Development of a self-consistent model of dust grain charging at elevated pressures using the method of moments

A model of dust grain charging is constructed using the method of moments. The dust grain charging process in a weakly ionized helium plasma produced by a 100-keV electron beam at atmospheric pressure is studied theoretically. In simulations, the beam current density was varied from 1 to 10⁶ μA/cm². It is shown that, in a He plasma, dust grains of radius 5 μm and larger perturb the electron temperature only slightly, although the reduced electric field near the grain reaches 8 Td, the beam current density being 10⁶ μA/cm². It is found that, at distances from the grain that are up to several tens or hundreds of times larger than its radius, the electron and ion densities are lower than their equilibrium values. Conditions are determined under which the charging process may be described by a model with constant electron transport coefficients. The dust grain charge is shown to be weakly affected by secondary electron emission. In a beam-produced helium plasma, the dust grain potential calculated in the drift-diffusion model is shown to be close to that calculated in the orbit motion limited model. It is found that, in the vicinity of a body perturbing the plasma, there may be no quasineutral plasma presheath with an ambipolar diffusion of charged particles. The conditions for the onset of this presheath in a beam-produced plasma are determined. __________ Translated from Fizika Plazmy, Vol. 29, No. 3, 2003, pp. 214–226. Original Russian Text Copyright ? 2003 by Filippov, Dyatko, Pal’, Starostin.     

Environmental Fate of Gallium Arsenide Semiconductor Disposal

This article describes a methodology for the quantitative assessment of the environmental fate of gallium and arsenic from the disposal of mobile phones containing gallium arsenide (GaAs) semiconductors, using data from Japan.
The product lifetime of mobile phones is short, and the recycling systems for such phones are currently underdeveloped. As a result, many mobile phones are disposed of via incineration and landfilling. The disposal of GaAs semiconductors could lead to some releases of gallium and arsenic to air and water. The methodology presented here begins with an estimation of the cumulative number of disposed mobile phones, using a logistic curve. Then, thermodynamic simulation and laboratory experiments are carried out to assess how much gallium and arsenic may be released into the environment. Using this method, the cumulative number of mobile phones disposed of in Japan is calculated to be 610 million by 2010. Distribution among air emissions, the leachate, and the insoluble residue (in landfilled incinerator ash) was determined to be 4.20 × 10^-2%, 1.58 × 10^-1%, and 99.8% for gallium, and 2.00 × 10^-1%, 19.5%, and 80.3% for arsenic, respectively. For phones that are disposed of directly in landfills, it is estimated that nearly 100% of the gallium and arsenic exists as the insoluble residue. We suggest that, in the conditions present in Japan, disposal of mobile phones directly into the landfill is preferable to the incineration with subsequent landfill of ash with respect to gallium and arsenic emissions into the environment. The proposed methodology may be adapted for the assessment of the environmental fate of problematic substances from the disposal of similar products.     

Simulation of oscillatory processes in a beam-plasma system with a virtual cathode in gas-filled interaction space

Physical processes occurring in an intense electron beam with a virtual cathode in an interaction space filled with neutral gas are studied in a two-dimensional model. A mathematical model is proposed for investigating complicated self-consistent processes of neutral gas ionization by the beam electrons and the dynamics of an electron beam and heavy positive ions in the common space charge field with allowance for the two-dimensional motion of charged particles. Three characteristic dynamic regimes of the system are revealed: complete suppression of oscillations of the virtual cathode as a result of neutralizing its space charge by positive ions; the pulsed generation regime, in which the ions dynamics repeatedly suppresses and restores the virtual cathode oscillations; and the continuous generation regime with an anomalously high level of noisy oscillations.     

Process of compensation of the space charge of a negative ion beam in a gas

The process of compensation of the space charge of a negative ion beam propagating through a neutral gas is investigated numerically. A comparison of the results obtained with experimental data unambiguously proves that, at high gas pressures, when the beam space charge is overcompensated, the electric field within the beam is determined by Coulomb collisions of the beam ions with plasma electrons. At low pressures, when the space charge is undercompensated, the field within the beam is determined by the dynamic processes related to oscillations of the beam current.     

