Life cycle assessment of Australian automotive door skins

Background, aim, and scope  Policy initiatives, such as the EU End of Life Vehicle (ELV) Directive for only 5% landfilling by 2015, are increasing the pressure for higher material recyclability rates. This is stimulating research into material alternatives and end-of-life strategies for automotive components. This study presents a Life Cycle Assessment (LCA) on an Australian automotive component, namely an exterior door skin. The functional unit for this study is one door skin set (4 exterior skins). The material alternatives are steel, which is currently used by Australian manufacturers, aluminium and glass-fiber reinforced polypropylene composite. Only the inputs and outputs relative to the door skin production, use and end-of-life phases were considered within the system boundary. Landfill, energy recovery and mechanical recycling were the end-of-life phases considered. The aim of the study is to highlight the most environmentally attractive material and end-of-life option. Methods  The LCA was performed according to the ISO 14040 standard series. All information considered in this study (use of fossil and non fossil based energy resources, water, chemicals etc.) were taken up in in-depth data. The data for the production, use and end-of-life phases of the door skin set was based upon softwares such as SimaPro and GEMIS which helped in the development of the inventory for the different end-of-life scenarios. In other cases, the inventory was developed using derivations obtained from published journals. Some data was obtained from GM-Holden and the Co-operative research Centre for Advanced Automotive Technology (AutoCRC), in Australia. In cases where data from the Australian economy was unavailable, such as the data relating to energy recovery methods, a generic data set based on European recycling companies was employed. The characterization factors used for normalization of data were taken from (Saling et. al. Int J Life Cycle Assess 7(4):203–218 2002) which detailed the method of carrying out an LCA. Results  The production phase results in maximum raw material consumption for all materials, and it is higher for metals than for the composite. Energy consumption is greatest in the use phase, with maximum consumption for steel. Aluminium consumes most energy in the production phase. Global Warming Potential (GWP) also follows a trend similar to that of energy consumption. Photo Oxidants Creation Potential (POCP) is the highest for the landfill scenario for the composite, followed by steel and aluminium. Acidification Potential (AP) is the highest for all the end-of-life scenarios of the composite. Ozone Depletion Potential (ODP) is the highest for the metals. The net water emissions are also higher for composite in comparison to metals despite high pollution in the production phases of metallic door skins. Solid wastes are higher for the metallic door skins. Discussion  The composite door skin has the lowest energy consumption in the production phase, due to the low energy requirements during the manufacturing of E-glass and its fusion with polypropylene to form sheet molding compounds. In general, the air emissions during the use phase are strongly dependent on the mass of the skins, with higher emissions for the metals than for the composite. Material recovery through recycling is the highest in metals due to efficient separation techniques, while mechanical recycling is the most efficient for the composite. The heavy steel skins produce the maximum solid wastes primarily due to higher fuel consumption. Water pollution reduction benefit is highest in case of metals, again due to the high efficiency of magnetic separation technique in the case of steel and eddy current separation technique in the case of aluminium. Material recovery in these metals reduces the amount of water needed to produce a new door skin set (water employed mainly in the ingot casting stage). Moreover, the use of heavy metals, inorganic salts and other chemicals is minimized by efficient material recovery. Conclusions  The use of the studied type of steel for the door skins is a poor environmental option in every impact category. Aluminium and composite materials should be considered to develop a more sustainable and energy efficient automobile. In particular, this LCA study shows that glass-fiber composite skins with mechanical recycling or energy recovery method could be environmentally desirable, compared to aluminium and steel skins. However, the current limit on the efficiency of recycling is the prime barrier to increasing the sustainability of composite skins. Recommendations and perspectives  The study is successful in developing a detailed LCA for the three different types of door skin materials and their respective recycling or end-of-life scenarios. The results obtained could be used for future work on an eco-efficiency portfolio for the entire car. However, there is a need for a detailed assessment of toxicity and risk potentials arising from each of the four different types of door skin sets. This will require greater communication between academia and the automotive industry to improve the quality of the LCA data. Sensitivity analysis needs to be performed such as the assessment of the impact of varying substitution factors on the life cycle of a door skin. Incorporation of door skin sets made of new biomaterials need to be accounted for as another functional unit in future LCA studies. Discussion contributions to this article from the readership would the highly welcome. The authors     

Life cycle assessment of bioenergy systems: State of the art and future challenges

