Product specific emissions from municipal solid waste landfills

For the inventory analysis of environmental impacts associated with products in Life Cycle Assessment (LCA) there is a great need for estimates of emissions from waste products disposed at municipal solid waste landfills (product specific emissions). Since product specific emissions can not be calculated or measured directly at the landfills, they must be estimated by modeling of landfill processes. This paper presents a landfill model based on a large number of assumptions and approximations concerning landfill properties, waste product properties and characteristics of various kinds of environmental protection systems (e.g. landfill gas combustion units and leachate treatment units). The model is useful for estimation of emissions from waste products disposed in landfills and it has been made operational in the computer tool LCA-LAND presented in a following paper. In the model, waste products are subdivided into five groups of components: general organic matter (e.g. paper), specific organic compounds (e.g. organic solvents), inert components (e.g. PVC), metals (e.g. cadmium), and inorganic non-metals (e.g. chlorine,) which are considered individually. The assumptions and approximations used in the model are to the extent possible scientifically based, but where scientific information has been missing, qualified estimates have been made to fulfill the aim of a complete tool for estimation of emissions. Due to several rough simplifications and missing links in our present understanding of landfills, the uncertainty associated with the model is relatively high.     

Pyrolysis of plant, animal and human waste: physical and chemical characterization of the pyrolytic products

Pyrolysis (carbonization) has been proposed as one of several optional technologies for disposing and recycling waste products in Japan. Plant wastes (sugarcane bagasse and rice husks), animal waste (cow biosolids) and human waste (treated municipal sludge) were pyrolyzed at temperatures from 250–800 °C in closed containers. The carbonized materials were evaluated for specific physical properties (yield, surface area, density) and specific chemical properties (total carbon, total nitrogen, pH, fixed carbon, ash content, volatility) in order to compare differences in properties among the four waste products. The results indicated that (1) surface area, total carbon, ash content and pH increased as the carbonization temperature increased, while carbonization yield decreased with increasing temperature, (2) product density however was not affected by temperature and (3) correlation coefficients were determined among the physical and chemical properties and several significant correlations were observed. The data indicate that source material had considerable influence on the physical and chemical properties of the carbonized products.     

不同规模餐馆食物浪费及其氮足迹——以北京市为例

餐饮食物浪费的普遍性和严重性已得到了社会各界的关注。通过实证研究的方法对餐饮消费中食物浪费问题进行了研究,并从食物全供应链的视角,对比分析了不同规模餐馆食物浪费的氮足迹及其环境影响。研究表明:北京市餐饮食物浪费人均浪费量为74.39g/人次,其含氮量为1.24g/人次,约占总浪费量的2%。北京市餐饮食物浪费所引起总的氮排放量为16.37 g/人次,其中有1.24g/人次的氮排放来自于食物的直接浪费,其余15.13g/人次氮排放来自于食物生产过程。北京市餐饮食物浪费的氮足迹为0.22g N/g,即每浪费1g的食物,就会有0.22 g的氮排放到环境中。对比不同规模餐馆的食物浪费情况可知,大型餐馆的人均浪费量最高,有99.38g/人次,其氮排放量也相应最大,为22.53g/人次;中型餐馆和小型餐馆的食物浪费人均量及N排放量依次减少,而快餐的最低,仅为北京市整体平均水平的1/3。     

The potential and limits of termites (Isoptera) as decomposers of waste paper products

Termites (Isoptera) have often been proposed as decomposers oflignocellulosic waste, such as paper products, while termite biomass could be harvested for food supplements. Groups of Coptotermes formosanus Shiraki and Reticulitermes speratus (Kolbe) were kept for 4 and 8 wk, respectively, in the laboratory and given up to 10 different types of paper as their food source. Paper consumption, survival, caste composition, and lipid content were recorded. Corrugated cardboard was by far the most consumed paper product, although survival on it was not necessarily favorable. In R. speratus, lipid reserves and neotenic numbers were quite high, but no breeding occurred. Cardboard may be the "junk food" equivalent for termites. Within the tested period, termites did not perform well on paper products that form the bulk of waste paper--corrugated cardboard, newsprint, and pamphlets and magazines. On all paper products (except recycled office paper), neotenic reproductives were formed, but larvae were observed only on kraft pulp and tissue paper. That all waste paper products contain lignocellulosic fibers does not automatically make them suitable for decomposition by termites. Each paper product has to be assessed on its own merit to see whether termites can reproduce on this diet, if it were to be a candidate for sustainable "termidegradation" and termite biomass production.     

