Subwavelength Focusing Using Plasmonic Wavelength-Launched Zone Plate Lenses

We propose a plasmonic wavelength-launched Fresnel zone plate structure for subwavelength focusing. The plasmonic structure consists of a central circular groove surrounded by 12 transparent and opaque zones. All the zones with widths smaller than one half of the incident wavelength are used to enhance the field of evanescent waves in the transmission. Based on the finite-difference time-domain analysis, a focus spot with a full-width at half-maximum of 270 nm (= 0.4λ _in ) can be achieved, accompanied by a largely reduced depolarization effect. The sharp waistline indicates that the surface waves are largely converged in the region of focus.     

Experimental Study of Metallic Elliptical Nano-Pinhole Structure-Based Plasmonic Lenses

An elliptical nano-pinhole structure-based plasmonic lens was designed and investigated experimentally by means of focused ion beam nanofabrication, atomic force microscope imaging, and scanning near-field optical microscope (NSOM). Two scan modes, tip scan and sample scan, were employed, respectively, in our NSOM measurements. Both the scan modes have their characteristics while probing the plasmonic lenses. Our experimental results demonstrated that the lens can realize subwavelength focusing with elongated depth of focus. This type of lens can be used in micro-systems such as micro-opto-electrical–mechanical systems for biosensing, subwavelength imaging, and data storage.     

Investigation of the Plasmonic Interaction of Gold Nanoparticles Toward Plasmonic Photothermal Therapeutics

Plasmonic interaction of nanoparticles located in close proximity, embedded in breast tissue, is simulated for estimating the optical characteristics like optical absorption cross-section, plasmonic wavelength as well as full-width half maxima (FWHM). The computations are done for the monomers, homodimers, and heterodimers of spherical and rod-shaped gold nanoparticles considering various interparticle spacings for gold nanospheres and the interparticle spacing as well as the orientation for gold nanorods (GNRs). The results indicate that for the spherical dimer, with the change in interparticle spacing from 1 to 20 nm, the peak absorption cross-section decreases by 43%. Whereas for the GNRs, the absorption cross-section increases/decreases, within 9–18%, depending on the homodimer or heterodimer configuration. Furthermore, secondary peaks for the absorption cross-section are obtained within wavelengths of 630–940 nm due to antibonding modes for GNR heterodimers. For GNR heterodimer located end-to-end, this secondary peak for the absorption cross-section appears at 780 nm irrespective of interparticle spacing within 1–5 nm. The absorption coefficient is considerably dependent on the configuration and proximity of GNRs located within the tissue. While FWHM is not significantly influenced by GNRs configuration and interparticle spacing. For interparticle spacing from 1 to 20 nm, the plasmonic wavelength shifts by 38 nm for the spherical dimer and by 35–86 nm for various GNR dimers. The findings of this study are useful for plasmonic photothermal therapeutics as the heat generation is governed by the resulting absorption cross-section due to plasmonic coupling of the closely spaced and different orientations of the nanoparticles.

     

Plasmonic Focusing in Nanostructures

In this review, we show that by designing the metallic nanostructures, the surface plasmon (SP) focusing has been achieved, with the focusing spot at a subwavelength scale. The central idea is based on the principle of optical interference that the constructive superposition of SPs with phase matching can result in a considerable electric-field enhancement of SPs in the near field, exhibiting a pronounced focusing spot. We first reviewed several new designs for surface plasmon focusing by controlling the metallic geometry or incident light polarization: We made an in-plane plasmonic Fresnel zone plates, a counterpart in optics, which produces an obvious SP focusing effect; We also fabricated the symmetry broken nanocorrals which can provide the spatial phase difference for SPs, and then we propose another plasmon focusing approach by using semicircular nanoslits, which gives rise to the phase difference through changing refractive index of the medium in the nanoslits. Further, we showed that the spiral metallic nanostructure can be severed as plasmonic lens to control the plasmon focusing under a linearly polarized light with different angles.