The use of different input data, functional units, allocation methods, reference systems and other assumptions complicates comparisons of LCA bioenergy studies. In addition, uncertainties and use of specific local factors for indirect effects (like land-use change and N-based soil emissions) may give rise to wide ranges of final results. In order to investigate how these key issues have been addressed so far, this work performs a review of the recent bioenergy LCA literature. The abundance of studies dealing with the different biomass resources, conversion technologies, products and environmental impact categories is summarized and discussed. Afterwards, a qualitative interpretation of the LCA results is depicted, focusing on energy balance, GHG balance and other impact categories. With the exception of a few studies, most LCAs found a significant net reduction in GHG emissions and fossil energy consumption when bioenergy replaces fossil energy.     

Life cycle assessment of biofuels: Energy and greenhouse gas balances

The promotion of biofuels as energy for transportation in the industrialized countries is mainly driven by the perspective of oil depletion, the concerns about energy security and global warming. However due to sustainability constraints, biofuels will replace only 10 to 15% of fossil liquid fuels in the transport sector. Several governments have defined a minimum target of GHG emissions reduction for those biofuels that will be eligible to public incentives, for example a 35% emissions reduction in case of biofuels in Members States of the European Union. This article points out the significant biases in estimating GHG balances of biofuels stemming from modelling choices about system definition and boundaries, functional unit, reference systems and allocation methods. The extent to which these choices influence the results is investigated. After performing a comparison and constructive criticism of various modelling choices, the LCA of wheat-to-bioethanol is used as an illustrative case where bioethanol is blended with gasoline at various percentages (E5, E10 and E85). The performance of these substitution options is evaluated as well. The results show a large difference in the reduction of the GHG emissions with a high sensitivity to the following factors: the method used to allocate the impacts between the co-products, the type of reference systems, the choice of the functional unit and the type of blend. The authors come out with some recommendations for basing the estimation of energy and GHG balances of biofuels on principles such as transparency, consistency and accuracy.     

Life cycle assessment of emerging environmental technologies in the early stage of development: A case study on nanostructured materials

The use of nanostructured materials has been recently proposed in the field of environmental nanoremediation. This approach consists in using nanomaterials not directly, but as building blocks for the design of nano‐porous micro‐dimensional systems, overcoming the eco‐ and health‐toxicology risks generally associated with the use of nano‐sized technologies. Herein we report the use of life cycle assessment (LCA) as an eco‐design tool for optimizing the production of cellulose nanosponges (CNS), nanostructured materials recently developed for water remediation purposes. LCA was applied from the acquisition of raw materials to the synthesis of CNS (from cradle‐to‐gate), considering three production systems, from the lab‐level to a modeled scale‐up system. The lab‐scale LCA identified the main environmental hotspots, namely the energy‐consuming steps and the final purification of the material (washing step). In a second lab‐scale production, an improvement action could be implemented, switching the washing solvent from methanol to water and decreasing the washing temperature. A second LCA showed a reduced contribution to the impacts from the materials, while the global impacts remained within the same order of magnitude. A simulated scale‐up of the process allowed to optimize the energy‐consuming steps and the water consumption, through internal recycling. A third LCA assessed the resulting benefits and a decrease in the global impacts by two orders of magnitude. Our study contributes to the discussion of LCA community, providing a focus on the importance of scaling‐up of emerging technologies, namely nanostructured porous materials, highlighting the benefits of a LCA based approach since the very beginning of product design (eco‐design).     

