Diagnostics of a nonequilibrium nitrogen plasma from the emission spectra of the second positive system of N2

A method is proposed for determining the electron density N _e and the electric field E in the non-equilibrium nitrogen plasma of a low-pressure discharge from the spectra of the second positive system of N₂. The method is based on measuring the specific energy deposition in the plasma and the distribution of nitrogen molecules over the vibrational levels of the C ³Π _u state, as well as on modeling this distribution for a given energy deposition. The fitting parameters of the model are the values of N _e and E. A kinetic model of the processes governing the steady-state density of the C ³Π _u nitrogen molecules is developed. The testing of this method showed it to be quite reliable. The method is of particular interest for diagnosing electrodeless discharges and provides detailed information on the processes occurring in the discharge plasma. Preliminary data are obtained on the plasma parameters in a cavity microwave discharge and an electrode microwave discharge. In particular, it is found that the electric field in an electrode microwave discharge in nitrogen is lower than that in a hydrogen discharge. This effect is shown to be produced by stepwise and associative processes with the participation of excited particles in nitrogen.     

Experimental study of a low-pressure glow discharge in air in large-diameter discharge tubes: I. conditions for the normal regime of a glow discharge

The initiation and characteristics of a low-pressure glow discharge in air in large-diameter discharge tubes are studied. A deviation from the Paschen law is observed: the breakdown curves U _dc(pL) shift toward the higher values of U _dc and pL as the interelectrode distance L increases. It is shown that the normal regime of a glow discharge is accompanied by gas ionization in the anode sheath. This takes place only for pL values lying to the right of the inflection point in the breakdown curve. The cathode-sheath characteristics in the normal and abnormal regimes of an air discharge for a duralumin cathode are determined. The axial profiles of the ion density, electron temperature, and plasma potential, as well as the anode voltage drop, are measured at various air pressures.     

Discharge dynamics and the production of active particles in a cathode-directed streamer

The emission spectroscopy technique is used to analyze a cathode-directed streamer discharge in air at atmospheric pressure in point-plane geometry at interelectrode distances of up to 100 mm and a high-voltage pulse amplitude of 18 kV. The densities of molecules in the N₂(C ³Π_u, v=0), N ₂ ⁺ (B ²Σ _u ⁺ , v=0) and NO(A ²Σ⁺, v=0) states are determined, and the reduced electric field in the streamer head is estimated. It is shown that the increase in the average electric field in the discharge gap substantially intensifies the production of active particles in the discharge plasma and makes the plasma more homogeneous. This effect is only related to the increase in the fraction of regions with a high electric field in the discharge gap and, as a result, the reduction of the discharge energy losses via rapidly thermalized degrees of freedom. The active particles are only produced in the streamer head, including the case in which the interelectrode gap is bridged by the streamer channel.     

Simulations of a longitudinal glow discharge in a hot air flow at atmospheric pressure

A one-dimensional axisymmetric time-dependent model of a discharge in a gas flow is developed. The model includes a fairly complete set of plasmochemical reactions and describes the heating and gasdynamic expansion of a plasma channel in air. The processes governing the distribution of nitrogen molecules in the N₂(C ³Π_u, v) state over vibrational levels are considered. The parameters of a longitudinal glow discharge in a hot (T ₀ = 1500?3000 K) air flow at atmospheric pressure are calculated. It is found that gas preheating considerably influences the parameters of the discharge channel. The results of calculations are compared with the experimental data.     

Characteristics of a transverse RF discharge in Xe/Cl<Subscript>2</Subscript> mixtures

Results are presented from the study of the electrical and optical characteristics of a transverse RF discharge in Xe/Cl₂ mixtures at pressures of p≤400 Pa. The working mixture was excited by a modulated RF discharge (f=1.76 MHz) with a transverse electrode configuration (L≤17 cm). The emission spectrum in the spectral range of 210–600 nm and the waveforms of the discharge current, discharge voltage, and plasma emission intensity were investigated. The UV emission power from the discharge was studied as a function of the pressure and composition of a Xe/Cl₂ mixture. It is shown that a discharge in a xenon-chlorine mixture acts as planar excimer-halogen lamp operating in the spectral range of 220–450 nm, which contains a system of overlapping XeCl(D, B-X; B, C-A) and Cl₂(D′-A′) bands. Transverse RF discharges in Xe/Cl₂ mixtures can be used to create a wideband lamp with two 50-cm² planar apertures and the low circulation rate of the working mixture.     

