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1.
Plasmonics - The novel surface plasmon resonance (SPR) sensor based on hybrid structure of Ag-indium tin oxide (ITO)-blue phosphorene (BlueP)/transition metal dichalcogenides (TMDCs)-graphene is...  相似文献   

2.
Wang  Jianshuai  Pei  Li  Wu  Liangying  Wang  Ji  Ruan  Zuliang  Zheng  Jingjing 《Plasmonics (Norwell, Mass.)》2020,15(2):327-333

A surface plasmon resonance (SPR) sensor based on a photonic crystal fiber (PCF) is proposed for low refractive index (RI) detection. The core of PCF is formed by two-layer air walls and either layer is composed of six identical sector rings with negative curvature. Plasmonic material gold (Au) is coated on the external cladding surface. Finite element method (FEM) is applied to investigate the performance of the SPR sensor. Results show that the sensor is independent of polarization due to the coincident coupling properties of the two polarized modes. Additionally, in low RI ranging from 1.20 to 1.33, the sensor keeps a high spectral sensitivity with an average value of 7738 nm/RIU. When RI varies from 1.32 to 1.33, the resolution reaches to its maximum of 8.3 × 10−6. The proposed sensor shows much significance in low RI detection, which is promising in real-time measurement for medical, water pollution, and humidity.

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3.
Du  Bobo  Yang  Yuan  Zhang  Yang  Yang  Dexing 《Plasmonics (Norwell, Mass.)》2019,14(2):457-463

In this article, a surface plasmon resonance (SPR) biosensor based on D-typed optical fiber coated by Al2O3/Ag/Al2O3 film is investigated numerically. Resonance in near infrared with an optimized architecture is achieved. Refractive index sensitivity of 6558 nm/RIU (refractive index unit) and detection limit of 1.5 × 10−6 RIU, corresponding to 0.4357 nm/μM and detection limit of 23 nM in BSA (bovine serum albumin) concentration sensing, are obtained. The analysis of the performance of the sensor in gaseous sensing indicates that this proposed SPR sensor is much suitable for label-free biosensing in aqueous media.

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4.

Continuous monitoring of air quality and rapid detection of pollutants are highly desirable in urban planning and development of smart cities. One of the primary greenhouse gases responsible for environmental degradation and respiratory diseases is nitrogen dioxide (NO2). Existing gas sensors for measuring NO2 concentration suffer from drawbacks such as cross-sensitivity, limited range, and short life span. On the other hand, optical sensors, in particular, surface plasmon resonance (SPR) sensors, have emerged as a preferred alternative owing to advantages like high selectivity, immunity to electromagnetic interference, and low response time. In this work, we design and simulate a NO2 sensor based on a glass waveguide coated with a gold film. Surface plasmons are excited at the interface by a 400–500-nm light source, incident at an angle of 43.16°. To enhance the sensitivity, we further coat the waveguide with three layers of carbon-silver (C–Ag) nanodots, which increases the surface plasmon field amplitude by nearly 7 times, in the absence of NO2. When NO2 concentration is varied in the range of 0–200 ppm, a corresponding change is observed in the reflected amplitude. In the absence of the C–Ag nanodots layer, the sensitivity is only 0.00042%/ppm, and on addition of C–Ag nanodots, the sensitivity increases significantly to 0.14235%/ppm which is nearly 343 times higher. These results demonstrate the efficiency of implementing nanodots in SPR sensor to detect and trace concentrations of contaminants in the gas phase.

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5.

The 2D material tin selenide monolayer (SnSe) has attracted a lot of attention due to its excellent optoelectronic properties. This study focuses on the investigation of the potential improvement of the response of surface plasmon resonance (SPR) sensors by coating the gold layer with SnSe allotrope (α, δ, ε) monolayers. Using an optimization algorithm along with the transfer matrix method (TMM), we determined the optimal thickness of the gold layer as a function of the number of monolayers added to significantly increase the sensor’s response in terms of reflectivity and phase. With respect to reflectivity, sensitivity increased by 20% in comparison with the optimal bare gold structure, whilst with respect to phase, sensitivity was approximately two orders of magnitude greater than the bare gold structure. Our results demonstrate that SPR sensors modified with SnSe monolayers could be used in diagnostic applications where both high sensitivity and small concentration of analyte are required.

