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1.
Kajsa Henryson Per-Anders Hansson Cecilia Sundberg 《The International Journal of Life Cycle Assessment》2018,23(1):70-81
Purpose
In life cycle assessment (LCA), eutrophication is commonly assessed using site-generic characterisation factors, despite being a site-dependent environmental impact. The purpose of this study was to improve the environmental relevance of marine eutrophication impact assessment in LCA, particularly regarding the impact assessment of waterborne nutrient emissions from Swedish agriculture.Methods
Characterisation factors were derived using site-dependent data on nutrient transport for all agricultural soils in Sweden, divided into 968 catchment areas, and considering the Baltic Sea, the receiving marine compartment, as both nitrogen- and phosphorus-limited. These new characterisation factors were then applied to waterborne nutrient emissions from typical grass ley and spring barley cultivation in all catchments.Results and discussion
The site-dependent marine eutrophication characterisation factors obtained for nutrient leaching from soils varied between 0.056 and 0.986 kg Neq/kg N and between 0 and 7.23 kg Neq/kg P among sites in Sweden. On applying the new characterisation factors to spring barley and grass ley cultivation at different sites in Sweden, the total marine eutrophication impact from waterborne nutrient emissions for these crops varied by up to two orders of magnitude between sites. This variation shows that site plays an important role in determining the actual impact of an emission, which means that site-dependent impact assessment could provide valuable information to life cycle assessments and increase the relevance of LCA as a tool for assessment of product-related eutrophication impacts.Conclusions
Characterisation factors for marine eutrophication impact assessment at high spatial resolution, considering both the site-dependent fate of eutrophying compounds and specific nutrient limitations in the recipient waterbody, were developed for waterborne nutrient emissions from agriculture in Sweden. Application of the characterisation factors revealed variations in calculated impacts between sites in Sweden, highlighting the importance of spatial differentiation of characterisation modelling within the scale of the impact.2.
Characterization factors for inland water eutrophication at the damage level in life cycle impact assessment 总被引:1,自引:0,他引:1
Jaap Struijs Arthur Beusen Dick de Zwart Mark Huijbregts 《The International Journal of Life Cycle Assessment》2011,16(1):59-64
Purpose
Life Cycle Impact Assessment methodology is still lacking a procedure that relates phosphorus emission to ecological damage in freshwater ecosystems. The aim of this study is to apply new insights in the characterization of aqueous eutrophication at the end-point level. Characterization factors for freshwater eutrophication in European waters caused by emissions of phosphorus to agricultural soils and freshwater were developed. The characterization factors are representative for emissions to the 101 most important European river catchments west of the Ural Mountains. 相似文献3.
Pierre-Olivier Roy Louise Deschênes Manuele Margni 《The International Journal of Life Cycle Assessment》2014,19(4):882-890
Purpose
Characterization factors (CFs) quantifying the potential impact of acidifying emissions on inland aquatic environments in life cycle assessment are typically available on a generic level. The lack of spatial differentiation may weaken the relevance of generic CFs since it was shown that regional impact categories such as aquatic acidification were influenced by the surroundings of the emission location. This paper presents a novel approach for the development of spatially differentiated CFs at a global scale for the aquatic acidification impact category.Methods
CFs were defined as the change in relative decrease of lake fish species richness due to a change in acidifying chemicals emissions. The characterization model includes the modelling steps linking emission to atmospheric acid deposition (atmospheric fate factor) change, which lead to lake H+ concentration (receiving environment fate factor) change and a decrease in relative fish species richness (effect factor). We also evaluated the significance of each factor (i.e. atmospheric fate, receiving environment fate and effects) to the overall CFs spatial variability and parameter uncertainty.Results and discussion
The highest CFs were found for emissions occurring in Canada, Scandinavia and the northern central Asia because of the extensive lake areas in these regions (lake areas being one of the parameters of the CFs; the bigger the lake areas, the higher the CFs). The CFs’ spatial variability ranged over 5, 6 and 8 orders of magnitude for NOx, SO2 and NH3 emissions, respectively. We found that the aquatic receiving environment fate factor is the dominant contributor to the overall spatial variability of the CFs, while the effect factors contributed to 98 % of the total parameter uncertainty.Conclusions
The resulting characterization model and factors enable a consistent evaluation of spatially explicit acidifying emissions impacts at the global scale. 相似文献4.