Life cycle assessment of printing and writing paper produced in Portugal

Goal, Scope and Background The environmental sustainability is one of the current priorities of the Portuguese pulp and paper industry. Life Cycle Assessment (LCA) was the methodology chosen to evaluate the sustainability of the printing and writing paper production activity. This paper grade represents about 60% of the total production of paper in Portugal and its production is expected to increase in the near future. The main goal of this study was to assess the potential environmental impacts associated with the entire life cycle of the printing and writing paper produced in Portugal from Eucalyptus globulus pulp and consumed in Germany, in order to identify the processes with the largest environmental impacts. Another goal of this study was to evaluate the effect on the potential environmental impacts of changing the market where the Portuguese printing and writing paper is consumed: German market vs. Portuguese market. Methods The main stages considered in this study were: forestry, pulp production, paper production, paper distribution, and paper final disposal. Transports and production of chemicals, fuels and energy in the grid were also included in these stages. Whenever possible and feasible, average or typical data from industry were collected. The remaining data were obtained from the literature and specialised databases. A quantitative impact assessment was performed for five impact categories: global warming over 100 years, acidification, eutrophication, non-renewable resource depletion and photochemical oxidant formation. Results In the German market scenario, the paper production stage was a remarkable hot spot for air emissions (non-renewable CO₂, NO_x and SO₂) and for non-renewable energy consumption, and, consequently, for the impact categories that consider these parameters: global warming, acidification and non-renewable resource depletion. These important environmental impacts are due to the energy requirements in the printing and writing paper production process, which are fulfilled by on-site fuel oil burning and consumption of electricity from the national grid, which is mostly based on the use of fossil fuels. The pulp production stage was identified as the largest contributor to water emissions (COD and AOX) and to eutrophication. Considering that energy consumed by the pulp production processes comes from renewable fuels, this stage was also the most contributing to renewable energy consumption. Discussion The paper distribution stage showed an important contribution to NO_x emissions, which, however, did not result in a major contribution to acidification or eutrophication. The final disposal stage was the main contributor to the photochemical oxidant formation potential due to CH₄ emissions from wastepaper landfilling. On the other hand, paper consumption in Portugal was environmentally more favourable than in Germany for the parameters/impact categories where the paper distribution stage has a significant contribution (non-renewable CO₂, NO_x, non-renewable energy consumption, acidification, eutrophication and non-renewable resource depletion) due to shorter distances needed to deliver paper to the consumers. For the remaining parameters/impact categories, the increase observed in the final disposal stage in the Portuguese market was preponderant, and resulted from the existence of significant differences in the final disposal alternatives in the analysed markets (recycling dominates in Germany, whereas landfilling dominates in Portugal). Conclusions The pulp and paper production stages were found to be of significance for almost all of the inventory parameters as well as for the impact assessment categories. The paper distribution and the final disposal stages were only of importance for some of the inventory parameters and some of the impact categories. The forestry stage played a minor role in the environmental impacts generated during the paper life cycle. The consumption of paper in Portugal led to a decrease in the environmental burdens of the paper distribution stage, but to an increase in the environmental burdens of the final disposal stage, when compared with the consumption of paper in Germany. Recommendations and Perspectives This study provides useful information that can assist the pulp and paper industry in the planning of future investments leading to an increase in its sustainability. The results of inventory analysis and impact assessment show the processes that play an important role in each impact category, which allow the industry to improve its environmental performance, making changes not only in the production process itself, but also in the treatment of flue gases and liquid effluents. Besides that concern regarding pollution prevention, other issues with relevance to the context of sustainability, such as the energy consumption, can also be dealt with.     

Yield and size of oyster mushroom grown on rice/wheat straw basal substrate supplemented with cotton seed hull

Oyster mushroom (Pleurotus ostreatus) was cultivated on rice straw basal substrate, wheat straw basal substrate, cotton seed hull basal substrate, and wheat straw or rice straw supplemented with different proportions (15%, 30%, and 45% in rice straw substrate, 20%, 30%, and 40% in wheat straw substrate) of cotton seed hull to find a cost effective substrate. The effect of autoclaved sterilized and non-sterilized substrate on growth and yield of oyster mushroom was also examined. Results indicated that for both sterilized substrate and non-sterilized substrate, oyster mushroom on rice straw and wheat basal substrate have faster mycelial growth rate, comparatively poor surface mycelial density, shorter total colonization period and days from bag opening to primordia formation, lower yield and biological efficiency, lower mushroom weight, longer stipe length and smaller cap diameter than that on cotton seed hull basal substrate. The addition of cotton seed hull to rice straw and wheat straw substrate slowed spawn running, primordial development and fruit body formation. However, increasing the amount of cotton seed hull can increase the uniformity and white of mycelium, yield and biological efficiency, and increase mushroom weight, enlarge cap diameter and shorten stipe length. Compared to the sterilized substrate, the non-sterilized substrate had comparatively higher mycelial growth rate, shorter total colonization period and days from bag opening to primordia formation. However, the non-sterilized substrate did not gave significantly higher mushroom yield and biological efficiency than the sterilized substrate, but some undesirable characteristics, i.e. smaller mushroom cap diameter and relatively long stipe length.     

