石膏改良苏打碱土.Ⅰ.经济改良层石膏用量的确定

石膏可以改良盐碱土,室内土柱淋洗试验是验证其改良效果的方法之一。本文将石膏计划改良层定为40cm,计算的定量石膏与0～10cm土层混匀后,装填0～40cm土柱于室内进行分次淋洗试验,将收集的滤液测定溶液离子组成并换算成盐分,应用推理计算法分析石膏溶解、转化、渗漏情况,以及石膏与碱性盐及交换性钠镁作用量。结果表明:将石膏与表层0～10cm土层混匀条件下,4次灌水后,0～40cm的土层物理通透性改善,渗透时间变小,pH由9.25降到8.20,碱化度均基本达到10,而且还有残余石膏,应用推理计算法得出,最经济纯石膏理论改良用量为0.05t·hm-2。     

Sodic Soil Properties and Sunflower Growth as Affected by Byproducts of Flue Gas Desulfurization

The main component of the byproducts of flue gas desulfurization (BFGD) is CaSO₄, which can be used to improve sodic soils. The effects of BFGD on sodic soil properties and sunflower growth were studied in a pot experiment. The experiment consisted of eight treatments, at four BFGD rates (0, 7.5, 15 and 22.5 t ha⁻¹) and two leaching levels (750 and 1200 m³ ha⁻¹). The germination rate and yield of the sunflower increased, and the exchangeable sodium percentage (ESP), pH and total dissolved salts (TDS) in the soils decreased after the byproducts were applied. Excessive BFGD also affected sunflower germination and growth, and leaching improved reclamation efficiency. The physical and chemical properties of the reclaimed soils were best when the byproducts were applied at 7.5 t ha⁻¹ and water was supplied at 1200 m³·ha⁻¹. Under these conditions, the soil pH, ESP, and TDS decreased from 9.2, 63.5 and 0.65% to 7.8, 2.8 and 0.06%, and the germination rate and yield per sunflower reached 90% and 36.4 g, respectively. Salinity should be controlled by leaching when sodic soils are reclaimed with BFGD as sunflower growth is very sensitive to salinity during its seedling stage.     

Salt impacts on organic carbon and nitrogen leaching from senesced vegetation

Senesced vegetation is exposed to a wide range of salt concentrations in surface waters resulting from human activities which include deicing salts and irrigation water chemistry. Both dissolved organic carbon (DOC) and salt concentrations are rising in northern hemisphere watersheds, yet there has been little investigation of sodium as a potential mechanism for DOC increases. The objective of this study was to investigate the impact of solution sodicity and salinity on DOC and dissolved organic nitrogen (DON) leaching from five types of senesced and cut vegetation. Vegetation was soaked for 24 h in a series of sodium chloride (NaCl)–calcium chloride (CaCl₂) solutions with sodium adsorption ratios (SAR) of 2, 10, or 30 and electrical conductivities of 0.1 dS m^?1 through 3.0 dS m^?1. Vegetation was also soaked in a sodium bicarbonate (NaHCO₃) solution at SAR = 30 and stream water from local watersheds with a range of sodicity and salinity. The mass of both DOC and DON released increased as SAR increased in the NaCl solutions, but the total salinity had inconsistent effects on DOC and DON release. NaHCO₃ leached similar amounts of DOC and DON as NaCl. The SAR of the stream water solutions was able to explain 88 % of the variability in DOC leached from vegetation (p < 0.05). The results indicated that sodicity, quantified by SAR, had a significant impact on DOC and DON leaching from senesced vegetation and could be a potential mechanism to explain the observed increases in surface water DOC.     

Copper removal from an industrial waste by bioleaching

Summary Copper contained in a solid industrial waste produced in a silicone manufacturing process was leached with spent iron medium from aThiobacillus ferrooxidans culture. Most effective leaching was observed in a continuously fed, dual reactor system. Spent iron medium was generated by growingT. ferrooxidans in 0.9 K iron medium at pH 1.5 in the first reactor, and was transferred to a second reactor in which it leached the copper from the waste. Leaching was effective at a pulp density of the waste material as high as 20%. In experiments run at a pulp density of 2.5%, the spent iron medium was most efficient in leaching copper when it was first diluted 100-fold with a mineral salts solution at pH 1.5. Removal of the copper from the waste appeared to involve its displacement by acid, dissolved mineral salts, and ferric iron. Potentials for practical application of this process are discussed.     