Fanny Lebailly Annie Levasseur Réjean Samson Louise Deschênes 《The International Journal of Life Cycle Assessment》2014,19(10):1745-1754
Purpose
Temporal variability is a major source of uncertainty in current life cycle assessment (LCA) practice. In this paper, the recently developed dynamic LCA approach is adapted to assess freshwater ecotoxicity impacts of metals. The objective is to provide relevant information regarding the distribution and magnitude of metal impacts over time and to show whether the dynamic approach significantly influences the conclusions of an LCA. An LCA of zinc fertilization in agriculture was therefore carried out.Methods
Dynamic LCA is based on the temporal disaggregation of the inventory, which is then assessed using time-horizon-dependent characterization factors. The USEtox multimedia fate model is used to develop time-horizon-dependent characterization factors for the freshwater ecotoxicity impact of 18 metals. Mass balance equations are solved dynamically to obtain fate factors as a function of time, providing both instantaneous (impact at time t following a pulse emission) and cumulative (total time-integrated impact following a pulse emission) characterization factors (CFs).Results and discussion
Time-horizon-dependent CFs for freshwater ecotoxicity depend on the emission compartment and the metal itself. The two variables clearly influence metal fate aspects such as the maximum mass loading reaching freshwater and the persistence time of metals into this compartment. The time needed to reach the total impact for each metal may exceed thousands of years, so the time horizon used in the analysis constitutes a determining factor. The case study reveals that the results of a classical LCA are always higher than those obtained from a dynamic LCA, especially for short time horizons. For instance, at the end of a 100-year fertilization treatment, only 25 % of the impacts obtained through traditional LCA occurred.Conclusions
Results show that dynamic LCA enables assessing freshwater ecotoxicity impacts of metals over time, allowing decision makers to test the sensitivity of their results to the choice of a time horizon. For the particular case study of zinc fertilization over a period of 20 years, the use of time-horizon-dependent CFs is more important in determining the dynamics of impacts than the timing of emission. 相似文献5.
Efthalia Chatzisymeon Spyros Foteinis Alistair G. L. Borthwick 《The International Journal of Life Cycle Assessment》2017,22(6):896-908
Purpose
As the scale of the organic cultivation sector keeps increasing, there is growing demand for reliable data on organic agriculture and its effect on the environment. Conventional agriculture uses chemical fertilizers and pesticides, whilst organic cultivation mainly relies on crop rotation and organic fertilizers. The aim of this work is to quantify and compare the environmental sustainability of typical conventional and organic pepper cultivation systems.Methods
Two open field pepper cultivations, both located in the Anthemountas basin, Northern Greece, are selected as case studies. Life cycle assessment (LCA) is used to quantify the overall environmental footprint and identify particular environmental weaknesses (i.e. unsustainable practices) of each cultivation system. Results are analysed at both midpoint and endpoint levels in order to obtain a comprehensive overview of the environmental sustainability of each system. Attributional LCA (ALCA) is employed to identify emissions associated with the life cycles of the two systems. Results are presented for problem-oriented (midpoint) and damage-oriented (endpoint) approaches, using ReCiPe impact assessment.Results and discussion
At midpoint level, conventional cultivation exhibits about threefold higher environmental impact on freshwater eutrophication, than organic cultivation. This arises from the extensive use of nitrogen and phosphorus-based fertilizers, with consequent direct emissions to the environment. The remaining impact categories are mainly affected by irrigation, with associated indirect emissions linked to electricity production. At endpoint level, the main hotspots identified for conventional cultivation are irrigation and fertilizing, due to intensive use of chemical fertilizers and (to a lesser degree) pesticides. For organic pepper cultivation, the main environmental hotspots are irrigation, machinery use, and manure loading and spreading processes. Of these, the highest score for irrigation derives from the heavy electricity consumption required for groundwater pumping associated with the fossil-fuel-dependent Greek electricity mix.Conclusions
Organic and conventional cultivation systems have similar total environmental impacts per unit of product, with organic cultivation achieving lower environmental impacts in ‘freshwater eutrophication’, ‘climate change’, ‘terrestrial acidification’ and ‘marine eutrophication’ categories. Conventional cultivation has a significantly greater effect on the freshwater eutrophication impact category, due to phosphate emissions arising from application of chemical fertilizers.6.
