Life Cycle Assessment of Water Production Technologies - Part 1: Life Cycle Assessment of Different Commercial Desalination Technologies (MSF,MED, RO) (9 pp)

- Preamble. This series of two papers analyses and compares the environmental loads of different water production technologies in order to establish, in a global, rigorous and objective way, the less aggressive technology for the environment with the present state of the art of the technology. Further, it is also presented an estimation of the potential environmental loads that the considered technologies could provoke in future, taking into account the most suitable evolution of the technology. - Part 1 presents the assessment of most commercial desalination technologies which are spread worldwide: Reverse Osmosis, Multi Effect Desalination and Multi Stage Flash. Part 2 presents the comparative LCA analysis of a big hydraulic infrastructure, as is to be found in the Ebro River Water Transfer project, with respect to desalination. - DOI: http://dx.doi.org/10.1065/lca2004.09.179.1 - Intention, Goal and Background. In this paper, some relevant results of a research work are presented, the main aim of which consists of performing the environmental assessment of different water production technologies in order to establish, in a global, rigorous and objective way, the less aggressive technology for the environment of potable water supply to the end users. That is, the scope of this paper is mostly oriented to the comparative Life Cycle Assessment of different water production technologies instead of presenting new advancements in the LCA methodology. In Part 1, the environmental loads associated with the most widespread and important commercial desalination technologies all over the world - Reverse Osmosis (RO), Multi Effect Desalination (MED) and Multi Stage Flash (MSF) – are compared. The assessment technique is the Life Cycle Analysis (LCA), which includes the entire life cycle of each technology, encompassing: extraction and processing raw materials, manufacturing, transportation and distribution, operation and final waste disposal.- Methods and Main Features. The software SimaPro 5.0, developed by Dutch PRé Consultants, has been used as the analysis tool, because it is a well known, internationally accepted and validated tool. Different evaluation methods have been applied in the LCA evaluation: CML 2 baseline 2000, Eco-Points 97 and Eco-Indicator 99. Data used in the inventory analysis of this Part 1 come from: a) existing plants in operation; b) data bases implemented in the SimaPro 5.0 software -BUWAL 250, ETH-ESU 96, IDEMAT 2001. Different scenarios have been analyzed in both parts in order to estimate, not only the potential of reduction of the provoked environmental loads with the present state of the art of technology, but also the most likely future trend of technological evolution. In Part 1, different energy production models and the integration of desalination with other productive processes are studied, while the effect of the most likely technological evolution in the midterm, and the estimation of the environmental loads to the water transfer during drought periods are considered in Part 2. Results and Discussion The main contribution to the global environmental impact of desalination technologies comes from the operation, while the other phases, construction and disposal, are almost negligible when compared to it. Energy is very important in desalination, for this reason the environmental loads change a lot depending on the technology used for providing the energy used in the desalination process. Among the different analyzed technologies, RO is the least aggressive desalination technology (one order of magnitude lower than the thermal processes, MSF and MED) for the environment. When integrating thermal desalination with other productive processes taking advantage of the residual heat, the environmental loads of thermal desalination technologies is highly reduced, obtaining similar loads to that of RO. The environmental loads of desalination technologies are significantly reduced when an energy model based on renewable energies is used. Taking into account the technological evolution, which is experiencing the RO, a reduction of its environmental load by about 40% is to be expected in the mid-term. Conclusion The main conclusion of Part 1 is that, with the present state of the art of the technology, RO is clearly the desalination technology with a reduced environmental load (one order of magnitude lower than the thermal processes, MSF and MED). In the case of thermal desalination technologies, their environmental load can be highly reduced (about 1,000 times less) when integrated with other industrial processes. In the case of RO, the scores and the airborne emissions obtained from an electricity production model based on renewable energies are about 65-70 times lower than those obtained when the electricity production model is mainly based on fossil fuels. Recommendations and Outlook Although desalination technologies are energy intensive and provoke an important environmental load, they present a high potential in being reduced since: a) in the mid-term, it is to be expected that the different technologies could improve their efficiency significantly, b) the environmental loads would be highly reduced if the energy production models were not mainly based on fossil fuels and c) the energy consumption, particularly in the case of thermal desalination, can be drastically reduced when integrating desalination with other productive processes. The results presented in this paper indicate that a very interesting and promising field of research is available in order to reduce the environmental load of these vigorous and increasing desalination technologies.     