Nonlinear dynamics and chaotization of oscillations of a virtual cathode in an annular electron beam in a uniform external magnetic field

Results are presented from a numerical study of the effect of an external magnetic field on the conditions and mechanisms for the formation of a virtual cathode in a relativistic electron beam. Characteristic features of the nonlinear dynamics of an electron beam with a virtual cathode are considered when the external magnetic field is varied. Various mechanisms are investigated by which the virtual cathode oscillations become chaotic and their spectrum becomes a multifrequency spectrum, thereby complicating the dynamics of the vircator system. A general mechanism for chaotization of the oscillations of a virtual cathode in a vircator system is revealed: the electron structures that form in an electron beam interact by means of a common space charge field to give rise to additional internal feedback. That the oscillations of a virtual cathode change from the chaotic to the periodic regime is due to the suppression of the mechanism for forming secondary electron structures.     

The charge mobilities in fused ring Oligothiophenes and their derivatives: influence of molecular structures

Fused ring oligothiophenes and their derivatives, as active organic semiconductors, are widely used in electronic devices. The influence of molecular conjunction length on reorganization energy, electronic coupling and charge mobility of two fused ring oligothiophenes are investigated theoretically. The charge mobility of 2, 5-di(thiophen-2-yl)thieno [3, 2-b]thiophene (T?T²?T) with longer molecular conjunction length is 0.226 cm²V^?1s^?1, which is nearly 3 times larger than that of 2, 2-bithieno[3, 2-b]thiophene (T²?T²) as 0.085 cm²V^?1s^?1. The investigation will provide a new perspective to design high mobility organic semiconductors.     

Characterization of 1064 nm Nd:YAG laser-produced cu plasma

The plasma was produced by focusing Nd:YAG laser pulses of 1064 nm wavelength on to a copper target at laser fluences of 5.35, 6.95, and 9.33 J/cm². An ion collector placed along the target surface normal was used to record the time-of-flight (TOF) ion signal during plasma expansion in vacuum. The TOF ion pulses were deconvoluted using the Coulomb-Boltzmann-shifted function to estimate the available Cu ion charge states, equivalent plasma ion temperature, and accelerating potential in the nonequilibrium plasma. The maximum available ion charge state, equivalent plasma ion temperature, and accelerating potential are found to increase with laser fluence. In the local thermal equilibrium conditions, the accelerating potential can be supposed to apply across a distance of the order of the Debye length. The Debye length and, hence, the electric field in the laser produced plasma at three laser fluences values were estimated. The electric field was in the range of 1 MV/cm and increased with laser fluence. In the laser fluence range used in this work, the sum of thermal and adiabatic energy of the ion was slightly higher than its Coulomb energy.     

Passage of electromagnetic waves through the critical surface

A study is made of the passage of electromagnetic waves through the critical surface at small angles between the plasma density gradient and the magnetic field. Expressions are derived for the transmission and reflection coefficients of electromagnetic oscillations that are periodic in the direction transverse to the density gradient. The penetration of wave beams is also analyzed. In the case of a wide beam, the incident and transmitted ray trajectories are shown to be mirror-image about the resonance surface. Behind the resonance surface, a narrow incident wave beam generates a beam propagating along the magnetic field.     

Acceleration of heavy multicharged ions in the interaction of a subrelativistic femtosecond laser pulse with a melted metal surface

Results are presented from experimental studies of ion acceleration under the action of femtosecond laser pulses with an intensity of 10¹⁷ W/cm², incident onto the free surfaces of melted gallium and indium. The effect of the polarization direction of a linearly polarized laser pulse and the amplitude of a short prepulse, which precedes the main pulse by several nanoseconds, on the parameters of accelerated ions is investigated. It is found that, even for such a moderate laser intensity, the characteristic velocity of fast ions ejected along the reflected beam is a factor of 1.5 higher than that of ions ejected along the normal to the target surface. It is shown that, as the prepulse energy increases, the hard X-ray yield and the mean energy of hot electrons increase substantially, whereas the velocity of both fast and slow ions decreases appreciably regard-less of laser polarization.     