Yan Dong Ralph K. Rosenbaum Michael Z. Hauschild 《The International Journal of Life Cycle Assessment》2018,23(8):1641-1653
Purpose
The study develops site-dependent characterization factors (CFs) for marine ecotoxicity of metals emitted to freshwater, taking their passage of the estuary into account. To serve life cycle assessment (LCA) studies where emission location is often unknown, site-generic marine CFs were developed for metal emissions to freshwater and coastal seawater, respectively. The new CFs were applied to calculate endpoint impact scores for the same amount of metal emission to each compartment, to compare the relative ecotoxicity damages in freshwater and marine ecosystems in LCA.Methods
Site-dependent marine CFs for emission to freshwater were calculated for 64 comparatively independent seas (large marine ecosystems, LMEs). The site-dependent CF was calculated as the product of fate factor (FF), bioavailability factor (BF), and effect factor (EF). USEtox modified with site-dependent parameters was extended with an estuary removal process to calculate FF. BF and EF were taken from Dong et al. Environ Sci Technol 50:269–278 (2016). Site-generic marine CFs were derived from site-dependent marine CFs. Different averaging principles were tested, and the approach representing estuary discharge rate was identified as the best one. Endpoint marine and freshwater metals CFs were developed to calculate endpoint ecotoxicity impact scores.Results and discussion
Marine ecotoxicity CFs are 1.5 orders of magnitude lower for emission to freshwater than for emission to seawater for Cr, Cu, and Pb, due to notable removal fractions both in freshwater and estuary. For the other metals, the difference is less than half an order of magnitude, mainly due to removal in freshwater. The site-dependent CFs generally vary within two orders of magnitude around the site-generic CF. Compared to USES-LCA 2.0 CFs (egalitarian perspective), the new site-generic marine CFs for emission to seawater are 1–4 orders of magnitude lower except for Pb. The new site-generic marine CFs for emission to freshwater lie within two orders of magnitude difference from USES-LCA 2.0 CFs. The comparative contribution share analysis shows a poor agreement of metal toxicity ranking between both methods.Conclusions
Accounting for estuary removal particularly influences marine ecotoxicity CFs for emission to freshwater of metals that have a strong tendency to complex-bind to particles. It indicates the importance of including estuary in the characterization modelling when dealing with those metals. The resulting endpoint ecotoxicity impact scores are 1–3 orders of magnitude lower in seawater than in freshwater for most metals except Pb, illustrating the higher sensitivity of freshwater ecosystems to metal emissions, largely due to the higher species density there.7.
Life cycle assessment of vegetable products: a review focusing on cropping systems diversity and the estimation of field emissions 总被引:1,自引:0,他引:1
Aurélie Perrin Claudine Basset-Mens Benoît Gabrielle 《The International Journal of Life Cycle Assessment》2014,19(6):1247-1263
Purpose
Recent life cycle assessment studies for vegetable products have identified the agricultural stage as one of the most important contributors to the environmental impacts for these products, while vegetable production systems are characterized by specific but also widely diverse production conditions. In this context, a review aiming at comparing the potential impacts of vegetable products and analyzing the relevance of the methods and data used for the inventory of the farm stage appeared necessary.Methods
Ten papers published in peer-reviewed scientific journals or ISO-compliant reports were selected. First, a presentation of the selected papers was done to compare the goal and scope and the life cycle inventory data to the related sections in the ILCD Handbook. Second, a quantitative review of input flows and life cycle impact assessment (LCIA) results (global warming, eutrophication, and acidification) was based on a cropping system typology and on a classification per product group. Third, an in-depth analysis of the methods used to estimate field emissions of reactive nitrogen was proposed.Results and discussion
The heated greenhouse system types showed the greatest global warming potential. The giant bean group showed the greatest acidification and eutrophication potentials per kilogram of product, while the tomato group showed the greatest acidification and eutrophication potentials per unit of area. Main sources of variations for impacts across systems were yields and inputs variations and system expansion rules. Overall, the ability to compare the environmental impact for these diverse vegetable products from cradle-to-harvest was hampered by (1) weaknesses regarding transparency of goal and scope, (2) a lack of representativeness and completeness of data used for the field stage, and (3) heterogeneous and inadequate methods for estimating field emissions. In particular, methods to estimate reactive nitrogen emissions were applied beyond their validity domain.Conclusions and recommendations
This first attempt at comparing the potential impacts of vegetable products pinpointed several gaps in terms of data and methods to reach representative LCIA results for the field production stage. To better account for the specificities of vegetable cropping systems and improve the overall quality of their LCA studies, our key recommendations were (1) to include systematically phosphorus, water, and pesticide fluxes and characterize associated impacts, such as eutrophication, toxicity, and water deprivation; (2) to better address space and time representativeness for field stage inventory data through better sampling procedures and reporting transparency; and (3) to use best available methods and when possible more mechanistic tools for estimating Nr emissions. 相似文献8.