Life Cycle Assessment of Water Supply Plans in Mediterranean Spain

Life cycle assessment (LCA) was used to compare the current water supply planning in Mediterranean Spain, the so‐called AGUA Programme, with its predecessor, the Ebro river water transfer (ERWT). Whereas the ERWT was based on a single interbasin transfer, the AGUA Programme excludes new transfers and focuses instead on different types of resources, including seawater and brackish water desalination and wastewater reuse, among others. The study includes not only water supply but the whole anthropic cycle of water, from water abstraction to wastewater treatment. In addition to standard LCA impact categories, a specific impact category focusing on freshwater resources is included, which takes into account freshwater scarcity in the affected water catchments. In most impact categories the AGUA Programme obtains similar or even lower impact scores than ERWT. Concerning impacts on freshwater resources, the AGUA Programme obtains an impact score 49% lower than the ERWT. Although the current water planning appears to perform better in many impact categories than its predecessor, this study shows that water supply in Spanish Mediterranean regions is substantially increasing its energy intensity and that Mediterranean basins suffer a very high level of water stress due to increasing demand and limited resources.     

Assessment of Environmental Impacts of an Aging and Stagnating Water Supply Pipeline Network

Aging urban infrastructure is a common phenomenon in industrialized countries. The urban water supply pipeline network in the city of Oslo is an example. Even as it faces increasing operational, maintenance, and management challenges, it needs to better its environmental performance by reducing, for instance, the associated greenhouse gas emissions. In this article the authors examine the environmental life cycle performance of Oslo's water supply pipelines by analyzing annual resource consumption and emissions as well as life cycle assessment (LCA) impact potentials over a period of 16 years, taking into account the production/manufacture, installation, operation, maintenance, rehabilitation, and retirement of pipelines. It is seen that the water supply pipeline network of Oslo has already reached a state of saturation on a per capita basis, that is, it is not expanding any more relative to the population it serves, and the stock is now rapidly aging. This article is part of a total urban water cycle system analysis for Oslo, and analyzes more specifically the environmental impacts from the material flows in the water distribution network, examining six environmental impact categories using the SimaPro (version 7.1.8) software, Ecoinvent database, and the CML 2001 (version 2.04) methodology. The long‐term management of stocks calls for a strong focus on cost optimization, energy efficiency, and environmental friendliness. Global warming and abiotic depletion emerge as the major impact categories from the water pipeline system, and the largest contribution is from the production and installation phases and the medium‐size pipelines in the network.     

Fertiliser drawn forward osmosis desalination: the concept, performance and limitations for fertigation

With the world??s population growing rapidly, pressure is increasing on the limited fresh water resources. Membrane technology could play a vital role in solving the water scarcity issues through alternative sources such as saline water sources and wastewater reclamation. The current generation of membrane technologies, particularly reverse osmosis (RO), has significantly improved in performance. However, RO desalination is still energy intensive and any effort to improve energy efficiency increases total cost of the product water. Since energy, environment and climate change issues are all inter-related, desalination for large-scale irrigation requires new novel technologies that address the energy issues. Forward osmosis (FO) is an emerging membrane technology. However, FO desalination for potable water is still a challenge because, recovery and regeneration of draw solutes require additional processes and energy. This article focuses on the application of FO desalination for non-potable irrigation where maximum water is required. In this concept of fertiliser drawn FO (FDFO) desalination, fertilisers are used as draw solutions (DS). The diluted draw solution after desalination can be directly applied for fertigation without the need for recovery and regeneration of DS. FDFO desalination can make irrigation water available at comparatively lower energy than the current desalination technologies. As a low energy technology, FDFO can be easily powered by renewable energy sources and therefore suitable for inland and remote applications. This article outlines the concept of FDFO desalination and critically evaluates the scope and limitations of this technology for fertigation, including suggestions on options to overcome some of these limitations.     