Dielectric saturation of the aqueous boundary layers adjacent to charged bilayer membranes

Summary The surface charge density resulting from the adsorption of hydrophobic anions of dipicrylamine onto dioleyl-lecithin bilayer membranes has been measured directly using a high field pulse method. The surface charge density increases linearly with adsorbate concentration in the water until electrostatic repulsion of impinging hydrophobic ions by those already adsorbed becomes appreciable. Then Gouy-Chapman theory predicts that surface charge density will increase sublinearly, with the power [z ⁺/(z ⁺+2)] of the adsorbate concentration, wherez ⁺ is the cation valence of the indifferent electrolyte screening the negatively charged membrane surface. The predicted 1/3 and 1/2 power laws for univalent and divalent cations, respectively, have been observed in these experiments using Na⁺, Mg⁺⁺, and Ba⁺⁺ ions. Gouy-Chapman theory predicts further that the change from linear to sublinear dependence takes place at a surface charge density governed by the static dielectric constant of water and the concentration of indifferent electrolyte. Quantitative agreement with experiment is obtained at electrolyte concentrations of 10^–4 m and 10^–3 m, but can be maintained at higher concentrations only if the aqueous dielectric constant is decreased. A transition field model is proposed in which the Gouy-Chapman theory is modified to take account of dielectric saturation of water in the intense electric fields adjacent to charged membrane surfaces.     

Sabkha and Burrow-Mediated Dolomitization in the Mississippian Debolt Formation,Northwestern Alberta,Canada

Dolomitized burrows in the Mississippian (Visean) Debolt Formation of northwestern Alberta, Canada form the primary reservoir intervals in the Dunvegan gas field. Sedimentological and ichnological analyses suggest a carbonate ramp setting that includes subenvironments such as sabkhas, hypersaline lagoons, restricted subtidal lagoons, intertidal mud flats, and peloidal shoals. Dolomitization occurs primarily within oxidized muds and highly bioturbated sediments, with the primary mode being sabkha-associated precipitation. In this context, dolomitization within the burrows also appears to be mediated by sulfate-reducing bacteria. δ¹⁸O values for dolomite within burrows (mean 2.4‰) are enriched by 1.3‰ relative to calcite values (mean 1.1‰) within the burrows. This degree of fractionation is similar for dolomite and calcite that have precipitated from the same solution. It is therefore suggested that the protodolomite precipitated in equilibrium with calcite rather than by replacement of pre-existing calcite. Isotopic values of δ¹³C measured for dolomite associated with burrows (mean 3.4‰) and matrix (mean 3.5‰) is slightly enriched relative to measured calcite values (mean 3.2‰ for matrix; mean 3.1‰ for burrows). These isotopic trends are common for modern dolomite that has precipitated in equilibrium with seawater where concomitant sulfate reduction and organic carbon-oxidation is inferred to occur near the surface.     

Effect of an external RF field on the beam-plasma discharge in a magnetic field

The effect of an RF field on a steady-state beam-plasma discharge with a plane electrode placed parallel to a sheetlike electron beam is studied experimentally. The plasma parameters were measured by a single probe, and the electron distribution function was determined with the use of an electrostatic analyzer. The energy and current of the electron beam were E _B=2.5 keV and J _B=0.05–1.5 A, respectively. The working pressure was p=2×10^?5–10^?3 torr. The frequency of the external RF field was 13.56 MHz. Both the steady-state regimes in which the RF field had no effect on the plasma parameters and regimes with a pronounced effect of the RF field were observed. The experiments show that the regime of the discharge depends strongly on the plasma density and the magnetic field. The parametric instability is studied theoretically in the weak-turbulence approximation. It is shown that, due to the decay nature of the spectrum of plasma oscillations, the onset of instability is accompanied by the transfer of the energy of fluctuations over the spectrum, from the pump frequency toward its harmonics.     

Interaction of an ion bunch with a plasma slab

Charge neutralization of a short ion bunch passing through a plasma slab is studied by means of numerical simulation. It is shown that a fraction of plasma electrons are trapped by the bunch under the action of the collective charge separation field. The accelerated electrons generated in this process excite beam?plasma instability, thereby violating the trapping conditions. The process of electron trapping is also strongly affected by the high-frequency electric field caused by plasma oscillations at the slab boundaries. It is examined how the degree of charge neutralization depends on the parameters of the bunch and plasma slab.     

