shuttle when compared to half cells combined with metallic sodium anodes. Further optimization involves the use of Na2S/P2S5 doped tetraethylene glycol dimethyl ether based electrolyte in the full cell for the formation of a second SEI, reducing polysulfide shuttle even further. More importantly, the electrochemical discharge processes in the cell are improved by adding this dissolved complexation agent to the electrolyte. As a result of this combination sodium‐sulfur cells with tailored cathode materials and electrolytes can achieve high discharge capacities up to 980 mAh g?1sulfur and 1000 cycles with 200 mAh g?1sulfur remaining capacity, at room temperature. 相似文献
16.
Zeheng Li Yaping Zhang Tiefeng Liu Xuehui Gao Siyuan Li Min Ling Chengdu Liang Junchao Zheng Zhan Lin 《Liver Transplantation》2020,10(20)
High‐capacity electrode materials play a vital role for high‐energy‐density lithium‐ion batteries. Silicon (Si) has been regarded as a promising anode material because of its outstanding theoretical capacity, but it suffers from an inherent volume expansion problem. Binders have demonstrated improvements in the electrochemical performance of Si anodes. Achieving ultrahigh‐areal‐capacity Si anodes with rational binder strategies remains a significant challenge. Herein, a binder‐lithiated strategy is proposed for ultrahigh‐areal‐capacity Si anodes. A hard/soft modulated trifunctional network binder (N‐P‐LiPN) is constructed by the partially lithiated hard polyacrylic acid as a framework and partially lithiated soft Nafion as a buffer via the hydrogen binding effect. N‐P‐LiPN has strong adhesion and mechanical properties to accommodate huge volume change of the Si anode. In addition, lithium‐ions are transferred via the lithiated groups of N‐P‐LiPN, which significantly enhances the ionic conductivity of the Si anode. Hence, the Si@N‐P‐LiPN electrodes achieve the highest initial Coulombic efficiency of 93.18% and a stable cycling performance for 500 cycles at 0.2 C. Specially, Si@N‐P‐LiPN electrodes demonstrate an ultrahigh‐areal‐capacity of 49.59 mAh cm?2. This work offers a new approach for inspiring the battery community to explore novel binders for next‐generation high‐energy‐density storage devices. 相似文献
17.
Revealing Pseudocapacitive Mechanisms of Metal Dichalcogenide SnS2/Graphene‐CNT Aerogels for High‐Energy Na Hybrid Capacitors
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Jiang Cui Shanshan Yao Ziheng Lu Jian‐Qiu Huang Woon Gie Chong Francesco Ciucci Jang‐Kyo Kim 《Liver Transplantation》2018,8(10)
SnS2 nanoplatelet electrodes can offer an exceptionally high pseudocapacitance in an organic Na+ ion electrolyte system, but their underlying mechanisms are still largely unexplored, hindering the practical applications of pseudocapacitive SnS2 anodes in Na‐ion batteries (SIBs) and Na hybrid capacitors (SHCs). Herein, SnS2 nanoplatelets are grown directly on SnO2/C composites to synthesize SnS2/graphene‐carbon nanotube aerogel (SnS2/GCA) by pressurized sulfidation where the original morphology of carbon framework is preserved. The composite electrode possessing a large surface area delivers a remarkable specific capacity of 600.3 mA h g?1 at 0.2 A g?1 and 304.8 mA h g?1 at an ultrahigh current density of 10 A g?1 in SIBs. SHCs comprising a SnS2/GCA composite anode and an activated carbon cathode present exceptional energy densities of 108.3 and 26.9 W h kg?1 at power densities of 130 and 6053 W kg?1, respectively. The in situ transmission electron microscopy and the density functional theory calculations reveal that the excellent pseudocapacitance originates from the combination of Na adsorption on the surface/Sn edge of SnS2 nanoplatelets and ultrafast Na+ ion intercalation into the SnS2 layers. 相似文献
18.