Assessing future energy and transport systems: the case of fuel cells

Goal, Scope and Background  Assessing future energy and transport systems is of major importance for providing timely information for decision makers. In the discussion of technology options, fuel cells are often portrayed as attractive options for power plants and automotive applications. However, when analysing these systems, the LCA analyst is confronted with methodological problems, particularly with data gaps and the requirement of an anticipation of future developments. This series of two papers aims at providing a methodological framework for assessing future energy and transport systems (Part 1) and applies this to the two major application areas of fuel cells (Part 2). Methods  To allow the LCA of future energy and transport systems forecasting tools like, amongst others, cost estimation methods and process simulation of systems are investigated with respect to the applicability in LCAs of future systems (Part 1). The manufacturing process of an SOFC stack is used as an illustration for the forecasting procedure. In Part 2, detailed LCAs of fuel cell power plants and power trains are carried out including fuel (hydrogen, methanol, gasoline, diesel and natural gas) and energy converter production. To compare it with competing technologies, internal combustion engines (automotive applications) and reciprocating engines, gas turbines and combined cycle plants (stationary applications) are analysed as well. Results and Discussion  Principally, the investigated forecasting methods are suitable for future energy system assessment. The selection of the best method depends on different factors such as required ressources, quality of the results and flexibility. In particular, the time horizon of the investigation determines which forecasting tool may be applied. Environmentally relevant process steps exhibiting a significant time dependency shall always be investigated using different independent forecasting tools to ensure stability of the results. The results of the LCA (Part 2) underline that principally, fuel cells offer advantages in the impact categories which are typically dominated by pollutant emissions, such as acidification and eutrophication, whereas for global warming and primary energy demand, the situation depends on a set of parameters such as driving cycle and fuel economy ratio in mobile applica-tions and thermal/total efficiencies in stationary applications. For the latter impact categories, the choice of the primary en-ergy carrier for fuel production (renewable or fossil) dominates the impact reduction. With increasing efficiency and improving emission performance of the conventional systems, the competition regarding all impact categories in both mobile and stationary applications is getting even stronger. The production of the fuel cell system is of low overall significance in stationary applications, whereas in automotive applications, the production of the fuel cell power train and required materials leads to increased impacts compared to internal combustion engines and thus reduces the achievable environmental impact reduction. Recommendations and Perspectives  The rapid technological and energy economic development will bring further advances for both fuel cells and conventional energy converters. Therefore, LCAs at such an early stage of the market development can only be considered preliminary. It is an essential requirement to accompany the ongoing research and development with iterative LCAs, constantly pointing at environmental hot spots and bottlenecks.     

Assessing the Environmental Impact of Water Consumption by Energy Crops Grown in Spain

The environmental impact of the water consumption of four typical crop rotations grown in Spain, including energy crops, was analyzed and compared against Spanish agricultural and natural reference situations. The life cycle assessment (LCA) methodology was used for the assessment of the potential environmental impact of blue water (withdrawal from water bodies) and green water (uptake of soil moisture) consumption. The latter has so far been disregarded in LCA. To account for green water, two approaches have been applied: the first accounts for the difference in green water demand of the crops and a reference situation. The second is a green water scarcity index, which measures the fraction of the soil‐water plant consumption to the available green water. Our results show that, if the aim is to minimize the environmental impacts of water consumption, the energy crop rotations assessed in this study were most suitable in basins in the northeast of Spain. In contrast, the energy crops grown in basins in the southeast of Spain were associated with the greatest environmental impacts. Further research into the integration of quantitative green water assessment in LCA is crucial in studies of systems with a high dependence on green water resources.     

Life cycle assessment of emerging technologies: Evaluation techniques at different stages of market and technical maturity

Life cycle assessment (LCA) analysts are increasingly being asked to conduct life cycle‐based systems level analysis at the earliest stages of technology development. While early assessments provide the greatest opportunity to influence design and ultimately environmental performance, it is the stage with the least available data, greatest uncertainty, and a paucity of analytic tools for addressing these challenges. While the fundamental approach to conducting an LCA of emerging technologies is akin to that of LCA of existing technologies, emerging technologies pose additional challenges. In this paper, we present a broad set of market and technology characteristics that typically influence an LCA of emerging technologies and identify questions that researchers must address to account for the most important aspects of the systems they are studying. The paper presents: (a) guidance to identify the specific technology characteristics and dynamic market context that are most relevant and unique to a particular study, (b) an overview of the challenges faced by early stage assessments that are unique because of these conditions, (c) questions that researchers should ask themselves for such a study to be conducted, and (d) illustrative examples from the transportation sector to demonstrate the factors to consider when conducting LCAs of emerging technologies. The paper is intended to be used as an organizing platform to synthesize existing methods, procedures and insights and guide researchers, analysts and technology developer to better recognize key study design elements and to manage expectations of study outcomes.     