In-vivo dosimetry for field sizes down to 6 × 6 mm2 in shaped beam radiosurgery with microMOSFET

The aim of this study is to evaluate microMOSFET as in-vivo dosimeter in 6 MV shaped-beam radiosurgery for field sizes down to 6 × 6 mm². A homemade build-up cap was developed and its use with microMOSFET was evaluated down to 6 × 6 mm². The study with the homemade build-up cap was performed considering its influence on field size over-cover occurring at surface, achievement of the overall process of electronic equilibrium, dose deposition along beam axis and dose attenuation. An optimized calibration method has been validated using MOSFET in shaped-beam radiosurgery for field sizes from 98 × 98 down to 18 × 18 mm². The method was detailed in a previous study and validated in irregular field shapes series measurements performed on a head phantom. The optimized calibration method was applied to microMOSFET equipped with homemade build-up cap down to 6 × 6 mm². Using the same irregular field shapes, dose measurements were performed on head phantom. MicroMOSFET results were compared to previous MOSFET ones. Additional irregular field shapes down to 8.8 × 8.8 mm² were studied with microMOSFET. Isocenter dose attenuation due to the homemade build-up cap over the microMOSFET was near 2% irrespective of field size. Our results suggested that microMOSFET equipped with homemade build-up cap is suitable for in-vivo dosimetry in shaped-beam radiosurgery for field sizes down to 6 × 6 mm² and therefore that the required build-up cap dimensions to perform entrance in-vivo dosimetry in small-fields have to ensure only partial charge particle equilibrium.     

Electrophoresis in protein crystal: nonequilibrium molecular dynamics simulations

Electrophoresis of a mixture of NaCl and CaCl₂ in a lysozyme crystal is investigated using nonequilibrium molecular dynamics (MD) simulations. Upon exposure to an electric field, the stability of lysozyme is found to decrease slightly. This finding is demonstrated by increases in the root mean-square deviations of the heavy atoms of lysozyme, in the solvent-accessible surface area of hydrophobic residues, and in the number of hydrogen bonds between lysozyme and water. The solvent-accessible surface area of hydrophilic residues changes marginally, and the number of hydrogen bonds between lysozyme molecules decreases. Water molecules tend to align preferentially parallel to the electric field, and the dipole moment along the pore axis increases linearly with increasing field strength. Two pronounced layered structures are observed for Na⁺ and Ca²⁺ in the vicinity of protein surface, but only one enriched layer is observed for Cl⁻. The number distributions of all ions are nearly independent of the electric field. The water coordination numbers of all ions are smaller in the crystal than in aqueous bulk solution; however, the reverse is found for the Cl⁻ coordination numbers of cations. Both the water and the Cl⁻ coordination numbers are insensitive to the electric field. Ion diffusivities in the crystal are ∼2 orders of magnitude smaller than those in aqueous bulk solution. The drift velocities of ions increase proportionally to the electric field, particularly at high strengths, and depend on ionic charge and coordination with oppositely charged ions. Electrical current exhibits a linear relationship with the field strength. The zero-field electrical conductivity is estimated to be 0.56 S/m, which is very close to 0.61 S/m as predicted by the Nernst-Einstein equation.     

Biochemical examination ofRana pipiens epithelial mucus

Summary The epithelial mucus ofRana pipiens is shown to be highly negative by histochemical procedures, uptake of tagged extracellular markers, equilibrium dialysis, and QAE-Sephadex G-25 ion exchange chromatography. The mucus is found to contain 0.4% (dry weight) sulfate, 16% (dry weight) protein and 9% (dry weight) neutral sugars, whereas no sialic acid is detected. A mucin charge of –40 equivalents mole^–1 is calculated by equilibrium dialysis using a molecular mass of 100,000 Dalton. An independent determination of in situ charge density by radionuclide uptake onto the frog surface (1.55 meq l^–1) suggests that this estimate of mucin charge is correct. Based on analysis of size-exclusion chromatography fractions, it is suggested that mucus contains a sulfated glyco-protein (100,000 Dalton) that forms aggregates of about one million Dalton.     