Life cycle assessment comparison of wooden and plastic pallets in the grocery industry

Wooden and plastic pallets are used extensively in global trade to transport finished goods and products. This article compares the life cycle performance of treated wooden and plastic pallets through a detailed cradle‐to‐grave life cycle assessment (LCA), and conducts an analysis of the various phytosanitary treatments. The LCA investigates and evaluates the environmental impacts due to the resources consumed and emissions of the product throughout its life cycle. The environmental impacts of the pallets are compared on a one‐trip basis and a 100,000‐trips basis. Impact categories are chosen with respect to environmental concerns. The results show that on a one‐trip basis, wooden pallets with conventional and radio frequency (RF) heat treatment incur an overall carbon footprint of 71.8% and 80.3% lower, respectively, than plastic pallets during their life cycle; and in comparison with wooden pallets treated with methyl bromide fumigation, they incur 20% and 30% less overall carbon footprint. Theoretical calculations of the resource consumption and emissions of RF treatment of pallets suggest that dielectric technology may provide a lower‐carbon alternative to both current ISPM 15‐approved treatments and to plastic pallets. Methyl bromide fumigation (15.95 kg CO₂ equivalent [eq.]) has a larger carbon footprint than conventional heat treatment (12.69 kg CO₂ eq.) of pallets. For the 100,000‐trips basis, the differences are even more significant. The results recommend that wooden pallets are more environmentally friendly than plastic pallets, and conventional and RF heat treatment for wooden pallets is more sustainable than methyl bromide fumigation treatment.     

Life cycle assessment and socioeconomic evaluation of the illicit crop substitution policy in Colombia

The peace treaty of Colombia contemplates a crop substitution policy seeking to replace coca crops with legal alternatives. Although crop substitution diverts funding of illegal activities and provides an income to farmers, it is important to understand how the change to a variety of legal crops (coffee, sugarcane, and cacao) affects the income of farmers, and whether there is an environmental advantage of a crop over another. This study applies life cycle assessment (LCA) coupled with socioeconomic indicators to two regions, Putumayo and Catatumbo, over different policy scenarios. LCA results show that a policy success does not ensure a lower environmental impact across the board. Legal crops consume less fuel than coca crops, which reduce fuel‐related impacts, but the use of fertilizer in coffee and pesticide use in sugarcane increase toxicity‐related impacts. The results, however, are affected by a lack of characterization factors of agrochemicals, but once these are replaced by proxies, coca crops appear to have greater toxicity impacts. In terms of individual crops, cacao crops have a lower environmental impact than coffee and sugarcane, but it also takes the longest to harvest, which may pose a financial risk to farmers. The socioeconomic analysis reveals that for Catatumbo farmers, a policy success reduces the income, whereas for Putumayo farmers, a policy success increases income and job generation. In general, it was observed that the dynamics of the illegal supply chain vary for each region, influencing the environmental and socioeconomic outcome of the substitution policy.     

Comparative life cycle assessment of centralized and distributed biomass processing systems combined with mixed feedstock landscapes

Lignocellulosic biofuels can help fulfill escalating demands for liquid fuels and mitigate the environmental impacts of petroleum‐derived fuels. Two key factors in the successful large‐scale production of lignocellulosic biofuels are pretreatment (in biological conversion processes) and a consistent supply of feedstock. Cellulosic biomass tends to be bulky and difficult to handle, thereby exacerbating feedstock supply challenges. Currently, large biorefineries face many logistical problems because they are fully integrated, centralized facilities in which all units of the conversion process are present in a single location. The drawbacks of fully integrated biorefineries can potentially be dealt by a network of distributed processing facilities called ‘Regional Biomass Processing Depots’ (RBPDs) which procure, preprocess/pretreat, densify and deliver feedstock to the biorefinery and return by‐products such as animal feed to end users. The primary objective of this study is to perform a comparative life cycle assessment (LCA) of distributed and centralized biomass processing systems. Additionally, we assess the effect that apportioning land area to different feedstocks within a landscape has on the energy yields and environmental impacts of the overall systems. To accomplish these objectives, we conducted comparative LCAs of distributed and centralized processing systems combined with farm‐scale landscapes of varying acreages allocated to a ‘corn‐system’ consisting of corn grain, stover and rye (grown as a winter double crop) and two perennial grasses, switchgrass and miscanthus. The distributed processing system yields practically the same total energy and generates 3.7% lower greenhouse gas emissions than the centralized system. Sensitivity analyses identified perennial grass yields, biomass densification and its corresponding energy requirements, transport energy requirements and carbon sequestration credits for conversion from annual to perennial crops as key parameters that significantly affect the overall results.     