     

Experimental Study of Indirect Phase Tuning-Based Plasmonic Structures for Finely Focusing

Three types of indirect phase tuning-based plasmonic structures with subwavelength circular grooves/slits and/or central apertures corrugated on Au film supported by glass substrate: depth modulation, width modulation, and hybrid depth-width modulation, were put forth in this paper. They were investigated experimentally by means of nanofabrication and near-filed scanning optical microscope characterization. The plasmonic structures were fabricated using the technique of focused ion beam direct milling. Our experimental results demonstrated that all of the phase tuning-based structures have focusing functions. Both the width and depth modulation-based structures can realize beam focusing and produce an elongated depth of focus. Moreover, after comparison among these three structures, we found that the width modulation-based structure has the best focusing performance.     

Far-Field Focusing of Spiral Plasmonic Lens

In this paper, we study the nanoscale-focusing effect in the far field for a spiral plasmonic lens with a concentric annular groove by using finite-difference time domain simulation. The simulation result demonstrates that a left-hand spiral plasmonic lens can concentrate an incident right-hand circular polarization light into a focal spot at the exit surface. And this spot can be focused into far field due to constructive interference of the scattered light by the annular groove. The focal length and the focal depth can be adjusted by changing the groove radius and number of grooves within a certain range. These properties make it possible to probe the signal of spiral plasmonic lens in far field by using conventional optical devices.     

Plasmonic Properties of Gold Nanostructures on Gold Film

This paper reports on a systematic study of the plasmonic properties of periodic arrays of gold cylindrical nanoparticles in contact with a gold thin film. Depending on the gold film thickness, it observes several plasmon bands. Using a simple analytical model, it is able to assign all these modes and determine that they are due to the coupling of the grating diffraction orders with the propagating surface plasmons travelling along the film. With finite difference time domain (FDTD) simulations, it demonstrates that large field enhancement occurs at the surface of the nanocylinders due to the resonant excitation of these modes. By tilting the sample, it also observes the evolution of the spectral position of these modes and their tuning through nearly the whole visible range is possible. Such plasmonic substrates combining both advantages of the propagative and localised surface plasmons could have large applications in enhanced spectroscopies.

     

Curved Gratings as Plasmonic Lenses for Linearly Polarised Light

The ability of curved gratings as sectors of concentric circular gratings to couple linearly polarised light into focused surface plasmons is investigated by theory, simulation, and experiment. The experimental and simulation results show that increasing the sector angle of the curved gratings decreases the width of the lateral distribution of surface plasmons resulting in focusing of surface plasmons, which is analogous to the behaviour of classical optical lenses. We also show that two faced curved gratings, with their groove radius mismatched by half of the plasmon wavelength (asymmetric configuration), can couple linearly polarised light into a single focal spot of concentrated surface plasmons with smaller depth of focus and higher intensity in comparison to single curved gratings. The major advantage of these structures is the coupling of linearly polarised light into focused surface plasmons with access to, and control of, the plasmon focal spot, which facilitate their potential applications in sensing, detection, and nonlinear plasmonics.     

Polarization Dependent of Plasmonic Lenses with Variant Periods on Superfocusing

A plasmonic lens with variant periods was investigated for optical behavior at near-field by means of numerical computational method. To study influence of incident light on different polarization modes, we considered linear polarization, circular polarization, elliptical polarization, radial polarization (RP), and azimuthally polarization in our computational analyses. A finite difference and time domain algorithm is employed in the numerical study. Our computational numerical calculation results demonstrate that focusing performance for the plasmonic lens illuminated under radial polarization is best in comparison to that of the illumination with the other four polarization states. The plasmonic lens with RP illumination can realize superfocusing with ultra-long depth of focus. It is possible to be used as an optical probe or a type of plasmonic lens for imaging with high resolution in the near future.     

Plasmonic Planar Lens Based on Slanted Nanoslit Array

The novel plasmonic lenses based on slanted nanoslits have been proposed theoretically. The slanted nanoslits with different slant angles can provide unequal propagation distances for the surface plasmon polaritons excited by incident light. The phase retardation for wavefront shaping can be obtained to realize constructive interference on a preset single spot. We can actively modulate the position of the optical focus by adjusting the slits slant angles properly. The simulation results of the finite element method are used to verify our proposals.     