Daesoo Kim Greg Thoma Darin Nutter Franco Milani Rick Ulrich Greg Norris 《The International Journal of Life Cycle Assessment》2013,18(5):1019-1035
Purpose
A life cycle assessment was conducted to determine a baseline for environmental impacts of cheddar and mozzarella cheese consumption. Product loss/waste, as well as consumer transport and storage, is included. The study scope was from cradle-to-grave with particular emphasis on unit operations under the control of typical cheese-processing plants.Methods
SimaPro© 7.3 (PRé Consultants, The Netherlands, 2013) was used as the primary modeling software. The ecoinvent life cycle inventory database was used for background unit processes (Frischknecht and Rebitzer, J Cleaner Prod 13(13–14):1337–1343, 2005), modified to incorporate US electricity (EarthShift 2012). Operational data was collected from 17 cheese-manufacturing plants representing 24 % of mozzarella production and 38 % of cheddar production in the USA. Incoming raw milk, cream, or dry milk solids were allocated to coproducts by mass of milk solids. Plant-level engineering assessments of allocation fractions were adopted for major inputs such as electricity, natural gas, and chemicals. Revenue-based allocation was applied for the remaining in-plant processes.Results and discussion
Greenhouse gas (GHG) emissions are of significant interest. For cheddar, as sold at retail (63.2 % milk solids), the carbon footprint using the IPCC 2007 factors is 8.60 kg CO2e/kg cheese consumed with a 95 % confidence interval (CI) of 5.86–12.2 kg CO2e/kg. For mozzarella, as sold at retail (51.4 % milk solids), the carbon footprint is 7.28 kg CO2e/kg mozzarella consumed, with a 95 % CI of 5.13–9.89 kg CO2e/kg. Normalization of the results based on the IMPACT 2002+ life cycle impact assessment (LCIA) framework suggests that nutrient emissions from both the farm and manufacturing facility wastewater treatment represent the most significant relative impacts across multiple environmental midpoint indicators. Raw milk is the major contributor to most impact categories; thus, efforts to reduce milk/cheese loss across the supply chain are important.Conclusions
On-farm mitigation efforts around enteric methane, manure management, phosphorus and nitrogen runoff, and pesticides used on crops and livestock can also significantly reduce impacts. Water-related impacts such as depletion and eutrophication can be considered resource management issues—specifically of water quantity and nutrients. Thus, all opportunities for water conservation should be evaluated, and cheese manufacturers, while not having direct control over crop irrigation, the largest water consumption activity, can investigate the water use efficiency of the milk they procure. The regionalized normalization, based on annual US per capita cheese consumption, showed that eutrophication represents the largest relative impact driven by phosphorus runoff from agricultural fields and emissions associated with whey-processing wastewater. Therefore, incorporating best practices around phosphorous and nitrogen management could yield improvements. 相似文献9.
Lycia Aziz Louise Deschênes Rifat-Ara Karim Laure Patouillard Cécile Bulle 《The International Journal of Life Cycle Assessment》2018,23(11):2178-2188
Purpose
The aim of the study is to calculate regionalized characterization factors for the atmospheric emissions of metals transferred to soil for zinc, copper, and nickel taking into account the atmospheric fate and speciation.Methods
In order to calculate characterization factors for all possible atmospheric emission locations around the world, the link between atmospheric deposition with regionalized soil fate factors and bioavailability factors accounting for the metal’s speciation was established. The methodology to develop the regionalized fate factors and characterization factors is threefold. First, the emitted metal fraction that is deposited on soils is calculated from atmospheric source-receptor matrices providing for each emission location the fraction of an emission that is deposited on each worldwide receiving cell (2°?×?2.5° resolution). Second, the fraction of metal deposited in different soil types is determined by overlapping the deposition map with a soil map, based on the 4513 different soil types from the Harmonized World Soil Database. Third, bioavailability factors are calculated for each soil type, which allows determining the bioavailable fraction of the deposited metal depending on the soil properties. Combining these steps with the effect factors results in a series of terrestrial ecotoxicological characterization factors. These characterization factors are then applied in an illustrative example and compared to results obtained with generic characterization factors. The case study focuses on the electricity production process in Québec, whose ecosystem impacts are currently dominated by metal ecotoxicity impacts. The uncertainty due to the spatial variability of the impact is quantified.Results and discussion
Our results show that regionalized characterization factors are over three orders of magnitude lower than generic characterization factors. They are presented on maps and their spatial variability was evaluated at different regional scales (region, country, world). The use of regionalized characterization factors with their spatial variability at different geographic resolution scales in the case study gives a result more or less precise depending on the level of resolution of the characterization factor applied (country or global-default). The impact scores of the three metals in the case study are three orders of magnitude lower when compared to the scores obtained with generic characterization factors.Conclusions
The development of those regionalized characterization factors improves the terrestrial ecotoxicity assessment in life cycle impact assessment by taking into account the atmospheric fate and the speciation of the metal for new 3 metals for the different soil types in the world and by documenting their spatial variability.10.