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6.
In this article, numerically a surface plasmon resonance (SPR) biosensor is developed based on Graphene-MOS2 with TiO2SiO2 hybrid structure for the detection of formalin. Based on attenuated total reflection (ATR) method, we used angular interrogation technique to sense the presence the formalin by observing the change of “minimum reflectance with respect to SPR angle” and “maximum transmittance with respect to surface plasmon resonance frequency (SPRF)”. Here, we used Chitosan as probe analyte to perform chemical reaction with formalin (formaldehyde) which is consider as target analyte. Simulation results show a negligible variation of SPRF and SPR angle for improper sensing of formalin that confirms absence of formalin whereas for proper sensing is considerably countable that confirms the presence of formalin. Thereafter, a comparison of sensitivity for different sensor structure is made. It is observed that the sensitivity without TiO2, SiO2, MoS2 and Graphene (conventional structure) is very poor and 73.67% whereas the sensitivity with graphene but without TiO2, SiO2 and MoS2 layers is 74.67% consistently better than the conventional structure. This is due to the electron loss of graphene, which is accompanying with the imaginary dielectric constant. Furthermore, the sensitivity without TiO2, SiO2 and graphene but with MoS2 layer is 79.167%. After more if both graphene and MoS2 are used and TiO2 and SiO2 layers are not used then sensitivity improves to 80.5%. This greater than before performance is due to the absorption ability and optical characteristics of graphene biomolecules and high fluorescence quenching ability of MoS2. Further again, if TiO2SiO2 composite layer is used with the Graphene-MoS2 then the sensitivity enhances from 80.5% to 82.5%. Finally, the sensitivity for the proposed structure has been carried out, and result is 82.83%, the highest value among all the previous structures to integrate the advantages of graphene, MoS2, TiO2 and SiO2.  相似文献   

7.
Han  Lei  Ding  Huafeng  Huang  Tianye  Wu  Xu  Chen  Bingwei  Ren  Kaixuan  Fu  Songnian 《Plasmonics (Norwell, Mass.)》2018,13(4):1309-1314

A surface plasmon resonance (SPR)-based optical reflection modulator consisting of vertically stacked silica-silicon-HfO2-ITO-HfO2-Ag-prism multilayer is proposed and numerically investigated. The free carrier-concentration-dependent permittivity of indium-tin-oxide (ITO) at the HfO2/ITO interface induces an epsilon-near-zero (ENZ) effect contributing to strong field enhancement and modifies the SPR condition of incident light. With optimal geometry parameters and proper design of carrier concentration at the accumulation layer, modulation depth (MD) of ~100% and insertion loss (IL) of 3.7% can be simultaneously achieved. The IL can be further reduced by engineering silicon layer thickness. Moreover, the device offers a broadband operation wavelength from 1.5 to 1.6 μm with the variations of MD and IL smaller than 4 and 3%, respectively.

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8.

Surface plasmon resonance (SPR)–based structures are finding important applications in sensing biological as well as inorganic samples. In SPR techniques, an angle-resolved reflection (R) profile of the incident light from a metal-dielectric interface is measured and the resonance characteristics are extracted for the identification of the target sample. However, the performance, and hence the applicability of these structures, suffers when the weight and concentration of the target samples are small. Here, we show that SPR-based sensors can create strong magnetism at optical frequency, which can be used for the detection of target samples instead of using the conventional R profiles, as the magnetic resonance varies depending on the refractive index of the target sample. Using scattering parameters retrieval method, we computationally find out the effective permeability (μeff) of a SPR sensor with a structure based on Kretschmann configuration, and use it to calculate the performance of the sensor. A comparison with the conventional technique that uses R profile to detect a target sample shows a significant increase in the sensor performance when μeff is used instead.

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9.
Owing to its large surface-to-volume ratio and good biocompatibility, graphene has been identified as a highly promising candidate as the sensing layer for fiber optic sensors. In this paper, a graphene/Au-enhanced plastic clad silica (PCS) fiber optic surface plasmon resonance (SPR) sensor is presented. A sheet of graphene is employed as a sensing layer coated around the Au film on the PCS fiber surface. The PCS fiber is chosen to overcome the shortcomings of the structured microfibers and construct a more stable and reliable device. It is demonstrated that the introduction of graphene can enhance the intensity of the confined electric field surrounding the sensing layer, which results in a stronger light-matter interaction and thereby the improved sensitivity. The sensitivity of graphene-based fiber optic SPR sensor exhibits more than two times larger than that of the conventional gold film SPR fiber optic sensor. Furthermore, the dynamic response analyses reveal that the graphene/Au fiber optic SPR sensor exhibits a fast response (5 s response time) and excellent reusability (3.5% fluctuation) to the protein biomolecules. Such a graphene/Au fiber optic SPR sensor with high sensitivity and fast response shows a great promise for the future biochemical application.  相似文献   