Dynamics of a relativistic electron beam in the vicinity of a spherical injecting body in space plasma

The dynamics of a relativistic electron beam in the vicinity of an injector in the form of a spherical conducting body in a space plasma is considered. An equation describing the radial evolution of a steady electron beam with a self-similar density profile in the electric field of the injector is formulated. A method for calculating the radial evolution of a relativistic electron beam in the vicinity of an injector is developed. The method is based on the numerical integration of a set of ordinary differential equations for the beam radius and field potential in the space charge region under the relevant boundary conditions at the injector surface. Results are presented from numerical simulations of the radial dynamics of an electron beam in the vicinity of a spherical screen system for neutralizing the electric charge carried away by the beam. The numerical results show that the electric field of the injector hastens the beam expansion.     

How organic molecules can control electronic devices.

This article examines a somewhat counter-intuitive approach to molecular-based electronic devices. Control over the electronic energy levels at the surfaces of conventional semiconductors and metals is achieved by assembling on the solid surfaces, poorly organized, partial monolayers (MLs) of molecules instead of the more commonly used ideal ones. Once those surfaces become interfaces, these layers exert electrostatic rather than electrodynamic control over the resulting devices, based on both electrical monopole and dipole effects of the molecules. Thus electronic transport devices, incorporating molecules, can be constructed without current flow through the molecules. This is illustrated for a gallium arsenide (GaAs) sensor as well as for gold-silicon (Au-Si) and Au-GaAs diodes. Incorporating molecules into solid interfaces becomes possible, using a 'soft' electrical contacting procedure, so as not to damage the molecules. Because there are only a few molecular restrictions, this approach opens up possibilities for the use of more complex (including biologically active) molecules as it circumvents requirements for ideal MLs and for molecules that can tolerate actual electron transport through them.     

Oscillations of H+ secretion and electrogenic properties in the isolated frog gastric mucosa

Oscillations of H⁺ secretion rate, active net charge transport measured as short-circuit current and transmucosal electric potential difference with a regular frequency of one period in 45 min appeared spontaneously in the isolated frog gastric mucosa. Similar oscillations were triggered by the addition of histamine at 45-min intervals.The spontaneous oscillations and the continuatino of histamine triggered oscillations after cessation of histamine administration indicates that there was a component of slow inherent rhytmicity in the mucosa. No oscillations were obtained when a small transmucosal gradient of Cl^? was used.With the histamine-triggered oscillations the H⁺ secretion rate was always 180° out of phase with the short-circuit current and the potential difference. This supports the hypothesis of an electrogenic mechanism for active transport of H⁺ in the mucosa that can function at least partially independently of that for Cl^?.     

Relation between energy production and adenine nucleotide metabolism in human blood platelets

The relation between ATP production and adenine nucleotide metabolism was investigated in human platelets which were starved by incubation in glucose-free, CN^?-containing medium and subsequently incubated with different amounts of glucose. In the absence of mitochondrial energy production (blocked by CN^?) and glycogen catabolism (glycogen almost completely consumed during starvation), lactate production increased proportionally with increasing amounts of glucose. The generated ATP was almost completely consumed in the various ATP-consuming processes in the cell except for a fixed portion (about 7%) that was reserved for restoration of the adenylate energy charge. During the first 10 min after glucose addition, the adenine nucleotide pool remained constant. Thereafter, when the glycolytic flux, measured as lactate formation, was more than 3.5 μmol · min^?1 · 10^?11 cells, the pool increased slightly by resynthesis from hypoxanthine-inosine and then stabilized; at a lower flux the pool decreased and metabolic ATP and energy charge declined to values found during starvation. Between moments of rising and falling adenylate energy charges, periods of about 10 min remained in which the charge was constant and ATP supply and demand had reached equilibrium. This enabled comparison between the adenylate energy charge and ATP regeneration velocity. A linear relation was obtained for charge values between 0.4 and 0.85 and ATP regeneration rates between 0.6 and 3.5 ATP equiv. · min^?1 · 10^?11 cells. These data indicate that in starved platelets ATP regeneration velocity and energy charge are independent and that each appears to be subject to the availability of extracellular substrate.