Tunable Goos-Hänchen Shift of Surface Plasmon Beam Due to Graphene in a Metal-Dielectric System

The tunneling of surface plasmon waves between two slabs of dielectric prisms superposed on the metal surface is studied. The prism with the incident surface plasmon wave is superposed by a stack of graphene sheets. The analytical theory is built to connect the Fermi energy of graphene with the Goos-Hänchen shift of the transmitted surface plasmon waves. The obtained results may be useful for developing integral switching devices on the basis of surface plasmon polaritons.

     

Sensitivity Enhanced by MoS2–Graphene Hybrid Structure in Guided-Wave Surface Plasmon Resonance Biosensor

Plasmonics - Compared with surface plasmon resonance (SPR) biosensor, guided-wave surface plasmon resonance (GWSPR) biosensor has a higher sensitivity. In order to further enhance the sensitivity...     

Contribution of the Resonance Raman Spectroscopy to the Identification of Z DNA

Abstract

Poly(dG-dC)?poly(dG-dC) at low salt concentration (0.1 M NaCl) and at high salt concentration (4.5 M NaCl) has been studied by Raman resonance spectroscopy using two excitation wavelengths: 257 nm and 295 nm. As resonance enhances the intensity of the lines in a proportion corresponding to the square of the molar absorption coefficient, the intensities of the lines with 295 nm wavelength excitation are enhanced about sevenfold during the B to Z transition.

With 257 nm excitation wavelength the 1580 cm^?1 line of guanosine is greatly enhanced in the Z form whereas with 295 nm excitation several lines are sensitive to the modifications of the conformation: the guanine band around 650 cm^?1 and at 1193 cm^?1 and the bands of the cytosines at 780 cm^?1, 1242 cm^?1 and 1268 cm^?1.

By comparison with the U.V. resonance Raman spectra of DNA, we conclude that resonance Raman spectroscopy allows one to characterize the B to Z transition from one line with 257 nm excitation wavelength and from three lines with 295 nm excitation. The conjoined study of these four lines should permit to observe a few base pairs being in Z form in a DNA.     

Electronic Beam Switching of Circularly Polarized Plasma Magneto-Electric Dipole Array with Multiple Beams

In this paper, different array arrangements based on magneto-electric (ME) dipole antenna with wideband circular polarization (CP) characteristics are designed and investigated. Planar, triangular prism, square prism, and hexagonal prism array arrangements are considered. Each prism face has a sub-array comprises 2 × 2 ME-dipole elements. Each sub-array has wide impedance matching of 73.7%, a maximum gain of 16.6 dBi, and CP bandwidth of 78.2%. It employs the plasma frequency of the ME-dipole antenna to control its radiation characteristics. Frequency-independent lumped element equivalent circuit is constructed for a single antenna element. It is used to represent the antenna input impedance at different plasma electron densities with fixed physical structure. The proposed equivalent circuit comprises a single series section used for matching enhancement with feeder circuit, and three parallel tuned circuits corresponding to the three resonance frequencies in the input impedance. The best values of the equivalent circuit elements are computed using the particle swarm optimization (PSO) technique. Different array arrangements, planar, triangular, square, and hexagonal prism are designed to create single or multiple beams in different directions. An electronic beam switching is achieved by tuning in the plasma inside the ME-dipole in the desired direction. The radiation characteristics are analyzed and investigated using the finite integration technique (FIT).

     

Actively Tunable Fano Resonance in H-Like Metal-Graphene Hybrid Nanostructures

Actively tunable Fano resonance has obvious advantages in applications such as chemical or biological sensors, switches, modulators, and optical filters. In this paper, we studied theoretically the actively tunable Fano resonance in H-like metal-graphene hybrid nanostructures at visible and near-infrared wavelengths. We found that the absorption spectrum of H-like metal-graphene hybrid nanostructures has two resonance peaks, and the absorption spectrum has an obvious blue shift compared with that of the H-like metal nanostructures without graphene. The optical properties of different nanostructures are explained by the electric field distribution. Then, the dependence of the Fano resonance on the nanostructure parameters, refractive index of host materials, and graphene Fermi energy is studied. The wavelength and intensity of absorption spectrum can be manipulated by adjusting the structure parameters and host materials. In addition, the wavelength and intensity of absorption spectrum can be manipulated actively by changing the Fermi energy levels of graphene. This study provides a method for designing the actively tunable Fano resonance in H-like metal-graphene hybrid nanostructures.

