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1.

Purpose

Diminishing fossil resources and environmental concerns associated with their vast utilization have been in focus by energy policy makers and researchers. Among the different scenarios put forth to commercialize biofuels, various biorefinery concepts have aroused global interests because of their ability in converting biomass into a spectrum of marketable products and bioenergies. This study was aimed at developing different novel castor-based biorefinery scenarios for generating biodiesel and other co-products, i.e., ethanol and biogas. In these scenarios, glycerin, heat, and electricity were also considered as byproducts. Developed scenarios were also compared with a fossil reference system delivering the same amount of energy through the combustion of neat diesel.

Materials and methods

Life cycle assessment (LCA) was used to investigate the environmental consequences of castor biodiesel production and consumption with a biorefinery approach. All the input and output flows from the cultivation stage to the combustion in diesel engines as well as changes in soil organic carbon (SOC) were taken into account. Impact 2002+ method was used to quantify the environmental consequences.

Results and discussion

The LCA results demonstrated that in comparison with the fossil reference system, only one scenario (i.e., Sc-3 with co-production of significant amounts of biodiesel and biomethane) had 16% lower GHG emissions without even considering the improving effect of SOC. Moreover, resource damage category of this scenario was 50% lower than that of neat diesel combustion. The results proved that from a life cycle perspective, energy should be given priority in biorefineries because it is essential for a biorefinery to have a positive energy balance in order to be considered as a sustainable source of energy. Despite a positive effect on energy and GHG balances, these biorefineries had negative environmental impacts on the other damage categories like Human Health and Ecosystem Quality.

Conclusions

Although biorefineries offer unique features as promising solutions for mitigating climate change and reducing dependence on fossil fuels, the selection of biomass processing options and management decisions can affect the final results in terms of environmental evaluations and energy balance. Moreover, if biorefineries are focused on transportation fuel production, a great deal of effort should still be made to have better environmental performance in Human Health and Ecosystem Quality damage categories. This study highly recommends that future studies focus towards biomass processing options and process optimization to guarantee the future of the most sustainable biofuels.
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2.

Introduction  

The limited availability of fossil fuel sources, worldwide rising energy demands and anticipated climate changes attributed to an increase of greenhouse gasses are important driving forces for finding alternative energy sources. One approach to meeting the increasing energy demands and reduction of greenhouse gas emissions is by large-scale substitution of petrochemically derived transport fuels by the use of carbon dioxide-neutral biofuels, such as ethanol derived from lignocellulosic material.  相似文献   

3.

Purpose

This study advocates a modular approach combining unit processes as building blocks to formulate biomass process chains. This approach facilitates a transparent environmental life cycle impact assessment for bio-based products. It also enhances the ability to develop and assess more complex biorefinery systems, identifies critical parameters and offers useful material to support environmental impact assessment in early design stages.

Methods

Twenty-three different products were assessed with regard to the environmental burden associated with their production paths. Life cycle inventories (LCIs) for 32 unit processes were compiled (using information from pilot plants, simulation and literature data) and organized in biomass process chains. Then, 58 study systems were formed based on various combinations of the unit processes, each study system referring to the production of a selected product. Three indicators were used for quantification of the impacts: non-renewable fossil cumulative energy demand (CED), global warming potential (GWP) and water depletion as defined in the ReCiPe method.

Results and discussion

Factors influencing the variation of results even for similar products are discussed (e.g. production path and allocation method lead to a range of GWP values for ethylene production from 0.43 to 3.37 kg CO2 eq/kg ethylene). For the majority of bio-products, CED has lower values than fossil-based equivalents (average difference 39–70 MJ eq/kg product depending on the allocation method), while mixed trends are obtained for the GWP and water depletion indicators. Assessments also highlight attributes that have a significant effect in the environmental profile of a production path such as the synthesis path, the process chemistry (water intensity) and process-related factors (energy intensity, degree of energy integration/heat recovery).

Conclusions

The analysis of impacts per unit process is able to demonstrate the particular production stages featuring high environmental intensities along a path further hinting to suggestions for amendments and improvements from an overall performance perspective. The study makes a useful source for biorefinery design studies especially in adopting a modular approach to represent and to analyse biomass process chains; it also provides a reference point for comparison (benchmarking) between different process technologies for biomass utilization. Finally, the analysis is compatible with the standards of the LCA methodology, and it is based on the use of the most common LCA databases, which facilitates the comparison of the results with other relevant studies.
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4.