Purpose
This paper compares 16 waste lubricant oil (WLO) systems (15 management alternatives and a system in use in Portugal) using a life cycle assessment (LCA). The alternatives tested use various mild processing techniques and recovery options: recycling during expanded clay production, recycling and electric energy production, re-refining, energy recovery during cement production, and energy recovery during expanded clay production.Methods
The proposed 15 alternatives and the actual present day situation were analyzed using LCA software UMBERTO 5.5, applied to eight environmental impact categories. The LCA included an expansion system to accommodate co-products.Results
The results show that mild processing with low liquid gas fuel consumption and re-refining is the best option to manage WLO with regard to abiotic depletion, eutrophication, global warming, and human toxicity environmental impacts. A further environmental option is to treat the WLO using the same mild processing technique, but then send it to expanded clay recycling to be used as a fuel in expanded clay production, as this is the best option regarding freshwater sedimental ecotoxicity, freshwater aquatic ecotoxicity, and acidification.Conclusions
It is recommended that there is a shift away from recycling and electric energy production. Although sensitivity analysis shows re-refining and energy recovery in expanded clay production are sensitive to unit location and substituted products emission factors, the LCA analysis as a whole shows that both options are good recovery options; re-refining is the preferable option because it is closer to the New Waste Framework Directive waste hierarchy principle. 相似文献11.
Gregory M. Peters Kathleen R. Murphy Anders Peter S. Adamsen Sander Bruun Magdalena Svanström Marieke ten Hoeve 《The International Journal of Life Cycle Assessment》2014,19(11):1891-1900
Purpose
Odour is an important aspect of systems for human and agricultural waste management and many technologies are developed with the sole purpose of reducing odour. Compared with greenhouse gas assessment and the assessment of toxicity, odour assessment has received little attention in the life cycle assessment (LCA) community. This article aims to redress this.Methods
Firstly, a framework for the assessment of odour impacts in LCA was developed considering the classical LCA framework of emissions, midpoint and endpoint indicators. This suggested that an odour footprint midpoint indicator was worth striving for. An approach to calculating an areal indicator we call “odour footprint”, which considers the odour detection threshold, the diffusion rate and the kinetics of degradation of odourants, was implemented in MATLAB. We demonstrated the use of the characterisation factors we calculated in a case study based on odour removal technology applied to a pig barn.Results and discussion
We produced a list of 33 linear characterisation factors based on hydrogen sulphide equivalents, analogous to the linear carbon dioxide equivalency factors in use in carbon footprinting, or the dichlorobenzene equivalency factors developed for assessment of toxic impacts in LCA. Like the latter, this odour footprint method does not take local populations and exposure pathway analysis into account—its intent is not to assess regulatory compliance or detailed design. The case study showed that despite the need for materials and energy, large factor reductions in odour footprint and eutrophication potential were achieved at the cost of a smaller factor increase in greenhouse emissions.Conclusions
The odour footprint method is proposed as an improvement on the established midpoint method for odour assessment in LCA. Unlike it, the method presented here considers the persistence of odourants. Over time, we hope to increase the number of characterised odourants, enabling analysts to perform simple site-generic LCA on systems with odourant emissions. 相似文献12.