Integrating life cycle costs and environmental impacts of composite rail car-bodies for a Korean train

Background, aim, and scope  A coupled Life Cycle Costing and life cycle assessment has been performed for car-bodies of the Korean Tilting Train eXpress (TTX) project using European and Korean databases, with the objective of assessing environmental and cost performance to aid materials and process selection. More specifically, the potential of polymer composite car-body structures for the Korean Tilting Train eXpress (TTX) has been investigated. Materials and methods  This assessment includes the cost of both carriage manufacturing and use phases, coupled with the life cycle environmental impacts of all stages from raw material production, through carriage manufacture and use, to end-of-life scenarios. Metallic carriages were compared with two composite options: hybrid steel-composite and full-composite carriages. The total planned production for this regional Korean train was 440 cars, with an annual production volume of 80 cars. Results and discussion  The coupled analyses were used to generate plots of cost versus energy consumption and environmental impacts. The results show that the raw material and manufacturing phase costs are approximately half of the total life cycle costs, whilst their environmental impact is relatively insignificant (3–8%). The use phase of the car-body has the largest environmental impact for all scenarios, with near negligible contributions from the other phases. Since steel rail carriages weigh more (27–51%), the use phase cost is correspondingly higher, resulting in both the greatest environmental impact and the highest life cycle cost. Compared to the steel scenario, the hybrid composite variant has a lower life cycle cost (16%) and a lower environmental impact (26%). Though the full composite rail carriage may have the highest manufacturing cost, it results in the lowest total life cycle costs and lowest environmental impacts. Conclusions and recommendations  This coupled cost and life cycle assessment showed that the full composite variant was the optimum solution. This case study showed that coupling of technical cost models with life cycle assessment offers an efficient route to accurately evaluate economic and environmental performance in a consistent way.     

Life cycle assessment in the minerals and metals sector: a critical review of selected issues and challenges

Background, aim and scope

The mining sector provides materials that are essential elements in a wide range of goods and services, which create value by meeting human needs. Mining and processing activities are an integral part of most complex material cycles so that the application of life cycle assessment (LCA) to minerals and metals has therefore gained prominence. In the past decade, increased use of LCA in the mineral and metal sector has advanced the scientific knowledge through the development of scientifically valid life cycle inventory databases. Though scientifically valid, LCA still needs to depend on several technical assumptions. In particular, measuring the environmental burden issues related to abiotic resource depletion, land use impacts and open-loop recycling within the LCA are widely debated issues. Also, incorporating spatial and temporal sensitivities in LCA, to make it a consistent scientific tool, is yet to be resolved. This article discusses existing LCA methods and proposed models on different issues in relation to minerals and metals sector.

Main features

A critical review was conducted of existing LCA methods in the minerals and metals sector in relation to allocation issues related to indicators of land use impacts, abiotic resource depletion, allocation in open-loop recycling and the system expansions and accounting of spatial and temporal dimension in LCA practice.

Results

Evolving a holistic view about these contentious issues will be presented with view for future LCA research in the minerals and metals industry. This extensive literature search uncovers many of the issues that require immediate attention from the LCA scientific community.

Discussion

The methodological drawbacks, mainly problems with inconsistencies in LCA results for the same situation under different assumptions and issues related to data quality, are considered to be the shortcomings of current LCA. In the minerals and metals sector, it is important to increase the objectivity of LCA by way of fixing those uncertainties, for example, in the LCA of the minerals and metals sector, whether the land use has to be considered in detail or at a coarse level. In regard to abiotic resource characterisation, the weighting and time scales to be considered become a very critical issue of judgement. And, in the case of open-loop recycling, which model will best satisfy all the stake holders? How the temporal and spatial dimensions should be incorporated into LCA is one of the biggest challenges ahead of all those who are concerned. Addressing these issues shall enable LCA to be used as a policy tool in environmental decision-making. There has been enormous debate with respect to on land use impacts, abiotic resource depletion, open-loop recycling and spatial and temporal dimensions, and these debates remain unresolved. Discussions aimed at bringing consensus amongst all the stake holders involved in LCA (i.e. industry, academia, consulting organisations and government) will be presented and discussed. In addition, a commentary of different points of view on these issues will be presented.