Controlling the characteristics of a repetitive volume discharge in CFC-12 and its mixtures with argon

The parameters of a repetitive volume discharge in CF₂Cl₂ (CFC-12) and its mixtures with argon at pressures of P(CF₂Cl₂)≤0.4 kPa and P(Ar)≤1.2 kPa are studied. The discharge was ignited in an electrode system consisting of a spherical anode and a plane cathode by applying a dc voltage U_ch≤1 kV to the anode. The electrical and optical characteristics of a volume discharge (such as the current-voltage characteristics; the plasma emission spectra; and the waveforms of the discharge voltage, the discharge current, and the total intensity of plasma emission) are investigated. It is found that, by shunting the discharge gap with a pulsed capacitor with a capacitance of C₀≤3.5 nF, it is possible to control the amplitude and duration of the discharge current pulses, as well as the characteristics of the pulsed plasma emission. The increase in the capacitance C₀ from 20 to 3500 pF leads to a significant increase in the amplitude and duration of the discharge current pulses, whereas the pulse repetition rate decreases from 70 to 3 kHz. The glow discharge exists in the form of a domain with a height of up to 3 cm and diameter of 0.5–3.0 cm. The results obtained can be used to design an untriggered repetitive germicidal lamp emitting in the Cl₂(257/200 nm) and ArCl (175 nm) molecular bands and to develop plasmachemical methods for depositing amorphous fluorocarbon and chlorocarbon films.     

Production of C 2 * radicals in a transverse volume discharge

Conditions for producing stable transverse volume discharges in freon-containing media (CCl₄/air mixtures at a pressure of P=0.1?2 kPa) are studied. It is shown that a transverse discharge produced in the CCl₄/air=(1–2)/0.03 kPa mixture at a moderate discharge voltage (U _ch=8–15 kV) and an interelectrode distance of d=2.2 cm is a selective source of C₂(d ³Π_g-a ³Π_u) 468.0-and 516.5-nm radiation and C(2p-3s) 247.9-nm radiation. The brightness of the C₂(d-a) band is comparable with that of the N₂(C-B) 337.1-and 357-nm bands. The transverse discharge in CCl₄ is of interest for generating pulsed emission via the d-a transitions of C₂ molecules in the blue-green region of the visible spectrum.     

High-frequency underwater plasma discharge application in antibacterial activity

Plasma discharge is a novel disinfection and effectual inactivation approach to treat microorganisms in aqueous systems. Inactivation of Gram-negative Escherichia coli (E. coli) by generating high-frequency, high-voltage, oxygen (O₂) injected and hydrogen peroxide (H₂O₂) added discharge in water was achieved. The effect of H₂O₂ dose and oxygen injection rate on electrical characteristics of discharge and E. coli disinfection has been reported. Microbial log reduction dependent on H₂O₂ addition with O₂ injection was observed. The time variation of the inactivation efficiency quantified by the log reduction of the initial E. coli population on the basis of optical density measurement was reported. The analysis of emission spectrum recorded after discharge occurrence illustrated the formation of oxidant species (OH^?, H, and O). Interestingly, the results demonstrated that O₂ injected and H₂O₂ added, underwater plasma discharge had fabulous impact on the E. coli sterilization. The oxygen injection notably reduced the voltage needed for generating breakdown in flowing water and escalated the power of discharge pulses. No impact of hydrogen peroxide addition on breakdown voltage was observed. A significant role of oxidant species in bacterial inactivation also has been identified. Furthermore the E. coli survivability in plasma treated water with oxygen injection and hydrogen peroxide addition drastically reduced to zero. The time course study also showed that the retardant effect on E. coli colony multiplication in plasma treated water was favorable, observed after long time. High-frequency underwater plasma discharge based biological applications is technically relevant and would act as baseline data for the development of novel antibacterial processing strategies.     

