黔北晚奥陶世和早志留世四射珊瑚新资料

报道黔北早志留志中期（Middle Llandovery)地层中新发现的四射珊瑚7属--Cantrillia,Neocantrillia,Prototryplasma,Pycnostylus,Dalmanophyllum?.Rhegmaphyllum,Schlotheimophyllum,并描述产自黔东北石阡奥陶纪末期（Late Ashgill)观音桥层四射珊瑚2种--Grewingkia cf.bilateralis Neuman,Brachyelasma cf.medioseptatum(Neuman)及晚奥陶世（Early Ashgill期）涧草沟组中首次发现的四射珊瑚Crassilasma sp.。全文共描述四射珊瑚13属18种,其中6新种,它们是Crassilasma fenggangense sp.nov.,C.crebrumseptatum sp.nov.,Dinophyllum insolitum sp.nov.,Neocantrillia silurica sp.nov.,Prototryplasma guizhouense sp.nov.,Schlotheimophyllum regeneranum sp.nov.。     

川西北石渠三叠纪地层中Ashgill期三叶虫灰岩的发现及其与板块运动的关系

四川西北石渠与西藏东部、青海南部相毗连,这一带大面积出露上三叠统变质碎屑岩,含双壳类Halobia cf.yunnanensis Reed,H.cf.pluriradiata Reed,H.ganziensis Chen,H.convexa Chen,H.cf.austriaca Mojsisovics等。1982年,四川区调队李庆祥等在川藏交界的金沙江东岸石渠县洛须区,该变质碎屑岩中发现一角砾岩化生物碎屑微晶灰岩体,长20余米,宽约10米,含三叶虫和牙形石。三叶虫有Mucronaspis cf.mucronata(Brongniart),Dicranopeltis cf.polytoma(Angelin),Pseudosphaerexochus(s.1.)ovalis sp nov.,Microparia(Microparia)chuanxiensis sp.nov.,Holotrachelus shiquensis sp.nov.,? Nileus luoxiensis sp.nov.,Remopleurides aff.emarginatus Toernquist,Remopleurides conicus sp.nov.,Remo-     

新疆南部早石炭世层孔虫新资料及其古地理意义

本文描述的层孔虫产自新疆南部西昆仑山北缘阿克陶地区下石炭统库山河组。经研究鉴定,计有Platiferostroma longtangshanense Wang,P.microcystosum sp.nov.,P. multibrachiatum sp.nov.,P.xinjiangense sp.nov.等。共生化石有腕足类、双壳类及四射珊瑚、床板珊瑚。这些层孔虫在新疆境内早石炭世早期地层中尚属首次发现,它增补了该区下石炭统的化石依据,对于国内外同期含层孔虫化石的地层划分和对比具有重要的意义。     

四川古蔺下奥陶统桐梓组笔石的发现

1978年7月,笔者与龚联瓒等同志在四川古蔺大坪测制奥陶纪地层剖面时,于下奥陶统桐梓组近顶部采得反称笔石科的笔石。计有Adelograptus sichuanensis sp. nov., Adelograptus minor sp. nov., Kiaerograptus? gulinensis sp. nov., Kiaerograptus? sp.等。这些笔石与三叶虫Tungizuella szechuanensis Sheng, T. kweichowensis sheng及腕足类Tritoechia cf. quebecensis Ulrich and Cooper, Lingulella sp.等产于同一层位。因此,该地桐梓组顶部可称为Adelograptus-Tungtzuella带,并与鄂西分乡组Acanthograptus sinensis带相当。     

西藏革吉和日土中生代珊瑚和海绵北大核心CSCD

首次描述西藏境内一类中生代非对称的珊瑚化石Paralveolites gen.nov.(新属),产自西藏西部革吉下白垩统。此属的特征是个体没有中生代石珊瑚类个体固有的六射对称性,但却有近似古生代床板珊瑚槽珊瑚(Alveolites)个体半月形截面的外貌。新建一个刺毛海绵新属Homochaetetes gen.nov.,该属的特征是有一列伸入管体轴部的隔壁。另外新建立一刺丝胞动物亚门中分类位置不明的新属Eupseudomillestroma gen.nov.,用以区别只有棱柱状管体而无圆柱状管体的属Pseudomillestroma Deng,1982。     