From Legal Transplants to Sustainable Transition

Extended producer responsibility (EPR), which assigns significant responsibility to producers to take back their end‐of‐life products to create incentives for redesign of products with lower life cycle environmental impacts, has come to a crossroad facing a trade‐off between the original innovation‐oriented regime design and the cost‐efficiency challenges in practice. This is particularly true in its implementation in non‐Organization for Economic Co‐operation and Development (OECD) countries as they are trying to transplant the “best practices” from OECD countries, for there is increasing skepticism as to whether EPR is suitable for developing countries at all. As an important producer of electronic products and destination of electronic waste (e‐waste) flows in the world, China has been expected to play a vital role in the evolution of global governance based on the idea of EPR, either to create new ways for producers to perform their end‐of‐life strategies, or to reshape the mode of production and consumption with its fast‐growing market. However, the establishment of EPR in China has been long and full of difficulties. This article reviews the status and trends in the establishment of an EPR system for waste electrical and electronic equipment (WEEE) management in China. We use the framework of a multilevel perspective of transition theory in our analysis to characterize the complex interactions among various agents in the evolution of the Chinese system from initial innovation‐oriented design to the current efficiency‐oriented version. An ongoing research framework for evaluation of the EPR program in China is outlined as the research agenda in coming years.     

Utilization of calcium carbonate particles from eggshell waste as coating pigments for ink-jet printing paper

The effective treatment and utilization of biowaste have been emphasized in our society for environmental and economic concerns. Recently, the eggshell waste in the poultry industry has been highlighted because of its reclamation potential. This study presents an economical treatment process to recover useful bioproducts from eggshell waste and their utilization in commercial products. We developed the dissolved air floatation (DAF) separation unit, which successfully recovered 96% of eggshell membrane and 99% of eggshell calcium carbonate (ECC) particles from eggshell waste within 2 h of operation. The recovered ECC particles were utilized as coating pigments for ink-jet printing paper and their impact on the ink density and paper gloss were investigated. The addition of the ECC particles as coating pigments enhances the optical density of cyan, magenta and yellow inks while decreasing the black ink density and the gloss of the coated paper.     

城市餐饮业食物浪费碳足迹——以北京市为例

食物浪费及其造成的环境影响已成为全球广泛关注的热点。无论从生命周期还是碳足迹的视角来看,食物浪费意味着生产、运输、加工与储存这些被浪费掉的食物过程中所投入的各种资源的浪费以及不必要的温室气体排放。以北京市餐饮食物浪费问题为切入点,在通过问卷调查和称重方法对餐饮食物浪费状况进行调查的基础上,将整个食物生命周期各供应链环节相应的温室气体排放纳入考量,估算了北京市餐饮食物浪费的碳排放量。研究结果表明:北京市餐饮食物浪费总量为39.86×10~4t/a。其中,蔬菜类浪费量最高,约占浪费总量的43.16%,其次为肉类和主食类,分别占食物浪费总量的20.59%和16.66%。北京市餐饮食物浪费所产生的总碳足迹为192.51×10~4—208.52×10~4t CO_2eq。其中,农业生产阶段的碳排放量最大为99.34×10~4t CO2eq,占食物浪费总碳足迹的47.64%。其次是消费阶段的碳足迹77.96×10~4t CO_2eq,占食物浪费总碳足迹的37.39%,再次是餐厨垃圾处理阶段的碳足迹28.54×104tCO2eq,占食物浪费总碳足迹的13.68%。这些不同供应链环节的碳排放比例,为透视食物浪费所带来的环境影响提供了新的认知,也为遏制食物浪费提供了科学的理论依据。     

System design for the autotrophic production of microalgae

The mass culture of microalgae has been explored over the past 35 years for the production of food, fuels and chemicals, as well as for waste treatment and gas exchange. Culture systems have evolved over this period from small experimental systems to the commercial systems which are presently in place for treatment of municipal wastewaters and for production of a number of specialty products. Further design innovation and refinement will need to draw heavily on the experience which has been gained through the operation of systems employing a wide variety of designs.     