Conclusions

This review shall bring into perspective some of those contentious issues that are widely debated by many researchers. The possible future directions proposed by researchers across the globe shall be presented. Finally, authors conclude with their views on the prospects of LCA for future research endeavours.

Recommendations and outlook

Specific LCA issues of minerals and metals need to be investigated further to gain more understanding. To facilitate the future use of LCA as a policy tool in the minerals and metals sector, it is important to increase the objectivity with more scientific validity. Therefore, it is essential that the issues discussed in this paper are addressed to a great detail.     

Life cycle assessment of emerging technologies: Evaluation techniques at different stages of market and technical maturity

Life cycle assessment (LCA) analysts are increasingly being asked to conduct life cycle‐based systems level analysis at the earliest stages of technology development. While early assessments provide the greatest opportunity to influence design and ultimately environmental performance, it is the stage with the least available data, greatest uncertainty, and a paucity of analytic tools for addressing these challenges. While the fundamental approach to conducting an LCA of emerging technologies is akin to that of LCA of existing technologies, emerging technologies pose additional challenges. In this paper, we present a broad set of market and technology characteristics that typically influence an LCA of emerging technologies and identify questions that researchers must address to account for the most important aspects of the systems they are studying. The paper presents: (a) guidance to identify the specific technology characteristics and dynamic market context that are most relevant and unique to a particular study, (b) an overview of the challenges faced by early stage assessments that are unique because of these conditions, (c) questions that researchers should ask themselves for such a study to be conducted, and (d) illustrative examples from the transportation sector to demonstrate the factors to consider when conducting LCAs of emerging technologies. The paper is intended to be used as an organizing platform to synthesize existing methods, procedures and insights and guide researchers, analysts and technology developer to better recognize key study design elements and to manage expectations of study outcomes.     

Environmental impacts and limitations of third‐generation biobutanol: Life cycle assessment of n‐butanol produced by genetically engineered cyanobacteria

Photosynthetic cyanobacteria have attracted interest as production organisms for third‐generation biofuels, where sunlight and CO₂ are used by microbes directly to synthesize fuel molecules. A particularly suitable biofuel is n‐butanol, and there have been several laboratory reports of genetically engineered photosynthetic cyanobacteria capable of synthesizing and secreting n‐butanol. This work evaluates the environmental impacts and cumulative energy demand (CED) of cyanobacteria‐produced n‐butanol through a cradle‐to‐grave consequential life cycle assessment (LCA). A hypothetical production plant in northern Sweden (area 1 ha, producing 5–85 m³ n‐butanol per year) was considered, and a range of cultivation formats and cellular productivity scenarios assessed. Depending on the scenario, greenhouse gas emissions (GHGe) ranged from 16.9 to 58.6 gCO₂eq/MJ_BuOH and the CED from 3.8 to 13 MJ/MJ_BuOH. Only with the assumption of a nearby paper mill to supply waste sources for heat and CO₂ was the sustainability requirement of at least 60% GHGe savings compared to fossil fuels reached, though placement in northern Sweden reduced energy needed for reactor cooling. A high CED in all scenarios shows that significant metabolic engineering is necessary, such as a carbon partitioning of >90% to n‐butanol, as well as improved light utilization, to begin to displace fossil fuels or even first‐ and second‐generation bioethanol.     

Mechanical properties of chitosan/bamboo charcoal composite films made with normal and surface oxidized charcoal

Chitosan/bamboo charcoal composite films were prepared by blending chitosan with either virgin bamboo charcoal or bamboo charcoal modified by nitric acid oxidation to provide more hydrophilic regions on the bamboo charcoal surface. Investigation of the physical properties of these composite films revealed that the tensile strength and Young’s modulus of the chitosan films were enhanced in a dose-dependent manner by the inclusion of modified bamboo charcoal at up to 1% (w/w), whilst the elongation at break was increased by inclusion of modified bamboo charcoal at up to 0.5% (w/w). In contrast, chitosan composites with virgin bamboo charcoal at up to 0.5% or 1.0% (w/w) showed no enhancement of the tensile strength or Young’s modulus, respectively, and both parameters were reduced with higher levels of virgin bamboo charcoal. Oil, and especially water, absorption of the composite films displayed a marked and dose-dependent increase compared to those of the pure chitosan film.     