     

Resonance Bandwidth Controllable Adjustment of Electromagnetically Induced Transparency-like Using Terahertz Metamaterial

In the fields of communication and sensing, resonance bandwidth is a very critical index. It is very meaningful to implement a broadband resonance device with a simple metamaterial structure in the terahertz band. In this paper, we propose a simple metamaterial structure which consists of one horizontal metal strip and two vertical metal strips. This structure can achieve an electromagnetically induced transparency-like (EIT-like) effect in the frequency range of 0.1~3.0 THz to obtain a transparent window with a resonance bandwidth as high as 1.212 THz. When the relative distance between two vertical metal strips is changed, the bandwidth can be effectively controlled. Furthermore, we found that the EIT-like effect can be actively adjusted by replacing vertical metal strips with photosensitive silicon.

     

Sensitive Gap-Enhanced Raman Spectroscopy with a Perfect Radially Polarized Beam

Gap mode surface-enhanced Raman spectroscopy (SERS) enables high enhancement of Raman signal. However, the polarization of excitation light shows great influence on the excitation of gap mode and hence on the Raman enhancement. Here, we propose a nanoparticle-on-film gap mode SERS accompanying with a new type of excitation source called as perfect radially polarized (PRP) beam. The PRP beam possesses a ring-shaped beam pattern that can be tuned to match the surface plasmon resonance angle under a tight focusing condition, hence improving greatly the excitation efficiency of surface plasmon polaritons, and eventually the sensitivity of gap mode SERS. Such kind of enhanced-Raman system with a PRP beam has a great potential on the applications such as single molecule Raman detection.

     

Analytical Approach to the Prism Coupling Problem in the Kretschmann Configuration

Prism coupling in the Kretschmann configuration is a well-known method for excitation of surface plasmon polaritons (SPP’s) in a metal film bounded from one side by a prism and from the other side by air. The analysis of the reflectance in the upper medium (prism) is based on the well-known Fresnel’s formula. Due to the fact that this formula cannot be inverted directly to give the complex dielectric permittivity and the thickness of the metal film from measured values of the reflectance at three or more different angles of incidence, an additional analysis is needed. Here, such an analysis is presented. The special case of illumination with He–Ne laser (λ = 632.8 nm) of silver film bounded by air is considered. A new asymptotic formula for the Lorentz dip is derived. Our experimental data for silver film are reported too.     

Photoreduction of Silver Salts Using Au Nanoparticles to Form a Core-Shell-Type Nanostructure: Insight into the Reaction Mechanism

In this paper, we highlight the formation of Ag/Au core-shell nanoparticles at room temperature by using a low-power laser. We have investigated the plasmon-induced reduction of Ag⁺ ions on bare Au nanoparticles synthesized by laser ablation technique, and citrate-capped Au nanoparticles synthesized by chemical method. It is demonstrated that citrate plays an important role for the reduction of silver ions. The citrate gets oxidized by the ‘hot’ holes produced due to the surface plasmon resonance (SPR) of the Au nanoparticles which then reduces the Ag⁺ ions to Ag. The importance of excitation laser wavelength is also demonstrated to facilitate the reduction process.

     

The Nature and Origin of Chemical Shift for Intracellular Water Nuclei in Artemia Cysts

We investigated the possible existence of chemical shift of water nuclei in Artemia cysts using high resolution nuclear magnetic resonance (NMR) methods. The results conducted at 60, 200, and 500 MHz revealed an unusually large chemical shift for intracellular water protons. After correcting for bulk susceptibility effects, a residual downfield chemical shift of 0.11 ppm was observed in fully hydrated cysts. Similar results have been observed for the deuterium and ¹⁷O nuclei.

We have ruled out unusual intracellular pH, diamagnetic susceptibility of intracellular water, or interaction of water molecules with lipids, glycerol, and/or trehalose as possible origins of the residual chemical shift. We conclude that the residual chemical shift observed for water nuclei (¹H, ²H, and ¹⁷O) is due to significant water-macromolecular interactions.

     

Ambiguous Refractive Index Sensitivity of Fano Resonance on an Array of Gold Nanoparticles

We investigate the optical response to refractive index changes of a Fano resonance occurring in a random array of gold nanoparticles supported on a glass substrate. The Fano resonance results from the interference between localized surface plasmon on a gold nanoparticle and the light reflected at the boundary of the glass substrate. We demonstrate that the sensitivity of the resonance to the refractive index of the surrounding medium is highly dependent on the excitation geometry and can assume either positive or negative values. We furthermore present a theoretical analysis explaining this behavior based on the rigorous coupled wave analysis (RCWA) as well as the island film theory.