Production of singlet oxygen in a non-self-sustained discharge

The production of O₂(a¹Δ_g) singlet oxygen in non-self-sustained discharges in pure oxygen and mixtures of oxygen with noble gases (Ar or He) was studied experimentally. It is shown that the energy efficiency of O₂(a¹Δ_g production can be optimized with respect to the reduced electric field E/N. It is shown that the optimal E/N values correspond to electron temperatures of 1.2–1.4 eV. At these E/N values, a decrease in the oxygen percentage in the mixture leads to an increase in the excitation rate of singlet oxygen because of the increase in the specific energy deposition per O₂ molecule. The onset of discharge instabilities not only greatly reduces the energy efficiency of singlet oxygen production but also makes it impossible to achieve high energy deposition in a non-self-sustained discharge. A model of a non-self-sustained discharge in pure oxygen is developed. It is shown that good agreement between the experimental and computed results for a discharge in oxygen over a wide range of reduced electric fields can be achieved only by taking into account the ion component of the discharge current. The cross section for the electron-impact excitation of O₂(a¹Δ_g and the kinetic scheme of the discharge processes with the participation of singlet oxygen are verified by comparing the experimental and computed data on the energy efficiency of the production of O₂(a¹Δ_g and the dynamics of its concentration. It is shown that, in the dynamics of O₂(a¹Δ_g molecules in the discharge afterglow, an important role is played by their deexcitation in a three-body reaction with the participation of O(³P) atoms. At high energy depositions in a non-self-sustained discharge, this reaction can reduce the maximal attainable concentration of singlet oxygen. The effect of a hydrogen additive to an Ar: O₂ mixture is analyzed based on the results obtained using the model developed. It is shown that, for actual electron beam current densities, a significant energy deposition in a non-self-sustained discharge in the mixtures under study can be achieved due to the high rate of electron detachment from negative ions. In this case, however, significant heating of the mixture can lead to a rapid quenching of O₂(a¹Δ_g molecules by atomic hydrogen.     

Cleaning of inner vacuum surfaces in the Uragan-3M facility by radio-frequency discharges

A method for cleaning vacuum surfaces by a low-temperature (T _e ～ 10 eV) relatively dense (n _e ≈ 10¹² cm^?3) plasma of an RF discharge was developed and successfully applied at the Uragan-3M torsatron. The convenience of the method is that it can be implemented with the same antenna system and RF generators that are used to produce and heat the plasma in the operating mode and does not require retuning the frequencies of the antennas and RF generators. The RF discharge has a high efficiency from the standpoint of cleaning vacuum surfaces. After performing a series of cleanings by the low-temperature RF discharge plasma (about 20000 pulses), (i) the intensity of the CIII impurity line was substantially reduced, (ii) a quasi-steady operating mode with a duration of up to 50 ms, a plasma density of n _e ≈ 10¹² cm^?3, and an electron temperature of up to T _e ～ 1 keV was achieved, and (iii) mass spectrometric analysis of the residual gas in the chamber indicated a significant reduction in the impurity content.     

Space-charge-limited current in a plane vacuum diode discharged by an electron current pulse

An unsteady discharge of a relativistic vacuum diode is studied analytically. The amplitude and rise time of the discharge current pulse are determined as functions of the input parameters of the problem. It is found that, in a nonrelativistic limit, the maximum attainable amplitude of the discharge current pulse is equal to J_Alim = 9/4J_CL, where J_CL is the vacuum-diode limiting current prescribed by the 3/2 law. The parameters of the dipole moment of the layer formed above the grid anode are found in the nonrelativistic limit.     