Purpose

The two main reasons for producing biomethane as renewable fuel are reduction of climate impacts and depletion of fossil resources. Biomethane is expected to be sustainable, but how sustainable is it actually? This article contributes to the clarification. Therefore, the environmental impacts of several biomethane facilities all over Europe were assessed. A special focus is put on the differences between the facilities as they follow different production routes.

Methods

The method used for evaluation is life cycle assessment (LCA) applied in a well-to-wheel approach. This enables to show the overall performance in terms of global warming potential (GWP), acidification potential (AP), eutrophication potential (EP), photochemical ozone creation potential (POCP) and PE fossil. The system boundary includes the entire chain from biogas production to upgrading, distribution and use. For evaluating the different production routes several years of measuring data, calculating and improving the LCA models in close cooperation with the plant operators were carried out.

Results and discussion

The evaluation of the production routes shows a high reduction potential compared to fossil fuels. Regarding the depletion of fossil resources, the amounts vary between the sites, but the reduction is at least 50 % and reaches almost 100 % reductions at some sites. The reduction of GWP is at least 65 %, because waste flows free of environmental burdens are used almost exclusively as substrate. Other dominant factors are power and heat demand, methane losses to the environment and the use of by-products, e.g. fertilizer.

Conclusions

Despite this caveat, the evaluated systems demonstrate the possible positive results of renewable fuel production if done properly.  相似文献   

5.

Purpose  

Recently, the Thai government has been advancing the expanded use of biomass as an alternative source of energy substituting it for the fossil fuels that have been shown to be harmful to the environment. Rice husk, one of the main sources of biomass in Thailand, has already been used as an energy source in many different applications and has been successful in reducing the consumption of fossil fuels. At present (2011), the main use of rice husk in Thailand is as fuel to generate electricity. However, rice husk can potentially be used to produce other forms of energy such as cellulosic ethanol. This paper compares the environmental performance of the current main use of rice husk for energy purposes in the Thai context, i.e., for electricity generation with the prospective use, i.e., for cellulosic ethanol production. The results from this study will identify the more environmentally friendly option for use of rice husk for energy purposes.  相似文献   

6.

Background  

Solenoid repeat proteins of the Tetratrico Peptide Repeat (TPR) family are involved as scaffolds in a broad range of protein-protein interactions. Several resources are available for the prediction of TPRs, however, they often fail to detect divergent repeat units.  相似文献   

7.
Life cycle assessment of mini-hydropower plants in Thailand   总被引:1,自引:0,他引:1  

Purpose  

The conversion of electricity in Thailand is mainly based on fossil fuels that account more than 90% of electricity generated in the country. The use of fossil fuels has large environmental impacts, and being largely imported, also affects the energy security of the country. From the oil shock situation in 1970s, there has been interest in renewable energy in Thailand resulting in the policy goal for the year 2020 to increase the portion of renewable energy to 20% of energy used in the country. Now, hydropower contributes a significant portion of the renewable energy in Thailand, and mini-hydropower (run-of-river type with capacity between 200 to 6000 kW) tends to be most attractive. This is particularly suitable for Thailand, and it is being applied at several locations. Thus, the overall life cycle assessment (LCA), from cradle to gate, of mini-hydropower plants needs to be assessed for quantitative evaluation.  相似文献   

8.

Purpose

Shifting the resource base for chemical and energy production from fossil feed stocks to renewable raw materials is seen by many as one of the key strategies towards sustainable development. The objective of this study is to assess the environmental burdens of producing polyitaconic acid (PIA), a water-soluble polymer derived from itaconic acid identified by the US Department of Energy as one of the top 12 value added chemicals from northeast (NE) US softwood biomass. Results are compared to corn-derived PIA and fossil-based poly acrylic acid (PAA) on the basis of 1 kg of polymer at the factory gate.

Methods

This study uses attributional life cycle assessment to quantify global warming potential (GWP), fossil energy demand (CED), acidification, eutrophication, water use, and land occupation of the polymer production routes. This includes feedstock growth and harvest, sugar extraction, fermentation, itaconic acid recovery, and subsequent polymerization. Foreground data for softwood-derived PIA comes from lab- and pilot plant runs undertaken by Itaconix LLC.