     

Lateral energy transfer model for adjacent light-harvesting antennae rods of C-phycocyanins

Modeling of excitation transfer pathways have been carried out for the structure of Spirulina platensis C-phycocyanin. Calculations by Förster mechanism using the crystal structure coordinates determined in our laboratory indicate ultra-fast lateral energy transfer rates between pairs of chromophores attached to two adjacent hexamer disks. The pairwise transfer times of the order of a few pico-seconds correspond to resonance transitions between peripheral β155 chromophores. A quantitative lateral energy transfer model for C-phycocyanin light-harvesting antenna rods that is suggestive to its native structural organization emerges from this study.     

Hypericin Site Specific Interactions Within Polynucleotides Used as DNA Model Compounds

Summary

Interactions of the antiretroviral hypericin molecule with polynucleotides, i.e. poly(dG-dC), poly(dA-dT), poly(rG) and poly(rC), have been studied in aqueous solutions by resonance Raman spectroscopy, using an UV excitation wavelength which induces a specific resonance enhancement of spectral band intensities corresponding to proper nucleic base modes of vibration. It is shown that : i) hypericin selectively interacts with the N7 sites of purines, ii) the strength of interaction depends on the polymer structure, and : iii) interaction with guanine is stronger than with adenine molecules.     

Plasmonic Behaviors of Two-Dimensional Ag/SiO2 Nanocomposite Gratings: Roles of Gap Diffraction and Localized Surface Plasmon Resonance Absorption

Two-dimensional Ag/SiO₂ nanocomposite gratings of 400 and 600 nm in grating constant are fabricated by etching the SiO₂ slabs implanted with Ag ions, and their plasmonic extinction, absorption, and reflection behaviors are investigated. Our results indicate that no scattering light fields can exist near the localized surface plasmon (LSP) resonance wavelength (about 405 nm) of Ag nanoparticles (NPs) due to the intense LSP resonance absorption. Especially, when the gaps between nanocomposite veins have a width close in value to the LSP resonance wavelength of Ag NPs, the local light fields in the grating plane can be slightly enhanced due to an in-phase addition of the incident light fields and the diffractive light fields induced by the gap diffraction, leading to a slight red shift of LSP resonance mode of Ag NPs. Moreover, in the LSP resonance absorption region, although the grating diffraction can still occur, the diffractive light fields are extremely weak, and thus, the local light fields in the grating plane cannot be modified by coherently adding these extremely weak diffractive light fields to the incident light fields. As a result, the LSP resonance mode of Ag NPs will keep its position unchanged even though the grating constant is set to make the first grating order rightly change from evanescent to radiative character.

     

Surface plasmon resonance imaging on a microchip for detection of DNA-modified gold nanoparticles deposited onto the surface in a non-cross-linking configuration

We report theoretical predictions and experimental observations of the reduced detection volume with the use of surface-plasmon-coupled emission (SPCE). The effective fluorescence volume (detection volume) in SPCE experiments depends on two near-field factors: the depth of evanescent wave excitation and a distance-dependent coupling of excited fluorophores to the surface plasmons. With direct excitation of the sample (reverse Kretschmann excitation) the detection volume is restricted only by the distance-dependent coupling of the excitation to the surface plasmons. However, with the excitation through the glass prism at surface plasmon resonance angle (Kretschmann configuration), the detection volume is a product of evanescent wave penetration depth and distance-dependent coupling. In addition, the detection volume is further reduced by a metal quenching of excited fluorophores at a close proximity (below 10nm). The height of the detected volume size is 40-70nm, depending on the orientation of the excited dipoles. We show that, by using the Kretschmann configuration in a microscope with a high-numerical-aperture objective (1.45) together with confocal detection, the detection volume can be reduced to 1-2attoL. The strong dependence of the coupling to the surface plasmons on the orientation of excited dipoles can be used to study the small conformational changes of macromolecules.     

Surface Plasmon Resonance Studies of the Hybridization Behavior of DNA-Modified Gold Nanoparticles with Surface-Attached DNA Probes

Colloidal gold nanoparticles (AuNPs) have been extensively investigated as amplification tags to improve the sensitivity of surface plasmon resonance (SPR) biosensors. When using the so-called AuNP-enhanced SPR technique for DNA detection, the density of single-stranded DNA (ssDNA) on both the AuNPs and planar gold substrates is of crucial importance. Thus, in this work, we carried out a systematical study about the influence of surface ssDNA density onto the hybridization behavior of various DNA-modified AuNPs (DNA-AuNPs) with surface-attached DNA probes by using surface plasmon resonance spectroscopy. The lateral densities of the ssDNA on both the AuNPs and planar gold substrates were controlled by using different lengths of oligo-adenine sequence (OAS) as anchoring group. Besides SPR measurements, the amount of the captured DNA-AuNPs after the hybridization was further identified via atomic force microscope (AFM). SPR and AFM results clearly indicated that a higher ssDNA density on either the AuNPs or the gold substrates would give rise to better hybridization efficiency. Moreover, SPR data showed that the captured DNA-AuNPs could not be removed from SPR sensor surfaces using various dehybridization solutions regardless of surface ssDNA density. Consequently, it is apparent that the hybridization behavior of DNA-AuNPs was different from that of solution-phase ssDNA. Based on these data, we hypothesized that both multiple recognitions and limited accessibility might account for the hybridization of DNA-AuNPs with surface-attached ssDNA probes.