Effect of sulphur inoculated with Thiobacillus on soil salinity and growth of tropical tree legumes.

A greenhouse experiment was carried out with the objective of evaluating the effects of the elementary sulphur inoculated with Thiobacillus, compared with gypsum, in the amendment of a alluvial sodic saline soil from the Brazilian semiarid region, irrigated with saline water and grown with the tropical legumes leucena and mimosa. The treatments consisted of levels of sulphur (0; 300 and 600 kg/ha) and gypsum (1,200 and 2,400 kg/ha), irrigation using different waters containing the salts NaHCO3, MgCl2, CaCl2, NaCl and KCl, with different electrical conductivities (ECs: 0.2. 6.1 and 8.2 dS/m at 25 degrees C). Based on the results it appears that saline water increased exchangeable Na+, K+, Ca2+, Mg2+, and soil pH. Sulphur inoculated with Thiobacillus was more efficient than gypsum in the reduction of the exchangeable sodium of the soil and promoting leaching of salts, especially sodium. Sulphur inoculated with Thiobacillus reduced the EC of the soil saturation extract to levels below that adopted in soil classification of sodic or saline sodic. Leucena was more tolerant to salinity and mimosa more resistant to acidity promoted by sulphur inoculated with Thiobacillus.     

Preliminary evaluation of H2SO4 application methods to soils

Summary The effects of sulfuric acid application to soils and water on growth and chemical composition of sorghum (Sorghum bicolor) were compared in a greenhouse experiment using high sodium bicarbonate irrigation water. Significant increases in dry matter yield and plant uptake of P en Fe were produced only by soil treatment of calcareous soils.Contribution from the Department of Soils, Water and Engineering, The University of Arizona, Tucson, Arizona 85721, as Technical Paper No. 2320. This work was supported by the Arizona Mining Association.Research assistants and Professor     

Radiolysis,racemization, and the origin of optical activity

An investigation has been undertaken to determine whether ionizing radiation might engender racemization (radioracemization) of optically active amino acids, along with their well-known radiolysis. We have exposed a number of solid and dissolved optically active amino acids to the ionizing radiation from a 3000-Ci ⁶⁰Co γ-ray source for periods of time which would engender substantial, but not total radiolysis. γ-Ray doses which caused 55–68% radiolysis of solid amino acids typically engendered 2–5% racemization. Aqueous solutions of the sodium salts of amino acids which underwent 53–66% radiolysis typically showed 5–11% racemization. The corresponding hydrochloride salts in aqueous solution, however, underwent little or no racemization. In aqueous solution both percentage degradation and percentage racemization were approximately proportional to γ-ray dosage within the range employed (1–36 × 10⁶ rads). Mechanisms for the radioracemization of amino acids in the solid state and as dissolved sodium salts are proposed, and the absence of racemization for dissolved hydrochloride salts is rationalized. Implications of these observations with regard to the origin of optical activity by the Vester-Ulbricht β-decay mechanism are discussed, as are their implications regarding the use of diagenetic racemization rates of ancient amino acid samples as criteria for geochronological and geothermometric calculations.     

Effect of brewery sludge amendments on some chemical properties of acid soil in pot experiments

A laboratory experiment was performed for an incubation period of 120 days in order to evaluate the changes in chemical properties of an acid soil amended with 0, 15, 30, 60 and 120 t ha-' of brewery sludge (BS). Increasing BS rates and incubation time reduced pH of the soil by 0.3-0.5 unit with respect to the control while soluble salts increased from 0.11 to 0.80 dS m(-1). Organic C, exchangeable cations, soluble cations and anions, NH4+-N and NO3--N contents of the amended soil increased as BS rates increased. In addition, BS application caused a slight increase in cation exchange capacity (CEC) and a slight decrease in exchangeable acidity.     

Effect of saline acclimation on body water and sodium compartmentalization in Pekin ducks (Anas platyrhynchos)

The compartmentalization of body fluids was measured in individual Pekin ducks ( Anas platyrhynchos) drinking freshwater and after sequential acclimation to 300 mM NaCl and 400 mM NaCl. Total body water, extracellular fluid volume, plasma volume and exchangeable sodium pool were measured using (3)H(2)O, [(14)C]-polyethylene glycol, Evans Blue dye, and (22)Na dilution, respectively. Following acclimation to 300 mM NaCl, body mass decreased, but total body water and total exchangeable sodium pool were unaltered. Na and water were redistributed from the extracellular fluid (interstitial fluid) compartment into the intracellular fluid compartment. Following further acclimation to 400 mM NaCl, body mass, total body water and intracellular fluid volume decreased, but exchangeable sodium pool and extracellular fluid volume were unchanged. Our results suggested that, when Pekin ducks drink high but tolerable salinities, they maintain total body water, but redistribute Na(+) and water from interstitial fluid to the intracellular fluid compartment. When stressed beyond their ability to maintain total body water, they lose water from the intracellular fluid.     