Results and discussion

Results indicate that the use of softwood-based PIA may be advantageous in terms of GWP, CED, and acidification when compared to both, the integrated corn biorefinery and fossil-based PAA production. When looking at impacts to eutrophication and water use, the use of softwood leads to lower potential impacts compared to its corn-based counterpart but to higher impacts when compared to fossil-based PAA. Land occupation, to a large extent, due to lower yields and longer growth cycles associated with softwood growth in the NE, is highest for softwood-derived PIA and lowest for fossil-based PAA. Environmental impacts are mainly the results of onsite electricity use, inputs of activated carbon and sodium hydroxide, as well as water use during sugar extraction and fermentation. Assumptions with regards to allocation, activated carbon inputs, and electricity mixes to processes of the foreground system are tested in a sensitivity analysis.

Conclusions

Wood-derived PIA production may be an interesting alternative to current fossil-based pathways and could contribute to a future biobased economy. However, currently, land occupation, water use, and eutrophication are high when compared to traditional PAA production. The use of short rotation crops or waste feedstocks and optimization with regards to water requirements and reuse should be investigated to further lower system-wide impacts.  相似文献   

9.

Background, aim, and scope  

The increasing gasoline price, the depletion of fossil resources, and the negative environmental consequences of driving with petroleum fuels have driven the development of alternative transport fuels. Bioethanol, which is converted from cellulosic feedstocks, has attracted increasing attention as one such alternative. This study assesses the environmental impact of using ethanol from switchgrass as transport fuel and compares the results with the ones of gasoline to analyze the potential of developing switchgrass ethanol as an environmentally sustainable transport fuel.  相似文献   

10.

Background, aim, and scope

Facing the threat of oil depletion and climate change, a shift from fossil resources to renewables is ongoing to secure long-term low carbon energy supplies. In view of the carbon dioxide reduction targets agreed upon in the Kyoto protocol, bioethanol has become an attractive option for one energy application, as transport fuel. Many studies on the LCA of fuel ethanol have been conducted, and the results vary to a large extent. In most of these studies, only one type of allocation is applied. However, the effect of allocation on outcomes is of crucial importance to LCA as a decision supporting tool. This is only addressed in a few studies to a limited extent. Moreover, most of the studies mainly focus on fossil energy use and GHG emissions. In this paper, a case study is presented wherein a more complete set of impact categories is used. Land use has been left out of account as only hectare data would be given which is obviously dominated by agriculture. Moreover, different allocation methods are applied to assess the sensitivity of the outcomes for allocation choices.

Materials and methods

This study focuses on the comparison of LCA results from the application of different allocation methods by presenting an LCA of gasoline and ethanol as fuels and with two types of blends of gasoline with ethanol, all used in a midsize car. As a main second-generation application growing fast in the USA, corn stover-based ethanol is chosen as a case study. The life cycles of the fuels include gasoline production, corn and stover agriculture, cellulosic ethanol production, blending ethanol with gasoline to produce E10 (10% of ethanol) and E85 (85% of ethanol), and finally the use of gasoline, E10, E85, and ethanol. In this study, a substantially broader set of eight environmental impacts is covered.

Results

LCA results appear to be largely dependent on the allocation methods rendered. The level of abiotic depletion and ozone layer depletion decrease when replacing gasoline by ethanol fuels, irrespective of the allocation method applied, while the rest of the impacts except global warming potential are larger. The results show a reduction of global warming potential when mass/energy allocation is applied; in the case of economic allocation, it gives contrary results. In the expanded systems, global warming potential is significantly reduced comparing to the ones from the allocated systems. A contribution analysis shows that car driving, electricity use for cellulase enzyme production, and ethanol conversion contribute largely to global warming potential from the life cycle of ethanol fuels.