Low-pressure glow discharge in a Xenon/Chlorine mixture

The spatial, electrical, and optical characteristics of a transverse glow discharge and a volume discharge with a spherical anode and plane cathode in low-pressure Xe/Cl₂ mixtures are studied. It is shown that the transverse glow discharge in mixtures with a low chlorine content occupies most of the interelectrode gap and exists in the form of strata. As the total pressure (P≥300 Pa) and the partial chlorine pressure (P(Cl₂)≥80 Pa) increase, a solitary plasma domain with a volume of 1–2 cm³ forms in the discharge gap. It acts as a selective source of UV radiation in the XeCl(D-X) 236-nm, Cl₂ (D′-A′) 257-nm, and XeCl(B-X) 308-nm bands. In certain Xe/Cl₂ mixtures, plasma self-oscillations in the frequency range 1–100 kHz are observed. The current of a low-pressure volume discharge with a spherical anode and plane cathode and the emission from it have both a dc and an ac component. The pressure and composition of the working mixture, as well as the average current of the volume discharge are optimized to attain the maximum emission intensity of the XeCl(D,B-X) bands. Low-pressure volume discharges in xenon/chlorine mixtures can be used as active media in low-pressure large-aperture planar or cylindrical excimer-halogen lamps emitting modulated or repetitive pulsed UV radiation.     

Preparation of carbonitride films in the active and afterglow phases of a glow discharge

The formation of carbonitride (C _x N _y ) films in the active and afterglow phases of a glow discharge in CH₄-N₂ mixtures (as well in these mixtures diluted with argon and helium) was studied experimentally. The dependences of the film growth rate on the discharge current and gas pressure are obtained. The composition (the N/C ratio) and IR absorption spectra of the films are determined. Measurements of the absorption spectra made it possible to identify bonds between C and N atoms. A novel method of carbonitride film deposition in the “double afterglow” mode was proposed. The use of this method appreciably increases the film deposition rate. Possible mechanisms of the formation and destruction of carbonitride films in the active and afterglow phases of the discharge are discussed.     

Analysis of cylindrical Langmuir probe using experiment and different theories

Cylindrical probe data have been analyzed using different theories in order to determine some plasma parameters (electron temperature and electron and ion densities). Langmuir probe data are obtained in a cylindrical DC glow discharge in the positive column plasma at argon gas pressures varied from 0.5 to 6 Torr and at constant discharge current equal to 10 mA. The electron density has calculated from the electron current at the space potential and from Orbital Motion Limited (OML) collisionless theory. Ion density has obtained from the OML analysis of the ion saturation currents. In addition, the electron temperature has measured by three different methods using probe and electrons currents. The electron temperature T _e , plasma density n _e , and space potential V _s , have been obtained from the measured single cylindrical probe I–V characteristic curves. The radial distribution of the electron temperature and plasma density along the glow discharge are measured and discussed. Using the collisionless theories by Langmuir cylindrical probe and up to several Torr argon gas pressures the differences between the values of electron temperature and electron and ion densities stay within reasonable error limits.     

Investigation of the electron energy distribution function in hollow-cathode glow discharges in nitrogen and oxygen

The mechanism for the formation of the inverse electron distribution function is proposed and realized experimentally in a nitrogen plasma of a hollow-cathode glow discharge. It is shown theoretically and experimentally that, for a broad range of the parameters of an N₂ discharge, it is possible to form a significant dip in the profile of the electron distribution function in the energy range ε=2–4 eV and, accordingly, to produce the inverse distribution with df(ε)/d?>0. The formation of a dip is associated with both the vibrational excitation of N₂ molecules and the characteristic features of a hollow-cathode glow discharge. In such a discharge, the applied voltage drops preferentially across a narrow cathode sheath. In the main discharge region, the electric field E is weak (E<0.1 V/cm at a pressure of about p～0.1 torr) and does not heat the discharge plasma. The gas is ionized and the ionization-produced electrons are heated by a beam of fast electrons (with an energy of about 400 eV) emitted from the cathode. A high-energy electron beam plays an important role in the formation of a dip in the profile of the electron distribution function in the energy range in which the cross section for the vibrational excitation of nitrogen molecules is maximum. A plasma with an inverted electron distribution function can be used to create a population inversion in which more impurity molecules and atoms will exist in electronically excited states.     

Gas-dynamics of the propagation of a microwave discharge excited by the H 10 waveguide mode

A two-dimensional gas-dynamic model is applied to calculate the characteristics of the steady-state propagation of a microwave discharge excited by the H ₁₀ waveguide mode. The stream pattern is found on the basis of gas dynamics of a slowly propagating discharge, taking into account the non-one-dimensional character of the gas flow ahead of the discharge front. The calculated values of the propagation velocity agree with the experimental results.     

