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1.
The retention of organic matter in soils   总被引:27,自引:8,他引:27  
The turnover of C in soils is controlled mainly by water regimes and temperature, but is modified by factors such as size and physicochemical properties of C additions in litter or root systems, distribution of C throughout the soil as root systems, or addition as litter, distribution of C within the soil matrix and its interaction with clay surfaces.Soil factors which retard mineralization of C in soils are identified from correlations of C contents of soils with other properties such as clay content and base status. The rate and extent of C mineralization depends on the chemistry of the added organic matter and interaction with clays of the microbial biomass and metabolites.The organomineral interactions are shown to depend on cation bridges involving mainly Ca in neutral to alkaline soils, Al in acid soils and adsorption of organic materials on iron oxide surfaces. The various organomineral interactions lead to aggregations of clay particles and organic materials, which stabilizes both soil structure and the carbon compounds within the aggregates.  相似文献   

2.
We examine the evolutionary stability of year-round residency in territorial populations, where breeding sites are a limiting resource. The model links individual life histories to the population-wide competition for territories and includes spatial variation in habitat quality as well as a potential parent-offspring conflict over territory ownership. The general form of the model makes it applicable to the evolution of dispersal, migration, partial migration, and delayed dispersal (offspring retention). We show that migration can be evolutionarily stable only if year-round residency in a given area would produce a sink population, where mortality exceeds reproduction. If this applies to a fraction of the breeding habitat only, partial migration is expected to evolve. In the context of delayed dispersal, habitat saturation has been argued to form an ecological constraint on independent breeding, which favors offspring retention and cooperative breeding. We show that habitat saturation must be considered as a dynamic outcome of birth, death, and dispersal rates in the population, rather than an externally determined constraint. Although delayed dispersal often associates with intense competition for territories, life-history traits have direct effects on stable dispersal strategies, which can often override the effect of habitat saturation. As an example, high survival of floaters selects against delayed dispersal, even though it increases the number of competitors for each breeding vacancy (the "habitat saturation factor"). High survival of territory owners, by contrast, generally favors natal philopatry. We also conclude that spatial variation in habitat quality only rarely selects for delayed dispersal. Within a population, however, offspring retention is more likely in high-quality territories.  相似文献   

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Abstract

Of the physical techniques available for the study of biopolymers and other macromolecular and colloidal systems, dynamic light scattering is, perhaps, the most fascinating. The very idea of extracting useful dynamical and structural information from random fluctuations in the intensity of light scattered from otherwise unperturbed equilibrium solutions1-3 seems, at first glance, almost too good to be true. Indeed, for fragile preparations that are prone to suffer undesirable fates at the slightest change in solution conditions, dynamic light scattering may be the perfect technique. It is nondestructive, relatively rapid, and typically requires only modest amounts of material. In routine applications, even on unfamiliar samples, the dust-removal procedure (either gravity flow Millipore ® filtration or low-speed centrifugation) requires 10 to 20 min, and determination of the translational diffusion coefficient to an accuracy of a few percent, or less, requires 5 min. Verification that the dynamical motions, in fact, obey the diffusion equation requires an additional 5 to 20 min. The amounts of solution required are typically a few milliliters, although similar experiments have been run on volumes as small as 15 μl.4 The concentrations needed, which depend on salt concentration and refractive index increment, and inversely on molecular weight, generally lie in the range 0.5 to 2.0 mg/ml for polypeptides with Mr ~ 100, 000.  相似文献   

5.
The design, synthesis and biological activity of non-covalent thrombin inhibitors incorporating 4,5,6,7-tetrahydroindazole, 2-methyl-4,5,6,7-tetrahydroindazole, 4,5,6,7-tetrahydroisoindole, 5,6,7,8-tetrahydroquinazoline and 5,6,7,8-tetrahydroquinazolin-2-amine as novel, partially saturated, heterobicyclic P(1)-arginine side-chain mimetics is described. The binding mode of the most potent candidate in the series co-crystallized with human alpha-thrombin, which exhibited an in vitro K(i) of 140nM and more that 478-fold selectivity against trypsin, is discussed.  相似文献   