Long-term availability of nutients in forest soil derived from fast- and slow-release fertilizers

The availability of P, K and Mg was studied in boreal forest soil treated 10 years earlier with slow- and fast-release fertilizers. Fast release superphosphate, potassium chloride and magnesium sulphate and slow-release apatite (P) and biotite (K, Mg) were applied alone or together with urea or urea+limestone. The concentrations of total and exchangeable nutrients in the organic horizon and the concentration of exchangeable nutrients in the uppermost mineral horizon were measured. CO₂ production during aerobic laboratory incubation was used to estimate the microbial activity and substrate-induced respiration to determine the microbial biomass C in soil. Biotite caused a moderate but persistent increase in pH in the organic horizon, but this increase was smaller than with lime. The fast-release fertilizers had no effects on the nutrient status of the soil 10 years after the fertilization. However, apatite and biotite still increased the total content of Mg, K and P and the concentrations of exchangeable Mg and soluble P in soil. On the other hand, simultaneous addition of lime and biotite reduced the release of soluble P from apatite. The reduction in soil microbial activity found with urea and the fast-release salts soon after application was no longer evident 10 years later. There was no increase in nitrification in the fertilized soils, not even with the urea+lime treatment. The previous results right after the application and the results presented here do not indicate major leaching of nutrients from the slow-release fertilizers to the deeper soil profiles.     

Zonation pattern of an isolated mangrove community at Playa Medina,Venezuela

This study focuses on a mangrove system which is completely isolated from the sea, lacking any connecting tidal channels or creeks and far enough from the coastline to prevent tidal flushing. The reason why it has become isolated remains unclear. But it is obvious that this situation may have introduced important changes in soil salinity and hydrological patterns, which might be reflected in the present composition and zonation patterns of the mangrove community. Main findings of this study suggest that: (1) Plant species distribution is affected mainly by water logging and mineral content of soils. (2) Ground water is the only permanent supply of water and salts to the isolated mangrove. (3) Soils are subjected to different degrees of leaching of salts. (4) The K: Na ratios support that mangrove community is not subjected to salinity stress. (5) Continuous leaching of salts favor the advance of terrestrial non-halophytes plants.     

Bile salt related secretion of acid phosphatase in rat bile

The biliary excretion of bile salts, lysosomal acid phosphatase, and total proteins were studied in rats under different experimental conditions: during bile salt loss through a bile fistula and after loading with exogenous sodium taurocholate. The experimental models were suitable to demonstrate that variations in the excretion of bile salts were associated with those of acid phosphatase output. During bile salt depletion, acid phosphatase output showed a decrease parallel to that of bile salts. Following a single i.v. injection of sodium taurocholate and during its i.v. infusion, a rapid increase of acid phosphatase excretion in bile was seen. The patterns of enzyme outputs observed after administration of sodium taurocholate suggested a bulk discharge in bile of lysosomal contents. The profiles of protein output were similar to those of acid phosphatase suggesting an association between the secretory mechanism of these bile constituents. In contrast to sodium taurocholate, 4-methylumbelliferone, which also increases canalicular bile flow, did not produce changes in the excretory patterns of the bile components studied. Therefore, the results suggested a bile salt related secretion of acid phosphatase in the rat, which may involve protein secretion in bile.     

Leaching of nitrogen from subtropical soils as affected by nitrification potential and base cations

A soil column method was used to determine the effect of nitrification on leaching of nitrate and ammonium from three acid subtropical soils after application of ammonium bicarbonate. Three soils, designated QF, GB and SU, derived from Quaternary red earth, granite and tertiary red sandstone, were collected from forest land, brush land and upland field, ranged in nitrification potential and cation exchange capacity. The results indicated that nitrate leaching increased with the soil nitrification potential. The soils with higher nitrification potential had a higher nitrate peak concentration and required a shorter time to reach it. In soils QF and GB with low cation exchange capacity, and a low content of exchangeable base cations, there were not sufficient base cations to accompany the nitrate leached with the result that ammonium and hydrogen ions were leached from the soil, and pH changes occurred in different layers of the soil column.     