Production of XeI(<Emphasis Type="Italic">B</Emphasis>) and I<Subscript>2</Subscript>(<Emphasis Type="Italic">B</Emphasis>) molecules in the plasma of a steady electric discharge in Xe/I<Subscript>2</Subscript> mixtures

The production of excited xenon iodides and iodine dimers in the plasma of a longitudinal dc glow discharge is investigated. The discharge was ignited in iodine vapor and Xe/I₂ mixtures at xenon pressures of P(Xe)=0.1–1.5 kPa and deposited powers of 10–100 W. The current-voltage characteristics of a glow discharge, the plasma emission spectra in the spectral range of 200–650 nm, and the intensities of spectral lines and molecular bands are studied as functions of the deposited power and the xenon partial pressure in a Xe/I₂ mixture. It is found that the discharge plasma emits within the spectral range of 206–343 nm, which includes the 206-nm resonant line of atomic iodine and the XeI(B-X) 253-nm and I₂(B-X) 343-nm molecular bands. The power deposited in the plasma and the xenon pressure P(Xe) are optimized to achieve the maximum UV emission intensity. The 7-W total UV power emitted from the entire surface of the cylindrical discharge tube is achieved with an efficiency of ≤5%.     

Study of the azimuthal magnetic fields and scaling laws at the KPF-4-Phoenix facility

Results are presented from magnetic probe measurements in the pinching region formed during the compression of the plasma current sheath (PCS) in a discharge in deuterium at the KPF-4-Phoenix plasma focus facility. The fine structure (shock front-magnetic piston) of the PCS and its time evolution in the course of plasma compression toward the facility axis was studied by means of magnetic probes. It is shown that the fraction of the current transported into the axial region by the PCS does not exceed 65% of the total discharge current. The integral neutron yield Y _n is well described by the formula Y _n ≈ (1.5–3) × 10¹⁰ I _p ⁴ , where I _p (in MA) is the pinch current flowing in the region r ≤ 22 mm.     

Influence of a Nitrogen Admixture on the Anomalous Memory Effect in the Breakdown of Low-Pressure Argon in a Long Discharge Tube

The memory effect (the dependence of the dynamic breakdown voltage U _b on the time interval τ between voltage pulses) in pulse-periodic discharges in pure argon and the Ar + 1%N₂ mixture was studied experimentally. The discharge was ignited in a 2.8-cm-diameter tube with an interelectrode distance of 75 cm. The measurements were performed at gas pressures of P = 1, 2, and 5 Torr and discharge currents in a steady stage of the discharge of I = 20 and 56 mA. Breakdown was produced by applying positive-polarity voltage pulses, the time interval between pulses being in the range of τ = 0.5–40 ms. In this range of τ values, a local maximum (the anomalous memory effect) was observed in the dependence U _b (τ). It is shown that addition of nitrogen to argon substantially narrows the range of τ values at which this effect takes place. To analyze the measurement results, the plasma parameters in a steady-state discharge (in both pure argon and the Ar + 1%N₂ mixture) and its afterglow were calculated for the given experimental conditions. Analysis of the experimental data shows that the influence of the nitrogen admixture on the shape of the dependence U _b (τ) is, to a large extent, caused by the change in the decay rate of the argon afterglow plasma in the presence of a nitrogen admixture.     

Optical characteristics of the plasma of a glow discharge in a He/H2O mixture

The emission from the plasma of a steady-state electric discharge in a He/H₂O mixture in the wavelength range 130–670 nm is investigated. It is shown that, at a water vapor partial pressure of P=2.0–2.5 kPa, the discharge mainly emits within the range 306–315 nm. The emission consists of an OH (A-X; 0-0) 307.4-nm narrow peak and a broad band with a maximum at λ_max=309.1 nm. As the partial pressure of water vapor decreases to 50–150 Pa, VUV emission at wavelengths of λ=186, 180, and 157 nm becomes dominant. In the visible region, H_α 656.3-nm and H_β 486.1-nm spectral lines and HeI lines in the range 447.1–667.8 nm, which are of interest for diagnosing the plasma, prevail. The intensities of the main bands and spectral lines are determined as functions of the helium partial pressure and discharge current.