10.
Gu  Sanfeng  Sun  Wei  Li  Meng  Zhang  Tianheng  Deng  Ming 《Plasmonics (Norwell, Mass.)》2022,17(3):1129-1137

A dual-core and dual D-shaped photonic crystal fiber (PCF)-based surface plasmon resonance (SPR) sensor with silver and aluminum nitride (AlN) films is designed. The distribution characteristics of the electromagnetic fields of core and plasmon modes, as well as the sensing properties, are numerically studied by finite element method (FEM). The structure parameters of the designed sensor are optimized by the optical loss spectrum. The results show the resonance wavelength variation of 489 nm for the refractive index (RI) range of 1.36?~?1.42. In addition, a maximum wavelength sensitivity of 13,400 nm/RIU with the corresponding RI resolution of 7.46?×?10?6 RIU is obtained in the RI range of 1.41?~?1.42. The proposed sensor with the merits of high sensitivity, low cost, and simple structure has a wide application in the fields of RI sensing, such as hazardous gas detection, environmental monitoring, and biochemical analysis.

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11.

Highly sensitive surface plasmon resonance (SPR) sensor consisting of Ag-Pt bimetallic films sandwiched with 2D materials black phosphorus (BP) and graphene over Pt layer in Kretschmann configuration is analyzed theoretically using the transfer matrix method. Numerical results show that upon suitable optimization of thickness of Ag-Pt layers and the number of layers of BP and graphene, sensitivity as high as 412°/RIU (degree/refractive index unit) can be achieved for p-polarized light of wavelength 633 nm. This performance can be tuned and controlled by changing the number of layers of BP and graphene. Furthermore, the addition of graphene and heterostructures of black phosphorus not only improved the sensitivity of the sensor but also kept the FWHM of the resonance curve much smaller than the conventional sensor utilizing Au as plasmonic metal and hence improved the resolution to a significant extent. We expect that this new proposed design will be useful for medical diagnosis, biomolecular detection, and chemical examination.

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12.

Chikungunya virus has been discovered in about 60 countries of the world. It leads to joint pain, joint swelling, headache, muscle pain, and fatigue of the human body. In this work, a surface plasmon resonance (SPR)based sensor is developed to detect chikungunya virus through normal and infected platelets and plasma blood cells. The proposed SPR-based sensor uses silicon and graphene layers coated over the base of a glass prism sputtered with a silver layer. The graphene layer has the advantage of enhancing the biomolecules adsorption on the metal layer. The silicon layer between silver and graphene enhances the sensor performance. The number of graphene layers along with the thicknesses of silicon and silver layers is optimized to get the highest sensitivity of the detector. To investigate the effect of the light source wavelength, simulations are performed for four different wavelengths. The highest sensitivities exhibited by the SPR-based sensor are 393 and 160 deg/RIU for the platelets and plasma cells, respectively.

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13.
Due to the industrial development, drinking water is getting polluted by disposing several waste products of the industries. Hardness is one of the prominent impurities in drinking water which is mainly due to the presence of carbonate and bicarbonate ions (CO3 2? and HCO3 ?) in it. Here, we present the synthesis of the zinc oxide (ZnO) and polyaniline (PANI) nanocomposite for the detection and estimation of hardness of the drinking water. The chemical formula of such a nanocomposite is defined in terms of the fraction of polyaniline nanoparticles reinforced in ZnO matrix and is derived as ZnO(1???x)PANI x (0?≤?x?≤?0.9); x is the composition ratio. Silver and ZnO(1???x)PANI x layers are coated over the unclad core of the optical fiber so as to create the four layer system as that of Kretschmann configuration SPR structure. The working principle involves the change in dielectric constant of (ZnO(1???x)PANI x ) by CO3 2? or HCO3 ? ions in aqueous atmosphere. Due to the strong interaction of the sensing surface to the CO3 2? and HCO3 ? ions, a red shift in the SPR spectrum is observed in the concentration range 0–200 μg/l. The sensitivity of the sensor depends on the composition ratio of the nanocomposite and has been found to be maximum for the composition ratio lying in the range 0.45–0.60. This has been further confirmed in terms of the enhancement of the electric field density and found to be in agreement with the experimental value. The sensitivity of the sensor with optimum value of the composition ratio is 0.094 and 0.065 nm/(μg/l) for CO3 2? and HCO3 ?, respectively. The sensor is highly selective to CO3 2? and HCO3 ?. The sensor has advantages of online monitoring and remote sensing of water quality because the probe is fabricated over an optical fiber.  相似文献   