Daniela Dressler Achim Loewen Michael Nelles 《The International Journal of Life Cycle Assessment》2012,17(9):1104-1115
Purpose
This article evaluates the parameters that influence the results of a life cycle assessment (LCA) of biogas production from maize and the conversion of biogas into electricity. The environmental impacts of biogas vary according to regional farming procedures and, therefore, the soil, climate conditions, crop yield, and cultivation management. This study focuses on these regional parameters and the existing infrastructure, including the number of installed biogas plants and their share of used heat.Materials and methods
To assess the regional impact, the LCAs of maize cultivation, on the one hand, and the production and use of biogas, on the other, were performed for three different areas. These areas were the administrative districts of Celle, Hildesheim, and Goettingen; all located in the south of Lower Saxony, Germany. The areas differed in geographic location conditions, crop yield, and the number of installed biogas plants. The necessary data for modeling the cultivation of maize were derived from the specific regional and local parameters of each area. The most important parameters were the soil characteristics and the climate conditions for cultivating maize. The share of used heat from combined heat and power unit (CHP) was another relevant factor for biogas production and use.Results
Our results demonstrate significant differences among the investigated areas. The smallest environmental impact of all the considered categories occurs in Goettingen and the largest in Celle. The net greenhouse gas emissions vary from 0.179?kg CO2 eq./kWhel in Celle to 0.058?kg CO2 eq./kWhel in Goettingen. This result is due to the maize cultivation system and the different credits for using heat from the CHP. Variances in energy crop cultivation result from different nitrogen and irrigation demands. In addition, despite higher applications of nitrogen fertilizer and irrigation, the maize yield is lower in Celle. The impact category of total fossil energy shows similar results to that of the greenhouse gas (GHG) emissions. The results range from ?0.274 to 0.175 kWh/kWhel. The results of acidification and eutrophication vary from 1.62 in Goettingen to 1.94?g SO2 eq./kWhel in Celle and respectively 0.330 to 0.397?g PO 4 3? eq./kWhel. These differences are primarily caused by maize cultivation, especially irrigation.Conclusions and perspectives
Cultivating maize and using waste heat from the CHP were identified as the most influential parameters for the GHG emissions and total fossil energy demand. Regarding acidification and eutrophication, the most relevant factors are the application of digester output and the emissions from the CHP. Our results show the need to consider regional parameters in the LCA of bioenergies, particularly biogas production and use, especially if the LCA studies are used for generalized evaluations such as statements on the climate protection potential of biogas. 相似文献13.
H. Aaltonen J. Aalto P. Kolari M. Pihlatie J. Pumpanen M. Kulmala E. Nikinmaa T. Vesala J. Bäck 《Plant and Soil》2013,369(1-2):241-256
Background and Aims
Volatile organic compound (VOC) emissions from biogenic sources are important contributors to chemical reactions in the air. Soil/forest floor VOCs contribute significantly to the ecosystem scale emissions, however, these emissions and their temporal and spatial variations are poorly characterised. The below-canopy VOC emissions have been measured mainly in campaigns; continuous measurements over the whole growing season are rare.Methods
VOCs were measured from boreal forest floor over the snow-free season 2010 in southern Finland with automated flow-through chambers connected to proton transfer reaction-mass spectrometer (PTR-MS). We measured 10 masses in total, of which five quantitatively (M33, M45, M59, M69, M137).Results
All of the fluxes showed clear diurnal and seasonal variation, being at their highest in early summer. Spatial variation in the fluxes was great and the lowest rates were found in chambers with dense vegetation cover. Also, VOCs deposition was observed regularly. Monoterpene (M137) emissions were one magnitude higher (up to 264 ng?m?2?s?1) than other emissions. The VOC fluxes correlated positively with temperature and light, while relative humidity correlated negatively.Conclusions
Results indicated that forest floor plays a substantial role in the boreal forest total VOC emissions. Understanding the processes controlling VOC emissions requires more detailed analysis and long-time measurements with sufficient time resolution and analytical accuracy. 相似文献14.
Susan Tandy Susan R. Brittain Barry M. Grail Cameron W. Mcleod Eric Paterson A. Deri Tomos 《Plant and Soil》2013,368(1-2):471-482
Background and aims
Residues from use of depleted uranium (DU) munitions pose a lasting environmental impact through persistent contamination of soils. Consequently, an understanding of the factors determining the fate of DU in soil is necessary. An understudied factor is the interaction of root exudates with DU. This study describes the use of ‘Single-Cell-Sampling-and-Analysis’ (SiCSA) for the first time in soil and investigates the effects of root exudates on DU dissolution.Methods
Soil solutions from soil and plant-soil microcosms containing DU fragments were sampled and analysed using SiCSA and capillary electrophoresis/ICP-MS for organic acids and uranium.Results
Nanolitre volumes of soil solution were sampled and analysed. Soils with DU fragments but no citrate addition showed low uranium concentrations in contrast to those with added citrate. Lupin root exudation gave concentrations up to 8 mM citrate and 4.4 mM malate in soil solution which solubilised DU fragments yielding transient solution concentrations of up to 30 mM.Conclusions
Root exudates solubilise DU giving high localised soil solution concentrations. This should be considered when assessing the environmental risk of DU munitions. The SiCSA method was used successfully in soil for the first time and enables investigations with high spatial and temporal resolution in the rhizosphere.15.