The potential of cellulases and cellulosomes for cellulosic waste management

Lignocellulose is the most abundant plant cell wall component of the biosphere and the most voluminous waste produced by our society. Fortunately, it is not toxic or directly harmful, but our major waste disposal facilities--the landfills--are rapidly filling up with few realistic alternatives. Because cellulose is pure glucose, its conversion to fine products or fuels has remained a romantic and popular notion; however, the heterogeneous and recalcitrant nature of cellulosic waste presents a major obstacle for conventional conversion processes. One paradigm for the conversion of biomass to products in nature relies on a multienzyme complex, the cellulosome. Microbes that produce cellulosomes convert lignocelluose to microbial cell mass and products (e.g. ethanol) simultaneously. The combination of designer cellulosomes with novel production concepts could in the future provide the breakthroughs necessary for economical conversion of cellulosic biomass to biofuels.     

The Impact of Scale,Recycling Boundary,and Type of Waste on Symbiosis and Recycling

Innovative waste recycling through industrial processes such as industrial and urban symbiosis has long been practiced and recently received much attention in the field of industrial ecology, with researchers making efforts to identify key contributing factors to successful industrial symbiosis. By analyzing 88 sample recycling projects in 23 eco‐towns in Japan, this article focuses on the factors of project scale, recycling boundary, and types of waste in relationship to environmental benefits and operational performance. The results showed that larger eco‐towns achieved more savings of virgin materials and higher stability in operation. Large‐scale projects tended to locate closer to the users of recycled products than did small‐scale projects. For treating similar types of waste, projects producing recycled products for special users (e.g., feedstock to a blast furnace for iron production) tended to locate closer to the users than those not producing for special users. The type of waste had a strong effect on the savings of virgin materials and recycling boundaries, while local factors had significant impacts on operational performance. The results also showed that agglomeration did not significantly contribute to the environmental benefits or operational performance of eco‐town projects. Another finding was that national agencies were helpful for facilitating cross‐prefecture transportation and long‐distance transaction of wastes. Implications of the findings are also discussed.     

Microbiological degradation of pesticides in yard waste composting.

Changes in public opinion and legislation have led to the general recognition that solid waste treatment practices must be changed. Solid-waste disposal by landfill is becoming increasingly expensive and regulated and no longer represents a long-term option in view of limited land space and environmental problems. Yard waste, a significant component of municipal solid waste, has previously not been separated from the municipal solid-waste stream. The treatment of municipal solid waste including yard waste must urgently be addressed because disposal via landfill will be prohibited by legislation. Separation of yard waste from municipal solid waste will be mandated in many localities, thus stressing the importance of scrutinizing current composting practices in treating grass clippings, leaves, and other yard residues. Yard waste poses a potential environmental health problem as a result of the widespread use of pesticides in lawn and tree care and the persistence of the residues of these chemicals in plant tissue. Yard waste containing pesticides may present a problem due to the recalcitrant and toxic nature of the pesticide molecules. Current composting processes are based on various modifications of either window systems or in-vessel systems. Both types of processes are ultimately dependent on microbial bioconversions of organic material to innocuous end products. The critical stage of the composting process is the thermophilic phase. The fate and mechanism of removal of pesticides in composting processes is largely unknown and in need of comprehensive analysis.     

A holistic approach to managing palm oil mill effluent (POME): biotechnological advances in the sustainable reuse of POME

During the last century, a great deal of research and development as well as applications has been devoted to waste. These include waste minimization and treatment, the environmental assessment of waste, minimization of environmental impact, life cycle assessment and others. The major reason for such huge efforts is that waste generation constitutes one of the major environmental problems where production industries are concerned. Until now, an increasing pressure has been put on finding methods of reusing waste, for instance through cleaner production, thus mirroring rapid changes in environmental policies. The palm oil industry is one of the leading industries in Malaysia with a yearly production of more than 13 million tons of crude palm oil and plantations covering 11% of the Malaysian land area. However, the production of such amounts of crude palm oil result in even larger amounts of palm oil mill effluent (POME), estimated at nearly three times the quantity of crude palm oil. Normally, POME is treated using end-of-pipe processes, but it is worth considering the potential value of POME prior to its treatment through introduction of a cleaner production. It is envisaged that POME can be sustainably reused as a fermentation substrate in the production of various metabolites, fertilizers and animal feeds through biotechnological advances. The present paper thus discusses various technically feasible and economically beneficial means of transforming the POME into low or preferably high value added products.     