河南晚石炭世太原组的一些四射珊瑚

河南晚石炭世太原组为一套海陆交互相的含煤地层,在灰岩层中含有一些保存较好的四射珊瑚化石,过去从未报道。本文记述的四射珊瑚化石是由笔者之一梁湘沅近年来在河南巩县、鹤壁及永城地区的太原组钻孔内采得的。经鉴定有4属6种1未定种,其中5新种,它们是:Lopholasma cratoseptatatum sp.nov,Lophocarinophyllum karpinskyi Fomichev,L.misticarinum sp.nov.,L.tenuiseptatum sp.nov.,L.sp.,Tachylasma carinum sp.nov.,yakovleuiella raridissepta sp.nov.。以上珊瑚中,Lopholasma最早出现在北美中泥盆统,后见于亚洲石炭系(Hill,1981),     

藏北班戈一带早白垩世早期菊石动物群

一前言本文记述的菊石化石,系原西藏第四地质大队梁寿生等同志于1978年,采自西藏北部班戈县夏穷错北岸的桂牙及其以东约7公里的波波雅拉两处(插图1).标本产自桂牙组下部的钙质泥岩中,个体较小,经笔者鉴定,计有:Neocosmoceras sp.,Neocomites neocomiensis (d'Orbigny),N.sp.,Kilianella cf.leptosoma Uhlig,K.cf.pexiptycha(Uhlig),Thurmanniceras cf.salientinum Sayn,Th.sp.,Olcostephanus(Ro-     

塔里木盆地西部西克尔兰多维列统珊瑚动物群北大核心CSCD

提要描述的珊瑚化石采自塔里木盆地西部伽师县西克尔地区,含珊瑚的地层是兰多维列统的柯坪塔格组。柯坪塔格组是目前塔里木盆地唯一有珊瑚的志留纪地层,西克尔又是塔里木盆地仅知有柯坪塔格组珊瑚动物群的地区,对我国志留纪古生物地理区系研究有重要意义。文内描述的柯坪塔格组珊瑚动物群包含床板珊瑚2属3种,日射珊瑚1属2种和皱纹珊瑚1属1种,属种名单是Paleofavosites schmidti Sokolov,P.schmidti borealis Sokolov,Schedohalysites raregonopora sp.nov.,Mcleodea jiashiensis sp.nov.,M.xikeerensis sp.nov.和Kodonophyllum cf.undulatun He and Huang。     

桂西和黔南中三叠世珊瑚

文内描述中三叠世安尼阶(Anisian)珊瑚化石分别采自桂西田阳板纳组和黔南贵阳青岩青岩组。板纳组珊瑚群中建立Pentasmilia guangxiensisgen.etsp.nov.,该新属种有5条第一周期原生隔片甚至有5条第二周期后生隔片,以此不同于有6条第一周期原生隔片和有6条第二周期后生隔片的石珊瑚类(scleractinians)的珊瑚。产于板纳组的另一新属种Radiophyllia astylatusgen.etsp.nov.,其隔片的排列格式与前人归纳的隔片周期插入示意图甚似,但它却发生在中生代最早期(Anisian)珊瑚的骸体内。文中还对青岩组的Pamiroseris silesiaca作了重新描述。     

西藏南部聂拉木志留纪笔石新材料

聂拉木是西藏南部志留纪含笔石地层(石器坡组)的主要产地。近期在该地亚来村新发现一批笔石标本,包括Normalograptus sp.、Glyptograptus sp.、Campograptus lobiferus、C. cf. lobiferus、C. cf. obtusus、C.? circularis、Lituigraptus cf.convolutus、Rastrites cf.perfectus、Stimulograptussedgwickii、Streptograptus sp.和Torquigraptus decipiens。该组合面貌确定其属于志留系兰多维列统埃隆阶上部Lituigraptusconvolutus带至Stimulograptus sedgwickii带。这一新材料的发现,使西藏南部的志留纪地层得以作全球对比。     

Distribution of N,P, K,Ca, Mg,S, Zn,Fe, Mn and Cu in groundnut

Summary Concentration of N, P, K, Ca, Mg and S in summer groundnut crop was higher than in kharif while Zn, Fe, Mn and Cu contents were higher in summer crop. Kernel's N, P and Zn; Leaflet's Ca and Mn; Stem's K and Fe; Root's S and Cu and Petiole's Mg contents were highest. Shell's N, P, K, Mg, S, Zn and Cu; Kernel's Ca, Fe and Mn contents were the least. N, P, K, S, Zn and Cu concentrations decreased linearly as the crop grew. Ca, Mg, Fe and Mn concentrations did not display any distinct pattern. Ca concentration was positively correlated with pod yield in both the seasons.     