Paula Quinteiro Marijn Van de Broek Ana Cláudia Dias Bradley G. Ridoutt Gerard Govers Luís Arroja 《The International Journal of Life Cycle Assessment》2017,22(2):159-171
Purpose
This study illustrates the applicability of a framework to conduct a spatially distributed inventory of suspended solids (SS) delivery to freshwater streams combined with a method to derive site-specific characterisation factors for endpoint damage on aquatic ecosystem diversity. A case study on Eucalyptus globulus stands located in Portugal was selected as an example of a land-based system. The main goal was to assess the relevance of SS delivery to freshwater streams, providing a more comprehensive assessment of the SS impact from land use systems on aquatic environments.Methods
The WaTEM/SEDEM model, which was used to perform the SS inventory, is a raster-based empirical erosion and deposition model. This model allowed to predict the amount of SS from E. globulus stands under study and route this amount through the landscape towards the drainage network. Combining the spatially explicit SS inventory with the derived site-specific endpoint characterisation factors of SS delivered to two different river sections, the potential damages of SS on macroinvertebrates, algae and macrophytes were assessed. In addition, this damage was compared with the damage obtained with the commonly used ecosystem impact categories of the ReCiPe method.Results and discussion
The relevance of the impact from SS delivery to freshwater streams is shown, providing a more comprehensive assessment of the SS impact from land use systems on aquatic environments. The SS impacts ranged from 15.5 to 1234.9 PDF m3.yr.ha?1.revolution?1 for macroinvertebrates, and from 5.2 to 411.9 PDF.m3.yr.ha?1.revolution?1 for algae and macrophytes.For some stands, SS potential impacts on macroinvertebrates have the same order of magnitude than freshwater eutrophication, freshwater ecotoxicity, terrestrial ecotoxicity and terrestrial acidification impacts. For algae and macrophytes, most of the stands present SS impacts of the same order of magnitude as terrestrial ecotoxicity, one order of magnitude higher than freshwater eutrophication and two orders of magnitude lower than freshwater ecotoxicity and terrestrial acidification.Conclusions
The SS impact results allow concluding that the increase of SS in the water column can cause biodiversity damage and that the calculated impacts can have a similar or even higher contribution to the total environmental impact than the commonly used ecosystem impact categories of the ReCiPe method. A wide application of the framework and method developed at a local scale will enable the establishment of a regionalised SS inventory database and a deep characterisation of the potential environmental impacts of SS on local aquatic environments.16.
Assessing freshwater use impacts in LCA: Part I—inventory modelling and characterisation factors for the main impact pathways 总被引:2,自引:1,他引:1
Llorenç Milà i Canals Jonathan Chenoweth Ashok Chapagain Stuart Orr Assumpció Antón Roland Clift 《The International Journal of Life Cycle Assessment》2009,14(1):28-42
Background, aim and scope
Freshwater is a basic resource for humans; however, its link to human health is seldom related to lack of physical access to sufficient freshwater, but rather to poor distribution and access to safe water supplies. On the other hand, freshwater availability for aquatic ecosystems is often reduced due to competition with human uses, potentially leading to impacts on ecosystem quality. This paper summarises how this specific resource use can be dealt with in life cycle analysis (LCA).Main features
The main quantifiable impact pathways linking freshwater use to the available supply are identified, leading to definition of the flows requiring quantification in the life cycle inventory (LCI).Results
The LCI needs to distinguish between and quantify evaporative and non-evaporative uses of ‘blue’ and ‘green’ water, along with land use changes leading to changes in the availability of freshwater. Suitable indicators are suggested for the two main impact pathways [namely freshwater ecosystem impact (FEI) and freshwater depletion (FD)], and operational characterisation factors are provided for a range of countries and situations. For FEI, indicators relating current freshwater use to the available freshwater resources (with and without specific consideration of water ecosystem requirements) are suggested. For FD, the parameters required for evaluation of the commonly used abiotic depletion potentials are explored.Discussion
An important value judgement when dealing with water use impacts is the omission or consideration of non-evaporative uses of water as impacting ecosystems. We suggest considering only evaporative uses as a default procedure, although more precautionary approaches (e.g. an ‘Egalitarian’ approach) may also include non-evaporative uses. Variation in seasonal river flows is not captured in the approach suggested for FEI, even though abstractions during droughts may have dramatic consequences for ecosystems; this has been considered beyond the scope of LCA.Conclusions
The approach suggested here improves the representation of impacts associated with freshwater use in LCA. The information required by the approach is generally available to LCA practitionersRecommendations and perspectives
The widespread use of the approach suggested here will require some development (and consensus) by LCI database developers. Linking the suggested midpoint indicators for FEI to a damage approach will require further analysis of the relationship between FEI indicators and ecosystem health. 相似文献17.