Valorization of Dairy Wastes: Integrative Approaches for Value Added Products

The era of rapid industrialization succeeded by a shift in organizational focus on research and technology development which has fueled many industries along with the dairy industry to grow at an exponential rate. The dairy industry has achieved remarkable growth in the last decade in India. Waste produced by dairy industry consists of a high organic load thus cannot be discharged untreated. Even though treatment and management of waste are well documented, but the main problem is concerned with sludge produced after treatment. There is a gap in the application of various methods for effective treatment of the waste, hence there is a need for technology-oriented research in this area because of a paradigm shift in perspectives towards sustainable management of waste to recover value added products including energy as energy demand is also rising. Sludge which is generally land spread can also be used for energy generation. This paper discusses the environmental effects of waste generated due to dairy industrial activities; various methods used for the advanced treatment of dairy waste. This review article aims to present and discuss the state-of-art information for recovery of value-added products (single cell protein, biofertilizers, biopolymers and biosurfactants) from dairy waste with emphasis on integration of technologies for environmental sustainability. This paper also includes challenges and future perspectives in this field.     

A review on economically adsorbents on heavy metals removal in water and wastewater

Heavy metals contamination in water has been an issue to the environment and human health. The persisting contamination level has been observed and concerned by the public due to continuous deterioration of water quality. On the other hand, conventional treatment system could not completely remove the toxic metals in the water, thus alternative purification methods using inexpensive materials were endeavor to improve the current treatment process. Wide ranges of low cost adsorbents were used to remove heavy metal in aqueous solution and wastewater. The low cost adsorbents were usually collected from agricultural waste, seafood waste, food waste, industrial by-product and soil. These adsorbents are readily available in a copious amount. Besides, the pretreatment are not complicated to be conducted on the raw products, which is economically sound for an alternative treatment. The previous studies have provided much evidence of low cost adsorbents’ efficiency in removing metal ions from aqueous solution or wastewater. In this review, several low cost adsorbents in the recent literature have been studied. The maximum adsorption capacity, affecting factors such as pH, contact times, temperature, initial concentration and modified materials were revised and summarized in this review for further reference. Comparisons of the adsorbent between the modified and natural products were also demonstrated to provide a clear understanding on the kinetic uptake of the selected adsorbents. Some of the natural adsorbents appeared as good heavy metal removal, while some were not and require further modifications and improvements to enhance the adsorption capacity. SWOT analysis (strength, weakness, opportunities, threat) was also performed on the low cost adsorbents to identify the advantages of using low cost adsorbents and solve the weaknesses encountered by the utilization of low cost materials. This tool helps to determine the potential quality of low cost materials in the application for water and wastewater treatment.     

Decomposition Analysis of Waste Generation From Stocks in a Dynamic System

We conducted a decomposition analysis of material flows in a dynamic system, focusing on factors in the generation of waste consumer durables. A methodology for the analysis of consumer durables was developed and applied to three common consumer durables: cathode ray tube TVs, refrigerators, and passenger cars. The methodology decomposed changes in the numbers of waste products into three factors: changes in lifespan distribution, past trends in replacement sales, and past trends in sales for additional purchases. The decomposed equation clearly showed that the number of waste products would not necessarily be reduced by lifespan extension alone. This is because the number of waste products generated is affected not only by current lifespan distribution but also by past trends in sales for replacement and in additional purchases. The results show that changes in past replacement sales influence the current generation of waste, even if current replacement sales are declining. To reduce the generation of waste products on a short‐term basis, lifespan must be extended until the waste‐reducing effect of lifespan extension exceeds the waste‐increasing effect of the other two factors. From a long‐term perspective, controlling current replacement and additional purchases can be used to prevent future waste product generation.     

Enhancement of the mutagenicity of polyphenols by chlorination and nitrosation in Salmonella typhimurium.

The hydrolytic products of lignins, humic acids and industrial waste including hydroquinone, catechol, resorcinol, pyrogallol and 1,2,4-benzenetriol are widely distributed in water sources. These polyphenols can interact with chlorine or nitrite to yield new derivatives. Generally, these new products possess more mutagenic potential than their original compounds. Furthermore, the mutagenicity of these polyphenols and their derivatives can be dramatically reduced by rodent liver microsomal enzymes (S9). The mutagenicity of polyphenols is in this order: hydroquinone greater than 1,2,4-benzenetriol greater than pyrogallol, while catechol, resorcinol and phloroglucinol are non-mutagenic. The ultimate product of chlorination or nitrosation of hydroquinone has been identified to be p-benzoquinone. The formation of active oxygen species including superoxide anion and hydrogen peroxide by polyphenols has been demonstrated and this may contribute partly to the molecular mechanisms of polyphenol mutagenicity.     