Assessing future energy and transport systems: the case of fuel cells

Goal, Scope and Background  Assessing future energy and transport systems is of major importance for providing timely information for decision makers. In the discussion of technology options, fuel cells are often portrayed as attractive options for power plants and automotive applications. However, when analysing these systems, the LCA analyst is confronted with methodological problems, particularly with data gaps and the requirement of forecasting and anticipation of future developments. This series of two papers aims at providing a methodological framework for assessing future energy and transport systems (Part 1) and applies this to the two major application areas of fuel cells (Part 2). Methods  To allow the LCA of future energy and transport systems, forecasting tools like, amongst others, cost estimation methods and process simulation of systems are investigated with respect to the applicability in LCAs of future systems (Part 1). The manufacturing process of an SOFC stack is used as an illustration for the forecasting procedure. In Part 2, detailed LCAs of fuel cell power plants and power trains are carried out including fuel (hydrogen, methanol, gasoline, diesel and natural gas) and energy converter production. To compare it with competing technologies, internal combustion engines (automotive applications) and reciprocating engines, gas turbines and combined cycle plants (stationary applications) are also analysed. Results and Discussion  Principally, the investigated forecasting methods are suitable for future energy system assessment. The selection of the best method depends on different factors such as required ressources, quality of the results and flexibility. In particular, the time horizon of the investigation determines which forecasting tool may be applied. Environmentally relevant process steps exhibiting a significant time dependency shall always be investigated using different independent forecasting tools to ensure stability of the results. The results of the LCA underline that, in general, fuel cells offer advantages in the impact categories usually dominated by pol-lutant emissions, such as acidification and eutrophication, whereas for global warming and primary energy demand, the situation depends on a set of parameters such as driving cycle and fuel economy ratio in mobile applications and thermal/total efficiencies in stationary applications. For the latter impact categories, the choice of the primary energy carrier for fuel production (renewable or fossil) dominates the impact reduction. With increasing efficiency and improving emission performance of the conventional systems, the competition in both mobile and stationary applications is getting even stronger. The production of the fuel cell system is of low overall significance in stationary applications, whereas in vehicles, the lower life-time of the vehicle leads to a much higher significance of the power train production. Recommendations and Perspectives  In future, rapid technological and energy economic development will bring further advances for both fuel cells and conventional energy converters. Therefore, LCAs at such an early stage of the market development can only be considered preliminary. It is an essential requirement to accompany the ongoing research and development with iterative LCAs, constantly pointing at environmental hot spots and bottlenecks.     

Life cycle assessment of emerging technologies: A review

In recent literature, prospective application of life cycle assessment (LCA) at low technology readiness levels (TRL) has gained immense interest for its potential to enable development of emerging technologies with improved environmental performances. However, limited data, uncertain functionality, scale up issues and uncertainties make it very challenging for the standard LCA guidelines to evaluate emerging technologies and requires methodological advances in the current LCA framework. In this paper, we review published literature to identify major methodological challenges and key research efforts to resolve these issues with a focus on recent developments in five major areas: cross‐study comparability, data availability and quality, scale‐up issues, uncertainty and uncertainty communication, and assessment time. We also provide a number of recommendations for future research to support the evaluation of emerging technologies at low technology readiness levels: (a) the development of a consistent framework and reporting methods for LCA of emerging technologies; (b) the integration of other tools with LCA, such as multicriteria decision analysis, risk analysis, technoeconomic analysis; and (c) the development of a data repository for emerging materials, processes, and technologies.     

