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1.
In our chemotaxonomic investigation of pharmaceutically relevant Crataegus species, the qualitative and quantitative flavonoid fingerprint of Crataegus monogyna and C. pentagyna is presented. Six flavonoids were identified as vitexin-2'-O-rhamnoside (1), vitexin (2), isovitexin (3), rutin (4), hyperoside (5), and isoquercitrin (6). Besides the verification of the main compounds isoorientin (7) and orientin (8) in C. pentagyna, further four flavonoids were isolated and identified as isoorientin-2'-O-rhamnoside (9), orientin-2'-O-rhamnoside (10), isovitexin-2'-O-rhamnoside (11), and 8-methoxykaempferol-3-O-glucoside (12) by means of 1D- and 2D-NMR, MS, and UV analyses. Compound 12 was isolated for the first time from C. pentagyna. In contrast to C. pentagyna, C. monogyna samples were predominated by 4'-acetylvitexin-2'-O-rhamnoside (13), which was missing in C. pentagyna. Hence, 13 represents an interesting compound for chemotaxonomy of C. monogyna, whereas the main flavonoids 7, 8, and 12 could be proposed as markers for C. pentagyna. The absence of 7, 8, 12, and 13 in C. laevigata offers an appropriate tool for additional differentiation from C. monogyna and C. pentagyna, and for sample identification and quality control of the three main Crataegus species used in European phytotherapy. 相似文献
2.
AL A. DÖNMEZ 《Botanical journal of the Linnean Society. Linnean Society of London》2007,155(2):231-240
The Turkish Crataegus taxa were investigated using morphological, palynological, and anatomical characters. A new series ( Crataegus Section Crataegus Series Peshmenia ), two new species ( Crataegus peshmenii and Crataegus christensenii ), and one variety ( Crataegus rhipidophylla var. kutahyaensis ) are described. Furthermore, Crataegus × browicziana has been assigned to Crataegus rhipidophylla with a new status. Illustrations of the described taxa and their distribution map are also given. The lectotype for Crataegus yaltirikii is designated here. © 2007 The Linnean Society of London, Botanical Journal of the Linnean Society , 2007, 155 , 231–240. 相似文献
3.
The phytochemical investigations on the leaves of Crataegus pinnatifida led to the isolation of 20 compounds, including seven triterpenoids (1-7), three hydroxycinnamic acids (8-10), three lignans (11-13) and seven flavonoids (14-20). All chemical structures were established on the basis of NMR (1H NMR, 13C NMR) spectroscopic data. Meanwhile, compounds 3-12 are reported for the first time from Crataegus genus. In addition, compounds 10-11 are isolated from the family Rosaceae for the first time. On the basis of chemical research, the chemotaxonomic significance of the isolated compounds has been discussed. 相似文献
4.
In connection with systematic study of European taxa of Crataegus (Rosaceae subfam. Maloideae) lectotypes are designated for Crataegus monogyna f. subdigyna and C. monogyna var. ronnigeri. C. microphylla subsp. malýana is described as a taxon new to science and a key to the recognised taxa of C. microphylla and of the closely related C. rhipidophylla is given. 相似文献
5.
Knud IB Christensen 《Nordic Journal of Botany》1983,2(6):537-548
Crataegus curvisepala Lindm., C. laevigata (Poiret) DC. and C. monogyna Jacq. (Rosaceae) form hybrid complexes in Denmark due to introgression. C. palmstruchii Lindm. seems to be variously introgressed individuals of C. laevigata. C. eremitagensis Raunk., C. raavadensis Raunk. and C. schumacheri Raunk. apparently belong to C. curvisepala x laevigata. The delimitation between C. curvisepala x laevigata and C. laevigata x monogyna is discussed. 相似文献
6.
β-eudesmol (1), cryptomeridiol (2), ilicic acid (3), 5,7-dihydroxyflavone (chrysin, 4) and 7-O-methyl-chrysin (tectochrysin, 5) were isolated as the major constituents from the acetone extract of the aerial parts of Flourensia resinosa S.F. Blake (Asteraceae), along with flourensiadiol (6), spathulenol (7), p-acetophenol (8), lupeol (9), β-sitosterol (10), triacontanol (11) and squalene (12). Based on previous studies, this chemical composition for F. resinosa is in accordance with the chemical profile of other species of Flourensia. The profile of flavonoids, sesquiterpenes and benzofurans may have chemotaxonomic significance within this genus. 相似文献
7.