Life cycle assessment of district heat distribution in suburban areas using PEX pipes insulated with expanded polystyrene

Goal, Scope and Background

Combined heat and power (CHP) is a strategy aimed at reducing the impact of the energy sector on the climate by more efficient use of the energy content of the fuel. The implementation of CHP requires the utilisation of the heat produced. Space heating by means of district heating is one possible use for such heat. In countries such as Sweden, where district heating is already extensively used, many multiapartment buildings are connected to district heating. For increased use, the distribution systems will have to expand into suburbs with single family homes. However, the environmental impact and cost of the district heat distribution system increase when the pipe networks are extended into such areas. This is due to the production and installation of longer pipe networks and increased heat losses from the system. Attempts have been made to find new types of pipe constructions in order to lower the costs of connecting single family homes to district heating. These should be evaluated from an environmental perspective. The EPSPEX system is a distribution system intended for suburban areas. This system consists of cross-linked polyethylene (PEX) pipes in insulating blocks of expanded polystyrene (EPS). This paper presents a life cycle assessment of the EPSPEX district heat distribution system. In a second scenario, sub-stations were added. The results indicate areas that require improvement and provide a basis for comparison with other types of district heat distribution systems.

Methods

Production, network construction and use of the district heat system were studied by means of life cycle methodology, employing specific data for the EPSPEX system and generic data for upstream impacts of the materials used. The system constructed in Vråen, Värnamo, Sweden, in 2002 was studied. The district heating used in Vråen is mainly based on biofuels. The functional unit was the use of one metre of an EPSPEX district heating system over a period of one year. The expected system life was 30 years. The results were characterised as global warming potential, acidification potential, eutrophication potential and the use of finite resources, as well as weighted by EPS 2000, ExternE and EcoIndicator 99. No external review was performed, but a reference group of district heating experts familiar with the practice has reviewed the study.

Results

Heat losses are clearly the main environmental impact in all characterisations and weightings (71–92% of the total impact), despite the fact that the heat production studied was mainly based on biomass combustion, generally perceived to be environmentally friendly. Of the system components, the production of EPS insulation blocks had the largest environmental impact.

Discussion

This impact, however, is compensated for by the fact that the need to produce less heat leads to a lower level of emissions. Several characterisation methods revealed that the production and combustion of diesel for excavating the pipe trench has a significant environmental impact. The jointing brass swaged coupling used for the PEX fluid pipes has a surprisingly high impact in terms of acidification and EPS 2000, considering the small amount of brass in the system.

Conclusions

The life cycle environmental impact is dominated by the heat production needed to compensate for heat losses from the system, despite the fact that the EPSPEX system is relatively well insulated compared to a conventional district heating system. It is possible to shut down the heating circuit and only use the hot tap water circuit during the summer months; this reduces the heat losses and is an advantageous feature of the system. The second largest environmental impact of the EPSPEX system arises from the production of the EPS insulation blocks. A decrease in nitrogen oxide emissions, especially those caused by the excavation and filling of pipe trenches, would be beneficial. A rough comparison has been made with available literature data for conventional DN25 twin pipes. The results indicate that the environmental impact of the EPSPEX system is probably lower. However, the pipes are not identical, as the water delivery capacity of the conventional pipe is slightly lower.

Recommendations and Perspectives

In Sweden, new types of pipes are being developed for district heating in suburban areas, and there is a need for an environmental comparison between such new alternatives and previous results for conventional polyurethane insulated steel pipes. This study reveals that biofuels, although perceived to be environmentally friendly, must be used with caution in order to ensure a satisfactory environmental performance. Heat loss from district heating should be minimized also when biofuels are used. The most immediate way to reduce such environmental impact is to increase the insulation. The environmental trade-off between lower heat losses achieved by the use of more insulation and the production of greater amounts of insulation material should be further studied.

     

A characterization model with spatial and temporal resolution for life cycle impact assessment of photochemical precursors in the United States