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Increase of belowground C allocation by plants under global warming or elevated CO2 may promote decomposition of soil organic carbon (SOC) by priming and strongly affects SOC dynamics. The specific effects by priming of SOC depend on the amount and frequency of C inputs. Most previous priming studies have investigated single C additions, but they are not very representative for litterfall and root exudation in many terrestrial ecosystems. We evaluated effects of 13C‐labeled glucose added to soil in three temporal patterns: single, repeated, and continuous on dynamics of CO2 and priming of SOC decomposition over 6 months. Total and 13C labeled CO2 were monitored to analyze priming dynamics and net C balance between SOC loss caused by priming and the retention of added glucose‐C. Cumulative priming ranged from 1.3 to 5.5 mg C g?1 SOC in the subtropical, and from ?0.6 to 5.5 mg C g?1 SOC in the tropical soils. Single addition induced more priming than repeated and continuous inputs. Therefore, single additions of high substrate amounts may overestimate priming effects over the short term. The amount of added glucose C remaining in soil after 6 months (subtropical: 8.1–11.2 mg C g?1 SOC or 41‐56% of added glucose; tropical: 8.7–15.0 mg C g?1 SOC or 43–75% of glucose) was substantially higher than the net C loss due to SOC decomposition including priming effect. This overcompensation of C losses was highest with continuous inputs and lowest with single inputs. Therefore, raised labile organic C input to soils by higher plant productivity will increase SOC content even though priming accelerates decomposition of native SOC. Consequently, higher continuous input of C belowground by plants under warming or elevated CO2 can increase C stocks in soil despite accelerated C cycling by priming in soils.  相似文献   

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12.
Iyer  J. G.  Shaw  B. H.  Dosen  R. C. 《Plant and Soil》1974,40(2):409-412
Plant and Soil - The phenomenon of the compensation of growth factors is revealed with greatest clarity by partially cut forest stands. This paper reports the complete recovery of timber production...  相似文献   

13.
To assess the possible involvement of catecholaminergic neurotransmitters in maintenance of spatial cognition, the present work investigated the effects of dopaminergic and noradrenergic receptor antagonists on memory performance of rats in a partially baited radial eight-arm maze. Food-deprived rats were first trained to enter the arms baited with chocolate, and each subject was then randomly assigned to receive further training in either a place version or a cue version of the task. A specific pattern with four arms being baited was used throughout experimentation as the procedure for the place task; whereas four randomly chosen arms, each cued with a piece of sandpaper on the arm entrance, were baited from trial to trial as the procedure of the cue task. For drug evaluation, well-trained subjects were challenged with systemic injections of SCH23390, spiperone, haloperidol, prazosin, yohimbine, and propranolol. Regarding the place task, SCH23390, haloperidol, and propranolol, but not the other three drugs, significantly impaired behavioral performance by increasing the number of arm entries as well as the time to complete the task. The accuracy of performance as measured by the number of entries on the cue task was not significantly affected by any of these drugs tested. However, the times to complete the cue task were significantly increased with all drugs except yohimbine. These data show that blocking different catecholaminergic receptor subtypes produced distinct deficit patterns on the retention performance in a partially baited radial eight-arm maze. Evidently, both D1 and D2 dopamine receptors as well as beta noradrenergic receptors are important in expression of spatial memory.  相似文献   

14.
The effect of three‐dimensional heterogeneity of saturated hydraulic conductivity on the vertical transport of solutes in soils is examined by means of controlled numerical experiments. Saturated hydraulic conductivity, an important transport parameter that controls the dispersion of pollutants in heterogeneous soils, is assumed to be composed of a homogeneous mean value and a perturbation caused by the vertical variability of soil properties, producing a stochastic process in the mean flow direction. The spatial heterogeneity of porous soils is characterized by the variance and correlation scale of the saturated hydraulic conductivity in the transport domain. Numerical experiments are carried out to evaluate the extent of contaminant dispersion in Hawaiian Oxic soils when uncertainty exists as a result of the spatial heterogeneity of saturated hydraulic conductivity. Statistical analysis of the saturated hydraulic conductivity measurements on undisturbed soil cores from two locations in Hawaiian Oxic soils indicated two different soils with the same mean and different variances. The partial differential equations describing three‐dimensional transient flow and solute transport in soils with a random conductivity field were solved to evaluate the effect of these two variance levels on the transport of a contaminant plume originating from the surface. The significance of the variance on the spatial and temporal distribution of tracer concentrations is demonstrated using solute breakthrough curves at various depths in the soil profile. The longitudinal macrodispersivity resulting from tracer spreading in the heterogeneous soils with a finite local dispersivity is also analyzed. The analysis shows a similar solute dispersion behavior for the two variances. However, there is an overall reduction in the dispersion of solutes resulting from a uniform velocity field with the same mean. Macrodispersivity values in heterogeneous soils are proportional to the variance at smaller travel distances but converge to the same value at larger travel distances.  相似文献   