This review summarizes the flavonoids isolated from three genera, namely, Aconitum, Delphinium, and Consolida, belonging to tribe Delphineae in the Ranunculaceae family for the first time. A total of 104 distinct flavonoid components, including 85 flavonols, 13 anthocyanins, four flavones, and two neoflavones, have been isolated from 44 members of tribe Delphineae. Flavonols account for the largest proportion and can be regarded as the dominant group of flavonoids in this tribe. Of the 104 isolated flavonoids, 55 are novel, indicating the high chemical diversity among the flavonoid constituents of Delphineae plants. Flavonoids in Delphineae plants exhibit chemotaxonomic significance, characterizing certain Delphineae species well. Flavonol glycosides, as the major flavonoid constituents in the investigated Delphineae species, could also serve as valuable chemotaxonomic markers in addition to diterpenoid alkaloids for the identification of Delphineae species. 相似文献
8.
A new apotirucallane-type triterpenoid, 3α-benzoate triterpenoid A (1), along with six known triterpenoids (2–7), one aromatic ester (8) and eight lignans (9–16), were isolated from the fruits of Melia azedarach Linn. The structure of 1 was determined by spectral analyses, including HR-ESI-MS, 1D NMR (1H NMR and 13C NMR) and 2D NMR (HSQC and HMBC) analyses. 10, 11 and 16 were reported for the first time from the family Meliaceae, 8 was identified from the genus Melia for the first time, and 2, 3, 5, 7, 9 and 12–15 were obtained from M. azedarach for the first time. The chemotaxonomic significance of these compounds is discussed. 相似文献
9.
JEAN I. BY ATT F.L.S. 《Botanical journal of the Linnean Society. Linnean Society of London》1974,69(1):15-21
Authentic herbarium material of Crataegus calycina Petermann (1849) supports Hrabetová-Uhrová's contention in 1969 that this is conspecific with C. macrocarpa Hegetschweiler; the name C. calycina , for which a Petermann specimen in Musée Botanique Cantonal, Lausanne is designated as lectotype, had been incorrectly applied in Flora Europaea.
Examination of the specimens in the Linnaean Herbarium has led to acceptance of Dandy's proposal in 1946 that sheet 643.12 should be designated as the lectotype of C. oxyacantha L. (1753). This specimen is not, as frequently assumed, C. laevigata (Poiret) DC. (C oxyacanthoides Thuill.) but the species described in Flora Europaea as "C. calycina Peterm. subsp. curvisepala (Lindman) Franco". It is suggested that the name C. oxyacantha L. is a source of confusion and should be rejected under Article 69 of the International Code of Botanical Nomenclature. This gives priority to the name C. curvisepala Lindman, which should replace C. calycina Peterm. in Flora Europaea. 相似文献
Examination of the specimens in the Linnaean Herbarium has led to acceptance of Dandy's proposal in 1946 that sheet 643.12 should be designated as the lectotype of C. oxyacantha L. (1753). This specimen is not, as frequently assumed, C. laevigata (Poiret) DC. (C oxyacanthoides Thuill.) but the species described in Flora Europaea as "C. calycina Peterm. subsp. curvisepala (Lindman) Franco". It is suggested that the name C. oxyacantha L. is a source of confusion and should be rejected under Article 69 of the International Code of Botanical Nomenclature. This gives priority to the name C. curvisepala Lindman, which should replace C. calycina Peterm. in Flora Europaea. 相似文献
10.
Fourteen compounds were isolated from Cremanthodium brunneo-pilosum, including two steroids (1 and 14), five sesquiterpenoids (2–6), six flavonoids (7–12) and one isoflavone (13). Graveolide (2) was obtained from a plant for the first time. 5,7-Dihydroxy-3,6,3′,4′-tetramethoxy-flavone (9), centaureidin (10) and tectoridin (13) have not been isolated from the family Compositae. The chemotaxonomic data support the relationship between this species and others in the family Compositae. 相似文献
11.
Phytochemical investigation of Murraya tetramera C. C. Huang led to the isolation of ten flavonoids (1−10) and three anthraquinones (11−13). Their structures were determined on the basis of MS, NMR, specific optical rotation, and CD spectroscopic data analysis, and by comparison of the obtained data with those reported in the literature. This is the first report for the occurrence of compounds 2, 4–7, and 11–13 in the Murraya species, and all the compounds were isolated from M. tetramera for the first time with the exception of compound 3. The chemotaxonomic significance of these compounds was also discussed. 相似文献
12.