Life Cycle Energy Assessment of Alternative Water Supply Systems (9 pp)

Goal, Scope and Background This paper discusses the merging of methodological aspects of two known methods into a hybrid on an application basis. Water shortages are imminent due to scarce supply and increasing demand in many parts of the world. In California, this is caused primarily by population growth. As readily available water is depleted, alternatives that may have larger energy and resource requirements and, therefore, environmental impacts must be considered. In order to develop a more environmentally responsible and sustainable water supply system, these environmental implications should be incorporated into planning decisions. Methods Comprehensive accounting for environmental effects requires life cycle assessment (LCA), a systematic account of resource use and environmental emissions caused by extracting raw materials, manufacturing, constructing, operating, maintaining, and decommissioning the water infrastructure. In this study, a hybrid LCA approach, combining elements of process-based and economic input-output-based LCA was used to compare three supply alternatives: importing, recycling, and desalinating water. For all three options, energy use and air emissions associated with energy generation, vehicle and equipment operation, and material production were quantified for life-cycle phases and water supply functions (supply, treatment, and distribution). The Water-Energy Sustainability Tool was developed to inform water planning decisions. It was used to evaluate the systems of a Northern and a Southern California water utility. Results and Discussion The results showed that for the two case study utilities desalination had 2–5 times larger energy demand and caused 2–18 times more emissions than importation or recycling, due primarily to the energy-intensity of the treatment process. The operation life-cycle phase created the most energy consumption with 56% to 90% for all sources and case studies. For each water source, a different life-cycle phase dominated energy consumption. For imported water, supply contributed 56% and 86% of the results for each case study; for desalination, treatment accounted for approximately 85%; for recycled water, distribution dominated with 61% and 74% of energy use. The study calculated external costs of air pollution from all three water supply systems. These costs are borne by society, but not paid by producers. The external costs were found to be 6% of desalinated water production costs for both case studies, 8% of imported water production costs in Southern California, and 1–2% for the recycled water systems and for the Northern California utility's imported water system. Conclusion Recycling water was found to be more energy intensive in Northern than in Southern California, but the results for imported water were similar. While the energy demand of water recycling was found to be larger than importation in Northern California, the two alternatives were competitive in Southern California. For all alternatives in both case studies, the energy consumed by system operation dominated the results, but maintenance was also found to be significant. Energy production was found to be the largest contributor in all water provision systems, followed by materials production. The assessment of external costs revealed that the environmental effects of energy and air emissions caused by infrastructure is measurable, and in some cases, significant relative to the economic cost of water. Recommendation and Perspective This paper advocates the necessity of LCA in water planning, and discusses the applicability of the described model to water utilities.     

Applying Life Cycle Tools and Process Engineering to Determine the Most Adequate Treatment Process Conditions. A Tool in Environmental Policy (12 pp)

Background The analysis of a wastewater treatment technology, under a expanded boundaries system which includes both the technology and the inputs required for its operation, quantifies the overall environmental impact that may result from the treatment of a wastewater stream. This is particularly useful for environmental policy makers being that a expanded boundaries system tends to provide a holistic view. The former view can be highly enriched with the use of process engineering tools, such as mathematical process modelling, process design, performance assessment and cost optimised models. Main Features The traditional approach used to assess waste treatment technologies is contrasted with a life cycle analysis (LCA) approach. The optimal design of a granular activated carbon adsorption (GAC) process is used as a model system to demonstrate the advantages of LCA approaches over traditional approaches. Further sections of the paper describe a mathematical framework for the assessment of technologies, design considerations applied in the cost optimised carbon adsorption model, the use of LCA techniques to perform an inventory of all emissions associated to the process system and, some of its environmental impacts. Results Economic and environmental considerations regarding the optimum process design are introduced as a basis for decision towards the selection and operating conditions of wastewater treatment technologies. Moreover, the use of LCA has revealed that the environmental burden associated with the wastewater treatment may produce a higher environmental impact than one that can be caused by untreated discharges. Conclusion The paper highlights the string advantages that environmental policy makers may have by combining LCA and process engineering tools. Furthermore, this approach can be incorporated into other existing treatment processes or for process designers.     