15.
The fate of an organic contaminant in soil depends on many factors, including sorption, biodegradation, and transport. The herbicide 2,4-dichlorophenoxyacetic acid (2,4-D) was used as a model compound to illustrate the impact of these interacting factors on the fate of an organic contaminant. Batch and column experiments performed with a sandy loam soil mixture under saturated and unsaturated conditions were used to determine the effects of sorption and biodegradation on the fate and transport of 2,4-D. Sorption of 2,4-D was found to have a slight but significant effect on transport of 2,4-D under saturated conditions (retardation factor, 1.8) and unsaturated conditions (retardation factor, 3.4). Biodegradation of 2,4-D was extensive under both batch and column conditions and was found to have a significant impact on 2,4-D transport in column experiments. In batch experiments, complete mineralization of 2,4-D (100 mg kg-1) occurred over a 4-day period following a 3-day lag phase under both saturated and unsaturated conditions. The biodegradation rate parameters calculated for batch experiments were found to be significantly different from those estimated for column experiments.  相似文献   

16.
The Middle Route of the South-to-North Water Diversion Project is a significant water diversion project intended to alleviate water shortages in the north China plains, especially for the capital (Beijing). After water retention, the potential ecological risk of metal contamination in the riparian soils of the Miyun Reservoir (MYR) to water quality has raised public concern. The remobilization characteristics of cobalt (Co) in MYR riparian soils are still unknown. Riparian soil samples (considering five different land use types and three vertical elevations) were collected from the MYR prior to water impoundment. Total Co concentrations, soil properties, total Co in soil solution, Co chemical fractions and labile Co measured by diffusive gradients in thin films (DGT) are applied to investigate the Co remobilization characteristics. The results showed that the total concentrations of Co (Ctotal-Co) were approximately equal to background values of Co in Beijing and China at most of the sites. The highest values of Ctotal-Co were observed at 140 m and 145 m in recreational land (S3), which may be influenced by the anthropogenic activities. No obvious differences in Ctotal-Co and DGT-labile Co (CDGT-Co) were found with the variation of land use types and vertical elevations in the soils of the MYR. CDGT-Co made up 9%-52% of the total dissolved Co, with an average value of 25%, indicating that Co in the soil solution was partially sustained by the solid phase. The highest CDGT-Co were observed in grassland and mountain land, indicating that the previous intensive mining in the upstream areas of the MYR is responsible for the release of Co. The results of the sequential extraction showed that Co is mainly bound to the residual fraction. DGT-labile Co had no correlation with non-residual fractions measured by sequential extraction, but had a significantly positive relationship with CDGT-Mn, indicating that Co trapped by DGT mainly came from the dissolution of MnOx. When the MYR riparian soils are submerged, a reducing environment will be formed. In this case, Co associated with MnOx may be also released into the water.  相似文献   

17.
N. Panda  U. K. Misra 《Plant and Soil》1970,33(1-3):225-234
Summary To examine the possibility of minimising phosphate fixation the lateritic soil at various levels of liming was incubated with phosphate rock from U.A.R. acidulated to different degree viz. 0, 10, 20, 50, and 100 per cent both with phosphoric and nitric acid. The soil was incubated for 90 days on addition of different phosphate carriers at the rate of 100 ppm total P2O5 containing different proportion of water-soluble, citrate-soluble and insoluble phosphorus. Samples were drawn at an interval of 30 days. Bray's p1 and pH of the soil samples were measured. The dry-matter yield and uptake of phosphorus by two successive crops of maize grown in pots, the treatments being same as in incubation study, were well correlated with the Bray's p1. Ground rock phosphate and 10 per cent acidulated material were effective in minimising the fixation in soil of pH 4.0 whereas 50 per cent acidulation was suitable for soils of higher pHi.e. 5.6 and 6.5. H3PO4 acidulated material was proved superior to HNO3 acidulated product. The use of partially acidulated rock phosphate for acid soils may be recommended to receive economic return. Associate Professor Senior Research Assistant.  相似文献   