Recycling of waste products in the induction of biofilms to remediate the visual impact generated by quartz mining

The present study was undertaken to investigate the viability of the use of two waste products, cheese whey and composted organic waste, as nutrient sources in the induction of biological films on quartz surfaces, with the final aim of reducing the visual impact generated by quartz mining. Experiments were carried in laboratory in which quartz samples were colonized with microorganisms (mainly cyanobacteria) forming biofilms. Previous studies have shown that a nutritional supplement must be added for good development of biofilms and, therefore, application of the two waste products was compared with application of the chemical nutrient medium on which these types of microorganisms are usually cultivated. Both products provided better results than the culture medium, in terms of the speed of formation of the biofilm, faster with the waste products, and the degree of cover of the brilliant white colour of the quartz, better masked by the biofilms formed when the waste products were applied as a darker biofilm was obtained.     

Biodegradation of natural and synthetic rubbers: A review

Since polymeric materials do not decompose easily, disposal of waste polymers is a serious environmental concern. Widespread studies on the biodegradation of rubbers have been carried out in order to overcome the environmental problems associated with rubber waste. This report provides an overview on the microbial degradation of natural and synthetic rubbers. Rubber degrading microbes, bacteria and fungi, are ubiquitous in the environment especially soil. The qualitative data like plate assay, scanning electron microscopy (SEM), attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR) and Sturm test indicated that both natural and synthetic rubbers can be degraded by microorganisms. It has confirmed that the enzymes latex clearing protein (Lcp) and rubber oxygenase A (RoxA) are responsible for the degradation of natural and synthetic rubbers. Lcp was obtained from Gram-positive bacterium Streptomyces sp. strain K30 and RoxA from Gram-negative bacterium Xanthomonas sp. strain 35Y. Analysis of degradation products of natural and synthetic rubbers indicated the oxidative cleavage of double bonds in polymer backbone. Aldehydes, ketones and other carbonyl groups were detected as degradation products from cultures of various rubber degrading strains. This review emphasizes the importance of biodegradation in environmental biotechnology for waste rubber disposal.     

Biodegradable and compostable alternatives to conventional plastics

Packaging waste forms a significant part of municipal solid waste and has caused increasing environmental concerns, resulting in a strengthening of various regulations aimed at reducing the amounts generated. Among other materials, a wide range of oil-based polymers is currently used in packaging applications. These are virtually all non-biodegradable, and some are difficult to recycle or reuse due to being complex composites having varying levels of contamination. Recently, significant progress has been made in the development of biodegradable plastics, largely from renewable natural resources, to produce biodegradable materials with similar functionality to that of oil-based polymers. The expansion in these bio-based materials has several potential benefits for greenhouse gas balances and other environmental impacts over whole life cycles and in the use of renewable, rather than finite resources. It is intended that use of biodegradable materials will contribute to sustainability and reduction in the environmental impact associated with disposal of oil-based polymers.The diversity of biodegradable materials and their varying properties makes it difficult to make simple, generic assessments such as biodegradable products are all ‘good’ or petrochemical-based products are all ‘bad’. This paper discusses the potential impacts of biodegradable packaging materials and their waste management, particularly via composting. It presents the key issues that inform judgements of the benefits these materials have in relation to conventional, petrochemical-based counterparts. Specific examples are given from new research on biodegradability in simulated ‘home’ composting systems. It is the view of the authors that biodegradable packaging materials are most suitable for single-use disposable applications where the post-consumer waste can be locally composted.     

Polymorphism for supernumerary chromosomes in populations of Rana temporaria L

Occurrence of B-chromosomes in four populations of Rana temporaria L. in Minsk, its suburb and Berezinski? biosphere reserve has been studied. The percentage of individuals with B-chromosomes and the average number of B-chromosomes per genome are shown to multiply increase in the population inhabiting for 40 years in the region polluted with waste products. The results obtained are discussed from the standpoint of the action of mechanism for the accumulation of additional chromosomes due to environmental pollution.