V N Odinokov I V Galyautdinov D V Nedopekin L M Khalilov A S Shashkov V V Kachala L Dinan R Lafont 《Insect biochemistry and molecular biology》2002,32(2):161-165
Seven phytoecdysteroids have been isolated from Serratula coronata L. One of them is a new phytoecdysteroid, 3-epi-20-hydroxyecdysone. Two further ecdysteroids, 20-hydroxyecdysone 22-acetate and taxisterone, are isolated from this species for the first time in addition to the typical S. coronata ecdysteroids, 20-hydroxyecdysone, ecdysone, ajugasterone C and polypodine B. The juice squeezed from aerial parts of fresh plants of S. coronata was extracted with ethyl acetate. The ecdysteroids were isolated by a combination of chromatographic techniques (mainly HPLC) and identified by 1D and 2D (1)H and (13)C NMR experiments and mass-spectrometry. The biological activities of 3-epi-20-hydroxyecdysone (EC(50)=1.6 x 10(-7) M), taxisterone (EC(50)=9.5 x 10(-8) M) and ajugasterone C (EC(50)=6.2 x 10(-8) M) have been determined in the Drosophila melanogaster B(II) bioassay for ecdysteroid agonist activity. 相似文献
13.
The phytochemical investigation on the aerial parts of Chromolaena congesta led to the isolation of nine flavonoids, known in the literature as genkwanin (1) kumatakenin (2) acacetin (3), kaempferol 3-methyl ether (4), apigenin (5), apigenin 5,7-dimethyl ether (6), apigenin 5-methyl ether (7), luteolin (8) and kaempferol (9). The chemical structures were established on the basis of spectral evidence. All the compounds were isolated from this species for the first time. The results from the present study provide further information about the flavonoids as taxonomic marker of the genus Chromolaena, and the chemotaxonomic significance of these compounds were also summarized. 相似文献
14.
Clerodendrum infortunatum L. (syn.: Clerodendrum viscosum Vent.), a member of the Lamiaceae, yielded one undescribed jasmonic acid derivative, ten acteosides, and two flavonoids. The jasmonic acid derivative was identified as 6'-O-caffeoyl-12-glucopyranosyloxyjasmonic acid. The acteosides were identified as isoacteoside, acteoside, 2''-O-acetyl-martyonside, 3''-O-acetyl-martyonside, martynoside, brachynoside, leucosceptoside A, jionoside C, jionoside D, incanoside C. The flavonoids were identified as apigenin 7-O-glucuronide and acacetin 7-O-glucuronide. The structures of the isolated components have been identified by UHPLC-HRMS, 1D and 2D NMR spectroscopic analyses, spectrometric techniques, and in comparison with published NMR data. The absolute sugar configuration was determined by GLC-MS/MS analysis of the octylated derivative of the sugar moiety after hydrolysis. Among the known compounds, ten are reported for the first time from this species, while the acteoside leucosceptoside A and the two flavonoids have been isolated for the first time from the genus Clerodendrum. The chemophenetic significance of the compounds obtained from C. infortunatum is summarized in comparison to those found in other Clerodendrum species. 相似文献
15.
Ahumada C García D Saenz T Gómez A Cert A 《Zeitschrift für Naturforschung. C, Journal of biosciences》2001,56(11-12):1091-1094
A phytochemical study of two plant species, Viscum cruciatum Sieber and Crataegus monogyna Jacq., was completed to investigate the influence of the parasite Viscum cruciatum on the host Crataegus monogyna. The study was carried out with two samples and consisted of hexane extracts of the Viscum cruciatum parasitizing on Crataegus monogyna and C monogyna. In these samples ursolic acid, beta-sitosterol and a triterpene fraction were found that contained mainly butyrospermol (3beta-lanost 8, 24-dien, 3-ol), 24-methylene-24-dihydrolanosterol (24-methylene-5alpha-lanost-8-en-3beta-ol), cycloartenol (9beta, 19-cyclo-5alpha, 9beta-lanost-24-en-3beta-ol), beta-amyrin (olean-12-en-3beta-ol) and several aliphatic alcohols identified as the C18 to C30 members of the 1-alkanol homologous series. beta-Amyrin acetate was only isolated from Viscum cruciatum and was not found in Crataegus monogyna. 相似文献
16.
Czernaevia Turcz. is a monotypic genus in the Umbelliferae, tribe Peucedaneae,
with the only species Cz. laevigata Turcz. occurring in northern East Asia. Although the species has often been included in Angelica L., and sometimes even in Ostericum Hoffm., the
present study indicates that it is distinct not only in having dimorphic petals, but also in its
fruit structure, pollen morphology and phytochemical components. The fruit has numerous,
compressed vittae, the pollen grains are not constricted at the equatorial region with a small
P/E ratio (1.7-2.1), and neither coumarins nor flavonoids have been found to be present at
significant level in the species. It is taxonomically probably rather isolated and the monotypic genus Czernaevia is tenable. 相似文献
17.