Simultaneous measurement of the trace elements Al, As, B, Be, Cd, Co, Cu, Fe, Li, Mn, Mo, Ni, Rb, Se, Sr, and Zn in human serum and their reference ranges by ICP-MS

The goal of this article was to establish reference ranges of the concentration of trace elements in human serum and to compare these results with those reported by other authors. We describe the sample preparation and measurement conditions that allow the rapid, precise, and accurate determination of Al, As, B, Be, Cd, Co, Cu, Fe, Li, Mn, Mo, Ni, Rb, Se, Sr, and Zn in human serum samples (n=110) by inductively coupled plasma-mass spectrometry (ICP-MS). Accuracy and precision were determined by analyzing three reconstituted reference serum samples by comparison with other methods and by the standard addition procedure. The advantages of the ICP-MS method include short time of analysis of the elements mentioned, low detection limit, high precision, and high accuracy. Disadventages include a high risk of contamination due to the presence of some of the elements of interest in the environment, the relatively delicate sample handling, and the high cost of the equipment.     

Reference values for the concentrations of As,Cd, Co,Cr, Cu,Fe, I,Hg, Mn,Mo, Ni,Pb, Se,and Zn in selected human tissues and body fluids

This report attempts to formulate reference ranges of elemental concentrations for 15 trace elements in selected human tissues and body fluids. A set of samples consisting of whole blood, blood serum, urine, milk, liver, and hair were chosen and considered for 15 elements of biological significance: As, Cd, Co, Cr, Cu, F, Fe, I, Hg, Mn, Mo, Ni, Pb, Se, and Zn. The results represent wholly or partially data received from 40 countries of the global regions of Africa, Asia, Europe, North, South, and Central America, Australia, and New Zealand. This survey, even if qualitative, has been useful in demonstrating certain trends of trace-element scenarios around the world. It is of course recognized that both diet and environment exert a strong influence on the distribution pattern of several elements, such as As, Cd, Mn, Pb, Se, and Zn. A limited comparison of the available information on soil status of different countries reflected some interesting associations for elements, such as Mn and Zn. Importantly, this study revealed that only a few countries were in a position to identify a reasonable amount of data on samples requested for this project. Regretably, for a number of countries, any dependable data for even such essential elements as Cu, Fe, and Zn were not available. In view of the nutritional importance of many elements, the time is ripe for concerted efforts by intergovernmental agencies to initiate investigations or commission task forces/projects to generate reliable reference data for selected global regions, which sadly lack data of any kind at present.     

Monovalent Cation Permeation through the Connexin40 Gap Junction Channel : Cs,Rb, K,Na, Li,TEA, TMA,TBA, and Effects of Anions Br,Cl, F,Acetate, Aspartate,Glutamate, and NO3

The unitary conductances and permeability sequences of the rat connexin40 (rCx40) gap junction channels to seven monovalent cations and anions were studied in rCx40-transfected neuroblastoma 2A (N2A) cell pairs using the dual whole cell recording technique. Chloride salt cation substitutions (115 mM principal salt) resulted in the following junctional maximal single channel current-voltage relationship slope conductances (γ_j in pS): CsCl (153), RbCl (148), KCl (142), NaCl (115), LiCl (86), TMACl (71), TEACl (63). Reversible block of the rCx40 channel was observed with TBA. Potassium anion salt γ_j are: Kglutamate (160), Kacetate (160), Kaspartate (158), KNO₃ (157), KF (148), KCl (142), and KBr (132). Ion selectivity was verified by measuring reversal potentials for current in rCx40 gap junction channels with asymmetric salt solutions in the two electrodes and using the Goldman-Hodgkin-Katz equation to calculate relative permeabilities. The permeabilities relative to Li⁺ are: Cs⁺ (1.38), Rb⁺ (1.32), K⁺ (1.31), Na⁺ (1.16), TMA⁺ (0.53), TEA⁺ (0.45), TBA⁺ (0.03), Cl⁻ (0.19), glutamate⁻ (0.04), and NO₃− (0.14), assuming that the monovalent anions permeate the channel by forming ion pairs with permeant monovalent cations within the pore thereby causing proportionate decreases in the channel conductance. This hypothesis can account for why the predicted increasing conductances with increasing ion mobilities in an essentially aqueous channel were not observed for anions in the rCx40 channel. The rCx40 effective channel radius is estimated to be 6.6 Å from a theoretical fit of the relationship of relative permeability and cation radius.     