     

Sensitivity enhancement of spectral surface plasmon resonance biosensors for the analysis of protein arrays

A novel method for sensitivity enhancement of spectral surface plasmon resonance (SPR) biosensors was presented by reducing the refractive index of the sensing prism in the analysis of protein arrays. Sensitivity of spectral SPR biosensors with two different prisms (BK-7, fused silica) was analyzed by net shifts of resonance wavelength for specific interactions of GST–GTPase binding domain of p21-activated kinase-1 and anti-GST on a mixed thiol surface. Sensitivity was modulated by the refractive index of the sensing prism of the spectral SPR biosensors with the same incidence angle. The sensitivity of a spectral SPR biosensor with a fused silica prism was 1.6 times higher than that with a BK-7 prism at the same incidence angle of 46.2°. This result was interpreted by increment of the penetration depth correlated with evanescent field intensity at the metal/dielectric interface. Therefore, it is suggested that sensitivity enhancement is readily achieved by reducing the refractive index of the sensing prism of spectral SPR biosensors to be operated at long wavelength ranges for the analysis of protein arrays.     

Asymmetrical membranes and surface tension

The (31)P-nuclear magnetic resonance chemical shift of phosphatidic acid in a membrane is sensitive to the lipid head group packing and can report qualitatively on membrane lateral compression near the aqueous interface. We have used high-resolution (31)P-nuclear magnetic resonance to evaluate the lateral compression on each side of asymmetrical lipid vesicles. When monooleoylphosphatidylcholine was added to the external monolayer of sonicated vesicles containing dioleoylphosphatidylcholine and dioleoylphosphatidic acid, the variation of (31)P chemical shift of phosphatidic acid indicated a lateral compression in the external monolayer. Simultaneously, a slight dilation was observed in the inner monolayer. In large unilamellar vesicles on the other hand the lateral pressure increased in both monolayers after asymmetrical insertion of monooleoylphosphatidylcholine. This can be explained by assuming that when monooleoylphosphatidylcholine is added to large unilamellar vesicles, the membrane bends until the strain is the same in both monolayers. In the case of sonicated vesicles, a change of curvature is not possible, and therefore differential packing in the two layers remains. We infer that a variation of lipid asymmetry by generating a lateral strain in the membrane can be a physiological way of modulating the conformation of membrane proteins.     

Electric field allowed molecular transitions for one and two photon excitation microscopy

We propose an excitation technique for observing single and two photon excitation in those molecules for which such transitions are forbidden by the selection rules. This is possible by the application of an external electric field that perturbs the molecular orbitals, thereby resulting in a significant shift of energy levels. Such a shift of energy levels may bring those levels in resonance with the radiation field which is normally forbidden by selection rules. Further, parity of the these states may significantly improve the emission process. The external electric field results in the mixing of excited (short lifetime) and metastable states (long lifetime), thus reducing the lifetime of metastable (or near metastable) states. This may provide an effective channel for allowing transition from the metastable states. An application of electric field may result in the excitation of poorly excitable biomolecules. This excitation technique may find applications in single- and multi-photon fluorescence microscopy, bioimaging and optical devices.     

Investigating the Effect of Ag and Au Nanostructures with Spherical and Rod Shapes on the Emission Wavelength of OLED

Noble metals, especially Ag and Au nanostructures, have unique and adjustable optical attributes in terms of surface plasmon resonance. In this research, the effect of Ag and Au nanoparticles with spherical and rod shapes on the light extraction efficiency and the FWHM of OLED structures was investigated using the finite difference time domain (FDTD) method. The simulation results displayed that by changing the shape and size of Ag and Au nanostructures, the emission wavelength can be adjusted, and the FWHM can be reduced. The presence of Ag and Au nanoparticles in the OLEDs showed a blue and red shift of the emission wavelength, respectively. Also, the Ag and Au nanorods caused a significant reduction in the FWHM and a shift to the longer wavelengths in the structures. The structures containing Ag nanorods showed the narrowest FWHM and longer emission wavelength than the other structures.