Near-Field Optical Experimental Investigation of Gold Nanohole Array

Gold nanohole arrays are fabricated with focused ion beam irradiating gold thin film supported on quartz substrate. The topography of the nanohole arrays is characterized using an atomic force microscope, and the near-field optical transmission properties of the nanohole array are investigated with a near-field scanning optical microscope. Our experimental results verify the near-optical transmission performance and further demonstrate that they are in agreement with the theoretical calculation results. The enhanced optical transmission of the nanohole arrays are expected to be used for a variety of applications in sensor and photonics devices.     

Optimal Dimensions of Gold Nanorod for Plasmonic Nanosensors

Localized surface plasmon resonance (LSPR) for longitudinal mode of gold nanorod is simulated by using Gans theory. The parameters like surface scattering, radiation damping, and dynamic depolarization of radiation across the surface of nanorod affecting response of free electrons towards optical excitation are considered. Simulation results show that refractive index sensitivity linearly rises with size and aspect ratio, whereas this leads to the broadening of resonant line width also. Therefore, to optimize the size of nanorod, figure of merit (FOM) is calculated and observed that optimized width is 15 nm for an aspect ratio of 2, whereas it is 12 nm for aspect ratios 3 and 4. Further, optimization by using newly modified figure of merit (MFOM) shows that optimized width is 39 nm for aspect ratio of 2 and 24 nm for 3 and 4 aspect ratios. It is also found that at aspect ratio 2, both FOM and MFOM are higher than the aspect ratios 3 and 4. The quality factor calculation for LSPR response of nanorod explains its dependence with aspect ratio and optimized dimensions.     

Plasmonic Fano Resonances in Single-Layer Gold Conical Nanoshells

Plasmonic Fano resonances arise in symmetric single-layer conical nanoshells, which can be switched on and off by changing the polarization of the incident electric field. By breaking the symmetry, higher-order dark hybridized modes emerge in the spectrum, which couple to the superradiant bright mode and induce higher-order plasmonic Fano resonances. From a comparison with spherical nanostructures, it comes out that single-layer conical nanoshells are found to be highly capable in the generation of higher-order Fano resonances with larger modulation depths in the optical spectra. Such nanostructures are also found to offer high values of figure of merit and contrast ratio due to which they are highly suitable for biological sensors.     

Gold Nanoring Arrays for Near Infrared Plasmonic Biosensing

Gold nanoring array surfaces that exhibit strong localized surface plasmon resonances (LSPR) at near infrared (NIR) wavelengths from 1.1 to 1.6 μm were used as highly sensitive real-time refractive index biosensors. Arrays of gold nanorings with tunable diameter, width, and spacing were created by the nanoscale electrodeposition of gold nanorings onto lithographically patterned nanohole array conductive surfaces over large areas (square centimeters). The bulk refractive index sensitivity of the gold nanoring arrays was determined to be up to 3,780 cm⁻¹/refractive index unit by monitoring shifts in the LSPR peak by FT-NIR transmittance spectroscopy measurements. As a first application, the surface polymerization reaction of dopamine to form polydopamine thin films on the nanoring sensor surface from aqueous solution was monitored with the real-time LSPR peak shift measurements. To demonstrate the utility of the gold nanoring arrays for LSPR biosensing, the hybridization adsorption of DNA-functionalized gold nanoparticles onto complementary DNA-functionalized gold nanoring arrays was monitored. The adsorption of DNA-modified gold nanoparticles onto nanoring arrays modified with mixed DNA monolayers that contained only 0.5 % complementary DNA was also detected; this relative surface coverage corresponds to the detection of DNA by hybridization adsorption from a 50 pM solution.