The phytochemical investigation of Grazielia multifida aerial parts yielded eight compounds, including four ent-kaurenic acid diterpenes derivatives, 15-tiglinoyloxy-ent-kaur-16-en-19-oic acid (1), 15-hydroxy-ent-kaur-16-en-19-oic acid (2), 17-hydroxy-ent-kaur-15-en-19-oic acid (3) and 15-isovaleroyloxy-ent-kaur-16-en-19-oic acid (4), one amino acid, tryptophan (5), and three flavonoids, eupafolin (6), guaijaverin (7) and quercitrin (8). The structures of the isolated compounds were established based on analysis of their spectroscopic data and comparison with literature. All the compounds were isolated from this species for the first time. The chemotaxonomic significance of the absence of sesquiterpene lactones in G. multifida has also been summarized. 相似文献
18.
Chemical investigation of the root of Rosa laevigata led to the isolation of sixteen phenolic compounds, including seven flavonoids (1–7), five condensed tannins (8–12), two stilbenes (13 and 14) and two benzoic acid derivatives (15 and 16). Their structures were identified as (+)-catechin (1), (+)-gallocatechin (2), (2R, 3S, 4S)-cis- leucocyanidin (3), (2R, 3S, 4S)-cis-leucofisetinidin (4), (2S, 3R, 4R)-cis- leucofisetinidin (5), dehydrodicatechin A (6), phloridzin (7), procyanidin B3 (8), fisetinidol-(4α, 8)-catechin (9), guibourtinidol- (4α, 8)-catechin (10), ent- isetinidol -(4α, 6)-catechin (11), fisetinidol-(4β, 8)-catechin (12), (Z)-3-methoxy-5-hydroxy- stilbene (13), (Z)-piceid (14), gallic acid (15) and 4-hydroxybenzoic acid- 4-O-β-D-glucopyranoside (16). Among them, compounds 3–7, 9–14, and 16 were isolated from R. laevigata for the first time, and compounds 3–7, 9, 10, 12–14 and 16 were reported for the first time from the genus Rosa. The chemotaxonomic significance of these compounds was summarized. 相似文献
19.
Nine species of Ocimum (Lamiaceae) were surveyed for leaf-surface flavonoids by means of HPLC with diode array detection and atmospheric pressure chemical ionisation (APCI) mass spectrometry. The analysis revealed the presence of 23 different flavones, most of which were identified by comparing their UV and mass spectra with those of standards. Almost all taxa investigated contained flavones methoxylated in the 6- and 8-positions, such as nevadensin, xanthomicrol and gardenin B. The same taxa also produced flavones methoxylated in the 6-position but hydroxylated in the 8-position, including isothymusin (5,8,4'-trihydroxy-6,7-dimethoxyflavone), pedunculin (5,8-dihydroxy-6,7,4'-trimethoxyflavone) and a new flavone, 5,7,8-trihydroxy-6,4'-dimethoxyflavone, which was given the trivial name pilosin. This compound was isolated from O. americanum var. pilosum and also detected as a minor constituent in O. x citriodorum leaf extracts. Its molecular structure was elucidated by means of NMR spectroscopy. 8-Oxygenated flavones were absent only from O. lamiifolium. APCI mass spectrometry of the flavonoids revealed that the product ions formed by collision induced dissociation of the protonated molecule provided structural information about the substitution pattern of the A-ring. The chemotaxonomic and biogenetic implications of the results are discussed. 相似文献
20.
This paper reports chromosome numbers of ten species and one variety
of the genus Campylotropis from China (Table 1, Plate 1 ). They are C. argentea
Schindl., C. bonatiana( pamp: ) Schindl., C. henryi Schindl., C. hirtella
(Franch.)Schindl., C. macrocarpa(Bunge )Rehd., C. diversifolia( Hemsl. )Schindl.,
C. polyantha (Franch.) Schindl., C. polyantha( Franch. )Schindl. var.
leiocarpa ( Pamp. ) Pet. -Stib., c. prainii ( Coll. et Hemal. ) Schindl., C.
pinetorum (kurz)Schindl. ssp. velutina (Dunn)Schindl., c. trigonoclada(Franch. )
Schindl. The chromosome numbers of these ten species are all 2n= 22 or n= 11,
but a few individuals in C. polyantha(Franch. )Schindl. var. leiocarpa(Pamp. )Pet.
-Stib., were found aneuploid with 2n=23. The chromosome numbers of c.
polyantha and C. macrocarpa have been reported by Maw-shing (1986)andLee(1972), while those of all the other species are first reported. 相似文献