18.
Yelin Deng Jianyang Li Ming Qiu Fan Yang Jingyi Zhang Chris Yuan 《The International Journal of Life Cycle Assessment》2017,22(2):222-236
Purpose
Graphene oxide (GO) nanomaterial has found wide potential industrial applications, but its life cycle environmental impact is not fully understood mainly because of lack of characterization factors (CFs) for the life cycle impact assessment. In this paper, we report the derivation of CF for freshwater ecotoxicity of GO based on the USEtox method.Methods
The CF is derived based on the toxic effect factor, fate factor, and exposure factor of GO in the aquatic environment. The toxic effect factor is extracted from mechanistic toxicity studies available in the literature. The fate factor is derived with the colloidal method, and the exposure factor is determined through Langmuir adsorption isotherm for interactions between GO and dissolve organic carbon. Additionally, both fate factor and exposure factor are re-calculated through the default mass-balanced model in USEtox. The apparent octanol-water partition coefficient (K ow) required in the mass balanced model is determined via experiment. Other parameters are calculated according to the apparent K ow.Results and discussion
The study derives a CF of 777.5 potentially affected species (PAF) day m3 kg?1 for GO with a fate factor of 27.2 days and an exposure factor of 0.93. Sensitivity analysis suggests that variability from the effect factor is the dominant source leading changes in CF. The uncertainty of CF value can vary between ~1 and 103 PAF day m3 kg?1. Comparison between the colloidal and the mass-balanced models indicates that heteroaggregation may be underestimated by using the apparent partition coefficient, and thus, a much higher estimate of fate factor is obtained from the mass-balanced model. Additionally, empirical formulae in the USEtox to correlate other coefficients with K ow are not proper to calculate bioaccumulation and adsorption with dissolved organic carbon since a virtually a unit exposure factor is obtained.Conclusion
The derived CFs can be readily incorporated into future toxicity assessment on GO. The fate factor is calculated in the colloidal model while adsorption of dissolved organic carbon onto GO surface should be derived from the Langmuir isotherm. Compared to the colloidal-based method, the conventional mass-balanced method may not be well applicable to GO due to the significant uncertainties in fate and exposure factors from applying the apparent partition coefficients. As three orders of magnitude variations in CF are caused by effect factor due to limited toxicity tests available for GO, more toxicological studies of GO on various species are needed in the future.19.
Estimating the impact of changing fertilizer application rate, land use, and climate on nitrous oxide emissions in Irish grasslands 总被引:1,自引:0,他引:1
Dong-Gill Kim Rashad Rafique Paul Leahy Mark Cochrane Gerard Kiely 《Plant and Soil》2014,374(1-2):55-71
Aim
This study examines the impact of changing nitrogen (N) fertilizer application rates, land use and climate on N fertilizer-derived direct nitrous oxide (N2O) emissions in Irish grasslands.Methods
A set of N fertilizer application rates, land use and climate change scenarios were developed for the baseline year 2000 and then for the years 2020 and 2050. Direct N2O emissions under the different scenarios were estimated using three different types of emission factors and a newly developed Irish grassland N2O emissions empirical model.Results
There were large differences in the predicted N2O emissions between the methodologies, however, all methods predicted that the overall N2O emissions from Irish grasslands would decrease by 2050 (by 40–60 %) relative to the year 2000. Reduced N fertilizer application rate and land-use changes resulted in decreases of 19–34 % and 11–60 % in N2O emission respectively, while climate change led to an increase of 5–80 % in N2O emission by 2050.Conclusions
It was observed in the study that a reduction in N fertilizer and a reduction in the land used for agriculture could mitigate emissions of N2O, however, future changes in climate may be responsible for increases in emissions causing the positive feedback of climate on emissions of N2O. 相似文献20.
PestLCI 2.0: a second generation model for estimating emissions of pesticides from arable land in LCA 总被引:1,自引:0,他引:1
T. J. Dijkman M. Birkved M. Z. Hauschild 《The International Journal of Life Cycle Assessment》2012,17(8):973-986