Background, aim, and scope  Traditional life cycle impact assessment methodologies have used aggregated characterization factors, neglecting spatial and temporal variations in regional impacts like photochemical oxidant formation. This increases the uncertainty of the LCA results and diminishes the ease of decision-making. This study compares four common impact assessment methods, CML2001, Eco-indicator 99, TRACI, and EDIP2003, on their underlying models, spatial and temporal resolution, and the level at which photochemical oxidant impacts are calculated. A new characterization model is proposed that incorporates spatial and temporal differentiation. Materials and methods  A photochemical air quality modeling system (CAMx-MM5-SMOKE) is used to simulate the process of formation, transformation, transport, and removal of photochemical pollutants. Monthly characterization factors for individual US states are calculated at three levels along the cause–effect chain, namely, fate level, human and ecosystem exposure level, and human effect level. Results and discussion  The results indicate that a spatial variability of one order of magnitude and a temporal variability of two orders of magnitude exist in both the fate level and human exposure and effect level characterization factors for NO_x. The summer time characterization factors for NO_x are higher than the winter time factors. However, for anthropogenic VOC, the summer time factors are lower than the winter time in almost half of the states. This is due to the higher emission rates of biogenic VOCs in the summer. The ecosystem exposure factors for NO_x and VOC do not follow a regular pattern and show a spatial variation of about three orders of magnitude. They do not show strong correlation with the human exposure factors. Sensitivity analysis has shown that the effect of meteorology and emission inputs is limited to a factor of three, which is several times smaller than the variation seen in the factors. Conclusions  Uncertainties are introduced in the characterization of photochemical precursors due to a failure to consider the spatial and temporal variations. Seasonal variations in photochemical activity influence the characterization factors more than the location of emissions. The human and ecosystem exposures occur through different mechanisms, and impacts calculated at the fate level based only on ozone concentration are not a good indicator for ecosystem impacts. Recommendations and perspectives  Spatial and temporal differentiation account for fate and transport of the pollutant, and the exposure of and effect on the sensitive human population or ecosystem. Adequate resolution for seasonal and regional processes, like photochemical oxidant formation, is important to reduce the uncertainty in impact assessment and improve decision-making power. An emphasis on incorporating some form of spatial and temporal information within standard LCI databases and using adequately resolved characterization factors will greatly increase the fidelity of a standard LCA. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Environmental Evaluation of Industry Cluster Strategies with a Life Cycle Perspective: Replacing Fossil Feedstock with Forest‐Based Feedstock and Increasing Thermal Energy Integration

Symbiotic linkages in industry clusters in the form of interconnected materials, energy and information flows, and close proximity provide unique opportunities to develop efficient environmental strategies. The purpose of our study is to examine the practical potential of applying a life cycle approach in strategy evaluations, as the environmental impact caused by industrial symbiosis systems outside the company gates has been scarcely addressed. This is done by evaluating two strategies for an industry cluster in Sweden: (1) to replace a share of the fossil feedstock used in the industry cluster with forest‐based feedstock and (2) to improve energy efficiency through thermal energy integration. The environmental impact reduction potential of the strategies is evaluated using life cycle assessment. The ratio between investment cost and reduced global warming potential is used as an indicator to evaluate the cost‐effectiveness of the strategies. Results demonstrate the importance of applying a life cycle perspective as the assessment outcome depends heavily on whether only on‐site consequences are assessed or if upstream and downstream processes are also included. 20% of the greenhouse gas emission reduction of the energy integration strategy occurs off‐site, whereas the forest strategy has the largest reduction potential off‐site, >80%.     

有机物料与锌肥配施对石灰性土壤锌有效性及形态转化的影响

采用尼龙网袋田间填埋培养法探究了外源施锌条件下石灰性土壤Zn有效性及形态转化对不同有机物料(作物秸秆、生物菌肥、黄腐酸和腐熟鸡粪)的响应.结果表明:与对照相比,Zn肥单施和与有机物料配施均显著提高了土壤全Zn含量(7.2%~13.8%)和DTPA-Zn含量(2.1~2.8倍).在施Zn条件下,有机物料对土壤全Zn和DTPA-Zn的贡献量表现为腐熟鸡粪>生物菌肥>玉米秸秆>黄腐酸,但外源锌的DTPA-Zn转化率以添加秸秆和生物菌肥处理最高.与单施Zn肥相比,有机物料与Zn配施处理显著提高了土壤有机质含量,促进了松结有机态Zn的形成,进而提高了土壤Zn转移因子,降低了Zn分配指数.不同物料与Zn肥配施土壤Zn有效性及形态转化之间存在差异,这可能与有机物料自身性质如腐熟度和含Zn量有关.尽管秸秆与Zn配施对DTPA-Zn含量的提升效果不及生物菌肥或腐熟鸡粪与Zn配施,但综合考虑环境和经济效益,其仍是改善缺锌石灰性土壤Zn有效性的最佳选择.