     

Tuning Plasmonic Properties of Truncated Gold Nanospheres by Coating

The influence of TiO₂ coating on resonant properties of gold nanoisland films deposited on silica substrates was studied numerically and in experiments. The model describing plasmonic properties of a metal truncated nanosphere placed on a substrate and covered by a thin dielectric layer has been developed. The model allows calculating a particle polarizability spectrum and, respectively, its surface plasmon resonance (SPR) wavelength for any given cover thickness, particle radius and truncation parameter, and dielectric functions of the particle, the substrate, the coating layer, and the surrounding medium. Dependence of the SPR position calculated for truncated gold nanospheres has coincided with the measured one for the gold nanoisland films covered with titania of different thicknesses. In the experiments, gold films with thickness of 5 nm were deposited on a silica glass substrate, annealed at 500 °C to form nanoislands of 20 nm in diameter, and covered with amorphous titania layers using atomic layer deposition technique. The resulting structures were characterized with scanning electron microscopy and optical absorption spectroscopy. The measured dependence of the SPR position on titania film thickness corresponded to the one calculated for truncated sphere-shaped nanoparticles with the truncation angle of ~50°. We demonstrated the possibility of tuning the SPR position within ~100 nm range by depositing to 30 nm thick titania layer.

     

Theoretical Study of a Planar Structure Plasmonic Nanolaser in Visible Regime

The potential of a plasmonic nanolaser using semiconductor gain to compensate the metal loss was investigated theoretically in multilayer planar structure geometry. The propagation constant of surface plasmon (SP) mode, Purcell factor, and modal gain were calculated via transfer matrix method. Near SP resonance, the Purcell factor shows sensitive frequency dependence and exponential decay with distance. The huge Purcell factor leads to an impractical current density about several hundreds kiloampere/square centimeter (kA/cm²). When the spectra peak of optical gain in a semiconductor is shifted about 0.7 eV below SP resonance, the moderate Purcell factor shows a rather broadband enhancement. Net modal gain was achieved at an injected current density of 12.1 kA/cm², comparable to that of conventional photonic laser diodes. The structure is further optimized by inserting a (low permittivity) dielectric spacer between the semiconductor active region and metal.

     

Multiple-Wavelength Focusing and Demultiplexing Plasmonic Lens Based on Asymmetric Nanoslit Arrays

A multiple-wavelength focusing and demultiplexing plasmonic lens based on asymmetric nanoslit arrays is designed. The nanoslit arrays are perforated in a gold film and act as metal–insulator–metal plasmonic waveguides. By manipulating the widths of the slit arrays, the plasmonic lens can concentrate two incident plane wave beams to two separated focal points corresponding to their wavelengths. The full wave simulation is performed to verify the designed lens. This work provides a way to design more compact and integrated wavelength-division multiplexing plasmonic devices for nanophotonic communication and spectral imaging.     

Orientation Effects on Plasmonic Heating of Near-Infrared Colloidal Gold Nanostructures

Plasmonics - Photothermal therapy assisted by plasmonic nanostructure relies on the absorption of light energy by the metallic nanoparticle. The manifestation of a rational use of...     

Features of the Secondary Emission Enhancement Near Plasmonic Gold Film

Plasmonic gold films (PGF) prepared by vacuum deposition of gold onto quartz slides possess unique property to enhance electromagnetic signal in the near field. Spectral tuning of PGF’s plasmon band to resonance with the electronic spectra of adsorbed molecules provides selective enhancement of fluorescence or surface-enhanced Raman scattering in the far field. Plasmon-enhanced fluorescence (PEF) of mitoxantrone (mitox) as a function of the distance between gold surface and adsorbed molecules for different polarization and incidence angle of exciting light is analyzed in this work. Spectrophotometric data reveal that probability of localized plasmon excitation in gold grains increases with growth of incidence angle for s-polarized and decrease for p-polarized excitation. This fact correlates well with oblate shape of gold particles detected by Atomic force microscope. However, the fluorescence intensity of dyes deposited at fixed distance from gold surface increase with angle of incidence of p-polarized light more noticeably than for s-polarized one. Nevertheless, the behavior of mitox PEF signal upon p-polarized laser excitation and different angle of incidence are similar in appearance to such phenomenon as selective photoelectric effect. According to this observation, the near-field interactions between plasmons and molecule as possible mechanism of PEF is discussed.