Discussion

The reason why the results of global warming potential show a reverse trend is that the corn/stover allocation ratio shifts from 7.5 to 1.7 when shifting from economic allocation to mass/energy allocation. When mass/energy allocation is applied, both more credits (CO2 uptake) and more penalties (N2O emission) in agriculture are allocated to stover compared to the case of economic allocation. However, more CO2 is taken up than N2O (in CO2 eq.) emitted. Hence, the smaller the allocation ratio is between corn and stover, the lower the share of the overall global warming emissions being allocated to ethanol will be. In the system expansion approach, global warming potentials are significantly reduced, resulting in the negative values in all cases. This implies that the system expansion results are comparable to one another because they make the same cutoffs but not really to the results related to mass, energy, and economic value-based allocated systems.

Conclusions

The choice of the allocation methods is essential for the outcomes, especially for global warming potential in this case. The application of economic allocation leads to increased GWP when replacing gasoline by ethanol fuels, while reduction of GWP is achieved when mass/energy allocation is used as well as in the system where biogenic CO2 is excluded. Ethanol fuels are better options than gasoline when abiotic depletion and ozone layer depletion are concerned. In terms of other environmental impacts, gasoline is a better option, mainly due to the emissions of nutrients and toxic substances connected with agriculture. A clear shift of problems can be detected: saving fossil fuels at the expense of emissions related to agriculture, with GHG benefits depending on allocation choices. The overall evaluation of these fuel options, therefore, depends very much on the importance attached to each impact category.

Recommendations and perspectives

This study focuses only on corn stover-based ethanol as one case. Further studies may include other types of cellulosic feedstocks (i.e., switchgrass or wood), which require less intensive agricultural practice and may lead to better environmental performance of fuel ethanol. Furthermore, this study shows that widely used but different allocation methods determine outcomes of LCA studies on biofuels. This is an unacceptable situation from a societal point of view and a challenge from a scientific point of view. The results from applying just one allocation method are not sufficient for decision making. Comparison of different allocation methods is certainly of crucial importance. A broader approach beyond LCA for the analysis of biorefinery systems with regard to energy conservation, environmental impact, and cost–benefit will provide general indications on the sustainability of bio-based productions.  相似文献   

11.

Purpose

Renewable energies are promoted in order to reduce greenhouse gas emissions and the depletion of fossil fuels. However, plants for renewable electricity production incorporate specifically higher amounts of materials being rated as potentially scarce. Therefore, it is in question which (mineral) resources contribute to the overall resource consumption and which of the manifold impact assessment methods can be recommended to cover an accurate and complete investigation of resource use for renewable energy technologies.

Methods

Life cycle assessment is conducted for different renewable electricity production technologies (wind, photovoltaics, and biomass) under German conditions and compared to fossil electricity generation from a coal-fired power plant. Focus is given on mineral resource depletion for these technologies. As no consensus has been reached so far as to which impact assessment method is recommended, different established as well as recently developed impact assessment methods (CML, ReCiPe, Swiss Ecoscarcity, and economic scarcity potential (ESP)) are compared. The contribution of mineral resources to the overall resource depletion as well as potential scarcity are identified.

Results and discussion

Overall resource depletion of electricity generation technologies tends to be dominated by fossil fuel depletion; therefore, most renewable technologies reduce the overall resource depletion compared to a coal-fired power plant. But, in comparison to fossil electricity generation from coal, mineral resource depletion is increased by wind and solar power. The investigated methods rate different materials as major contributors to mineral resource depletion, such as gallium used in photovoltaic plants (Swiss Ecoscarcity), gold and copper incorporated in electrical circuits and in cables (CML and ReCiPe), and nickel (Swiss Ecoscarcity and ReCiPe) and chromium (ESP) for stainless steel production. However, some methods lack characterization factors for potentially important materials.

Conclusions

If mineral resource use is investigated for technologies using a wider spectrum of potentially scarce minerals, practitioners need to choose the impact assessment method carefully according to their scope and check if all important materials are covered. Further research is needed for an overall assessment of different resource compartments.
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12.

Premise of the Study

The fossil record is critical for testing biogeographic hypotheses. Menispermaceae (moonseeds) are a widespread family with a rich fossil record and alternative hypotheses related to their origin and diversification. The family is well‐represented in Cenozoic deposits of the northern hemisphere, but the record in the southern hemisphere is sparse. Filling in the southern record of moonseeds will improve our ability to evaluate alternative biogeographic hypotheses.