Effect of sulfuric acid on sodium-hazard of irrigation water

Summary The sodium adsorption ratio (SAR), exchangeable sodium percentage (ESP) and saturated hydraulic conductivity were measured under laboratory conditions in one neutral and four calcareous soils using simulated alkaline irrigation waters having salt concentrations ranging from 7 to 39 meq/l with the SAR from 3.8 to 8.4. Sulfuric acid was applied to the waters at sufficient rates to prevent calcium precipitation under an open system, ranging from 2.1 to 4.7 meq/l. At these acid rates, the pH of irrigation waters remained above neutral. This treatment reduced SAR and ESP in all cases tested, and increased the hydraulic conductivity of some soils when the SAR of the original irrigation waters was greater than approximately 7. The experimentally determined SAR was then compared with the values predicted based on some of the existing theories. The results indicated that the conventional method to estimate SAR with adjustment using the pH_C index of Langelier overestimates the effect of HCO₃ ^-, whereas the equation based on carbonate equibria gives a reasonable prediction of SAR in waters containing HCO₃ ^- as well as H₂SO₄. The SAR calculated by the latter method was also linearly related to the measured ESP with an equation, ESP=0.761 SAR, r²=0.986.Arizona Agr. Exp. Sta. J. No. 2449. Contribution from the Department of Soils, Water and Engineering. The University of Arizona, Tucson 85721. Supported in part by a grant from the Arizona Mining Association.Arizona Agr. Exp. Sta. J. No. 2449. Contribution from the Department of Soils, Water and Engineering. The University of Arizona, Tucson 85721. Supported in part by a grant from the Arizona Mining Association.     

Effects of water quality changes on phytoplankton and lesser flamingo Phoeniconaias minor populations at Kamfers Dam,a saline wetland near Kimberley,South Africa

Kamfers Dam, a wetland near Kimberley, South Africa, supports a population of Near Threatened lesser flamingos Phoeniconaias minor. The cyanobacterium Arthrospira fusiformis (Voronikhin) Komarek and Lund 1990, the flamingos’ food source, was in bloom in April 2009. The city's wastewater treatment plant discharges partially treated and untreated sewage directly into Kamfers Dam, creating elevated water levels, poor water quality and hypereutrophication. Subsequently, a crash in the A. fusiformis population compromised the lesser flamingos’ food source. The water quality and algal community of Kamfers Dam were monitored using historical water quality data plus water quality analyses from 2009 to 2011. Conductivity, pH, sodium, chloride and total dissolved salts showed significant decreases over time. Spearman rank correlation was used to measure relationships among physico-chemical parameters and densities of algae. Arthrospira fusiformis was positively correlated with conductivity (Spearman ρ = 0.561, p = 0.029), total dissolved salts (Spearman ρ = 0.572, p = 0.026) and negatively correlated with total phosphorus (Spearman ρ = ?0.718, p = 0.003). While significant correlations were found, attempts to develop a model for predicting algal community composition were unsuccessful due to strong multicollinearity among the water chemistry parameters.     

Relation of solute and sorbed boron to the boron hazard in irrigation water

Summary The current criteria for evaluating the boron (B) hazard of irrigation water for specified crops are based on the concentration of B in the irrigation water without consideration of soil properties or the leaching fraction. Experiments were conducted to determine the influence of B sorption capacity on plant uptake of B at rates of 0.1, 2.5, 5.0 and 10.0 ppm B in the irrigation water with a leaching fraction of 0.5. A relatively B sensitive crop, oats (Avena sativa), was grown on four arid-region soils of varying B sorption capacities. The results show that B in solution rather than sorbed B influenced B toxicity. Contribution from the Department of Soils, Water and Engineering, The University of Arizona, Tucson, Arizona 85721. Arizona Agricultural Experiment Station No. 2508. Research Associates and Associate Professor, respectively. The senior author is currently at the Department of Soils and Irrigation, American University of Beirut Beirut, Lebanon.     