14.
Zhu  Jun  Xu  Zhengjie  Xu  Wenju  Fu  Deli  Song  Shuxiang 《Plasmonics (Norwell, Mass.)》2018,13(2):681-686

The field of plasmonics has experienced a renaissance in recent years by providing a large variety of new physical effects and applications. Here, we demonstrate a light humidity sensor of surface plasmon resonance (SPR) by a symmetric metal film, which uses P polarised light of emergent He–Ne laser to stimulate SPR. Resonance angle change received by the spectrum detector can determine humidity via the relationship between humidity and effective refractive index. When the relatively short wavelengths are shown in the model, the evanescent wave penetration depth is shallow, resonance state is weak and energy loss is low. The opposite results are obtained, when the wavelength is long. Also, with increasing thickness, the resonance peak becomes acute, thereby indicating the improvement in detection accuracy. When the metal thickness of our model is 50 nm, the resonance peak of the reflection spectrum is narrower, accuracy is high and reflectivity is close to 0. By analysing the experimental results, the SPR resonance phenomenon is shown. The electromagnetic field energy is highly concentrated near the interface between the metal and SiO2, which appears highly localized. The resolution of the structure can reach 0.37% RH (relative humidity), which is significantly more than the resolution of capacitive humidity sensor, i.e., resolution is usually 1% RH to 2% RH. The optical sensor of our development can provide a key device for long-distance transmission sensing, in special conditions such as low temperature.

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15.
We propose a surface plasmon resonance (SPR)-based refractive index sensor using gold-alumina grating over aluminum film for biosensing. Conventional SPR sensor based on gold grating exhibits broader SPR dips whereas that based on aluminum grating exhibits narrow reflection dip. A narrow reflection dip is desirable as it provides good resolution and improves the accuracy of measurement. Aluminum is less stable and generally is not preferred for an SPR-based sensor. It is more prone to being oxidized, which reduces the sensitivity and increases the width of the reflection dip of the sensor. While gold cannot provide narrow SPR reflection dips, but is used as an SPR active metal due to its more chemical stability. In order to improve the accuracy of gold grating-based sensor while taking care of oxidation problem of aluminum, in this paper, we propose a gold grating over aluminum film for SPR-based sensor and show that this configuration improves the sensitivity and the detection accuracy of the conventional sensor. Moreover, the oxidation problem is reduced to some extent as a part of aluminum is covered with gold. In order to completely avoid the oxidation of aluminum, we further propose to cover the exposed part of the aluminum with alumina and show that this configuration further improves the accuracy by reducing the width of the SPR reflection dip without affecting the sensitivity significantly. Numerical simulations show that sensitivity of proposed sensor is 270.33°/RIU with quality factor of more than 267.65 RIU?1.  相似文献   

16.

The influence of TiO2 coating on resonant properties of gold nanoisland films deposited on silica substrates was studied numerically and in experiments. The model describing plasmonic properties of a metal truncated nanosphere placed on a substrate and covered by a thin dielectric layer has been developed. The model allows calculating a particle polarizability spectrum and, respectively, its surface plasmon resonance (SPR) wavelength for any given cover thickness, particle radius and truncation parameter, and dielectric functions of the particle, the substrate, the coating layer, and the surrounding medium. Dependence of the SPR position calculated for truncated gold nanospheres has coincided with the measured one for the gold nanoisland films covered with titania of different thicknesses. In the experiments, gold films with thickness of 5 nm were deposited on a silica glass substrate, annealed at 500 °C to form nanoislands of 20 nm in diameter, and covered with amorphous titania layers using atomic layer deposition technique. The resulting structures were characterized with scanning electron microscopy and optical absorption spectroscopy. The measured dependence of the SPR position on titania film thickness corresponded to the one calculated for truncated sphere-shaped nanoparticles with the truncation angle of ~50°. We demonstrated the possibility of tuning the SPR position within ~100 nm range by depositing to 30 nm thick titania layer.