A Life Cycle Assessment on the Dehairing of Rawhides: Chemical Treatment versus Enzymatic Recovery through Solid State Fermentation

The leather industry needs to switch from the traditional chemically based dehairing process to an environmentally friendly one so that the overall burdens to the environment are reduced. The primary goal of the work was thus to compare the chemical leather dehairing process to an enzymatically based one using the enzymes that are extracted after the application of solid state fermentation (SSF) on hair wastes generated after dehairing. The environmental burdens of the dehairing stage were determined using a life cycle assessment (LCA) approach by comparing the two aforementioned management scenarios. The first scenario was the commonly used technology in which hair is removed via a chemical process and then composted in open piles. This scenario included two subscenarios where hair waste is either incinerated or landfilled. In the second scenario, the proteolytic enzymes extracted during the SSF of the residual hair are used to dehair the new rawhides instead of chemicals. Industrial and laboratory data were combined with international databases using the SimaPro 8.0 LCA software to make comparisons. The environmental impacts associated with the enzymatic dehairing were significantly lower than the ones associated to the conventional chemical dehairing process. This difference is attributed to the impacts associated with the original production of the chemicals and to the electricity consumed in the conventional method. A sensitivity analysis revealed that the results are affected by the amounts of chemicals used during dehairing.     

Life cycle assessment of desktop PCs in Macau

Purpose

With the tremendous growth in the worldwide electronic information and telecommunication industries, there continues to be an increasing awareness of the environmental impacts related to the accelerating mass production, electricity use, and waste management of electrical and electronic products (e-products). Although Macau is a small region with a total land area of about 29.5 km² and a population of 557,000 in 2011, there are two personal computers (PCs) for every household in Macau.

Methods

This paper aims to describe the application of life cycle assessment (LCA) to investigate the environmental performance of PCs in Macau. An assessment of the PC (focusing on the desktop PC) was carried out using a detailed modular LCA based on the international standards of the ISO 14040 series. The LCA was constructed using SimaPro software version 7.2 and expressed with both the Eco-indicator'99 method and the Centrum voor Milieuwetenschappen method. Life cycle inventory information was compiled by Ecoinvent 2.2 databases, combined with literature and field investigations of the actual situations.

Results and discussion

The established LCA study showed that the manufacturing and the use of such devices are of the highest environmental importance. In the manufacturing stage, the desktop contributes the most to the total environmental impacts (44.89 Pt), followed by the LCD screens (about 27.53 Pt), while the CRT screen, keyboard, and mouse are of minor importance. During the use phase, the environmental impact is due entirely to the consumption of electricity generated by coal, oil, natural gas, and hydropower. The electricity generated by coal is by far the most important, accounting for about 66 % of the total environmental impact, followed by oil and gas. Within the EoL treatment phase, using incineration, there will be little environmental impact. When adopting recycling technology in the EoL phase, apparent environmental benefits will be generated due mainly to avoiding emissions to water (arsenic ions and cadmium ions) and to air (SO₂) in the primary production phase. For the competing technologies of CRT and LCD screens, the environmental impacts are different in different phases, but the total impacts over their entire life cycle are similar.

Conclusions

Results from a life cycle assessment can be used to compare the relative environmental impacts of competing technologies; it can also help designers and managers to focus efforts toward making environmental improvements to a particular technology.     

Comparative LCA of industrial objects

Goal, Scope and Background  This paper is the second part of the publication which is devoted to comparative LCA analysis of the industrial pumps. The previous paper deals with the methodological aspects concerning quality assessment and forms an independent work. This paper uses practically only the methodological suggestions made there. The main aim of the presented study is to make a comparison between the industrial pumps which are based on two different technologies. The Life Cycle Assessment method is used to check whether the differences of the manufacturing processes influence the level of the potential environmental impact during the whole life cycle of the analysed products. Methods  The Life Cycle Assessment is carried out using the Ecoindicator99 method. Additionally, an extensive quality analysis of the LCA study is made (Part I). To make the process of an identification of the data easier and faster, they are assigned to a special data documentation form. To ensure the credibility of the LCA results different methods of interpretation are used. Results and Discussion  The LCA analysis shows clear superiority of the pumps manufactured using modern technology. It seems that this superiority results not only from the differences in the emissions, but also from different characteristics of effectiveness in the usage stage. Thanks to the uncertainty analysis, each LCA result is provided with the range of uncertainty. Conclusions  The LCA results are supported by different techniques of interpretation: the sensitivity-, the contribution-, the comparative-, the discernability- and the uncertainty analysis. There is strong evidence of the superiority of the pumps based on the modern technology. Recommendations and Outlook  The main source of the environmental impact in the case of pumps is the usage stage and the consumption of energy. That is why it should be the main area to improve. The LCA results show that actions taken in the usage stage and energy consumption can lead to a considerable reduction of the environmental impacts.     