18.
Novel, highly selective and potent thrombin inhibitors were identified as a result of combing the 3-benzylsulfonylamino-2-pyridinone acetamide P(2)-P(3) surrogate with weakly basic partially saturated heterobicyclic P(1)-arginine mimetics 1-8. The design, synthesis, biological activity, and the binding modes of non-covalent thrombin inhibitors featuring P(1)-4,5,6,7-tetrahydroindazole, 5,6,7,8-tetrahydroquinazoline, and 4,5,6,7-tetrahydrobenzothiazole moieties are described.  相似文献   

19.
The effects of increased reactive nitrogen (N) deposition in forests depend largely on its fate in the ecosystems. However, our knowledge on the fates of deposited N in tropical forest ecosystems and its retention mechanisms is limited. Here, we report the results from the first whole ecosystem 15N labeling experiment performed in a N‐rich old‐growth tropical forest in southern China. We added 15N tracer monthly as 15NH415NO3 for 1 year to control plots and to N‐fertilized plots (N‐plots, receiving additions of 50 kg N ha?1 yr?1 for 10 years). Tracer recoveries in major ecosystem compartments were quantified 4 months after the last addition. Tracer recoveries in soil solution were monitored monthly to quantify leaching losses. Total tracer recovery in plant and soil (N retention) in the control plots was 72% and similar to those observed in temperate forests. The retention decreased to 52% in the N‐plots. Soil was the dominant sink, retaining 37% and 28% of the labeled N input in the control and N‐plots, respectively. Leaching below 20 cm was 50 kg N ha?1 yr?1 in the control plots and was close to the N input (51 kg N ha?1 yr?1), indicating N saturation of the top soil. Nitrogen addition increased N leaching to 73 kg N ha?1 yr?1. However, of these only 7 and 23 kg N ha?1 yr?1 in the control and N‐plots, respectively, originated from the labeled N input. Our findings indicate that deposited N, like in temperate forests, is largely incorporated into plant and soil pools in the short term, although the forest is N‐saturated, but high cycling rates may later release the N for leaching and/or gaseous loss. Thus, N cycling rates rather than short‐term N retention represent the main difference between temperate forests and the studied tropical forest.  相似文献   

20.
Phosphorus (P) retention by headwater ditch sediments adsorption plays a pivotal ecological role in P buffering in freshwater ecosystems. Previous studies focused on headwater ditch sediment adsorption and its P retention capacity in acid conditions, but little information is available for headwater ditches under alkaline condition. In this study, adsorption behavior of phosphorus was investigated in headwater ditch sediments under alkaline condition using a batch equilibrium technique, thus determining phosphorus retention capacity of headwater ditch sediments collected at 11 sites at base-flow on 2 March 2006 in purple soils area of China. Results showed that headwater ditch sediments had elevated phosphorus sorption maximum (Smax) values (122.72–293.23 mg P kg?1) and P binding energy (K) values (1.64–8.65 L mg?1), while they had low equilibrium phosphorus concentration (EPC0) (0.001–0.108 mg L?1) and degree of phosphorus saturation (DSP) (1.93–10.19%). Analysis of EPC0 and soluble P concentration indicated that sediments acted as a sink for P across all headwater ditches. Therefore, there were high intrinsic P retention capacities of headwater ditch sediments. Positive correlations of both K and Smax with oxalate-extractable Fe (r of 0.93 and 0.81, p < 0.05) and total carbon (TC) (r of 0.89 and 0.74, p < 0.05) were found, thus suggesting that organic matter and amorphous or poorly crystalline Fe would play dominant roles in P adsorption in the headwater ditch sediments under alkaline condition. Since neither Smax nor K were correlated with CCE (CaCO3) (r of 0.15 and ?0.06, p > 0.05), the high-energy sorptive surfaces of Fe oxides were more important than CaCO3 in P sorption of sediment under alkaline condition. At the same time, these poor correlations between CCE and K and Smax imply a non-linear relationship between P retention and the content of carbonate. The negative correlations of both K and Smax with pH (r of–0.73, and–0.58, p < 0.05) revealed that an increase in pH would not improve sediment retention capacity under alkaline conditions.  相似文献   

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