Methods

Fossils were collected from the Salamanca (early Paleocene, Danian) and the Huitrera (early Eocene, Ypresian) formations in Chubut Province, Argentina. We photographed them using light microscopy, epifluorescence, and scanning electron microscopy and compared the fossils with similar extant and fossil Menispermaceae using herbarium specimens and published literature.

Key Results

We describe fossil leaves and endocarps attributed to Menispermaceae from Argentinean Patagonia. The leaves are identified to the family, and the endocarps are further identified to the tribe Cissampelideae. The Salamancan endocarp is assigned to the extant genus Stephania. These fossils significantly expand the known range of Menispermaceae in South America, and they include the oldest (ca. 64 Ma) unequivocal evidence of the family worldwide.

Conclusions

Our findings highlight the importance of West Gondwana in the evolution of Menispermaceae during the Paleogene. Currently, the fossil record does not discern between a Laurasian or Gondwanan origin; however, it does demonstrate that Menispermaceae grew well outside the tropics by the early Paleocene. The endocarps’ affinity with Cissampelideae suggests that diversification of the family was well underway by the earliest Paleocene.  相似文献   

13.

Background

Molecular dating has gained ever-increasing interest since the molecular clock hypothesis was proposed in the 1960s. Molecular dating provides detailed temporal frameworks for divergence events in phylogenetic trees, allowing diverse evolutionary questions to be addressed. The key aspect of the molecular clock hypothesis, namely that differences in DNA or protein sequence between two species are proportional to the time elapsed since they diverged, was soon shown to be untenable. Other approaches were proposed to take into account rate heterogeneity among lineages, but the calibration process, by which relative times are transformed into absolute ages, has received little attention until recently. New methods have now been proposed to resolve potential sources of error associated with the calibration of phylogenetic trees, particularly those involving use of the fossil record.

Scope and Conclusions

The use of the fossil record as a source of independent information in the calibration process is the main focus of this paper; other sources of calibration information are also discussed. Particularly error-prone aspects of fossil calibration are identified, such as fossil dating, the phylogenetic placement of the fossil and the incompleteness of the fossil record. Methods proposed to tackle one or more of these potential error sources are discussed (e.g. fossil cross-validation, prior distribution of calibration points and confidence intervals on the fossil record). In conclusion, the fossil record remains the most reliable source of information for the calibration of phylogenetic trees, although associated assumptions and potential bias must be taken into account.  相似文献   

14.

Background  

The production of fuel-grade ethanol from lignocellulosic biomass resources has the potential to increase biofuel production capacity whilst minimising the negative environmental impacts. These benefits will only be realised if lignocellulosic ethanol production can compete on price with conventional fossil fuels and if it can be produced commercially at scale. This paper focuses on lignocellulosic ethanol production in Europe. The hypothesis is that the eventual cost of production will be determined not only by the performance of the conversion process but by the performance of the entire supply-chain from feedstock production to consumption. To test this, a model for supply-chain cost comparison is developed, the components of representative ethanol supply-chains are described, the factors that are most important in determining the cost and profitability of ethanol production are identified, and a detailed sensitivity analysis is conducted.  相似文献   

15.

Purpose  

Ambitious targets for the use of renewable energy have recently been set in the European Union. To reach these targets, a large share of future energy generation will be based on the use of woody biomass. Therefore, there is an increasing interest in the cultivation of fast-growing tree species on agricultural land outside forests. Intensive crop production is always considered to harm the environment. The study explores the environmental burdens of the cultivation of fast-growing tree species on agricultural land and their subsequent energetic conversion in comparison to the fossil reference energy system.  相似文献   

16.
Newly discovered fossil assemblages of small bodied Homo sapiens from Palau, Micronesia possess characters thought to be taxonomically primitive for the genus Homo.

Background

Recent surface collection and test excavation in limestone caves in the rock islands of Palau, Micronesia, has produced a sizeable sample of human skeletal remains dating roughly between 940-2890 cal ybp.

Principle Findings

Preliminary analysis indicates that this material is important for two reasons. First, individuals from the older time horizons are small in body size even relative to “pygmoid” populations from Southeast Asia and Indonesia, and thus may represent a marked case of human insular dwarfism. Second, while possessing a number of derived features that align them with Homo sapiens, the human remains from Palau also exhibit several skeletal traits that are considered to be primitive for the genus Homo.