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17.
We design terahertz (THz) surface-plasmon-resonance (SPR) sensors using a ferroelectric polyvinylidene fluoride (PVDF) thin layer for biological sensing. The reflectivity properties based on SPR are described using transfer matrix method (TMM) and numerically simulated using finite-difference time domain (FDTD) method. The sensing characteristics of the structure are systematically analyzed through the examination of the reflectivity spectrum. The results reveal that the pronounced SPR resonance peak has quasi-linear relationship with the refractive index variation of the material under investigation. Through analyzing and optimizing the structural parameters of the THz SPR sensor, we achieved the theoretical value of the refractive index detection sensitivity as high as 0.393 THz/unit change of refractive index (RIU) for a 20-μm-thick liquid sample with a 10-μm PVDF layer. This work shows great promise toward realizing a THz SPR sensor with high sensitivity for identifying the signatures of biological fluid sample.  相似文献   

18.
Diagnostic biomarkers such as proteins and enzymes are generally hard to detect because of the low abundance in biological fluids. To solve this problem, the advantages of surface plasmon resonance (SPR) and nanomaterial technologies have been combined. The SPR sensors are easy to prepare, no requirement of labelling and can be detected in real time. In addition, they have high specificity and sensitivity with low cost. The nanomaterials have also crucial functions such as efficiency improvement, selectivity, and sensitivity of the detection systems. In this report, an SPR‐based sensor is developed to detect lysozyme with hydrophobic poly (N‐methacryloyl‐(L)‐phenylalanine) (PMAPA) nanoparticles. The SPR sensor was first characterized by attenuated total reflection‐Fourier transform infrared, atomic force microscope, and water contact angle measurements and performed with aqueous lysozyme solutions. Various concentrations of lysozyme solution were used to calculate kinetic and affinity coefficients. The equilibrium and adsorption isotherm models of interactions between lysozyme solutions and SPR sensor were determined and the maximum reflection, association, and dissociation constants were calculated by Langmuir model as 4.87, 0.019 nM−1, and 54 nM, respectively. The selectivity studies of SPR sensor were investigated with competitive agents, hemoglobin, and myoglobin. Also, the SPR sensor was used four times in adsorption/desorption/recovery cycles and results showed that, the combination of optical SPR sensor with hydrophobic ionizable PMAPA nanoparticles in one mode enabled the detection of lysozyme molecule with high accuracy, good sensivity, real‐time, label‐free, and a low‐detection limit of 0.66 nM from lysozyme solutions. Lysozyme detection in a real sample was performed by using chicken egg white to evaluate interfering molecules present in the medium.  相似文献   

19.

A self-referencing plasmonic platform is proposed and analyzed. By introducing a thin gold layer below a periodic two-dimensional nano-grating, the structure supports multiple modes including localized surface plasmon resonance (LSPR), surface plasmon resonance (SPR), and Fabry-Perot resonances. These modes get coupled to each other creating multiple Fano resonances. A coupled mode between the LSPR and SPR responses is spatially separated from the sensor surface and is not sensitive to refractive index changes in the surrounding materials or surface attachments. This mode can be used for self-referencing the measurements. In contrast, the LSPR dominant mode shifts in wavelength when the refractive index of the surrounding medium is changed. The proposed structure is easy to fabricate using conventional lithography and electron beam deposition methods. A bulk sensitivity of 429 nm/RIU is achieved. The sensor also has the ability to detect nanometer thick surface attachments on the top of the grating.

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20.

Surface plasmon resonance (SPR), a highly sensitive and label-free optical biosensing technique, is a powerful tool for studying biomolecular interactions. An immunosensor for rapid, sensitive, and selective detection of Vibrio cholerae on the basis of SPR is reported. Recombinant OmpW antigen (a bacterial outer-membrane protein) of V. cholerae was expressed and purified and raising of polyclonal rabbit anti-OmpW was done. Antibodies were immobilized on a sensor surface and interactions between OmpW protein and the whole cell of V. cholerae with immobilized antibodies were studied in different experiments. The aim of this study was to evaluate the potential of anti-OmpW in detection of V. cholerae by developing an immunosensor based on SPR. The results showed high affinity interaction between OmpW and anti-OmpW (K D = 2.4 ± 0.07 × 10−9 M) and SPR signals had a linear relationship with the number of V. cholerae ranging from 1 × 102 to 1 × 107 cells/mL with limit of detection of 50 cells/mL. The specificity of the developed immunoassay was examined using some non-V. cholerae bacteria which did not produce any significant responses. This method is rapid, sensitive, and specific to target V. cholerae with a total analysis time of less than 60 min.

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