Benefiting from the high abundance and low cost of sodium resource, rechargeable sodium‐ion batteries (SIBs) are regarded as promising candidates for large‐scale electrochemical energy storage and conversion. Due to the heavier mass and larger radius of Na+ than that of Li+, SIBs with inorganic electrode materials are currently plagued with low capacity and insufficient cycling life. In comparison, organic electrode materials display the advantages of structure designability, high capacity and low limitation of cationic radius. However, organic electrode materials also encounter issues such as high‐solubility in electrolyte and low conductivity. Here, recently reported organic electrode materials, which mainly include the reactions based on either carbon‐oxygen double bond or carbon‐nitrogen double bond, and doping reactions, are systematically reviewed. Furthermore, the design strategies of organic electrodes are comprehensively summarized. The working voltage is regulated through controlling the lowest unoccupied molecular orbital energies. The theoretical capacity can be enhanced by increasing the active groups. The dissolution is inhibited with elevating the intermolecular forces with proper molecular weight. The conductivity can be improved with extending conjugated structures. Future research into organic electrodes should focus on the development of full SIBs with aqueous/aprotic electrolytes and long cycling stability. 相似文献
19.
Ying‐Ying Wang Bao‐Hua Hou Jin‐Zhi Guo Qiu‐Li Ning Wei‐Lin Pang Jiawei Wang Chang‐Li Lü Xing‐Long Wu 《Liver Transplantation》2018,8(18)
Presently, commercialization of sodium‐ion batteries (SIBs) is still hindered by the relatively poor energy‐storage performance. In addition, low‐temperature (low‐T) Na storage is another principal concern for the wide application of SIBs. Unfortunately, the Na‐transfer kinetics is extremely sluggish at low‐T, as a result, there are few reports on low‐T SIBs. Here, an advanced low‐T sodium‐ion full battery (SIFB) assembled by an anode of 3D Se/graphene composite and a high‐voltage cathode (Na3V2(PO4)2O2F) is developed, exhibiting ultralong lifespan (over even 15 000 cycles, the capacity retention is still up to 86.3% at 1 A g?1), outstanding low‐T energy storage performance (e.g., all values of capacity retention are >75% after 1000 cycles at temperatures from 25 to ?25 °C at 0.4 A g?1), and high‐energy/power properties. Such ultralong lifespan signifies that the developed sodium‐ion full battery can be used for longer than 60 years, if batteries charge/discharge once a day and 80% capacity retention is the standard of battery life. As a result, the present study not only promotes the practicability and commercialization of SIBs but also points out the new developing directions of next‐generation energy storage for wider range applications. 相似文献
20.
Jin Zhao Yi‐Zhou Zhang Fan Zhang Hanfeng Liang Fangwang Ming Husam N. Alshareef Zhiqiang Gao 《Liver Transplantation》2019,9(7)
The current Na+ storage performance of carbon‐based materials is still hindered by the sluggish Na+ ion transfer kinetics and low capacity. Graphene and its derivatives have been widely investigated as electrode materials in energy storage and conversion systems. However, as anode materials for sodium‐ion batteries (SIBs), the severe π–π restacking of graphene sheets usually results in compact structure with a small interlayer distance and a long ion transfer distance, thus leading to low capacity and poor rate capability. Herein, partially reduced holey graphene oxide is prepared by simple H2O2 treatment and subsequent low temperature reduction of graphene oxide, leading to large interlayer distance (0.434 nm), fast ion transport, and larger Na+ storage space. The partially remaining oxygenous groups can also contribute to the capacity by redox reaction. As anode material for SIBs, the optimized electrode delivers high reversible capacity, high rate capability (365 and 131 mAh g?1 at 0.1 and 10 A g?1, respectively), and good cycling performance (163 mAh g?1 after 3000 cycles at a current density of 2 A g?1), which is among the best reported performances for carbon‐based SIB anodes. 相似文献