Changes in forest soils and vegetation in Søgne, southern Norway, during a 20 year period

An investigation of the edaphic conditions and the vegetation of 21 fixed plots in Søgne municipality, Vest-Agder, South Norway was carried out in 1967-69 and 1987. Loss on ignition, pH, total nitrogen, total exchangeable bases, base saturation, exchangeable hydrogen, sodium, potassium, magnesium, calcium and manganese was analysed. The species composition of vascular plants was investigated. The total cover of the bottom layer was scored.
The soil pH had decreased in the more basic soils but had increased in the more acidic soils. The organic content had increased and base saturation had decreased in most samples. Na⁺ had increased in more than half of the plots, Ca²⁺ and Mg²⁺ had not changed, and K⁺ and Mn²⁺ had decreased in most plots. Salt depositions from the neighbouring North Sea and leaching from the soil accounted for these changes. In many of the parameters opposite changes were found in the poorer soils compared to the richer soils. In the field layer Deschampsia flexuosa, Convallaria majalis had increased, and Oxalis acetocella, Galium odoratum had decreased. The cover of cryptogams had decreased in most of the plots.     

Total exchangeable sodium in rats with mestranol-induced hypertension

Rats were fed a diet containing mestranol, an orally active estrogen, while control rats were fed the same diet without mestranol. After 6 months of these diets, the rats were weighed, blood pressures were measured, and total exchangeable sodium was determined by injecting 24Na and determining the amount of 24Na in the plasma, the plasma Na concentration, and the residual 24Na in each rat. The 16 mestranol-treated rats were hypertensive (mean arterial pressure 135 +/- 3 mm Hg) when compared with the 17 controls (116 +/- 3 mm Hg). Total exchangeable sodium in the mestranol-treated rats averaged 39.94 +/- 0.49 (SEM) mEq/kg body wt, which was very similar to the value of 39.87 +/- 0.63 mEq/kg found in the control rats. Thus, no changes in total exchangeable sodium in mestranol-hypertensive rats were found in these studies.     

Flue gas desulfurization gypsum improves orchardgrass root density and water extraction in an acid subsoil

In Appalachia, many soils are acidic, high in exchangeable aluminium, and low in calcium. Large amounts of high gypsum flue gas desulfurization (FGD) by-products are currently disposed of into landfills, although they have potential value as a soil amendment for the region. This study was conducted to determine if leaching an acid subsoil with a saturated solution of a FGD by-product can improve the subsoil as a rooting media for orchardgrass (Dactylis glomerata L.) which is widely used for pasture in the region. Orchardgrass was grown in soil from a pHc 3.8 (in 0.01 M CaCl₂) Lily loam Bt horizon (fine loamy siliceous, mesic, Typic Hapludult) leached with two different rates of a saturated FGD by-product aqueous solution, as well as in soil that was limed, and an unamended soil. Water use by a clipped and partially enclosed vegetative canopy was measured in a growth chamber during two drying cycles. Small but consistent increases in water use were correlated with decreases in aluminium saturation of the soil. The effect was greatest during the second drying cycle. Increases in root biomass were also correlated with decreases in aluminium saturation. The effect of treatment on the pattern of water use altered after the first drying cycle when water uptake became most restricted in the unamended treatment. The manganese content of leaf tissue increased from 208 mg kg^-1 to 570 mg kg^-1 between the unaltered and highest leaching rate treatment. The highest level was still below the 2000 mg kg^-1 that is considered toxic to grazing animals. These results suggest that the application of high gypsum FGD by-products to pastures in Appalachia has the potential to improve root growth and functioning in subsoil horizons, but some care may be needed to monitor forage quality.     

华南赤红壤无机复合肥氮磷淋失特征

采用室内土柱淋溶模拟试验,研究了不同施肥水平下无机复合肥中氮和磷在华南赤红壤中的淋失特征.结果表明: 铵态氮、硝态氮和总氮淋失量均随施肥量增加而提高;肥料中氮的淋失率在36.8%～49.2%之间,总氮淋失量（y）与施肥量（x）之间的回归方程为y=0.3667x+66.483（R²=0.992）;铵态氮和总氮的淋失主要集中在前5次淋洗,硝态氮的淋失持续时间更长.施肥量对可溶性磷淋失量无显著影响,但颗粒磷和总磷淋失量均随施肥量增加呈上升趋势;肥料磷淋失率在0.002%～0.010%之间,总磷淋失量（y）与施肥量（x）之间的回归方程为y=7e^-5x+0.0538（R²=0.931）;磷的淋失动态与氮显著不同,为缓慢的持续累积过程.硝态氮与铵态氮淋失量比值和可溶性磷与颗粒磷淋失量比值均随施肥量增加呈下降趋势.