Extending the Life Cycle Methodology to Cover Impacts of Land Use Systems on the Water Balance (7 pp)

Goal, Scope and Background Whilst initially designed for industrial production systems, environmental life cycle assessment (LCA) has recently been increasingly applied to agriculture and forestry projects. Several authors suggested that the standard LCA methodology needs to be refined to cover the particularities of agri- and silvicultural production systems. Until now, water quantity received little attention in these methodological revisions, notwithstanding the well-known impact of agriculture and forestry on issues like water availability, drought and flood risk. This paper proposes an add-on to existing LCA methods in the form of an indicator set that integrates water quantity impacts of agri- and silvicultural production. Method First, system boundaries are discussed in order to identify the water flows between the production system and the environment. These flows are attributed to impact categories, linked to environmental burdens and to the areas of protection. Appropriate indicators are selected for each potential burden. Results and Discussion At the present, two input related impact categories deal with water quantity: Abiotic resource depletion and land use. The list of output related impact categories presented by Udo de Haes et al. (1999) does not include water quantity impacts like flood and drought risk. A new impact category “regional water balance” is introduced to cover these risks. Exceedance probabilities are used as indicators for these temporal variations in streamflow. Conclusion and Outlook The method presented in this paper can bring a life cycle assessment closer to real world concerns. The main drawback, however, is the increasing data requirement that might hinder the feasibility of the method. Future research should focus on this problem, for instance by applying a relatively simple numerical model that can calculate the indicator scores from more easily accessible data.     

Understanding the future of lithium: Part 2, temporally and spatially resolved life‐cycle assessment modeling

An array of emerging technologies, from electric vehicles to renewable energy systems, relies on large‐format lithium ion batteries (LIBs). LIBs are a critical enabler of clean energy technologies commonly associated with air pollution and greenhouse gas mitigation strategies. However, LIBs require lithium, and expanding the supply of lithium requires new lithium production capacity, which, in turn, changes the environmental impacts associated with lithium production since different resource types and ore qualities will be exploited. A question of interest is whether this will lead to significant changes in the environmental impacts of primary lithium over time. Part one of this two‐part article series describes the development of a novel resource production model that predicts future lithium demand and production characteristics (e.g., timing, location, and ore type). In this article, part two, the forecast is coupled with anticipatory life‐cycle assessment (LCA) modeling to estimate the environmental impacts of producing battery‐grade lithium carbonate equivalent (LCE) each year between 2018 and 2100. The result is a normalized life‐cycle impact intensity for LCE that reflects the changing resource type, quantity, and region of production. Sustained growth in lithium demands through 2100 necessitates extraction of lower grade resources and mineral deposits, especially after 2050. Despite the reliance on lower grade resources and differences in impact intensity for LCE production from each deposit, the LCA results show only small to modest increases in impact, for example, carbon intensity increases from 3.2 kg CO₂e/kg LCE in 2020 to 3.3 kg CO₂e/kg LCE in 2100.     

Challenges of reducing excess nitrogen in Japanese agroecosystems

Fertilizer N use in Japan has decreased by about 30% from 1960 to 2000, while keeping a little increase in cereal yields. This has resulted in a significant increase in apparent nitrogen use efficiency, in particular for rice. On the other hand, national N load on the environment associated with the production and consumption of domestic and imported agricultural products has almost tripled during this period, mainly due to the dramatic increase of imports of food and feedstuffs. The environmental problems, including water and air pollution, caused by the excessive loads of N are serious public concerns and there is an urgent need to minimize N losses from agricultural production. In order to meet the necessity for reducing the environmental impacts by excess N, political and technological measures have been taken at regional and country levels. In recent years, the Japanese government has embarked on a series of policies to encourage transition to an environmentally conscious agriculture. Promoting proper material circulation with reducing fertilizer impact and utilizing biomass and livestock wastes is emphasized in these policies. The effectiveness of environmental assessment and planning for reducing regional and national N load has been discussed. Implementation of environmentally friendly technologies and management, both conventional and innovational, have been developed and adopted in Japanese agriculture. The effectiveness of conventional technologies in reducing environmental reactive N has been re-evaluated. Innovative technologies, such as use of controlled availability fertilizers and livestock wastes compost pellets, are being investigated and extended. A comprehensive approach that applies political and technological measures with closer co-operation is necessary to control reactive N in the environment.