Crystal structure, detonation performance, and thermal stability of a new polynitro cage compound: 2, 4, 6, 8, 10, 12, 13, 14, 15-nonanitro-2, 4, 6, 8, 10, 12, 13, 14, 15-nonaazaheptacyclo [5.5.1.13, 11. 15, 9] pentadecane

A new polynitro cage compound 2, 4, 6, 8, 10, 12, 13, 14, 15-nonanitro-2, 4, 6, 8, 10, 12, 13, 14, 15-nonaazaheptcyclo [5.5.1.1(3,11).1(5,9)] pentadecane (NNNAHP) was designed in the present work. Its molecular structure was optimized at the B3LYP/6-31 G(d,p) level of density functional theory (DFT) and crystal structure was predicted using the Compass and Dreiding force fields and refined by DFT GGA-RPBE method. The obtained crystal structure of NNNAHP belongs to the P-1 space group and the lattice parameters are a = 9.99 ?, b = 10.78 ?, c = 9.99 ?, α = 90.01°, β = 120.01°, γ = 90.00°, and Z = 2, respectively. Based on the optimized crystal structure, the band gap, density of state, thermodynamic properties, infrared spectrum, strain energy, detonation characteristics, and thermal stability were predicted. Calculation results show that NNNAHP has detonation properties close to those of CL-20 and is a high energy density compound with moderate stability.     

Reliability of Analyses of Hg,Fe, Ca,K, P,pH, Alkalinity,Conductivity, Hardness and Colour from Lakes

The aim of this report has been to present results concerning analytical quality controls of Hg analysis of fish and sediment, analyses of Fe, Ca, total-P, K, pH, alkalinity, conductivity, colour and hardness (Ca + Mg) of lake water samples. Despite the fact that these are standard parameters in many regular water control programs, there are major differences in the reliability with which these parameters can be determined. The focus here is on an overall inter-laboratory comparison between the parameters. Six laboratories have been involved in the analysis. Selected results: pH gives the lowest (average) relative standard deviation (error), about 2 %; conductivity gives an error of about 5–7 %; alkalinity yields an average error of as much as 13–25 %, which is the largest among the parameters studied here; colour also gives a high error, 9–15 %; hardness gives a relative standard deviation of about 6–7 %. Of the other parameters (i. e., Hg, Fe, Ca and P), Hg gives the best reliability and Fe and P the lowest. To have knowledge of the reliability of the analytical data is of paramount importance in most control programs and research projects.     

Competitive inhibition and selectivity enhancement by Ca in the uptake of inorganic elements (Be, Na, Mg, K, Ca, Sc, Mn, Co, Zn, Se, Rb, Sr, Y, Zr, Ce, Pm, Gd, Hf) by carrot (Daucus carota cv. U.S. harumakigosun)

We investigated the uptake of inorganic elements (Be, Na, Mg, K, Ca, Sc, Mn, Co, Zn, Se, Rb, Sr, Y, Zr, Ce, Pm, Gd, and Hf) and the effect of Ca on their uptake in carrots (Daucus carota cv. U.S. harumakigosun) by the radioactive multitracer technique. The experimental results suggested that Na, Mg, K, and Rb competed for the functional groups outside the cells in roots with Ca but not for the transporter-binding sites on the plasma membrrane of the root cortex cells. In contrast, Y, Ce, Pm, and Gd competed with Ca for the transporters on the plasma membrane. The selectivity, which was defined as the value obtained by dividing the concentration ratio of an elemental pair, K/Na, Rb/Na, Be/Sr, and Mg/Sr, in the presence of 0.2 and 2 ppm Ca by that of the corresponding elemental pair in the absence of Ca in the solution was estimated. The selectivity of K and Rb in roots was increased in the presence of Ca. The selectivity of Be in roots was not affected, whereas the selectivity of Mg was increased by Ca. These observations suggest that the presence of Ca in the uptake solution enhances the selectivity in the uptake of metabolically important elements against unwanted elements.     