Significance

These features may be previously unrecognized developmental correlates of small body size and, if so, they may have important implications for interpreting the taxonomic affinities of fossil specimens of Homo.  相似文献   

17.
18.

Background, aims and scope  

Food production is essential to life. Modern farming uses considerable resources to produce arable crops. Analysing the environmental burdens of alternative crop production methods is a vital tool for policymakers. The paper describes the production burdens (calculated by life cycle analysis) of three key arable crops: bread wheat, oilseed rape and potatoes as grown in England and Wales using organic and non-organic (contemporary conventional) systems. Resource use (e.g. abiotic and energy) and burdens from emissions are included (e.g. global warming potential on a 100-year basis, global warming potential (GWP), and eutrophication and acidification potentials).  相似文献   

19.

Background, aim and scope

After China and India, Thailand is considered another emerging market for fuel ethanol in Asia. At present, ethanol in the country is mainly a fermentation/distillery product of cane molasses, although cassava and cane juice are considered other potential raw materials for the fuel. This study aims to evaluate the environmental impacts of substituting conventional gasoline (CG) with molasses-based gasohol in Thailand.

Materials and methods

The life cycle assessment (LCA) procedure carried out follows three interrelated phases: inventory analysis, characterization and interpretation. The functional unit for the comparison is 1 l gasoline equivalent consumed by a new passenger car to travel a specific distance.

Results

The results of the study show that molasses-based ethanol (MoE) in the form of 10% blend with gasoline (E10), along its whole life cycle, consumes less fossil energy (5.3%), less petroleum (8.1%) and provides a similar impact on acidification compared to CG. The fuel, however, has inferior performance in other categories (e.g. global warming potential, nutrient enrichment and photochemical ozone creation potential) indicated by increased impacts over CG.

Discussion

In most cases, higher impacts from the upstream of molasses-based ethanol tend to govern its net life cycle impacts relative to CG. This makes the fuel blend less environmentally friendly than CG for the specific conditions considered. However, as discussed later, this situation can be improved by appropriate changes in energy carriers.

Conclusions

The LCA procedure helps identify the key areas in the MoE production cycle where changes are required to improve environmental performance. Specifically, they are: (1) use of coal as energy source for ethanol conversion, (2) discharge of distillery spent wash into an anaerobic pond, and (3) open burning of cane trash in sugar cane production.

Recommendations and perspectives

Measures to improve the overall life cycle energy and environmental impacts of MoE are: (1) substituting biomass for fossil fuels in ethanol conversion, (2) capturing CH4 from distillery spent wash and using it as an energy supply, and (3) utilizing cane trash for energy instead of open burning in fields.  相似文献   

20.

Purpose

In life cycle impact assessment, various proposals have been made on how to characterise fossil resource scarcity, but they lack appropriateness or completeness. In this paper, we propose a method to assess fossil resource scarcity based on surplus cost, which is the global future cost increase due to marginal fossil resource used in the life cycle of products.

Methods

The marginal cost increase (MCI in US dollars in the year 2008 per kilogram per kilogram produced) is calculated as an intermediate parameter for crude oil, natural gas and coal separately. Its calculations are based on production cost and cumulative future production per production technique or country. The surplus cost (SC in US dollars in the year 2008 per kilogram) is calculated as an indicator for fossil resource scarcity. The SC follows three different societal perspectives used to differentiate the subjective choices regarding discounting and future production scenarios.

Results and discussion

The hierarchist perspective SCs of crude oil, natural gas, and coal are 2.9, 1.5, and 0.033 US$2008/GJ, respectively. The ratios between the indicators of the different types of fossil resources (crude oil/natural gas/coal) are rather constant, except in the egalitarian perspective, where contrastingly no discounting is applied (egalitarian 100:47:21; hierarchist 100:53:1.1; individualist 100:34:0.6). The ratio of the MCIs (100:48:1.0) are similar to the individualist and hierarchist SC ratios.

Conclusions

In all perspectives, coal has a much lower resource scarcity impact factor per gigajoule and crude oil has the highest. In absolute terms of costs per heating value (US dollars in the year 2008 per gigajoule), there are large differences between the SCs for each perspective (egalitarian > hierarchist > individualist).  相似文献   

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