     

A review of thermochemical upgrading of pyrolysis bio‐oil: Techno‐economic analysis,life cycle assessment,and technology readiness

Technologies for upgrading fast pyrolysis bio‐oil to drop‐in fuels and coproducts are under development and show promise for decarbonizing energy supply for transportation and chemicals markets. The successful commercialization of these fuels and the technologies deployed to produce them depend on production costs, scalability, and yield. To meet environmental regulations, pyrolysis‐based biofuels need to adhere to life cycle greenhouse gas intensity standards relative to their petroleum‐based counterparts. We review literature on fast pyrolysis bio‐oil upgrading and explore key metrics that influence their commercial viability through life cycle assessment (LCA) and techno‐economic analysis (TEA) methods together with technology readiness level (TRL) evaluation. We investigate the trade‐offs among economic, environmental, and technological metrics derived from these methods for individual technologies as a means of understanding their nearness to commercialization. Although the technologies reviewed have not attained commercial investment, some have been pilot tested. Predicting the projected performance at scale‐up through models can, with industrial experience, guide decision‐making to competitively meet energy policy goals. LCA and TEA methods that ensure consistent and reproducible models at a given TRL are needed to compare alternative technologies. This study highlights the importance of integrated analysis of multiple economic, environmental, and technological metrics for understanding performance prospects and barriers among early stage technologies.     

Challenges of reducing excess nitrogen in Japanese agroecosystems

Fertilizer N use in Japan has decreased by about 30% from 1960 to 2000, while keeping a little increase in cereal yields. This has resulted in a significant increase in apparent nitrogen use efficiency, in particular for rice. On the other hand, national N load on the environment associated with the production and consumption of domestic and imported agricultural products has almost tripled during this period, mainly due to the dramatic increase of imports of food and feedstuffs. The environmental problems, including water and air pollution, caused by the excessive loads of N are serious public concerns and there is an urgent need to minimize N losses from agricultural production. In order to meet the necessity for reducing the environmental impacts by excess N, political and technological measures have been taken at regional and country levels. In recent years, the Japanese government has embarked on a series of policies to encourage transition to an environmentally conscious agriculture. Promoting proper material circulation with reducing fertilizer impact and utilizing biomass and livestock wastes is emphasized in these policies. The effectiveness of environmental assessment and planning for reducing regional and national N load has been discussed. Implementation of environmentally friendly technologies and management, both conventional and innovational, have been developed and adopted in Japanese agriculture. The effectiveness of conventional technologies in reducing environmental reactive N has been re-evaluated. Innovative technologies, such as use of controlled availability fertilizers and livestock wastes compost pellets, are being investigated and extended. A comprehensive approach that applies political and technological measures with closer cooperation is necessary to control reactive N in the environment.     

Life cycle assessment of emerging technologies at the lab scale: The case of nanowire‐based solar cells

Nanomaterials are expected to play an important role in the development of sustainable products. The use of nanomaterials in solar cells has the potential to increase their conversion efficiency. In this study, we performed a life cycle assessment (LCA) for an emerging nanowire‐based solar technology. Two lab‐scale manufacturing routes for the production of nanowire‐based solar cells have been compared—the direct growth of GaInP nanowires on silicon substrate and the growth of InP nanowires on native substrate, peel off, and transfer to silicon substrate. The analysis revealed critical raw materials and processes of the current lab‐scale manufacturing routes such as the use of trifluoromethane (CHF₃), gold, and an InP wafer and a stamp, which are used and discarded. The environmental performance of the two production routes under different scenarios has been assessed. The scenarios include the use of an alternative process to reduce the gold requirements—electroplating instead of metallization, recovery of gold, and reuse of the InP wafer and the stamp. A number of suggestions, based on the LCA results—including minimization of the use of gold and further exploration for upscaling of the electroplating process, the increase in the lifetimes of the wafer and the stamp, and the use of fluorine‐free etching materials—have been communicated to the researchers in order to improve the environmental performance of the technology. Finally, the usefulness and limitations of lab‐scale LCA as a tool to guide the sustainable development of emerging technologies are discussed.