Relations of the Al,B, Ba,Br, Ca,Cl, Cu,Fe, K,Li, Mg,Mn, Na,P, S,Si, Sr,and Zn mass fractions to morphometric parameters in pediatric and nonhyperplastic young adult prostate glands

The variation with age of the 18 trace element mass fractions and some histological characteristics of intact prostate glands of 50 subjects aged 0–30 years was investigated by instrumental neutron activation analysis, inductively coupled plasma atomic emission spectrometry, and a quantitative morphometric analysis. Mean values ± standard error of the mean (M ± SΕΜ) for the mass fractions (in milligrams per kilogram wet tissue) of these trace elements in pre-puberty were: Al 28.5 ± 9.0, B 0.40 ± 0.11, Ba 1.48 ± 0.44, Br 10.5 ± 1.5, Ca 241 ± 30, Cl 3,203 ± 278, Cu 3.51 ± 0.89, Fe 33.7 ± 4.1, K 2,364 ± 145, Li 0.020 ± 0.004, Mg 153 ± 23, Mn 0.46 ± 0.06, Na 2,286 ± 130, P 1,391 ± 100, S 1,698 ± 132, Si 62 ± 11, Sr 0.38 ± 0.08, and Zn 27.6 ± 2.3. During puberty and postpuberty, when there is a significant increase in circulating androgens, the mean values were: Al 7.2 ± 1.4, B 0.21 ± 0.05, Ba 0.25 ± 0.06, Br 5.8 ± 1.0, Ca 433 ± 81, Cl 2,314 ± 201, Cu 1.77 ± 0.13, Fe 20.9 ± 1.6, K 2,585 ± 118, Li 0.0088 ± 0.0014, Mg 232 ± 27, Mn 0.34 ± 0.04, Na 1,875 ± 107, P 1,403 ± 98, S 1,673 ± 73, Si 22.2 ± 3.1, Sr 0.22 ± 0.03, and Zn 93.3 ± 8.9. Mean values (M ± SΕΜ) of percent volumes (%) of the stroma, epithelium and lumen in the prostate before puberty were 73.4 ± 2.6, 20.4 ± 1.7, and 4.45 ± 0.94, respectively, versus 46.5 ± 2.5, 38.5 ± 1.9, and 14.9 ± 1.2 during puberty and postpuberty. This work’s results confirm that the Zn mass fraction in prostate tissue is an androgen-dependent parameter. For the first time it has been demonstrated that the glandular lumen is a main pool of Ca, Mg, and Zn accumulation and that the stroma is a main pool of Al, B, Ba, Br, Cl, Cu, Fe, Mn, Na, and Si accumulation in the normal human prostate, for the age range 0–30 years. It was concluded that the Ca, Mg, and Zn binds tightly within the prostatic fluid, because the volume of glandular lumen reflects the volume of prostatic fluid.     

The Effect of Age and Gender on Al, B, Ba, Ca, Cu, Fe, K, Li, Mg, Mn, Na, P, S, Sr, V, and Zn Contents in Rib Bone of Healthy Humans

The effect of age and gender on major, minor, and trace element contents in the intact rib bone of 80 relatively healthy 15–55-year-old women and men was investigated. Contents or upper limit of contents of 16 chemical elements in the rib bone were determined by inductively coupled plasma atomic emission spectrometry (ICP-AES). Mean values (M?±?SΕΜ) for the mass fraction of Ba, Ca, Cu, Fe, K, Li, Mg, Na, P, S, Sr, and Zn (milligram per kilogram of dry bone) were as follows: 2.54?±?0.16, 171,400?±?4,050, 1.35?±?0.22, 140?±?11, 1,874?±?71, 0.049?±?0.011, 2,139?±?38, 5,378?±?88, 75,140?±?1,660, 1,881?±?51, 291?±?20, and 92.8?±?1.5, respectively. The upper limits of contents of Al, B, Mn, and V were <7.20, <0.65, <0.36, and <0.03, respectively. Statistically significant tendency for the Ca, Mg, and P content to decrease with age was found in the human rib bone, regardless of gender. The mass fraction of Fe in the male rib bone increases with age. It was shown that higher Ca, Mg, Na, P, and Sr mass fractions as well as lower Fe content were typical of female ribs as compared to those in male ribs.